Professional Documents
Culture Documents
Pplant PDF
Pplant PDF
ii
.. 2558
(Power Plant Engineering)
E-book 4 e-mail
e-mail
2558
(1)
(2) (3) 13
13 4
4
e-mail: somchart@engr.tu.ac.th
2558
iii
iv
1.1
1.2
1.3
1.4
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1
1
3
4
5
2.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
2.3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
9
9
13
17
3.1 . . . . . . . . . . . . . . . . .
3.2 . . . . . . . . . . . . . . . . .
3.3 . . . . . . . . . . . . . . . . .
3.4
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27
27
33
35
38
4.1 . . . . . . . . .
4.2
4.3 . . . . . . . . . . . . .
4.4 . . .
4.5 . . . . . . . . . . . .
4.6 . . . . . . . . . . .
4.7 . . . . . . . . . . . .
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41
41
43
46
49
53
55
56
5.1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
5.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
5.3 . . . . . . . . . . . . . . . . . .
67
67
70
72
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vi
5.4
5.5
5.6
5.7
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82
83
85
90
6.1 . . . . . . . . . . . . .
6.2 . . . . .
6.3 . . . . . . . . . . . . .
6.4 . . . . . . . . . . . . . . . . . . .
6.5 . . . . . . . . . . . . . . . . .
6.6 .
6.7 . . . . . . . . . . . .
6.8 . . . . . . . . . . . . .
6.9 . . . . . . . . . . . . . . . . .
6.10 . . . . . . . . . . . . . . . . . .
6.11 . . . . . .
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95
95
96
97
99
101
103
105
108
109
111
113
7.1 . . . . . . . . .
7.2 . . . . . . . . . . . .
7.3 . . . . . . .
7.4 . . . . . . .
7.5 . . . .
7.6 . . . . .
7.7
7.8 . . . . . . . . .
7.9 . .
7.10 . . . . .
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121
121
122
124
126
131
136
139
142
143
146
8.1
8.2 . . . . . . . . . . . . . . .
8.3 . . . . . . . . . . . . . .
8.4 . . . . . . . . . . . . . . . . .
8.5 . . . . . . . . . . . . .
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151
151
151
155
158
162
167
9.1 . . . . . . . . . . . . . . . . . . . . 167
9.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 169
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9.3
9.4
9.5
9.6
9.7
vii
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184
186
189
189
192
10
10.1 . . . . . . . . . .
10.2 . . . . . . . . . . . .
10.3 . . . . . . . . .
10.4
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195
195
201
205
215
11
11.1 . . . . . . . .
11.2 . . . . . . . . . . . .
11.3 . . . . . . . . . .
11.4 . . . . . . .
11.5 . . . . . . . .
11.6
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221
221
222
224
225
231
233
12
12.1 . . .
12.2 . . . . . . . . . . .
12.3 . . . . . . .
12.4 . . . . . . . . . . . .
12.5 . . . . . . . . . . . . . . . . .
12.6 . . . . . . . . . . . . .
12.7
12.8 . . .
12.9 . . . . . . . . . . .
12.10 . . . . . . . .
12.11
12.12 .
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237
237
238
239
240
243
244
246
247
251
253
254
256
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261
261
265
269
273
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13
13.1 . . . .
13.2
13.3 . . . . . . .
13.4 . . . . . . . . .
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viii
13.5
13.6
. . . . . . . . . . . . . . . . . . . . . . . 276
. . . . . . . . . . . . . . . . . . . . . . 278
1.1
1.1
.. 2555 2557
(power generation system)
(power transmission system)
(substation)
1.
1.1: .. 2548
(W/)
1683
1114
804
774
622
581
458
377
286
225
147
131
75
52
39
28
69 kW 115 kW 230 kW 500 kW
(power distribution system)
11 kW 12 kW 22 kW 24 kW 33 kW
380/220 V
3
(1) (.)
(2) (.)
.
1.2.
(3) (.)
. .
.
1.2
(thermal power plant)
(renewable energy)
1.
1.3
MW
MW 1.2 ..
2558
1.2: .. 2558
(MW) (%)
23313
53.5
8176
18.7
3406
7.8
8741
20.0
(1) . (2)
(independent power producer) IPP (3) (small power producer)
SPP
.
.
IPP
SPP
IPP . .
IPP (1)
(2)
. (3) .
(4)
SPP .
90 MW SPP
1.4.
(cogeneration)
10%
45%
1.3 ..
2557 IPP
1.3: .. 2557
(MW) (%)
.
15482
45
13167
38
3615
10
()
2404
7
1.4
1.
1.4.
1.
2.
3.
4.
5.
6.
7.
8.
9. (IPP) (SPP)
10. EIA
1.
2.1
(discount
rate) (future value)
(present value)
P V = fP V F V
(2.1)
P V , F V n
fP V =
1
(1 + i)n
(2.2)
1 3
1.1
P V = 1000000 F V = 1100000
PV
FV
= 0.909
1
=
(1 + i)3
fP V =
10
2.
i = 0.0323
(series payment)
(2.1) (2.2)
500000 600000 5%
700000 4.5%
P V = P V0 + P V1 + P V2
P V0 = 500000
600000
P V1 =
(1 + 0.05)
= 471729
700000
P V2 =
(1 + 0.045)2
= 641011
= P V = 1612740
n
F Vk k
F Vk+1 = (1 + r)F Vk
PV =
[
(
) ]
1+r n
F V1
1
ir
1+i
(2.3)
r = i (2.3) P V
PV =
nF V1
1+i
(2.4)
2.1.
11
1000000
5% 5
7%
(optimization
process)
(levelized value)
(annual value)
n
(fP V 1 , fP V 2 , ..., fP V n ) (2.2)
(P V1 , P V2 , ..., P Vn ) (2.1) AV
AV =
P V1 + P V2 + + P Vn
fP V 1 + fP V 2 + + fP V n
(2.5)
50 /GJ 2-5
5% 5
4.5%
(2.1)
12
2.
1
2
3
4
5
FV
50.00
52.50
55.13
57.88
60.78
fP V i
0.9569
0.9157
0.8763
0.8386
0.8025
P Vi
47.85
48.07
48.31
48.54
48.78
P Vi fP V i (i = 1, 2, 3, 4, 5) (2.5)
47.85 + 48.07 + 48.31 + 48.54 + 48.78
0.9569 + 0.9157 + 0.8763 + 0.8386 + 0.8025
= 55.02 /GJ
AV =
(net present value) (internal
rate of return)
1500
150 20
8%
1500 (P Vout )
1500 20 (P Vin )
(2.3) r = 0
P Vin
[
(
) ]
150
1 + 0 20
=
1
i0
1+i
i = 0.08 1500
2.2.
2.2
13
(load curve)
2.1
2.1
(load) 2.1
(load curve) 1
1 1
2.1: 12
14
2.
(peak load)
(load factor)
2.2
(blackout)
15-20%
2.2:
2.1 93 MW 7
2.1
.. 2548-2557
kW kW.h 1
(average load)
(Pave ) (Pmax ) (LF)
LF =
Pave
Pmax
(2.6)
2.2.
15
2.1: .. 2548-2557
.. (MW) (MW)
2548
20538
26450
2549
21064
27106
2550
22586
28530
2551
22568
29892
2552
22045
29212
2553
24010
30920
2554
23900
31447
2555
26121
32600
2556
26598
33681
2557
26942
34668
2.1
2.1
2.1
(rated capacity)
(capacity factor)
CF =
Pave
Prated
(2.7)
Pave (2.7)
Prated Pmax (2.6)
Pave (2.6)
(2.7)
LF.Pmax
(2.8)
CF =
P
rated
16
2.
(h) 0-6 6-10 10-12 12-16 16-20 20-22 22-24
(MW) 30 70
90
60
100
80
60
.
.
100 MW
.
70 MW 70 MW 24
30 MW 70 MW
2.3
30 6 + 70 4 + 90 2 + 60 4 + 100 4 + 80 2 + 60 2
24
= 65 MW
65
= 0.65
LF = 100
Pave =
2.3:
CF = LF Pave
Prated = Pmax = 100 MW
2.3
2.3.
17
30 6 + 70 6 + 60 4 + 70 6 + 60 2
24
= 57.5 MW
57.5
CF1 =
= 0.82
70
Pave,1 =
70 MW 24 h
20 2 + 30 4 + 10 2
24
= 7.5 MW
7.5
CF2 =
= 0.25
30
Pave,2 =
2.3
(variable cost) (xed cost)
2.4
(fuel cost) (operation and maintenance cost)
(construction cost)
2.3.1
18
2.
2.4:
(cf ) (Cf )
(E ) E kJ cf (kW.h) cf
cf =
3600Cf
E
(2.9)
E = .Q
(2.10)
Q
(HHV) kJ/kg (mf ) /kg
Q = mf .HHV
(2.11)
(Ff )
Cf = mf .Ff
(2.12)
3600Ff
.HHV
(2.13)
E Cf (2.9)
cf =
2.3.
19
(2.12) cf
Ff /HHV Ff /HHV 4
Ff
(/kg)
1.0
1.5
1.3
1.1
HHV
(MJ/kg)
20
22
18
15
(/MJ)
0.050
0.068
0.072
0.073
Ff /HHV
800 MW 38%
82% 20000 kJ/kg 0.5
Ff (2.13)
cf ..HHV
3600
0.5 0.38 20000
=
3600
= 1.06 /kg
Ff =
2.3.2
com =
Com
E
(2.14)
20
2.
Com E
8760
E = 8760Pave
(2.15)
Pave (2.7)
(2.14)
com =
Com
8760.CF.Prated
(2.16)
600 MW 500
35%
500 106
8760 0.35 600 103
= 0.27 /kW.h
com =
2.3.3
(depreciation)
30-40
(salvage value)
(A) (G) (D)
N
(staight-line method)
D=
AG
N
(2.17)
2.3.
21
(sinking-fund method)
D=
(A G)i
(1 + i)N 1
(2.18)
(xed-charge rate)
Cc I
cc =
ICc
8760.CF.Prated
(2.19)
Cc = Fc Prated
(2.20)
Fc Fc
65 15
5% 5
A = 65 G = 5 N = 15
65 5
15
= 4
D=
150 MW
20000 /kW 10%
120 MW 50%
22
2.
0.5 120
150
= 0.4
CF =
cc =
2.3.4
2.5 1
1
2
2
3
3
1 ()
2 (
) 3
()
2.1 %
(load distribution curve)
2.6
(base load) (intermediate load)
(peak load)
2.6
1
2.5 1
2
3
1, 2 3
2.3.
23
2.5:
2.6:
24
2.
2.3.5
(http://www.mea.or.th)
(http://www.pea.or.th)
(energy charge)
(kW.h) (demand charge)
15
(supply and demand)
(peak period)
(off-peak period) 9.00-22.00 .
2.3.
25
(time of use TOU)
26
2.
1. 3
2.
3.
4.
5.
6.
7.
8. TOU
9. 50 /GJ 5%
2 5 5% 5
10. 6000 500
30
(internal return rate)
11. 800 MW
(peak load) 750 MW 8760
5 (capacity factor)
12. 42% 22000 kJ/kg
1500
13. 0.31
700 MW 8600 45%
14. 800 20
4% (salvage value) 60
(sinking-fund method)
15. 450 MW 18000 /kW
24 365 9%
37%
3.1
(coal)
(biomass)
3.1.1
4 (Anthracite)
(Bituminous) (Sub-bituminous) (Lignite)
(proximate analysis) (ultimate analysis)
4
(moisture) (volatile matter) (ash) (free carbon)
3.1
28
3.
(mi )
(mM )
(coke)
(mV M )
mA (mF C )
xF C =
mF C
m
m
m
; xV M = V M ; xM = M ; xA = A
mi
mi
mi
mi
(3.1)
50%
(bound water)
(free water)
(uniform burning)
(tempering process)
3.1
954 C
CH4 CO2
3.1:
3.1.
29
(spontaneous combustion)
Al2 O3 , Fe2 O3 , CaO, P2 O5
(ash fusion temperature)
(slag)
3.1 4
3.1:
(%) (%) (%) (%)
4.3
9.6
5.1
81.0
8.5
10.8
36.4
44.3
22.2
4.3
33.2
40.3
36.8
5.9
27.8
29.5
(C) (H) (O) (N) (S)
(dry ash-free coal)
m = mF C + mV M
(3.2)
30
3.
5
xC =
mC
m
m
m
m
; xH = H ; xO = O ; xN = N ; xS = S
m
m
m
m
m
(3.3)
5 1
(3.1) mi
(as-received coal) mi m
mi m = mM + mA
(3.4)
m = mi (1 xM xA )
(3.5)
C, H, O, N, S (3.3)
(3.1) C, H, O, N, S
xC,ar = xC (1 xM xA )
(3.6)
xC,ar =
mC
mi
(3.7)
xC,ar
(1 xM xA )
0.3958
=
(1 0.3354 0.1346)
xC =
= 0.7468
3.1.
31
(calorimeter)
(grindability)
(Hardgrove machine)
(Hardgrove index)
(abrasivity)
(carbon steel)
(swelling index)
(stationary grate)
32
3.
800 C
1 9
0
3.1.2
3.2 (
)
3.2:
(%) (%)
(%)
(%)
(kJ/kg)
12.00 12.65
56.46 18.88
14,755
10.00 10.39
60.70 18.90
13,650
50.73 1.43
41.98
5.86
9,243
40.00 0.90
45.42 13.68
11,298
59.40 1.50
31.00
8.10
7,451
3.2.
33
3.2
3.2.1
40705 45520
kJ/kg 1, 2, 4,
5 6 ( 3 )
3.2.2
80% 20%
(emulsied diesel)
34
3.
3.2.3
(specic gravity)
s=
15.6 C
15.6 C
141.5
131.5 + API
(viscosity)
ASTM Standard D445 (centistoke)
(viscometer)
(pour point)
3.3.
35
(ash point)
4-5 C
6
1% 3-4% 2%
SO3
(steam coil)
(1)
(2) (3)
3.3
(natural gas) (synthetic gas) (biogas)
3.3.1
(CH4 )
CO2
36
3.
(H2 S)
CO2
(methyl alcohol)
(ethyl alcohol)
(propylene)
(polypropylene)
(liqueed petroleum gas LPG)
LPG
LPG
Mi
V
= i
M
V
Mi Vi i M V
3.3.
37
MBtu (1 Btu = 1.055 kJ)
3.3.2
(coal gasication) (coke-oven gas) (producer gas) (water gas) (synthetic natural gas SNG)
(coke)
+ + +
H2 CH4
(exothermic)
+ CO + N2 +
CO N2 CO
CO H2
(endothermic)
+ + CO + H2
SNG N2 CO
CO + H2 O CO2 + H2
SNG SNG H2
CO CH4
CO + 3H2 CH4 + H2 O
(catalyst)
(blast-furnace gas) CO2
(sewer gas) CH4
38
3.
3.3.3
(biogas) (anaerobic digestion) 5 C, H,
O, N S
Ca Hb Oc Ne Se
(
)
b
c 3d e
Ca Hb Oc Nd Se + a 4 2 + 4 + 2 H2 O
(
)
(
)
a b
c 3d e
c 3d e
a b
+
CH4 + 2 8 + 4 + 8 + 4 CO2
2 8 2
8
4
+ dNH3 + eH2 S
CO2 , NH3 H2 S
BOD (biochemical
oxygen demand) COD (chemical oxygen demand) BOD
80% COD BOD COD
3.4
7
(proven reserve) (probable
reserve) (possible reserve)
3.3
(
)
3.4.
39
3.3:
()
P1 P1+P2 P1+P2+P3 P1 P1+P2 P1+P2+P3
223 553
741
4
11
15
()
LPG
182 411
()
7752 15560
()
1181 2007
()
P1
P2
P3
476
12
14
18885
13
16
2007
18
65
111
3.4
20
.. 2549 .. 2529
5.6%
21.8%
5.5%
13.1%
17.2%
21.8%
66.5%
40.3%
5.2%
3.0%
70%
40
3.
1.
2. 4
3.
4.
5.
6. (coke)
7. (ultimate analysis)
8.
9.
10. (water gas)
11. (biogas)
12.
13.
14.
4.1
(ue gas)
3
C + O2 CO2
H2 + 12 O2 H2 O
S + O2 SO2
(4.1)
(4.2)
(4.3)
(CH4 )
(4.4)
(4.1) - (4.4)
(reactant)
(product)
(ignition temperature)
O2
N2 , O2 , Ar CO2
42
4.
4.1:
N2
O2
Ar
CO2
(%)
78.084
79
20.946
21
0.934
0
0.036
0
(complete combustion)
(stoichiometric combustion)
C, H, S CO
(incomplete combustion)
O2 O2
(stoichiometric air) (theoretical air) H2 O, CO2 N2
O2
(Cm Hn )
Cm Hn + (m + n4 )(O2 + 3.76N2 ) mCO2 + n2 H2 O + 3.76(m + n4 )N2
(4.5)
CO CO
CO + 12 (O2 + 3.76N2 ) CO2 + 1.88N2
(4.6)
CO
CO
4.2.
43
4 (1) (2)
(3) (4)
(excess air)
4.2
(theoretical air-fuel ratio) AF RT
AF RT kgair /kgfuel
molair /molfuel
= 28.84
(4.7)
Mf uel
28.84 Mf uel
C, H S (4.1)-(4.3)
O N
Ca Hb Sc Od Ne
C
)
b
d
a+ +c
(O2 + 3.76N2 )
4
2
[
(
)
]
b
b
d
e
aCO2 + H2 O + cSO2 + 3.76 a + + c
+
N2
2
4
2
2
Ca Hb Sc Od Ne +
(4.8)
(
b
d
AF RT = 4.76 a + + c
4
2
molair /molfuel
(4.8)
(4.9)
4.2 AF RT (4.9)
N, O2 CO2 AF RT
AF RT
k y1 , y2 , ..., yk
AF RT AF RT,1 , AF RT,2 , ..., AF RT,k AF RT
44
4.
4.2: AF RT
C
H
S
CH4
C2 H6
C3 H8
CO
AF RT
(molair /molfuel )
4.76
1.19
4.76
9.52
16.66
23.8
2.38
C3 H8 1 C4 H10 2 y1
= 0.4, y2 = 0.6, AF RT,1 = 23.8, AF RT,2 = 30.94
AF RT = 0.4 23.8 + 0.6 30.94
= 28.1
molair /molfuel
CH4 , C2 H6 , C3 H8 CO2 1, 2, 3 4
y1 = 0.7, y2 = 0.1, y3 =
0.1, y4 = 0.1, AF RT,1 = 9.52, AF RT,2 = 16.66, AF RT,3 = 23.8, AF RT,4 = 0
AF RT = 0.7 9.52 + 0.1 16.66 + 0.1 23.8 + 0.1 0
= 10.7
molair /molfuel
AF RT
(4.9)
(4.7)
28.84 4.76
AF RT =
Mf uel
(
)
b
d
a+ +c
4
2
kgair /kgfuel
(4.11)
4.2.
45
Ca Hb Sc Od Ne
(4.12)
C, H, S O
12a
Mf uel
b
xH =
Mf uel
32c
xS =
Mf uel
16d
xO =
Mf uel
(4.13)
xC =
(4.14)
(4.15)
(4.16)
xC , xH , xS xO a, b, c d (4.11)
AF RT = 11.44xC + 34.32xH + 4.29xS 4.29xO
kgair /kgfuel
(4.17)
xM
xA
AF RT = (11.44xC + 34.32xH + 4.29xS 4.29xO )(1 xM xA )
(4.18)
xC , xH , xS xO
(3.6) (4.18)
AF RT = 11.44xC,ar + 34.32xH,ar + 4.29xS,ar 4.29xO,ar
(4.19)
4% 5%
C 83.1%, H 5.5%, O
7.4%, N 2.1% S 1.9% AF RT
(4.18) AF RT
AF RT = (11.44 0.831 + 34.32 0.055 + 4.29 0.019 4.29 0.074)
(1 0.04 0.05)
= 10.2
kgair /kgfuel
46
4.
4.3
(formation enthalpy)
(adiabatic ame
temperature)
(heating value)
1 kg 1 m3 (bomb
calorimeter)
(higher heating value)
(lower heating value)
4.3 C
4.3: C H S
C
H
S
HHV (kJ/kg)
C + O2 CO2
33700
H + 0.25O2 0.5H2 O 144200
S + O2 SO2
9300
S 4.3 H
1 kg O 8 kg
(
x )
HHV = 33700xC + 144200 xH O + 9300xS
(4.20)
8
(Dulongs formula) (4.20)
(
x )
HHV = (33700xC + 144200 xH O + 9300xS )(1 xM xA )
8
(4.21)
4.3.
47
(
xO,ar )
+ 9300xS,ar
HHV = 33700xC,ar + 144200 xH,ar
8
(4.22)
4.3 C S H
9 kg 1 kg H
9
25 C 2442 kJ/kg
LHV = HHV 2442(9xH,ar + xM )
(4.23)
Cm Hn Cm Hn , CO H2
4.4
4.4:
CH4
C2 H6
C3 H8
H2
CO
k y1 , y2 , ..., yk
HHV1 , HHV2 , ..., HHVk
(4.24)
k x1 , x2 , ..., xk
HHV1 , HHV2 , ..., HHVk
(4.25)
48
4.
4.4
CO Vi i 1
m3 1 m3 k
V = y1 V1 + y2 V2 + ... + yk Vk
(4.26)
25 C 1962 kJ/m3
(4.27)
(4.20) xM = 0
4 100%
xC,ar
= 0.70, xH,ar = 0.05, xO,ar = 0.04, xS,ar = 0.01, xM = 0.10 xA = 0.10
(4.22)
HHV = 33700(0.7) + 144200(0.05 0.04/8) + 9300(0.01)
= 30172 kJ/kg
(4.23)
LHV = 30172 2440(9 0.05 + 0.1)
= 28828 kJ/kg
(4.24) 4.4
HHV = 39700(0.8) + 12700(0.15) + 12600(0.05)
4.4.
49
= 34295 kJ/m3
1 m3 (4.26) 4.4
V = 2 0.8 + 1 0.15
= 1.75 m3
(4.27)
LHV = 34295 1960 1.75
= 30865 kJ/m3
4.4
2
(Orsat apparatus)
CO2 , CO O2
(CO2 , CO, O2 N2 )
N2
yN2 = 1 yCO2 yCO yO2
(4.28)
(AF RA )
4.4.1
AF RA
AF RA
(
)
N
1
2
=
0.767
AF RA =
50
4.
(
N2 N2
(
)
1
28( N2 )
=
xN,ar
0.767
1
=
0.767
(4.29)
xN N C CO CO2
xcb C 1 kg
CO CO2
12()(yCO + yCO2 )
=
xcb
(4.30)
xcb C (4.30)
(4.29)
1
AF RA =
0.767
28xcb yN2
xN,ar
12(yCO + yCO2 )
(4.31)
xcb
(xA )
(refuse)
(xcr ) xcb
xcb
= 1 x
cr
= x
A
= xA
(1 xcr
) (
)
=
=
xcb =
xcr xA
1 xcr
4.4.
=
51
xcb = xC,ar
xcr xA
1 xcr
(4.32)
1
0.767
= 4.11
4.4.2
0.0718 0.1552
1 0.0718
)
28 0.348 0.748
0.0084
12(0.0066 + 0.1857)
kgair /kgfuel
Ca Hb Sc Od (4.8)
(
)
d
b
(O2 + 3.76N2 )
a+ +c
4
2
(
)
b
d
b
N2
aCO2 + H2 O + cSO2 + 3.76 a + + c
2
4
2
Ca Hb Sc Od +
(4.33)
O2
CO
(
)
b
d
Ca Hb Sc Od + a + 4 + c 2 (O2 + 3.76N2 ) (a )CO2 + CO +
[
(
)
]
b
b
d
H2 O + cSO2 + ( 1) a + 4 + c 2 + 2 O2 +
2
52
4.
(
)
b
d
3.76 a + + c
N2
4
2
(4.34)
(air ratio) AF RA AF RT
O2 , CO N2 (4.29)
=
Ntotal
3.76(a + b/4 + c d/2)
=
Ntotal
yO2 =
(4.35)
yCO
(4.36)
yN2
(4.37)
(4.38)
(4.32) (4.33)
yN2
3.76
=
yO2 0.5yCO
( 1)
yN2
yN2 3.76(yO2 0.5yCO )
(4.39)
AF RA
(4.40)
AF RA = AF RT
C3 H8 CO2 , O2
CO 11.5%, 2.7% 0.7%
AF RT C3 H8 23.8 / (4.31)
N2
yN2 = 1 yCO2 yO2 yCO
= 0.851
N (e = 0)
=
0.851/(0.027 007/2)
0.851/(0.027 007/2) 3.76
= 1.116
= AF RA = 1.116 23.8 = 26.56
molair /molfuel
4.5.
4.5
53
(lean mixture) (rich mixture)
20% 20%
(e)
(
e=
AF RA AF RT
AF RT
)
100
(4.41)
N2 O2
(burner)
15-30% 5-10%
3-15%
O2 CO2
Cm Hn O2
Cm Hn +
(
m+
[
(
n)
n )]
(O2 + 3.76N2 ) mCO2 + ( 1) m +
O2
4
4 )
(
n
n
+ H2 O + 3.76 m +
N2
2
4
(4.42)
O2 , CO2
[( 1)(m + n/4)
4.76(m + n/4) n/4
m
=
4.76(m + n/4) n/4
yO2 =
yCO2
e = 100( 1)
yO2 yCO2 e
yO2 =
0.01e
4.76(1 + 0.01e) n/(4m + n)
54
4.
yCO2 =
4m/(4m + n)
4.76(1 + 0.01e) n/(4m + n)
O2
CO2
CO2 O2 CO2
O2
CO2 O2 CO2
4.2 CO2 , O2 CO
CO2
O2
O2
O2
4.6.
55
4.2: O2 CO2 CO
O2 O2
O2
CO
O2 CO
O2
CO CO
4.6
SO2
S + O2 SO2
SO2 O2 SO3
SO2 + 12 O2 SO3
SO3 (sulfuric acid)
SO3 + H2 O H2 SO4
56
4.
SO2
SO2
(p) 1 atm
(partial pressure) (pH2 O )
pH2 O = yH2 O p
yH2 O
1 atm (dewpoint temperature) pH2 O
4.7
1. (ignition temperature)
4.5
4.5:
( C)
C
700
S
243
H2
500
CO
609
CH4
580
C2 H6
515
C3 H8
480
4.7.
57
2.
3.
(furnace)
(1) (2)
(3)
4.7.1
(burner)
4.3
4.3
4.3:
11 kV (pilot ame)
58
4.
(main ame)
(turndown ratio)
(atomizer)
(1) (2)
(3)
4.7.2
H2 , CH4 CO
(mechanical stoker)
(pulverizer-burner system) (uidized bed combustion system)
(grate)
4.7.
59
(spreader)
(arch)
4.4 (spreader
stoker)
4.4:
(pulverizer)
3
26 112
60
4.
4.3
4 (1)
(2) (3)
(ashback)
(4)
4.5
4.5:
32 mm
0.6-4.6 m/s
4.7.
61
(CaCO3 )
MgCO3 CaCO3 CaO CO2
CaCO3 CaO + CO2
CaO SO2 O2
CaO + SO2 + 0.5O2 CaSO4
SO2 815 C 870 C
CaSO4
900 C
NOx
(bubbling uidized bed combustion) (bubbling uidized bed combustion) 4.6
4.7
62
4.
4.6:
(SH) (RH)
(Eco) (AH)
4.7:
SO2
4.7.
63
64
4.
1.
2. (stoichiometric combustion)
(complete combustion)
3.
4. H xH O xO
(free hydrogen)
5. (air ratio)
6. Orsat apparatus
7.
8.
9.
10. O2
11. CO2 O2
12.
13.
14.
15.
16. (uidized-bed combustion system)
17. (uidized bed) SO2
18. NOx
19. (HHV) C4 H10 128400 kJ/m3
1960 kJ/m3 (LHV) C4 H10
4.7.
65
66
4.
5.1
5.1
(compressed liquid
subcooled liquid)
(saturated liquid)
(saturated vapor) (superheated vapor)
5.1:
68
5.
5.1 5.2
(saturated liquid
line) (saturated vapor line)
374 C 22 MPa
(vapor dome)
5.2
5.2:
(T ) (p) (v) (h) (s)
(steam table) (steam chart)
5.3 h-p
(steam quality)
5.1.
69
5.3: h-p
x = 1 x = 0
5.3
x
70
5.
5.4:
5.2
(Carnot cycle) 5.4
1-2 (boiler)
2-3 (turbine)
3-4 (condenser)
4-1 (compressor)
1-2 3-4
1-2
3-4
=1
T4
T1
(5.1)
5.2.
71
5.5:
1-2
2-3
3-4
4-1
T-s 5.4 5.5
4-1
wnet
qin
(5.2)
(5.3)
(5.4)
72
5.
5.3
5.5
(5.1)
5 (1)
(2) (3)
(4) (5)
5.3.1
5.6
T-s
( 5.6)
(heat sink)
15%
5.6:
5.3.2
1-2 5.5 (superheater)
(superheated steam) 5.7
5.3.
73
5.5
650 C
5.7:
5.3.3
5.8 T-s
( )
(22.1 MPa)
5.9
(supercritical Rankine cycle)
74
5.
5.8:
5.9:
5.3.4
3
(reheat)
5.10
(reheater)
20%
5.3.
75
5.10:
850 K 15 MPa 0.01 MPa
0.9
5.11:
5.11 T-s
6 h6 = 192 kJ/kg
p6 p1 h1 = h6
2 h2 = 3510 kJ/kg.K
5 0.01 MPa 0.9 h5 = 2340 kJ/kg.K 5.11 s4 =
s5 T4 = T2 (s4 T4 )
4 h4 3620 kJ/kg p4 = 3.5 MPa
76
5.
3 p3 =
p4 s3 = s2 h3 = 3090 kJ/kg
wnet = wt
= h2 h3 + h4 h5
= 1700 kJ/kg
qin = h2 h1 + h4 h3
= 3848 kJ/kg
1700
= 0.44
=
3848
5 s5 = s2
p5 = 0.01 MPa h5 = 2100 kJ/kg
wnet = h2 h5
= 1410 kJ/kg
qin = h2 h1
= 3318 kJ/kg
1410
= 0.42
=
3318
5.3.5
(feed
water)
5.12
(regeneration)
(1-2-3-4-5-1) (1-2-3 -4 1)
5.3.
77
5.12:
(feed water
heater)
2 (1) (open feed water
heater) (2) (closed feed water heater )
5.13
5.14 T-s
5.13:
(5.2)
5.14
78
5.
5.14:
=
w net
w net
qin
(5.5)
qin
w net = h1 h2 + (1 m)(h2 h3 ) (1 m)(h5 h4 ) (h7 h6 )
qin = h1 h7
(5.6)
(5.7)
m
1 kg/s m
m=
h6 h1
h2 h5
(5.8)
(shell-and-tube
heat exchanger)
5.15
(drain)
TTD (terminal temperature difference)
5.16
()
5.3.
79
5.15:
(throttle valve)
()
5.16: ()
()
5.17 T-s
(5.5) w net , qin m
w net = h1 h2 + (1 m)(h2 h3 ) (h7 h4 )
qin = h1 h8
m=
h8 h7
h2 h5
(5.9)
(5.10)
(5.11)
80
5.
TTD T8
T8 = Tsat TTD
(5.12)
Tsat p2
5.17:
5.18 T-s
5.14 5.14
(feed water pump) 5.16
5.14 (5.5) w net
qin
w net = h1 h2 + (1 m)(h2 h3 ) (1 m)(h5 h4 ) m(h8 h6 )
qin = h1 h9
(5.13)
(5.14)
m h9 (5.13) (5.14)
(mixing chamber)
m=
h7 h5
h2 h6 + h7 h5
(5.15)
h9 = (1 m)h7 + mh8
(5.16)
T7 = Tsat TTD
(5.17)
TTD T7
Tsat p2
5.3.
81
5.18:
70 bar 540 C
7 bar 0.07 bar TTD = 3 C
5.18
h1 = 3500 kJ/kg
h2 = 2860 kJ/kg
h3 = 2150 kJ/kg
h4 = 163 kJ/kg
h5 = h4
h6 = 697 kJ/kg
h8 = h6
7 h7 p7 T7 5.18 p7 = p1 = 70
bar T7 (5.17) 7 bar Tsat = 165 C
T7 = 162 C
h7
162 C
h7 = 684 kJ/kg
82
5.
m (5.15)
684 163
2860 697 + 684 163
= 0.194 kg
m=
5.4
(pump efciency, p ) (turbine efciency, t )
wps
wp
wt
t =
wts
p =
wps wp wps
(isentropic process)
wp wt wts
5.5.
83
h1s h4
h1 h4
h2 h3
t =
h2 h3s
p =
5.5
5.20
(o )
Pe
o =
(5.18)
m
.HV
f
Pe , m f HV (heating value)
HV (HHV ) (LHV )
HV HV
o
o = b ..g
(5.19)
84
5.
5.20:
(boiler efciency)
b =
m
s (hout hin )
m
f .HV
(5.20)
m s , hin
hout
(Pnet ) (Qin )
Pnet
Qin
(5.21)
Qin (5.20)
g (Pe )
g =
Pe
Pnet
(5.22)
1 kW.h
(heat rate)
HR =
mf .HV
Pe t
(5.23)
5.6.
85
t mf
HR kJ/kW.h HR o
HR =
5.6
3600
o
(5.24)
5.21
(5.20)
(input-output method)
(heat-loss method) (5.20)
(Q l )
b = 1
Q l
m
f .HV
(5.25)
5.21
6
Li =
Q l,i
m
f .HV
(5.26)
b = 1 (L1 + L2 + L3 + L4 + L5 + L6 )
(5.27)
86
5.
5.21:
1.
Ta Tg
L1 =
(5.28)
xdg
cpg ( 1.0 kJ/kg. C)
Tg
Ta
CO2 , CO, O2
N2 NCO2 , NCO , NO2 NN2
(5.29)
(4.30)
mf =
(5.30)
(5.31)
5.6.
87
2.
H
O
L2 =
(5.32)
3.
L3 =
(5.33)
L3
L2
L3 L3 = 0
4.
(refuse)
L4 =
xuc .HHVC
HHV
(5.34)
xuc HHVC
(32800 kJ/kg)
5. CO
CO CO
C
CO
=
C
L5 =
88
5.
CO
(5.35)
xcb CO
(MCO ) 28 C (MC ) 12 CO (HHVCO )
10100 kJ/kg
6.
1%
L6
= 0.860
5.6.
89
= 12.9
(5.28)
12.9 1.0 (167 27)
30369
= 0.0595
L1 =
(5.32)
(0.06 + 9 0.05)[2442 + 1.9(167 27)]
30369
= 0.0455
L2 =
= 0
0.01
(5.34)
L3
0.01 32800
30369
= 0.0108
L4 =
CO (5.35)
L5 =
= 0.0186
L1 L5 L6 (5.27)
b = 1 0.0595 0.0455 0 0.0108 0.0186 0.0050
= 0.861
90
5.
(4.23) HV
(5.20) (5.25) LHV
(L2 )
b = 1 (L1 + L3 + L4 + L5 + L6 )
HHV
LHV
(5.36)
(4.23)
b = 30369 2442(9(0.05) + 0.06)
= 29124
b =
0.861 30369
= 0.898
29124
5.7
(cogeneration)
(bottoming system) (topping system) 5.22
(absorption chiller)
(trigeneration)
5.7.
91
5.22: () ()
5.23:
5.23
92
5.
(back-pressure turbine)
5.24
(extraction turbine)
5.24:
5.7.
93
1.
2.
3.
4.
5.
6. (
, , )
7.
8.
9. T-s
10.
11. T-s
12.
13. 6 MPa 850 K
14. 900 K 12 MPa
TTD 5 K
15.
10 MPa 700 K 3 MPa
0.01 MPa (
)
94
5.
16.
8 MPa
850 K 0.8 MPa
0.01 MPa (drain cooler) TTD
5 C ()
17. 9000 kJ/kW.h
6.1
(process boiler)
(utility boiler)
2
(re-tube boiler) (water-tube boiler)
18 bar
6.2 kg/s
(boiler shell)
(tensile stress)
pD
2t
(6.1)
96
6.
p D t
(D )
6.2
(steam generator)
(drum-type steam generator)
(once-through steam generator) 6.1
(furnace) (evaporator) (drum)
(superheater) (reheater) (economizer)
(air heater)
22.1 bar
( 5.11)
6.3.
97
6.1:
6.1
(steam separator)
6.3
(refractory)
98
6.
6.2:
6.3
(convection)
(bubbly
ow)
(slug ow)
(annular ow)
(mist ow) 6.3
(h) h
h
h
h
h
6.4.
99
6.3:
6.4
(pressure vessel)
(6.1) 30
m 4.5 m 30
(riser) (downcomer)
6.4
100
6.
6.4:
6.5 (bafe)
(screen)
(cyclone separator)
(d ) (r )
(p) p (H )
d r
(natural circulation)
d r
H r
d
6.5.
101
6.5:
H r
d
d r
180 bar
(forced circulation)
H
6.5
(total dissolved solid, TDS)
ppm (part per million)
102
6.
(blowdown)
m
b=m
s
xw xs
xd xw
(6.2)
(xs = 0) (6.2)
(
m
b=m
s
xw
xd xw
(6.3)
6.6:
m b d
(t)
xd1 xd2 xd2 xd1
6.7
m
b=
m
s (xw xs )(d + t)
[0.5(xd1 + xd2 ) xw ]d
(6.4)
6.6.
t = 0 xd1
(6.2)
103
= xd2 = xd
(6.4)
6.7:
6.6
100 MW
(radiant superheater)
(convective superheater)
104
6.
6.8
(parallel ow)
(counter-ow)
6.8
6.8:
(6.1)
6.7.
105
20-30 C
(soot
blower)
6.7
5 C
4
(attemperation)
(gas recirculation)
1.
106
6.
6.9
6.9:
2. (attemperator)
6.10
(m w )
m
s hs1 + m
w hw = (m
s+m
w )hs2
3.
6.11 (Q)
(Qa ) (Qg )
(Qr )
6.7.
107
6.10:
6.11:
4.
108
6.
6.12
6.12:
6.8
(thermal stress)
30 C
6.9.
109
10-12 m/s
6.9
110 C 4%
280 C 11%
150-420 C
280-400 C
135-180 C
(recuperator)
(regenerator)
6.13
6.13()
6.13()
(hopper) 30-60 W/m2 . C
50-65
mm
110
6.
6.13: () ()
(matrix)
6.14 (Ljungstrom regenerator) (Rothemuhle regenerator)
(effectiveness)
(self-cleaning)
6.10.
111
6.14: () ()
120 MW
10 m 0.5-3 rpm
6.10
112
6.
(soot blower)
6.15:
6.11.
113
6.16
50 cm
6.16:
6.11
(draft)
2 (natural
draft) (mechanical draft)
6.11.1
(stack) 6.17
114
6.
H (p) H
6.17:
6.11.2
6.11.
115
PF D =
m
f .AF RA .va .p
F D
(6.5)
va F D
(PID ) p
PID =
m
f (1 + AF RA )vg .p
ID
vg ID
(balanced draft)
6.11.3
(axial type) (centrifugal type)
(single-stage axial fan) (twostage axial fan)
116
6.
(forward-curved)
(at) (backwardcurved) 6.18
6.1
6.18: ,
(characteristic curve)
(system resistance curve)
6.19
6.11.
117
6.1:
78-83%
84-91%
70-72%
6.19:
(inlet vane
control) 6.20
sp1 sp2
sp2 sp3 p1 p2
118
6.
p2 p3
a b b c
a p1 b p2
b p2 c p3
6.20:
(variable-speed
control) sp1 p1 sp2 p2
sp3 p3
6.21:
6.11.
119
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
120
6.
7.1
(radial-ow turbine) (axial-ow turbine)
(stator) (rotor) 7.1
122
7.
7.1:
7.2
(stage)
7.2 4
(impulse stage)
(reaction stage)
7.2: 5
7.2.
7.2.1
123
7.3
7.3:
(pressure compound
stage) 7.4
7.4
(velocity compound stage) 7.5
7.2.2
124
7.
7.4:
(reaction degree)
R=
hr
hs + hr
(7.1)
hs hr
0 1 50%
7.6
50%
(air foil)
7.3
(nozzle)
7.3.
125
7.5:
7.6: 50%
(nozzle efciency)
126
7.
(isentropic ow)
N =
h
hs
(7.2)
(h0 ) (V0 ) (h1 )
(V1 )
h0 +
V02
V2
= h1 + 1
2
2
= h = h0 h1 =
V2
V12
0
2
2
V0 V1
V12
2
V1 = 2h
h =
(7.3)
(7.4)
0.4 MPa
0.1 MPa 90%
J/kg
h (7.4)
V1 =
2 2.16 105
= 657 m/s
7.4
(velocity triangle)
7.4.
127
V
(absolute velocity) U W
=W
+U
(7.5)
7.7
V1 (nozzle angle)
(1 ) (2 )
7.7: () ()
U = r
(7.6)
rad/s r
N rpm
=
2N
60
(7.7)
128
7.
F = m(V
1 cos 1 + V2 cos 2 )
(7.8)
P = mU
(V1 cos 1 + V2 cos 2 )
(7.9)
[
)]
1( 2
P =m
h1 h2 +
V1 V22
2
(7.10)
W1 W2
[
)]
1( 2
2
0=m
h1 h2 +
W1 W2
2
)
1( 2
W1 W22
= h1 h2 =
2
(7.11)
h1 h2 (7.10)
P =
) (
)]
m
[( 2
V1 V22 W12 W22
2
(7.12)
(7.12)
V12 = W12 + U 2 + 2W1 U cos 1
V22 = W22 + U 2 2W2 U cos 2
(7.12)
P = mU
(W1 cos 1 + W2 cos 2 )
(7.13)
7.4.
129
7.7
(7.9) (7.13)
(vertex)
7.8 50%
1 = 2
50%
50%
1 = 2 2 = 1 W1 = V2 W2 = V1
7.8: () 50% ()
(blade efciency)
B =
P
mh
(7.14)
h (7.3)
(7.14)
P
B = 1
(7.15)
2
1
2 mV
h (h0 h1 )
(h1 h2 ) V12 /2 (7.3)
h1 h2 (7.11)
h =
1 2
[V + (W22 W12 )]
2 1
(7.16)
B =
1 m[V
2
2 1
P
+ (W22 W12 )]
(7.17)
130
7.
3000 rpm
600 mm 800 mm
U=
50% 20 C
50 m/s 30 m/s
8 kg/s
(1 ) (1 )
W1 sin 1 = V1 sin 1
W1 cos 1 = V1 cos 1 U
[
]
V1 sin 1
1 = tan1
V1 cos 1 U
[
]
50 sin 20
= tan1
50 cos 20 30
= 45.2
W1
V1 sin 1
sin 1
50 sin 20
=
sin 45.2
= 24.1 m/s
W1 =
P (7.11) B (7.15)
50% (2 = 1 W2 = V1 )
P = 8 30(24.1 sin 45.2 + 50 sin 20 )
= 15.4 kW
7.5.
131
B =
1
2
1.54 104
8[502 + (502 24.12 )]
= 0.87
7.5
Pact
P (7.10)
7.5.1
(1 = 2 )
(W1 = W2 ) V2
(2 = 90 )
7.9 (Uopt )
Uopt = W2 cos 2
Uopt =
V1 cos 1
2
(7.18)
Uopt (7.1)
Pmax =
(V1 cos 1 )2
2
(7.19)
Pmax (7.13)
B,max = cos2 1
(7.20)
132
7.
(7.16) 1 1 = 0
1 0
7.10
(Uopt )
Uopt = W4 cos 2
(W3 = W4 )
V3 cos 2 = 2Uopt
(7.21)
7.5 V2 V3
(V2 = V3 )
V2 cos 2 = 2Uopt
(7.22)
7.9:
7.5.
133
7.10:
Uopt W2
W2 cos 1 = V2 cos 2 + Uopt
= 3Uopt
(W1 = W2 )
V1 cos 1 = 4Uopt
(7.23)
Uopt =
V1 cos 1
4
n
Uopt =
V1 cos 1
2n
(7.24)
134
7.
(P1 ) (P2 ) (7.7)
P1 = mU
opt (V1 cos 1 + V2 cos 2 )
P2 = mU
opt (V3 cos 2 )
(7.25)
(7.26)
3 : 1
3
5 : 3 : 1 2
h n
h/n
V1 =
2h
n
(7.27)
(7.16) Uopt n
7.4
7.5.2
50%
7.11
Uopt = V1 cos 1
(7.28)
7.5.
135
Uopt 2 = 90 (7.11)
Pmax = m
(V1 cos 1 )2
(7.29)
B,max =
2 cos2 1
1 + cos2 1
(7.30)
7.11: 50%
W2 = kW1 k < 1
1
136
7.
7.13
V1 cos 1 = W1 cos 1 + Uopt
Uopt = W2 cos 2 = kW1 cos 1
Uopt
+ Uopt
(k
)
k
=
V1 cos 1
k+1
V1 cos 1 =
= Uopt
7.12:
(7.7) (7.13)
P = mU
opt (V1 cos 1 )
(
)
k
=m
(V1 cos 1 )2
k+1
(
)
k
B = 2
cos2 1
k+1
7.6
mh
s hs
1. (turbulence) mh
s
2.
7.6.
137
3. 7.7
(PS ) P (7.7) (7.11)
4.
5.
7.12
(W )
(Wm )
PS P
7.13:
(stage efciency)
S =
PS
mh
(7.31)
(7.29)
(
S =
h
hs
) (
) ( )
P
PS
.
.
mh
138
7.
2 3-5
PS
= 1 fL
P
(7.32)
S = N B (1 fL )
S N , B fL
hs () ( ) PS /m
PS
=
m
(7.34)
hs
(7.35)
S =
(N ) rpm
=
2N
= 157 rad/s
60
(7.33)
S =
1000 157
= 0.785
2.00 105
J/kg
7.7.
7.7
139
PT
n=
PT
PS
(7.36)
S 4
7.14 1 2s, 3ss, 4ss
5ss 1 2, 3, 4 5
T =
PT
PT
m(h
1 h5ss )
(7.37)
4
PT = PS1 + PS2 + PS3 + PS4
S
PT = m
S [(h1 h2s ) + (h2 h3s ) + (h3 h4s ) + (h4 h5s )]
PT (7.35)
[
T = S
7.14
(h1 h2s ) + (h2 h3s ) + (h3 h4s ) + (h4 h5s ) > h1 h5ss
T S
T = fR S
fR (reheat factor) 1
(7.38)
140
7.
7.14: 4
2 2
50% 2
(1 )
h(1) 2
h(1) /2 (7.4)
V1 =
h(1)
(7.16)
2U
cos 1
(
)2
U
=4
cos 1
V1 =
= h(1)
h(2)
(7.4)
V1 =
2h(2)
7.7.
141
(7.22)
V1 =
4U
cos 1
(
= h(2) = 8
U
cos 1
)2
h(3)
h(3) /2 50%
h(3)
V1 =
(7.23)
U
cos 1
(
)2
U
=2
cos 1
V1 =
= h(3)
7.15
7.15
142
7.
7.15:
7.8
P F
(axial thrust)
T = (p1 p2 )A m(W
1 sin 1 W2 sin 2 )
(7.39)
A (7.31)
7.3 p1 p2
7.9.
143
7.6 p1
p2
7.16
7.16:
7.9
(high-pressure section) (low-pressure section) 7.17
7.17
144
7.
7.17:
(back-pressure turbine)
7.18
(hp turbine)
(ip turbine)
(lp turbine)
7.19
7.17 (double-ow
turbine)
7.9.
145
7.18:
7.20
3000 rpm
(tandem-compound turbine)
3000 rpm
1500 rpm
7.21 (cross-compound turbine)
146
7.
7.21:
7.10
50% (7.29) U
7.10.
147
(Uopt = V1 cos 1 )
(governor)
7.22 (yball
governor) (sleeve)
7.22:
10% 3000 rpm
3300 rpm
148
7.
1.
2.
3.
4. 50%
5.
6. 50%
7.
V1 1
8.
9.
10.
11.
12.
13.
14.
15. 3100 kJ/kg
3000 kJ/kg
16. 500 mm
3600 rpm
17. 900 m/s 20
300 m/s
7.10.
149
20. 50% 15
150
7.
8.1
(cooling tower)
8.1
8.2
(shell-and-tube heat exchanger)
(one-pass)
(two-pass) 8.2
U (four-pass)
8.3
152
8.
8.1:
8.2:
8.2.
153
Q = U ATlm
ITD TTD
Tlm =
ln(ITD/TTD)
(8.1)
(8.2)
ITD TTD
U A
(8.1)
ITD TTD
Q
8.3:
8.1
(admilralty copper) 304 (304 stainless steel)
(fouling)
90-10
154
8.
4
8.4
8.4:
1.8
3 m/s
8.3.
155
(vacuum pump) (ejector)
8.3
8.3.1
(deaerator)
O2 CO2
O2 CO2
8.5
(heater) (vent condenser) (storage tank)
(trays)
156
8.
8.5:
8.3.2
(LP heater) (HP heater)
(desuperheater) (condensing section)
(drain cooler)
8.6
8.3.
157
8.7
8.6:
8.7:
158
8.
8.3.3
8.1
200 MW 3 8
200 MW
8.1:
(MW)
0 50
3 5
50 100
5 6
100 200
5 7
200
6 8
8.4
(once-through system)
(thermal pollution)
(closed-loop system)
(cooling tower)
8.4.
159
2
(wet cooling tower) (dry cooling tower)
8.4.1
(approach) (range)
(wet-bulb temperature)
(natural draft) (mechanical
draft)
(i ) (o ) H (p)
p = (o i )gH
(8.3)
p
(hyperbola)
8.8
150 m 2.5-5
160
8.
8.8:
(forced draft)
(induced
draft)
(counter-ow) 8.9
(cross-ow) 8.10
8.8-8.10
(ll)
(packing)
(makeup water)
11.5%
8.4.
161
8.9:
8.10:
(drift) (drift eliminator)
162
8.
0.03% (bafe)
(blowdown)
1-1.5%
(recirculation)
(interference)
8.4.2
8.11
8.12
8.5
(blowdown)
(makeup
8.5.
163
8.11:
8.12:
water) 1.5-2%
3 Ca+ , Mg2+ , Na+
3 HCO3 , Cl , SO2
4
164
8.
(scale)
CO2 O2
(sedimentation)
(coagulation)
(internal treatment)
(external treatment)
(ion
exchange process) (cation resin) (anion
resin) ( Ca+ , Mg2+ , Na+ ) ( HCO3 , Cl , SO2
4 )
R H+ + C+ R C+ + H+
2+
2R H+ + C2+ R
+ 2H+
2C
R+ OH + A R+ A + OH
2
2R+ OH + A2 R+
+ 2OH
2A
R
C Ca+ , Mg2+ , Na+
A HCO3 , Cl , SO2
4
H+ OH (H2 O)
8.5.
165
(regeneration)
2
2R C+ + H2 SO4 2R H+ + C+
2 SO4
R+ A + NaOH R+ OH + Na+ A
R+2 A2 + 2NaOH 2R+ OH + Na+2 A2
166
8.
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
9.1
(open-loop control)
(closed-loop control) 9.1
(output) (input) (set point)
(controller) (control element)
(process equipment)
168
9.
(sensor)
(feedback)
9.1:
9.1 (feedback control) (disturbance)
(feedforward controller) 9.2
(cascade control) 9.3
1 (primary control loop)
1 2 (secondary control loop)
2 1 2
2 1 2
1
1
9.2.
169
9.2:
9.3:
9.2
170
9.
9.2.1
(manometer) (Bourdon gauge) (bellows
gauge) (diaphragm gauge)
(strain gauge)
9.4
p1
p2 p2
h p1
p2
p1 p2 = gh
(9.1)
9.4:
p2 p1 p2
9.5
9.2.
171
9.5:
9.6
9.6:
9.7
9.8
172
9.
9.7:
9.8:
(differential pressure transmitter)
(block valve)
(equalizing valve) 9.9
9.2.2
(level gauge)
9.2.
173
9.9: (DPT)
(displacer level gauge) (differential pressure level
gauge)
9.10
9.10:
9.11
9.12
174
9.
9.11:
(9.1) (h)
DPT
9.12:
9.2.3
(bimetallic thermometer)
(lled-bulb thermometer) (resis-
9.2.
175
9.13:
9.14
(bellows)
RTD
RTD
176
9.
9.14:
(Seebeck effect)
9.15
9.16
V1 V2 V1 1 V2
2 2 0 C 2
V2 V1
1 2
2
1 0 C RTD
2 V2
V1 1
9.15:
9.2.
177
9.16:
9.17:
(thermowell) 9.17
9.2.4
178
9.
(pressure-difference ow meter)
(velocity-based ow meter)
(positive-displacement ow meter)
(DPT)
(orice meter) (Venturi tube) (ow nozzle) 90
(elbow meter) (Pitot tube) (averaging Pitot tube)
(Annubar)
9.18
9.19
9.20
(9.2)
Q=k
p1 p2
(9.2)
k
(d)
(D) ( = d/D)
9.21
(throat)
(9.2) k
9.22
90 9.23
9.2.
179
9.18:
9.19:
9.24
90 (p1 )
(total pressure)
1
p2 = p1 + V 2
2
(9.3)
180
9.
9.20:
9.21:
9.22:
V
Q=A
2(p2 p1 )
(9.4)
9.2.
181
9.23: 90
A
9.24:
9.25
90
9.26
182
9.
9.25:
9.26:
(turbine ow meter) (vortex ow meter)
(magnetic ow meter)
9.27
9.28
(vortex)
9.2.
183
9.27:
9.28:
9.29
(1)
(2) (3)
184
9.
9.29:
9.30 (gear ow meter)
9.30:
9.3
9.3.
185
50 Hz
50 Hz
50 Hz
(load demand signal)
(ET)
EC
(PC)
(pressure set point)
PC
(PT)
9.31:
186
9.
PT
PC
9.32 EC
PC
9.32:
9.33 EC
9.4
9.4.
187
9.33:
9.34
9.34
(cross-limited control) 9.35
(FT)
(FC)
(low select)
(high select)
188
9.
9.34:
9.35:
9.34
9.5.
189
9.34
9.5
9.36
(PT) (PC)
PC
PC
9.36
9.6
190
9.
9.36:
(single-element control) 9.37 (LT)
(LC)
(two-element control) 9.38
FT
9.6.
191
9.37:
9.38:
192
9.
9.39:
9.7
6
9.40
(primary superheater) (secondary superheater)
9.7.
193
(attempetor)
1 ( TT1)
2 (TT2) 1 (TC1) TT1
2 (TC2) TC2 TT2
TC2
9.40:
194
9.
1.
2.
10 cm
3.
4.
5.
6.
7.
8.
9.
10. RTD
11.
12.
13.
14. (total pressure)
(static pressure) (dynamic pressure)
15.
16.
17.
18.
19.
20.
10
10.1
(gas turbine cycle)
10.1 (compressor)
(combustor)
(gas turbine)
10.1:
(open Brayton cycle) 10.2
(heater)
196
10.
10.2:
10.3 (closed Brayton cycle)
(cooler)
T1
(ideal gas)
T-s 10.3 4
1-2
2-3
3-4
4-1
(wnet ) (qin )
(10.1)
qin = cp (T3 T2 )
(10.2)
cp (B )
wnet = cp (T3 T4 ) cp (T2 T1 )
B = 1
T4 T1
T3 T2
10.1.
197
10.3:
=1
T1 (T4 /T1 1)
T2 (T3 /T2 1)
1-2 3-4
2-3 4-1
T2
T3
(k1)/k
= rp
=
(10.3)
T
T
1
k = cp /cv rp = p2 /p1
B = 1
=1
T1
T2
1
(10.4)
(k1)/k
rp
(10.4) k k
He Ar k 1.67
k 1.4
(T3 ) (T1 ) rp
rp
(
rp.max =
T3
T1
)k/(k1)
(10.5)
T3 T1
(10.3) (10.1)
[
wnet = cp T3
1
(k1)/k
rp
T1
(k1)/k
rp
)
1
(10.6)
198
10.
rp wnet (10.6)
(
rp,opt =
T3
T1
)k/2(k1)
(10.7)
(
wmax = cp T3
T1
T3
)2
(10.8)
10.4
1-2 3-4
T2s T1
T2 T1
T3 T4
t =
T3 T4s
c =
(10.9)
(10.10)
100%
10.4:
10.1.
199
(regenerator)
10.5
T-s
10.5:
10.5 (Tx ) (T4 )
Tx T4
(regenerator effectiveness, )
=
Tx T2
T4 T2
(10.11)
T4
T2
T4 T2 (reheating)
(intercooling) 10.6
(LC)
(HC) (LT)
200
10.
(HT)
10.6:
10.5 1 atm
15.6 C 1093.3 C 4
0.88 0.85 0.7
cp = 1.005 kJ/kg.K k = 1.4
(
T2s = T1
p2
p1
)(k1)/k
= 288.6(4)0.4/1.4 = 429 K
T2s T1
= c = 0.85
T2 T1
= T2 = 454 K
( )(k1)/k
p4
T4s = T3
p3
10.2.
201
= 1366.3(4)0.4/1.4 = 919 K
T3 T4
= t = 0.88
T3 T4s
= T4 = 973 K
=
Tx T2
= 0.7
T4 T2
= Tx = 817 K
wc = cp (T2 T1 )
= 166 kJ/kg
wt = cp (T3 T4 )
= 395 kJ/kg
qin = cp (T3 Tx )
= 552 kJ/kg
395 166
=
= 41.5%
552
10.2
10.7
(heat recovery steam
generator HRSG)
cc =
w B + w R
qin
(10.12)
w B w R qin
(B )
(R )
w B = B qin
w R = R (1 B )qin
w B w R (10.12)
cc = R + B R B
(10.13)
202
10.
10.7:
HRSG
10.8
q1
q2
w B = B q1
w R = R [(1 B )q1 + q2 ]
w B + w R
q1 + q2
B q1 + R [(1 B )q1 + q2 ]
=
q1 + q2
cc =
= cc
(10.14)
x=
q2
q1 + q2
= q2 = x(q1 + q2 )
10.2.
203
q2 (10.14)
cc = B + R B R xB (1 R )
(10.15)
10.8: HRSG
(10.13)
(10.12) w B , w R qin
w B = m
g cpg (T3 T4 T2 + T1 )
w R = m
s (ha hb hd + hc )
qin = m
g cpg (T3 T2 )
(10.16)
(10.17)
(10.18)
m g m s
cpg m g m s
HRSG HRSG
m
g cpg (T4 T5 ) = m
s (ha hd )
(10.19)
204
10.
10.7
7.5 15 C
750 C 100 C
50 bar 500 C
0.1 bar 200 MW
cpg = 1.1 kJ/kg.K k = 1.4
(
T2 = T1
p2
p1
)(k1)/k
w B (10.16)
w B = 196.1m
g
(10.20)
qin = 561.9m
g
(10.21)
qin (10.18)
ha = 3670 kJ/kg
hb = 2305 kJ/kg
hc = 192 kJ/kg = hd
w R (10.17)
w R = 1365m
s
(10.22)
(w B + w R )
196.1m
g + 1365m
s = 200 103
(10.23)
10.3.
205
MW w B (10.20) w R
(10.22) kW kW
(10.19)
m
s
= 0.0712
m
g
(10.24)
(10.23) (10.24) m g m s
m
g = 681.9 kg/s
m
s = 48.6 kg/s
m g , m s (10.20)-(10.22) (10.12)
w B = 133.8 MW
qin = 383.2 MW
w R = 66.3 MW
cc = 0.52
10.3
10.3.1
(aeroderivative gas turbine)
(industrial gas turbine)
206
10.
10.1
10.1:
30
16
50 MW
300 MW
10.3.2
(compressor) (combustor) (turbine) (casing)
10.9
(positive displacement)
(centrifugal ) (axial)
10.10 (lift)
() ()
10.3.
207
10.9:
(W ) (chord line) ()
10.11
(guide vane)
7
10.10:
(stall)
10.12
208
10.
10.11:
(V ) ()
(variable-angle guide vane)
10.12:
(lowpressure compressor) (high-pressure compressor)
(low-pressure turbine)
(high-pressure turbine)
10.13
10.3.
209
10.13:
(compressor wash)
(, SNG) ( , , 2)
3 (tubular) (tuboannular)
(annular) 10.14
(ame tube)
10.15
(recirculation zone)
(burning zone)
(dilution zone)
NOx NOx
NOx
210
10.
10.14:
10.15:
(single-shaft gas turbine)
10.16 (two-shaft gas turbine)
10.3.
211
10.16:
(creep)
(Larson-Miller parameter)
LM LM ( K)
( )
LM = T (20 + log t)
(10.25)
LM T1 = 900 K T2 = 890
K (10.1) t1 = 25000 T2 = 47000
10 K
10.17
212
10.
10.17:
10.3.3
ISO 15 C
60% 1 atm
1 atm
10.3.
213
NOx
100%
10.3.4
15 C
10.18
10.18:
(evaporative cooling system)
214
10.
(fogging system)
10.19
(steam injection cycle)
10.1
10.19:
10.20 (evaporation cycle)
10.1
10.4.
215
10.20:
10.4
HRSG
HRSG
10.21
Ty Tx (pinch point)
HRSG Tx Ty
HRSG HRSG
5-30 C
HRSG (horizontal) (vertical)
(once-through) 10.22 HRSG
HRSG
HRSG
216
10.
10.21: HRSG
10.23 HRSG
HRSG
HRSG
HRSG HRSG HRSG
HRSG
10.22:
10.4.
217
10.23:
10.24
HRSG HRSG
HRSG (triplepressure HRSG)
10.24: HRSG
HRSG
HRSG
HRSG
218
10.
HRSG
HRSG
HRSG
HRSG
10.4.
219
1.
2.
3.
4. T-s
5.
6.
7.
8.
9.
10.
11.
12.
13. NOx
14.
15.
16. ISO
17.
18.
19.
20.
220
10.
21.
22.
23.
24. 50% 300 C
200 C 100 C
25. 30 C 2000 C
4
26. 50%
( k = 1.4, cp = 1.005 kJ/kg.K)
27. 300 K 1 atm
80% 8 atm
( k = 1.4)
28. 1300 K 8 atm
80%
1 atm ( k = 1.4)
29.
2
300 K 1300 K
0.8 ( cp = 1.005
kJ/kg.K k = 1.4)
30. 200 MW 7.5
15 C 750 C
750 C HRSG
50 bar 600 C
0.1 bar ( cp = 1.11 kJ/kg.K, k =
1.33 )
11
11.1
(hydroelectric power plant)
100 kW 30 MW
(1) (run-of-river plant)
(2)
(impoundment plant)
(3) (pumpedstorage plant)
11.1 (dam)
(penstock)
(hydraulic turbine)
222
11.
(generator)
11.1:
H Q
gQH 75%
= p .t .g
(11.1)
11.2
11.2.
223
(rock-lled dam) (earth dam)
(gravity
dam) (arc dam) (buttress dam)
(buttress)
20-30%
11.1
(spillway)
224
11.
11.1:
(m3 )
(MW)
13462
731
17745
720
9510
500
8860
300
3057
240
1420
72
2263
55
1967
36
(service spillway)
(emergency spillway)
11.3
(low-pressure conduit)
(screen)
,
(surge tank)
(penstock)
PVC (polyethelene)
(expansion joint)
1
p
p1
+ V12 + L = gH
(11.2)
H p1
pL (pressure loss) V1
11.4.
225
p = 1
pL
gH
(11.3)
p 1
(water hammer)
11.4
226
11.
11.2:
p1
1
p2
1
+ V12 =
+ V22 + E
(11.4)
E=
)
p1 p2
1( 2
+
V1 V22
(11.5)
Eact
E
(11.6)
t =
Eact
11.3:
11.4.1
(11.5)
(reaction degree)
R=
(p1 p2 )/
E
(11.7)
11.4.
227
R (impulse turbine) R
(reaction turbine) R
(Pelton turbine)
11.4
(nozzle)
(needle valve)
(deector)
11.4:
11.5
= 180
(V2 = 0)
180
170 1
(V2 > 0)
228
11.
11.5:
(casing)
(Francis turbine)
(Kaplan turbine)
11.6
(1) (2) (guide vane) (wicket
gate)
(3)
(runner blade)
(propeller) 4
8 11.7
(servo-motor)
11.4.
229
11.6:
11.7:
V1 E p2 V2
Emax =
p1
1
+ V12
(11.8)
p2 = 0 V2 = 0 p2
V2
E Emax
E Emax
11.5
11.4.2
230
11.
(head) (specic
speed)
( 60 m) (60350 m) ( 350 m)
(H ) (P ) (N )
N P
Ns = 5/4
H
(11.9)
N (rpm) P kW H m
4 1100
11.8
11.8:
100%
11.9
(propeller) (xed-blade)
11.5.
231
11.9:
11.4.3
(runaway speed)
11.10 (turbine governing system)
(speed governor) (electro-hydraulic governor)
(speed sensor)
(actuator)
() ()
(runner)
11.5
(11.5)
E Emax (11.8)
p2 V2
11.11
232
11.
11.10:
z 1 2
3
1 3
E=
)
p1 p3
1( 2
+
V1 V32
(11.10)
p3 = 0
(V3 0) E Emax
E z
11.11:
2 3
V2
V2
p2
+ 2 + gz = 3
2
2
11.6.
233
[
)
1 (
p2 = gz + V22 V32
2
(11.11)
(11.11) p2 z V2 V3
E p2 p2
(cavitation)
(vapor pressure)
(101.3 kPa) 100 C
27 C
3.54 kPa
27 C
7000 atm
p2
pv patm pv patm (11.11)
p2
11.6
11.12
234
11.
100%
11.12
(pump-turbine)
(motor-generator)
11.12:
(centrifugal pump)
620-660 m
350 m
250 MW 4
11.6.
235
1.
2.
3. 100 m
3.6 105 kg/h
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14. 60 m
15.
16.
17.
18.
19.
20.
236
11.
12
12.1
(nucleus)
(nucleon)
(mn ) 1.008665 amu
(mp ) 1.007277 amu (me ) 0.0005486 amu amu
atomic mass unit 1.66 1027 kg
H 1 He 2
C 12 (atomic number Z ) (mass number A)
(AZ ) (nuclear symbol) AZ X X
11 H 42 He
126 C
10 e -1
10 n
1
(neutrino) 00
(isotope)
(11 H) 1 (21 H)
(tritium) (31 H)
1 2
X-Z X
238
12.
(periodical table)
He-3 32 He U-235 235
92 U
D T
U-235, U-238 U-234
99.282%, 0.712% 0.006%
3 U-227 U-240
(H2 O)
(D2 O) 1 3200
0.03%
H2 O D2 O
D2 O
H2 O
12.2
C + O2 CO2
C O2
(valence electron)
A2
A3
A4
A1
Z1 K Z2 L Z3 M Z4 N
A1
Z1
A3
A4
K +A2
Z2 L Z3 M +Z4 N
Z1 + Z2 = Z3 + Z4
A1 + A2 = A3 + A4
12.3.
239
X
27
13
A
Al + 42 He 30
14 Si + Z X
13 + 2 = 14 + Z
Z=1
27 + 4 = 30 + A
A=1
1 1 11 H
1 H 1 p
1
1
12.3
(mass defect) AZ X
m = (A Z)mn + Z(mp + me ) mX
(12.1)
(Einsteins law)
E = mc2
(12.2)
Fe, Co Ni
240
12.
12.1:
7.5 MeV
7.5 MeV
1 H 1 H
1
1
4
2 He (fusion)
11 H
(ssion)
12.4
(radioactive matter)
1. (gamma ray)
12.4.
241
(excited state) (ground
state)
(
A
Z
A
Z
X+
2. (beta ray)
1
60
27
0
Co 60
28 Ni +1 e + +
3. (alpha ray)
239
94
Pu
235
92
U +42 He +
N (t) t
dN
= N
dt
(12.3)
(12.4)
N (0)
(half-life)
(12.4) t = t1/2 N (t1/2 ) = 0.5N0
0.5N0 = N (0)et1/2
242
12.
12.1:
C-14
N-16
P-32
K-40
Co-60
Sr-90
I-131
Xe-135
Cs-137
Rn-222
U-235
U-238
Pu-239
(MeV)
5715
0.156
7.13 , 4.24 (), 6.129 ()
14.28
1.170
9
1.25 10
1.312
5.271 , 0.315 (), 1.332 ()
29.1
0.546
8.021 , 0.606 (), 0.364 ()
9.10 , 0.910 (), 0.250 ()
30.2 , 0.514 (), 0.662 ()
3.823 , 5.490 (), 0.510 ()
7.40 108
4.152
9
4.47 10
4.040
4
2.41 10
5.055
= t1/2 =
0.6931
(12.5)
t1/2 12.1
Co-60 3 1000
(12.4)
0.6931
t1/2
(
)
0.6931t
N (t) = N (0) exp
t1/2
(
)
0.6931 3
= 1000 exp
5.271
= 674
12.5.
12.5
243
U-235, U-238, Pu-239 Th-232
2-3 (ssion)
A
Z
X + 10 n
A1
Z1 1
A2
Z2 2
+ m10 n
AZ X AZ11 F1 AZ22 F2 m
235
92 U U-235 U235
U-235
235
92
U + 10 n
140
54
1
Xe + 94
38 Sr + 20 n
U-235 75 160
(delay process)
U-235
U-236 U-236
235
92
U + 10 n
236
92
U-236
2.34 107 U-236
14% 86%
235
92
U + 10 n
137
56
1
Ba + 97
36 Kr + 20 n
244
12.
12.2: U-235
(MeV)
166
14
10
5
5
200
U-235 1 MW
1
6.02 1023 E
235
= 6.69 1010 J
E=
86400 U-235 1 g
P =
6.69 1010
= 0.774 MW
86400
1 MW U-235 1.3 g
12.6
U-235
12.6.
245
(chain reaction)
2-3
12.2
U-235
U-235
U-235 U-236
U-235
U-235
U-235
86% U-235
(slow neutron)
(thermal neutron)
(fast neutron)
(prompt neutron)
U-235
(En2 )
(En1 ) A
En2
=
En1
A1
A+1
)2
(12.6)
2% U-238
246
12.
28% C-12
12.7
(1) (fuel core) (2)
(coolant) (3) (moderator) (4) (control rod) (5)
(reactor vessel)
(UO2 )
(UC) (cladding material) Al, Mg, Zr,
3
(shim rod) (regulating rod)
(safety rod)
(boron steel)
12.8.
247
1.8 m
12.8
(1)
(pressurized water reactor, PWR) (2) (boiling water reactor,
BWR) (3) (advanced gas-cooled reactor, AGR) (4)
(pressurized heavy water reactor, PHWR) (5) RBMK
( Reaktor Bolshoy Moshchnosti Kanalniy High
Power Channel Reactor)
12.8.1
200-300
150-250
(zircaloy) 12.2
PWR 12.2
(primary loop)
(secondary loop)
325 C
150 (pressurizer)
PWR
PWR 374 C
374 C
230
248
12.
12.2:
12.8.2
U-235 1.9-2.6 % 750 90-100
12.3
PWR
75
285 C
12.3
BWR
PWR BWR
PWR
12.8.
249
12.3:
12.8.3
250
12.
12.4: CANDU
12.8.4
12.5
U-235 2.5-3.5%
CO2
CO2
650 C
AGR PWR BWR AGR PWR BWR
12.8.5 RBMK
RBMK 12.6
290 C BWR
.. 2529 RBMK
12.9.
251
12.5:
12.6: RBMK
12.9
252
12.
(U3 O8 )
3.3
(27%)
(17%) (15%) (11%) (8%) (7%) (5%)
(4%) (4%) (leaching)
(yellow cake)
1000 MW 200
U3 O8 (UF6 )
U-235 1% 4% U-238
85%
(depleted uranium) U-235
(0.7%) (gas centrifuge)
(gas diffusion)
12.7
235
UF6 238
92 UF6 92 UF6
235
92 UF6 UF6
235
92 UF6 UF6 UF6
U-235 U-235 UF6
UF6 U-235
U-235
UF6
12.8 (stage)
(membrane) UF6
235
238
92 UF6 92 UF6
235 UF 235 UF UF
6
6
6
92
92
235 UF UF 235 UF UF
6
6
6
6
92
92
U-235
UF6
UF6
UF6 (UO2 )
1 cm 2 cm
12.10.
253
12.7:
12.8:
(fuel pellet)
60 cm 4 m
12.10
(1) (low-level waste)
(2) (intermediate-level waste)
(3) (high-level waste)
254
12.
5-10
(borosilicate glass)
500
U-235 1% U-238 93%
Pu-239 0.5% 5.5%
U-235,
U-238 Pu-239 U-235
Pu-239 U-235
Pu-239 U-235
Pu-239
12.11
H+
OH
(somatic
effect) (genetic effect)
(cosmic ray)
12.11.
255
(radiation dose) SI
(Gy) 1 Gy 1 J 1 kg
(equivalent radiation dose) (quality factor)
(Sv) 12.3
12.3:
, ,
1
10
10
20
20
1
4 Sv
2-6 mSv
1 kg 4 103 J
256
12.
12.12
(International Atomic Energy Agency) IAEA
IAEA 3
U-235 95%
U-235 2-3%
(reactor meltdown)
12.12.
257
26 .. 2529 (Chernobyl)
() RBMK
31 203
11 .. 2554 8.9
10
(Fukushima) (Fukushima Daiichi)
BWR 6
14
4
258
12.
1.
2. 239
94 Pu
3.
4.
5.
6.
Sr 90
39 Y
90
38
7. 360 2
6
8.
9.
10.
11.
12.
13.
14.
15.
16. RBMK
17.
18. (U3 O8 )
19.
20.
12.12.
259
21.
22.
23.
24. 1.007277 amu 1.008665 amu
168 O 15.99491 amu 168 O (1 amu = 1.66 1027 kg,
1 eV = 1.6 1019 J c = 3.0 108 m/s)
25. U-235 200 MeV 1 20000 kJ
1 g U-235 (1 eV = 1.6
1019 J 6.022 1023 1 mol U-235)
260
12.
13
13.1
13.1.1
N2 79% O2 21%
(particulate)
(NOx ) (SO2 )
(NO) (NO2 )
NO
262
13.
NO2
NOx
13.1
13.1:
1.
1.1
1.2
1.3
1.4
2.
2.1
(1) 300 MW
(2) 300 - 500 MW
(3) 500 MW
2.2
(1) 300 MW
(2) 300 - 500 MW
(3) 500 MW
2.3
2.4
SO2 NOx
(ppm) (ppm) (mg/m3 )
700
950
60
60
400
200
200
200
320
240
60
320
640
450
320
350
350
350
120
120
120
640
450
320
20
60
180
180
180
120
200
120
120
120
60
120
AW + BX + CY + DZ
13.1.
263
B
C
D
W
X
Y
Z
13.1
A
13.1:
13.1.2
264
13.
(cooling tower)
1. (pH) 5 9
2. 40 C
3. 3000 mg/L
4. 50 mg/L
5. BOD 20 mg/L
6. COD 120 mg/L
7.
13.2.
13.1.3
265
(stabilization)
13.2
NOx NOx
(combustion control) NOx
NOx (post-combustion control) NOx
NOx (NH3 )
NOx NOx NOx
NOx SCR (selective catalytic reduction) NOx
SCNR (selective non-catalytic reduction)
13.2.1
NOx
NOx
(ue gas recirculation)
NOx
NOx
266
13.
NOx NOx (low NOx burner)
(air staging) (fuel
staging) NOx
13.2
13.2: NOx
(exothermic)
(160 350 C)
NOx SCR 95%
SCR
13.2.
267
SO + 12 O2 SO3
NH3 + SO3 + H2 O NH4 HSO2
1
2NH3 + 2SO3 + H2 O + O2 2NH4 SO4
2
(ammonium bisulfate, NH4 HSO2 ) (ammonium
sulfate, NH4 SO4 ) 1 3
SCR
5 ppm
SCR (titanium dioxide, TiO2 )
(vanadium pentoxide, V2 O5 ) (tungsten oxide, WO3 )
SCR
13.1 6 7.5 mm SCR
3.3 5 mm
2 3 mm
2 4 NOx
20 30% NOx SCR
268
13.
SCR
900 1050 C
SNCR NO2 NOx
NO 95% NO2 5% SNCR NOx
70 80% SCR SNCR
SCR SNCR SCR
NO (nitrous oxide, N2 O)
N2 O
NOx SNCR
NOx
SNCR NOx
(computational uid dynamics)
SNCR
13.3.
13.3
269
(bottom ash)
(y ash)
13.2
13.2:
(%)
(%)
(%)
60-80
0-5
20-40
10-30
0-10
70-90
5-90
0-5
10-95
(cyclone separator)
(electrostatic precipitator) (fabric lter)
13.3.1
(emitting electrode)
(grounded collecting plate)
30 80 kV
13.4
270
13.
13.4:
(ash hopper)
13.5
13.5:
(elec-
13.3.
271
13.3.2
(lter bag)
125 300 mm
12.5 m
(cell plate)
(reverse gas fabric lter) 13.6
272
13.
13.6:
13.7:
13.4.
13.3.3
273
13.8
13.8:
13.4
(extrinsic ash)
(intrinsic ash)
(silicon) (aluminum) (alkali)
(bottom ash)
274
13.
(y ash)
(mechanical stoker) 60 80% 20 40%
(pulverized coal) 10 30%
70 90%
13.4.1
(hopper)
13.9 (silo)
13.9:
(pneumatic)
13.4.
275
(Bernoulli equation)
(uidization)
60
13.4.2
276
13.
13.5
(SO2 )
S + O2 SO2
SO2 (sulfuric acid, H2 SO4 )
SO2
SO2
SO2
70%
SO2
SO2 SO2 (ue gas desulfurization)
SO2 (sulfurous acid, H2 SO3 )
(H+ ) (HSO3 )
H+ (SO2
3 )
SO2 + H2 O H2 SO3
H2 SO3 H+ + HSO3
+
H+ + HSO3 SO2
3 + 2H
SO2 SO2 SO2
H+ (alkaline ion)
(OH ) (CO2
3 ) (HCO3 )
SO2
SO2 (limestone)
13.5.1 SO2
SO2 (CaCO3 )
SO2 95 - 98% 13.10
SO2
13.5.
277
13.10: SO2
SO2
(saturated)
278
13.
(mist eliminator)
(hydrocyclone)
SO2
13.5.2 SO2
pH 8 CO2
3 HCO3
SO2 SO2
13.11
SO2
2
SO2 + CO2
3 SO3 + CO2
SO2 + HCO3 HSO3 + CO2
SO2
3 HSO3
SO2
3 HSO3 O2
1
2
SO2
3 + 2 O2 SO4
HSO3 + 12 O2 HSO4
pH 6 7 pH pH
13.6
(continuous emission monitoring, CEM)
13.6.
279
13.11: SO2
CEM
NO, NO2 SO2
13.6.1
13.12
(single-pass)
280
13.
13.13 (double-pass)
NOx , SO2
13.12:
13.13:
13.6.
281
(dry extractive)
(wet extractive)
(dilution extractive)
(lter)
(membrane)
SO2
NOx
NOx
NOx SO2
50:1 250:1
13.3 NOx SO2
13.6.2
(light extinction)
282
13.
13.3: NOx SO2
NOx SO2
2% 3%
- 48% 9%
- 1% 1%
-
49% 87%
13.12 13.13
(beta ray
attenuation) C-14
(probe electrication)
13.6.
283
284
13.
1. NOx
2.
3. NOx SCR
4. NOx SCR
5. NOx SNCR
6.
7.
8.
9.
10.
11. SO2
12.
13.
14. CEM
15.
16.
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[13] K. Rayaprolu, Boilers for Power and Process, CRC Press, 2009.
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285