GaOOH NRs

(d

(1
(
)
(110
)

t (a.u.)

1 m

)
200 nm

20

(d
)

600

gth (nm)

343
343/GaOOH

650

Emission I

EtOH/pure Au
EtOH/GaOOH

700

2000

1000

450

500

Wav

(d
10000

CB

GaOOH

FL

A1

A2

<>

ket (s-1)

11000

3.820

361

0.390

3.809

2.26

9200

3.630

981

0.386

3.594

2.20

0.157x107(C343GaOOH)

10986

3.812

364

0.387

3.801

2.28

0.055x107(C343Au)

10985

3.811

370

0.387

3.799

2.00

0.069x107(C343Au)

10990

3.815

363

0.388

3.804

2.07

0.034x107(C343Au)

10999

3.818

362

0.389

3.807

2.03

0.013x107(C343Au)

8180

3.390

2810

0.365

3.282

2.30

2.590x107(GaOOHAu)

7950

3.000

2850

0.363

2.890

2.38

6.700x107(GaOOHAu)

8230

3.571

1642

0.378

3.505

2.19

0.672x107(GaOOHAu)

8450

3.572

1158

0.381

3.526

2.05

0.523x107(GaOOHAu)

ket(C343GaOOH)
1/ (C343/GaOOH-Au) - 1/
(C343/GaOOH) ket(C343Au)=
ket(GaOOHAu)

DDL

180min

0.15
0.10
0.05

th (nm)

550

600

(d
)

)
eOH

500

0.00

0.040

20

40

comm

slope

R2

Commercial Ga2O3

1.101x10-4

0.967

P-25 TiO2

1.847x10-4

0.984

GaOOH

1.356x10-4

0.982

GaOOH-Au, 0.5mol%

1.774x10-4

0.989

GaOOH-Au, 1.0mol%

2.125x10-4

0.980

GaOOH-Au, 2.0mol%

1.638x10-4

0.990

GaOOH-Au, 4.0mol%

1.524x10-4

0.991

Ga, weight%
O, weight%
Au, weight%

40 nm

0.25 nm

(111)

Au

0.24 nm

GaOOH
NRs

1 nm

2 m

(d)

1 m

(d)

+
+
+
kMeOH

4.75 eV

1 m

(d)

Au

4.75eV

+
+
+

kMeOH

ket

CH3COCH2COCH
(acetylacetone)

formati

00 nm

(e)
CuCl2

500 nm

Mg(no3)2

Mgcl2

InCl3

CaCl2

NiCl2
Cu(NO3)2

CuSO4
Co(NO3)2

2.96 A
(001)

2.95A
(001)

(2.24A, (200))
(2.4A, (111))

e-like GaO

180min

500

th (nm)

550

600

Ga
(001
O
)