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Thermal PDF
Thermal PDF
(Proven reserved)
3,708
150
1,239
126
600
350
5,529
60,600
114,500
76,400
0
()
Source : BP Statistical Review of World Energy June 2012
Reserves-to-production (R/P) ratios (Years)
Vietnam
15.0
Thailand
13.9
Taiwan
41.6
South Korea
79.4
Philippines
8.3
Malaysia
15.0
Japan
117.7
Indonesia
44.0
India
China
295.6
1839.4
Australia
49.8
0.0
100.0
200.0
300.0
400.0
Coal consumption (Million tonnes oil equivalent)
500.0
(, )
17%
47%
(Subbituminous)
(Hard coal)
52%
(Bituminous)
30%
(Thermal coal)
53%
(Anthracite)
(Coking coal)
60 %
:
16,800 kJ/kg
>
75%
60
71%
2.05.0%
23,000
kJ/kg
30-38%
1520%
7177 %
0.1-1.5%
29,300 kJ/kg
2430%
1-12%
7787 %
0.1
1.5
32,500 kJ/kg
8-15%
1-10%
8798%
0.1-1.0
36,250 kJ/kg
5-8%
0.510%
11
(Clean coal technologies)
12
13
(Reduce emission)
(Reduce waste)
(Increase energy
production)
14
15
Bottom ash
Steam coal
Fly ash
(Boiler) Slag
(FGD sludge)
Coking coal
(SOx, NOx)
16
1
2
3
4
5
17
http://www.energyboom.com/coal/10-reasons-clean-coal-offensive
http://teeic.anl.gov/er/coal/restech/tech/index.cfm
18
19
(Physical Cleaning)
(Pyritic Sulfur)
(Chemical Cleaning)
(Molten Caustic Leaching)
(Biological Cleaning)
20
(Coal washing)
21
(Upgrading Brown Coal, UBC)
(Low-rank coal)
http://www.kobelco.co.jp/english/about_kobelco/csr/environment/2009/1182273_12555.html
22
(Upgrading Brown Coal, UBC)
1)
/
2)
/
3)
(Briquetting)
23
(Coal water mixture technology)
24
(Coal water mixture technology)
25
26
/
(IPP)
(SPP)
??
1
2
3
4
5
http://www.transport.vic.gov.au/__data/assets/pdf_file/0019/60805/EV-fact-sheet-SECONDARY-renewable-energy-and-EVs.pdf
http://www.afriboilers.co.za/
(Pulverized Fuel Combustion, PFC)
(Coal pulverizer)
33
(Fluidized
Bed Combustion, FBC)
34
()
(Fluidized Bed Combustion, FBC)
(Bed)
http://www.brighthubengineering.com/power-plants/26547-how-does-a-circulating-fluidized-bed-boiler-work/
35
36
(Integrated Gasification Combined Cycle, IGCC)
37
(IGCC)
(Coal Gasification)
(Gas Fired Combined Cycle Plant)
(Gas turbine)
38
IGCC
: IGCC
20
: IGCC
IGCC
: IGCC
IGCC
(Desulfurization)
39
4
(PostCombustion Technology)
(SOx)
(NOx)
(Dust and Particulate matter)
()
41
2513
2523
2533
2543
2553
(EP)
(FGD)
Low NOx burner
(Scrubber)
SCR
(Bag filter)
Activated carbon injection (ACI)
(EP)
(FGD)
Low NOx burner
(Scrubber)
SCR
>
(EP)
(EP)
(EP)
(FGD)
(FGD) Low NOx burner
(Scrubber)
Selective catalyst
reduction (SCR)
(SOx reduction)
Flue Gas Desulfurization (FGD)
(Wet process)
(Dry process)
43
FDG -
(Wet limestone-gypsum process)
(Limestone)
(Gypsum,
CaSO4-2H2O)
CaCO3 + SO2 + 0.5H2O CaSO3-0.5H2O + CO2
CaSO3-0.5H2O + 0.5O2 + 1.5H2O CaSO4-2H2O
44
45
FGD
(Dry limestone-gypsum process)
[Ca(OH)2]
46
(NOx reduction)
(NOx)
2
LOW NOx burner
NOx
oSelective Non-Catalytic Reduction (SNCR)
o Selective Catalytic Reduction (SCR)
47
SNCR Reaction:
2NO + NH2CONH2 + O2 2N2 + CO2 + 2H2O
(Ammonia, NH3)
48
(N2)
SCR Reactions:
4NO + 4NH3 + O2 4N2 + 6H2O
2NO2 + 4NH3 + O2 3N2 + 6H2O
49
SNCR Reaction:
2NO + NH2CONH2 + O2 2N2 + CO2 + 2H2O
SCR Reactions:
CATALYST
4NO + 4NH3 + O2 4N2 + 6H2O
CATALYST
SNCR
SCR
/
/
NOX (%)
40-60
80 - 90
50
(Electrostatic Precipitator)
()
()
51
Fly ash
(85-95%)
Bottom ash
(5-15%)
http://www.jcoal.or.jp/coaltech_en/coalash/coalash_en.html
52
(Fly ash)
(Silica, SiO2)
(Alumina, Al2O3) 70-80 %
(Bottom ash)
53
(Fly ash)
(Bottom ash)
(Boiler slag)
FGD
FGD
FGD
(FBC)
54
(Cement mixture)
(Cement
admixture)
55
56
()
500
450
400
350
300
250
200
150
100
50
57
(Greenhouse gases)
:
Carbon dioxide
CO2
GWP*
(100-year)
1
Methane
CH4
25
(CO2)
Nitrous oxide
N2O
298
(N2O)
(CH4) []
IPCC 2006
58
59
60
Supercritical technology
Integrated Gasification Combined Cycle
(IGCC)
(CCS)
61
(Carbon capture and storage, CCS)
/
/
CCS 3
1)
2)
3)
(Capture)
(Transportation)
(Storage)
62
63