Euroclaus process.

ng dng: Qu trnh c pht trin thu hi S nguyn t t H2S trong kh thi

sinh ra t cc thit b x l kh nh l phn x amin. Euro claus process l s ci
tin ca superclaus process, hiu sut t 99,7%.
M t cng ngh:
Euroclaus process bao gm 1 stage nhit vi 3 tng phn ng xc tc, trong lu
hunh s c ly ra gia cc tng bi cc my condensers. 2 tng phn ng u
c lp y bi xc tc Claus thng thng trong khi tng phn ng cn li c
lp y bi mt loi xc tc oxi ha chn lc. Trong tng nhit, kh acid c t
chy vi mt lng khng kh va lng kh thi ra 2 sector ny ch t 0.8
-1% th tch H2S v khong 100- 200ppmv S02. Lng S02 sinh ra t bi v xc tc
Hydro ha chuyn S02 -> H2S di y ca tng xc tc 2 . Xc tc trong tng
cui oxi ha H2S thnh S vi hiu sut ln hn 85%. ng thi bi v xc tc ny
khng oxi ha c H2S v SO2 hay lm o chiu phn ng ca S v H20 thnh H2S
v SO2. Hiu sut tng t c 99.3%. phn ng t c trn 99.3% mt
reactor ph thm dng trn tng xc tc oxi ha.
LS-SCOT AND SUPER-SCOT PROCESS
ng dng:
The Shell Claus Off-gas Treating (SCOT) process c pht trin loi b lu hunh
hp cht t dng Claus tail gas p ng nhng tiu chun kh thi hin thi.
gm 2 loi chnh : Low Sulfur-SCOT v Super-SCOT.
The LS-SCOT s dng mt lng nh cht ph gia gi r cho amin
The Super-SCOT p dng 2 tng ti sinh kt hp vi dung mi nng thp.
M t cng ngh:
Low Sulfur-SCOT
Cht ph gia lm tng s ti sinh ca dung mi to ra dung mi tt hn t to ra
dng h2S off-gas t hn. Hiu qu t ti 10ppmv H2S hoc 50 ppmv tng lng S (
bao gm c COS/CS2)
Super-SCOT
Hiu sut : h2S 10ppmv, tng hm lng S < 50ppm
Thit k da trn tch 2 tng, c th kt hp vi dung mi lean nhit thp.
Tng s tch thng qua 2 tng hi sinh v tng hp th bng dung mi nhit
thp c th c ng dng c kt hp 2 cch hoc ring tng cch.
t c hp th ca dung mi, mt dng hi nc c s dng.
Khi dung mi hp th tt hn s lm cho lng H2S thp hn trong dng off-gas

SCOT PROCESS

 tan ca H2S trong dung mi amin s tng khi nhit gim. nhit thp s
lm cho p sut ring phn trong dung mi, lm gim nng H2S trong dng off
gas.
SCOT PROCESS
Phng php SCOT bao gm 1 khu vc kh, 1 khu vc ADIP hp th. Trong khu vc
kh tt cc hp cht cha lu hunh trong dng kh ko t c tail gas (S02, COS,
CS2 v S) th c chuyn i hon ton thnh H2S bi xc tc Co/Mo ti 300 0C vi
s c mt ca H2 hoc hn hp H2 v CO
Dng kh Claus tail gas c gia nhit n 300 0C bi mt h thng inline burner
hoc heat exchanger ng thi c th thm vo H2 hoc hn hp H2/CO. Nu ko s
dng kh H2, CO kh, h thng bun t c hot ng to ra kh kh. Kh
c gia nhit chy qua cc tng xc tc ti hp cht S, CS2 v COS c kh
thnh H2S. Hi nc h thng c to ra bng dng kh lm lnh n khong 165
0
C trong thit b heat recovery boiler v sau c cho tip xc trc tip vi nc
n 400C. Hi nc trong dng kh c ngng t, v chuyn n b phn tch nc
chua( sour water stripper). Kh c lm lnh, thng cha 3% vol H2S v n 20%
CO2 c ra bi dung mi amin trong ct hp th , c thit k hp th hu
ht lng H2S nhng ch 1 lng t CO2. Kh sau x l ch cha 1 lng nh H2S v
c t trong Claus incinerator thng thng. H2S sau c thu hi li t vic
gii hp dung mi trong thit b tch stripper v c hi lu li phn xng Claus.
Phn xng SCOT c thit k s st p l ti thiu m h thng c th c
thm vo d dng cho phn xng Claus c sn. Nu p sut khng , 1 gas
booster c th c b sung, thng thng gia thp lm mt v thp hp th

SCOT PROCESS