are CA : cis KC tela 20H 4E Chemistry Prelim 2011 Answer Scheme Paper 1 ‘Guestion ‘Question number Answer number Answer 7 c a B 2 2 D 3 c 23 > ef 4 5 2 x 5 S Fs 5 | 6 3S 26 D 7 D a D 3 5 ard 8 3 c 28 c a) B 30 S i c ca D 2 8 32 D 3 D 3B D 14 8 4 5 5 x 3% a 76 € 36 eS 7 5 7 s 8 5 38 B 48 x a c 20 5 ao4E Chemistry Prefim 2011 Answer Scheme Paper 2 No [Answer i MarkslRemarks 7 (@) arnmnonium chloride [i] each, max 5] (6) sodium chloride;‘ammonium chloride (0) aluminium chloride, hydrogen chloride, ammonium chloride, copper(\) chloride () hydrogen chloride _{e) silver chloride 2 (@) Reddish brown Ti (6) Kron(lt) hydroxide ot (6) Heating causes the precipitates to decompose to form —_| [1] metal oxides and water. (2) The precipitate, zinc hydroxide is amphoteric and 1 dissolves in the excess aqueous sodium hydroxide. (2) kon) hydroxide oxidises in arto produce iron) i hydroxide. =) Iron(lly hydroxide has a larger relative molecular mass, | [1] hence the mass is greater. 3 1a) hydrogen from cracking of petroleum, nitrogen from [al each, max fractional distillation of air (8) 400 atm and 350°C nM (6) Increasing the pressure wilincrease the amount of ty particles per unitvolume, This wil lead to greater colisions and hence areatér effective colisions between the W nirogen and hydrogen atoms, resulting in a faster rate of reaction, producing more ammonia In a shortes time: (2 Wen te ompefatr soo low partis Wil move very 0 the rate of formation of ammonia wil be v 0 Siow, This snot feasible for an industal process. temperature of 450°C is used as the yield at this temperature is reasonable and the particles have more, {netic eneray at'a hi ich results in| {1} ‘more effective collisions and the rate of which ammonia forms willbe faster. % [Energy absorbed to break the bonds x3xNH+2xC=0 X3x386 +2799 2316 + 1598 914 kd m Energy given out when forming bonds XO-H+4xNH + 2x C-N+ C=O 459 + 4 x 386 + 2X 305 + 799 B71 ks m Enthalpy change = 3914 ~ 3874 43k awNo of moles of Zions = 0.02 mol Relative atomic mass of Z = 0.78 / 0.02 = 39 fy) {@) Concentrated sulfuric acd. (©) Xethanot Y: propanole acid (© ety prepanoate H Hot Hoe Ee HOH @ ti a i {] BOPP Epes HOH HOH (11 10 (@) buiylamine ty (0) CoHayesNHe a oo [1] correctly shown bonds (il key, no marks for key i Key drawn incorrectly ‘@ electron from N electron from H © election from C (® CHANH, + HCI CH.NHCI TRO Au ME As UALS OEE AME OT LE {d) CO;, CO, NO, NOz, #0 (1) {1() Gel: DAF faq) +28 >) i Cell il: Cut (aq) + 2e > Cu(s) a (©) @) The reading of the ammeter willbe greatly reduced as, Sugar exists as molecules dnd cannot conduct electricity. | [1] (i) Barium sulfate wil be fofmed. White precipitate will be observed and the reading will decrease as well a (©) The blue colour copper sulfate solution will not decolourisefremain blue. oT The positive electrode of cell I! will decrease in size. ty @)AG™ NOs, KT, HY OF tt (b) sitver iodide (1) =™ -Aa"(ad) + Maa)? Aal (8), oy (©). The Ag" ions migrate towards thé cathode whilé the T ions | (1) towards the anode when the D.C supply ts connected. Ag’, being lighterAwhich ha a smalier retalve molecular | (4) ‘mass, 108 compared to 127, moves faster than tion | [i] Elements Ba o % by mass 55.1 193 ‘No.of moles $6.1aT [19.716 402 20 a ‘Simplest ratio 0.402/0.400 Empirical formula ts Cua, | a HW Group! oT {i) 22:5) + 24,0 () > 2Z0H (aq) + He (@) tt oo i i [1] correctly drawn i jonic bonds [1] key. i no marks if : diagram is wrong Key (pee {electron from F (©) © 22 (5) +2 Fs (9) > 22F (9) ‘Mass of fluoride ions = 1.16 ~ 0.78 389 No of moles of fluoride ions = 0/38/19 = 0,02 mol ]a {(@) Reduction takes place as ihe oxidation state of Cu ‘explanation for decreases from +2 in CuSO, to +1 in Cul. Oxidation takes | both O and Rmust Place as oxidation state of increases from-1 in KI to 0 in | be present for [1] oo Let the oxidation state of Sin Na,S;0, be x. 241) + 2x+3¢-2) =0 2+2x-6=0 aes x=42 1 -Let the oxidation stale of S in Na;S,05 be x 2(+1) + 4x+ 662) =0 244x—12=0 4x=10 x=425 m (i) b+ 2Na,S,05 > Na,S.O4 + 2Nal W (©) () No of moles of sodium thiosulfate = 18.5/1000 x 0.035 .0006475 mol No of moles of iodine = 0.5 x 0.006475 0,00032375 mot 0 Mass ofjodine = 0.00032375 x 127 x 2 = 0.0822 9 tH (li) No of motes of coppertil) sulfate = 0.00032375 x2 (0006475 mol 1 Concentration of copper) sulfate = 0.0006475/ (20/1000) .0323 motrin? i (8) Blue colour solution would decolourise. tn é Magnesium is more reactive than copper. Itwould displace | [1] copper from the solution, 82 (@) Colour changes from orange fo green Ti (&) Comparing Expts 1, 2 and 6-As the concentration of | [1] Cr,0,* increases while concentration of His kept constant, rate of reaction increases. | Comparing Expts 2, 4 and 5 ~ an increase in the n concentration of H" increases the rale of reaction. . Hence the rate of reaction increases as the concentrations | {1} {reactants increase, (©) The higher the concentration, the areater the number of | [1] paiticles for the same volume. Hence frequency of solisions increases and the chances of effective colisions | (1) increase, leading to an increase in the rate of reaction. (8) Comparing Expts 1 and 2, doublina the concéntration of . | {1} C1,0;* increases the rate of reaction by 4 limes.‘Comparing Expis 2 and 4 (or T and 3), doubling the concentration of H” doubles the rate of reaction. Hence the rate is more dependent on the concentration of Cr0;*. ti on her (@)W) 2ZAST) + 30a) > BAO) + FSO) (i) Limestone is added to remove'the impurities like sand presentin zinc Sulfide, «i. 1 Coke reacis with oxygen from the air toform CO, and alot of heat. G+ o>. Carbon dioxide reacts with more coke to foim carbon monoxide. Co + C >. 20 Carbon monaxide reacts with ZnO to produce molten Zn, which runs down to the:bottom of the furnace. ZnO Re ehiCONS 5} ae niger COs Limestone is decomposed by heat to produce célcium ‘oxide and carbon dioxide, CaO; cad_+ CO, Calcium oxide reacts with the impurities to form stag Si, + Cad. Casio, (©) @ amide linkage ® Ho HO) Ho. Hoo Loo fof pop a —C-C-N- G — C{n-C-C-N—C— C- ford raf HH HOCH, H HOH CH, one repeat unit (Gi) Relative molecular mass of one repeat unit 5x 1242x144 2x 16+8x1 = 128 Relative molecular mass of protein = 128 x 20 000 2560 000 tt io) point 1 or 2, [1] ny oy (1 mM iO} 0 aGi.) Reddish brown substance Tormns on electrode V (i) X:2CF (aq) > Ch (9) +2 Cu" (aq) + 20> Cu (s) (ii) Colourtess solution tums reddish brown: Chlorine is. ‘more reactive that iodide s0 it displaces iodine from the solution, ioding is formed. (Wy) Halogen displacement, Iredox, oxidation not accepted) (8) @ Compound ¥. tts reaction with water's an exothermic reaction and it gives off the, most heat‘on reaction with water, thus it Is most suitable for use in the hand warmer. ~ i) Rb,O (6) + H.0() > 2RLOH(eq) k ‘ io} 1 ty a io) a a) [i] correctty drawn ‘exothermic diagram, [1] correctly labeled diagram