Ok, here is the issue: if you imagine that there is any way to compare complex numbers, e.g.
z < w, then you would want the following properties to be true:
For any two complex numbers z and w, either z < w, w < z, OR w = z. Now, imagine that we have such a way to compare imaginary numbers. Since i 6= 0, the above condition tells us that either 0 < i or i < 0. If it is the first one, then we find that 0<i
0 i < i2
0 < 1.
However, you also have that
0<i
0 i < i4
0 < 1,
which means that
0 < 1 0 + 1 < 1 + 1 1 < 0; thus we find that 0 < 1 AND 1 < 0, contradicting the property above. A similar argument works for the case i < 0, and so no such ordering is possible.