TAT CaF 8474L 036 JOp. Center JOBN® 7 JOp. Center Doc. N°, [DOCUMENT CLASS TX IFEED Doc. NT Cid rSUIENT ——PETROVIETRAM Fechnip AE a LOEATION DUNG GUAT Nitrogen System Unit 036 Operating Manual G.viGuy Witten by ISSUE FOR REVIEWVIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) DUNG QUAT REFINERY OPERATING MANUAL VOLUME 20 NITROGEN SYSTEM UNIT 036 BOOK 1/1 8474L-036-ML-001-A keptVIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) _] April 2007 DUNG QUAT REFINERY Rev. :A OPERATING MANUAL Chapter 1 UNIT 36 Page 1 1. BASIS OF DESIGN DUTY OF THE PLANT FEED CHARACTERISTICS PRODUCT SPECIFICATION MATERIAL BALANCES BATTERY LIMIT CONDITIONS. DESIGN FEATURE 2. DESCRIPTION OF PROCESS DESCRIPTION OF UNIT CONTROL UTILITY, CHEMICAL AND CATALYST REQUIREMENTS 4.1 UTILITY CoNsUMPTION 4.2 CHEMICAL CONSUMPTION AND HANDLING 5. DRAWINGS 5.1 PLOT PLAN 5.2 PROCESS FLOW DIAGRAMS AND MATERIAL SELECTION DIAGRAMS 5.3 PIPING AND INSTRUMENTATION DIAGRAMS 5.4 OTHER DRAWINGS aebeRe‘VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) ‘April 2007 ee DUNG QUAT REFINERY Rev. A Technip th OPERATING MANUAL Chapter 4 — UNIT 36 Page :2 FOREWORD For information related to: + Process description and Material Balance + Control and Shutdown philosophy - Safety = _ Normal operation + Start-up and Shutdown Refer to attached Vendor Data Book doc. 8474L-036-A0401-4112-001-001, especially the sections: “Control System description, operating principles, functional design specification” “Operation and Maintenance manuals" “Installation, Start-up and commissioning”1 VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) DUNG QUAT REFINERY ‘OPERATING MANUAL UNIT 36 ‘Apri 2007 Rev: Chapter Page ab BASIS OF DESIGN DUTY OF THE PLANT The Nitrogen unit consists of a gaseous and liquid nitrogen generation unit with associated liquid nitrogen storage and vaporization facilities. ‘The unit is a package designed to provide the following: + Gaseous nitrogen (GAN) to process users in normal operation + Liquid nitrogen (LIN) sent to cryogenic liquid storage + Liquid vaporization to meet peak loads and start-up/shutdown demands. ‘The unit is made of the following elements: Cryogenic Nitrogen Generator Unit (A-3603) Nitrogen is generated by cryogenic air separation to a purity of 99.7% by volume. The cryogenic separation unit has a single, multistage centrifugal type compressor (a spare rotor is also provided and kept in warehouse) with inter plus after-coolers. Regenerative, molecular sieve towers (two in parallel) are included for the removal of carbon dioxide and moisture. Nitrogen Generation Unit is designed to provide both liquid and gaseous products simultaneously. The nitrogen generation design capacity is as follows: Nm®fh (atm / °C) Liquid Nitrogen 647 Gaseous Nitrogen 367 Total 994 The ratio of liquid to gaseous nitrogen production is variable up to the maximum liquid production rates indicated above. The LIN production rate will allow storage vessels to be fl led in 10 days approximately. Liquid Storage and Vaporization Air separation unit liquid nitrogen product is sent to the Plant Liquid Nitrogen Storage Vessels, \V-3601A/B (2 x 50% capacity) and the CCR Regeneration Liquid Nitrogen Storage Vessels, V-3602A/B/C (3 x 33% capacity). From each pair of storage vessels, liquid nitrogen is sent, when required, to ambient air vaporizers A-3601-E-01 and A-3602-E-02. To prevent the possibility of cross contamination from refinery process sources, CCR Regeneration nitrogen is provided as a separate dedicated system. Vaporized gaseous CCR Regeneration nitrogen operates at a higher pressure than the Plant nitrogen header. Plant Li Storage, AB Vaporized plant liquid nitrogen is normally not required in normal refinery operation, liquid storage provides a butfer capacity for emergency and high consumption operations such as start-up, shutdown, peak nitrogen blanketed tank in-breathing and maintenance. Nitrogen storage vessels, V-3601AVB, are each sized to hold 53 m? minimum liquid nitrogen. This ensures storage capacity for 4 days of operation approximately, based on normal demand plus one CCR unit shutdown and re-start-up.12 ‘VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) DUNG QUAT REFINERY OPERATING MANUAL UNIT 38 ‘April 2007 ‘These storage vessels are provided with hose connections for liquid nitrogen to be both imported and exported by road tanker. Pl Nitrogen Vaporization, 1 Vaporization of liquid nitrogen is achieved by heat exchange with ambient air in vaporizer ‘A-3601-E-01 ‘The design requirements for vaporized plant nitrogen are as follows: N*M (tatm /0°C) ‘Short duration peak for max tank in-breathing (20 minutes) 12,000 Long duration for plant start-up (12 hours) 41,500 Supply of gaseous nitrogen to the refinery is ensured with a pressure control valve on the vaporizer outlet line. The vaporizer is designed to supply gaseous nitrogen at a minimum pressure of 7.5 kg/omég downstream of pressure control valve on a continuous basis. CCR Regeneration Liquid Nitrogen Storage, V-3602//B/C_ Nitrogen storage vessels, V-3602A/BIC, are each sized to hold 40 m? minimum liquid nitrogen. This ensures storage capacity for 2 CCR regeneration cycles (2x48 hours) when demand is at peak. These storage vessels are provided with suitable hose connections for liquid nitrogen to be both imported and exported by road tanker. Regens Jguid Nitrogen Vapori \-9602-E-01 \Vaporization of liquid nitrogen shall be achieved by heat exchange with ambient air in vaporizer ‘A-3602-E-01. ‘The normal requirement for vaporized CCR nitrogen is 95.1 NmY%n, Each month, a peak requirement of 800 Nm*h is required for a two day period, The design requirements for vaporized plant nitrogen are as follows: Nm*ih (tatm / 0°C) Peak for 2 days/month (48 hours) 955 Continuous vaporization (20 days) 95 ‘The supply of gaseous nitrogen to the refinery shall is controlled with a pressure control valve on the vaporizer outlet line. The vaporizer is designed to supply gaseous nitrogen at a minimum Pressure of 8.7 kg/emég down stream of pressure control valve at vaporizer outiet on a Continuous basis. This pressure is higher than the Plant Nitrogen supply pressure to avoid the possi flow contamination of this nitrogen network. FEED CHARACTERISTICS The air taken into compressors is a standard atmospheric air with the following design characteristics: Maximum temperature 36°C Minimum temperature 16°C Relative humiaity 100%‘VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) | April 2007 DUNG QUAT REFINERY Rev. A OPERATING MANUAL Chapter: 1 UNIT 36 Page 5 1.3. PRODUCT SPECIFICATION Gaseous and liquid nitrogen product quality is: Nitrogen 98.7 %vol. min Carbon monoxide 20pm vol. max ‘Oxygen 10 ppm vol. max Carbon dioxide 20 ppm vol. max Hydrocarbons 5 ppm vol. max Hydrogen 20 ppm vol. max Chiorine 1 ppm vol. max Water 5 ppm vol. max Noble gases remainder 1.4 MATERIAL BALANCES Refer to Nitrogen Balance attached here after:NITROGEN BALANCE oe saan] a, | urs elise osenr-unepe] | rows | Dome'| roman a ea ed rd hd ob EES : [| == _| ppeLininanY al f i gugais g<2 — +000 fone i le is i e ales oir alele| ie Teg post eee aig) & |a| \8) a a gees oe {Temata stn rset eral ete nr or cae Nz rat ed et18 16 1.6.1 162 Tecip EDC ‘VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) DUNG QUAT REFINERY OPERATING MANUAL UNIT 36 Rev. A Chapter 31 BATTERY LIMIT CONDITIONS The table below shows operating and design conditions of feed supply into Plant and Instrument Air Unit and product to consumer's battery limit. PRESSURE, kg/cm’g TEMPERATURE, °C. DESCRIPTION | NOR | MAX | MIN_| DES | NOR | MAX | MIN | DES. Feed Atmospheric Air_| 1.029 | 1.033 | 1.008| - | 27 | 96 | 16 | - Product, CCR Nitrogen | 85 | 9.0 | eo | 117] 90 | 40 | 10 | 65 Refinery Nitrogen| a5 | - | - |1os! a1 | - | - | 65 DESIGN FEATURE Actual LIN to GAN ratio ‘The plant is actually capable of producing GAN and LIN in the ranges given below: Max LIN mode Max GAN mode Liquid Nitrogen (Nm) 679 158 Gaseous Nitrogen (Nm®/h) 347 1611 Total (Nm*in) 1026 1769 LIN to GAN Ratio 1:05 1:10 Operation with back-up Air In the event of A-3603 compressor failure (A-3603-C-01), wet air can be sourced from Unit 35, Air Compressors A-3501A/B/C discharge. The air system spare compressor will be dedicated to this service. Wet air from A-3501A/B/C is available at 8.5 kg/em*g 100% water saturated at 41°C. Wet ait will be introduced at the inlet of the Main Air Compressor after cooler A-3603-E-06 within A- 3603. Due to the lower air supply pressure, Refinery Nitrogen production pressure will be reduced to 7.0 kg/em’g, In order to maintain the CCR nitrogen pressure to the minimum of 8.0 kg/cm*g, a LIN transfer Pump (A-3601-P-01) is provided to batch transfer LIN from V-3601A/B to V-3602A/B/C Operating at a higher pressure. ‘The expected GAN and LIN production capacities are indicated below: Max LIN mode Max GAN mode Liquid Nitrogen (Nm®/n) 350 263 Gaseous Nitrogen (Nm°/h) 424 1149 Total (Nem) 774 sa12VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) DUNG QUAT REFINERY OPERATING MANUAL UNIT 36 ‘April 2007, ‘The max LIN production rate will allow storage vessels to be filled in 18 days approximately.VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) | April 2007 DUNG QUAT REFINERY Rev. A ‘OPERATING MANUAL Chapter :2 UNIT 36 Page it 2 DESCRIPTION OF PROCESS Refer to attached Process Description 8474L-036-A0101-4112-001-0013. ‘VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) DUNG QUAT REFINERY OPERATING MANUAL UNIT 36 DESCRIPTION OF UNIT CONTROL Refer to attached Control Narrative 8474L-036-A3501-4112-001-001. “April 2007 Rev. A Chapter :3 Page 144 42 i OPERATING MANUAL Chi 4 Tecip FE me an ‘VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) —] April 2007 DUNG QUAT REFINERY Rev. A UTILITY, CHEMICAL AND CATALYST REQUIREMENTS UTILITY CONSUMPTION Refer to Nitrogen Unit Utility Consumption Summary 8474L-036-CN-0008-001. Note that the unit is self-sufficient for Instrument Air consumption, under normal operation. 1A will be required at start-up only CHEMICAL CONSUMPTION AND HANDLING. There is no chemical consumption in Unit 36.5A 52 53 54 ‘VIETNAM OIL AND GAS CORPORATION (PETROVIETNAM) DUNG QUAT REFINERY OPERATING MANUAL UNIT 36 DRAWINGS PLOT PLAN 8474L-031-DW.-0051-001 Block area Plot Plan 8474L-036-A0201-4112-001-003 Package Unit Plot Plan NA Hazardous Area Classification PROCESS FLOW DIAGRAMS AND MATERIAL SELECTION DIAGRAMS, 84741-036-PFD-0010-001 8474L-036-PFD-0010-002 8474L-036-A0102-41 12-001-001 (package PFD) 18474L-036-MSD-0011-001 (8474L-036-MSD-0011-002 PIPING AND INSTRUMENTATION DIAGRAMS, 8474L-031-PID-0021-021 8474L-051-PID-0031-005 8474L-036-A0103-4112-001-001 (package P&ID) OTHER DRAWINGS Electric Single Line Diagram Underground Sewer Network Fire Fighting Water Distribution Diagram ‘April 2007 Rev. Chapter Page A 25 cal