158.3 ample 151, Sail + Gas = Sad + Gas permanent con enone 80) ae suum ke a = ge ad at em pate15.9.2 Example 18.14 ‘One ofthe most important indus reactions isthe ctaltic proton ofthe “sys a ch, + H,0-00 + 3H, ‘An aditinal action tak place to a iif exten: CO + H,0+00, + H, ‘Stating with «aio ofS mols of stax to 1 mole of mathane, i. with an ace of ar for estes that wil be dice in Exel 1816, cael {he uibriom compotion ofthe resting mint at GOO and | stm. Athi temperate, the equim constants forthe ft ad second reason ae re pectively Cougenet al, 1959) K, = 0504; Ky = 221 Let component, CH: 2, Hi0; 3, CO; 4 Hy and 5, COs and he vas ‘ofthe progres ofthe rection vail forthe find and sccond rexton respectively egiibriun, Then: melee, BH ler@nOqre? w Yas” WimeSe 9) water) oe -221 MEE LSE Si We have ths 2 system of tw epations wih to unknowns, which we wll solve wth the graphical method as flaws LLAsume 4 vile fore, and determine th correponding value of ¢) from Eg(A) by taka, ice ira fourth depres equa ‘An examination ofthe second re 2UFor th seme vale of, calle, by solving E(B) which is quartic. 00. 2 Repost, wing new vale fore ‘Plath ona ales fe, vee fo the two equtons. The intersections indicts tat an ees of wate the sluton, giving: aout of CO, This ines, 2 ‘othe Lf, prohibiting the une methane ai wil ctbom be foe 4, =0912and = 0633. Hence: = 00112,95 = 0.4416,» = 0.0387, 4» 0.806, y, = 2.0809. 15.9.3. Example 15.15 Following Example 15.14, we With ference tothe as presente in Example 15.14, thi posible reaction umber of moles oft pe i ‘in esting fe the formation 2c0=¢ + 00; of thes equtions wth three ul with a vale of Ky» 814 at 600°C This reston i undesirable case the Carton depois n the eta recing ite activity. Considering the conditions fof Example 15.14, sl there be any carbon deposition? The vale of fo this esti, cle from the eu of Example 15.14 ing 4.15.83, i: Krys hich mach ger than the squirm value of 8.14 No cubon, therefore, whee: Wat 4 1 4 26, “This se canbe sled ‘by finding the point of inter {Assume a value of; Pat, verms forthe hs Sept wt the bined "The is devonettd in Fi F138; ¢, = 0538: and15.13 Consider the esibity of producing ethanol thraigh the vapor-phase ydtion of eye: Gaile + #0 c,th08 Deterie the eur conversion for an enol fonda 20°C an: ‘ua: bain1827 The following simansous reactions AsIaI0+D K-50 ReCOD+E Kr088 take place inthe vapor phase t 1 bu. Staring with oe mol of A and ne of B, bow many mols of €,D, and E we present at elit,15.52 Assuming tha the pyrolysis of propane invlves the following to ra Sally Cale Cie CoH CH, ‘alculate the composton of he eqlibviam mixture at 1000K aod 1 sim 45.534 minture of BuCO, and Cis boatad w 1482 K in a erat batch onic, where te following reactions cur BxCO, = B40 + CO, K-0.1 abe) C0, + C200 ‘Wha pressure wil be develop at guia?remeron wrt tempers oa cor 1 it reno ni he ne ee epee tc ‘Sines qn bum comer ceased ee ae Prt ett on ii ie mere sn cme st wasn ht np ar pe ain soLUCION 1) Can ero cles aetna, UC Enns a Soci ihr dees pt hemp t= Aye =1830 cad o pai de neal om ic 25°C veep yy TAS 13120 mot como cde enn acon temper conse de galt Ereulqertenpmnn Necalodespete de neato AN a ami ok Reema ig aed ecm (Hsbc eS Gate ta GeO ad Mae Sa pera nara crn cae OC 0 ee 2 A pid a en oon een ie pm > a a panThang Na Ts Deena: econo al peme w atta 497 men 2 tot of Ong in 8 de? se aed ‘235 mole of Nagin 3d, wring toh gus ction Oxy + Naps 2NOgy en that Re = 13 10 USisencamnpict knogmeasorahrosmes uv? hae enthw h=vkslea art 1 mead te quincy. 2 Menthe pected Ong, Nay an NO Alpe tein 'he anos pe hoe ths 8 Romoeaets ‘cule one ne tn) 5, TRetelace chamsaleusonieskety hen he gestion: Org) FB INO. 4 k= NOP ONO = 413 «1. 5 = NO) Tey) =. Heath Mand aS ‘Seta Ong = mn tat 9 Aaa Ita ememeatian of Ny = 228 ola 39d 075ml Om + Mp NO, Intieone M08 07s « Now 3x Gime O48 1 Ke=ISOF N11) =#1«10-7= (29705075) A Stor kr VU te equ tee toe Ie ame ensugds bie knee 5)n079) 4154107 He S79 Wana 190 1 9 Gani = (9) 10-05) ~ aos a OI SMa WOON = OMEN Ley bth ae = jee asap made wre ve ni ot ery temic qd eqns ta ucton 10 Gayl 05 Nghe thy ey ear Dia We) = 38t A ag etine‘othgh py boca ts tmp 0K th ft 529+ 04-5049 oneleanree w ene teen1. yf gt gt tan a LRA ‘rani And esa palo wi ns"FeQ(6)+ 3COK@)= 2Fets) + 30,2) 2COKe) +08) ives (75) 10" ‘critic perf enh pinaT RE Sree ae Ting oue eee eee te ottaas marc tere ner 0: 2 eee Le ead es Set enn St ci ikon PER Ry Be ti pte aie, (rsa + teat a wo 7 a82 x ao 1? aye (n03)). ioe ean ete oes So ee sane ett bar aT 1.7 a tated meine te rapt os rt EES ie BS ta + Hy) =m yA end (658 mis mis Bi To hat (2. ie mts =m BiB et (230 alt eB et (0 He) Some) 6+ 385 10 Loin Uae sae et ate Spmte) 430+ 0081 103 tot) Beas 6298 0183 Faye Spmiy) =F Mare) (97 00) pata 208 allan mt) (0.28 3 wre itt Teen oa 12 tase ret srs 10 0 Peon 4 gta tian hari ernoe evi teat ce «Yin (LES Ma nop = tye Psa. 2691 Tea (LOH 3987 0) in) = 8-79 8.0 Fe (NINE 887), rion ios 2 eran ats de os sitet tan pin si sen Wr ct soe ln cw an tn #1 (T09T atae presi bL a8 we) ig +g = Wome Was Cag ta tet (sar Haas Tey F841) nes 0 a at of eat 16. 1 et = yn = 50,9 Yet (Bh. 2.59.@ asec Thepeccn miei pation farther oman Hp eg he ‘Sita ou Babe C nuh ourpap sor ar ona Seon ps ne gave (Ds oH some crt ae The ‘eto, arc a al mt of np eae (€4050;-~00 wichperba wan eymo-H.+c0 sy Theron mine of CO ce The npn sith te wt ter iui ee COuHO= 40, us) 0431 aa +40 easy Solin oh to ions tin Ep 432 al 438 depend ce ‘smn of Oana tata tn eat thar an 81 fn fre seo eee ea eat ow Fad Sinan oh tag a we ma ‘Biouane tw ante penae garcons ara shy ‘am eam Fo shen be ata hae rs eft ch as an cand nga ae eon cpa stah connEfemplo 1-4 Se planen produc hidrdgeno y monéxido de earbomo por me diode la eaccén de metano y vapor de agus CH, + 1,0 43H, = CO ‘Sn enim, tien soi bins de cafe, mika xb, cm do se usr ext reac de gs de ag. ©O+H,0-+00; + Hy La sims case on dbs mas de CH, y 3 mks de HO. Cake fc sin mame ge cavink < CO » COp apes oe a ‘spline un waste que pea 1000 K y sam. Los vas de AFF en es condiciones son a ‘a emperia de raecin, ky ~ 2657 y Ky 2.200. La psi ol 10 ay a ale mein al eco ne un tps de 3 mcs Ay T mol de. Cale a compos ‘lat dl evete dt cor oberee cgi con peso anbis rans 1. metal pode fbvicase por edo dea asin cn ie asst cO-1H, +cH,0n) En compos de mec, cg de quien 400K yt at coe 40 mol la iar ot pecs pcsens son CO y CHYOH, A 400K. la constants de Soll S 1383 ae S15 Se anal de CO ‘@)Supoiendo un somporumicn a et as. jel I composé wl los de lio? (@) Consens la miso comps de mena, ei el equi a 500K y {tm sapere err aa de Ht 12) Comins beeen sea os cs BWyeiN nt etn bn hg he la rly ce pi225, Lacie pa et i a py penn ny {00k stidah pb oe Fe peprsomre ond ins 2 onl sin espns y Fe ‘hugh the cong me {Dees la congski ous am 40K pan ann din sialnte d myc neo yea inde pala mei ay 00K yea ab seit Lipa open ie rele eon Jan)