02-3544226-30

02-3544226-30 104

ISBN 978-616-7217-71-0

8
6
4
3
3
3

1
2554

2550
4,750











2553

1.
2.

2.1
2.2
2.3
2.4
2.5
2.6
3.
3.1
3.2
3.3
3.4
3.5
3.6
3.7
3.8
3.9
3.10

1
4
4
13
15
16
19
20
24
24
24
25
26
27
27
28
29
30
31

 ()

3.11
3.12
3.13
3.14
4.
4.1
4.2
5.
5.1
5.1.1

5.1.2

5.1.3
5.1.4
5.1.5
5.1.6
5.2
5.3

31
33
33
37
38
38
39
40
40
40
41
42
44
45
47
48
50

 ()

5.4
5.4.1
5.4.2
5.4.3
5.4.4
5.4.5

5.4.6

5.5
(Chemical Safety)
6.
6.1
6.2
6.3 (3A 6.2)
6.4

55
55
57
59
60
61

74

61
67
69
69
71
72
73

1.

.. 2535

(Tank)
(Silo) (Portable/Bulk Container Cryogenic
liquefied gas or Refrigerated liquefied gas)

30 60 120 180
(packages) Intermediate Bulk
containers (IBCs)

(packages)
450 400

Intermediate Bulk Containers (IBCs)

- 3.0 (3,000 )
II III
- 1.5
IBCs

- 3.0 I
IBCs

2.
2.1
2
1.
2.

1 (Explosives)

1.1

(Mass Explosive)

1.2

1.3


1.4


1.5

1.6

2 (Gases)

50
300
20 101.3


/
3

2.1 (Flammable Gases)

20
101.3

13
12



2.2 (Non-flammable
Non-toxic Gases)
280

20



2.3 (Poison Gases)

3 (Flammable Liquids)

(Flash Point) 60.5
(Closed-cup Test)
65.6
(Opened-cup Test)

3
4.1 (Flammable Solids)
/




() ()

4.2 (Substances
Liable to Spontaneous Combustion)

4.3 (Substances
which in Contact with Water Emit Flammable Gases)

5
2

5.1 (Oxidizing Substances)

5.2 (Organic Peroxides)

-O-O-

6 2

6.1 (Toxic Substances)

6.2 (Infectious Substances)

(Radioactive Materials)
0.002
-60

(Corrosive Substances)

10

(Miscellaneous Dangerous
Substances and Articles)

1 8

100
240

1
2A
2B
3A
3B
4.1A
4.1B

()
< 60 C

11


4.2
4.3
5.1A
5.1B
5.1C
5.2
6.1A
6.1B
6.2
7
8A
8B
9
10
11
12
13

3A 3B

12

2.2

NFPA (National Fire Protection Agency)
4
(Special hazard) W
(Water reactive); Ox Oxidizer; Cor
Corrosive NFPA 0-4

1 NAPA

13

 1 NFPA
(National Fire Protection Agency)

(Flammability)

0=

1=

Fp>930.

2=
Fp>380.
<930.

(Health hazard)

(Reactivity hazard)

(Oral LD50
>2000 ./.)

(Oral LD50
>500-2000 ./.)

(Oral LD50 >50-500

./.)

(Special hazard)
Fp = (Flash point) ; Bp= (Boiling point)

3=
Fp<23 0.
Bp>=380.
Fp>23 0. <380.

(Oral LD50 >5-50

./.)

4=
Fp<220.
Bp<380.

(Oral LD50
<=5 ./.)

14

2.3 (Toxic chemicals)

TLV
(Threshold limit values) PEL (Permissible exposure limits)

(Toxic chemicals) TLV PEL 50 ppm
LD50
(Lethal dose) LC50 (Lethal concentration) LD50
50%
(Absorption)
LC50

(MSDS)
2
LD50 LC50

(./.) *
<=1
1-50
50-500
500-5,000

<10 ppm
10-100 ppm
100-1,000 ppm
1,000-10,000 ppm

(./.)*
<=5
5-50
50-500
500-5,000

* . 1 .

15

2.4

2.4.1

http://msds.pcd.go.th

www.anamai.moph.go.th

http://www..chemtrack.org website
MSDS http://www.SIRI.org

1.
2. CAS registry number
(Chemical Abstract Services)
3.

16

4.

5.
6.
7.
8.

2.4.2

()

17

3A 3B

18

2.5

2.5.1 (Separate Storage)

-
90
- ( )
5
10
90
2.5.2 (Segregate Storage)
2

19

2.6
2.6.1
(Flammable and combustible liquid)


Oxidizer
(Organic acids) (combustible)
(Inorganic acids) Oxidizer
2.6.2 Oxidizer
Oxidizer
Oxidizer

2.6.3 (Health hazard)

(Health hazard)
(Carcinogen)
(Mutagen)

20

2.6.4 (Incompatible chemicals)

Cyanide salts,
Cyanide solution

Sulfide salts,
Sulfide solution

(Bleach)
Oxidizing acid (e.g.,nitric acid) Alcolhol, solvent
Alkali metals

(e.g.,sodium,potassium)
Oxidizing agents (e.g.,nitric
Reducing agents
acid)
Hydrogen peroxide
Acetone

Hydrogen peroxide

Acetic acid

Hydrogen peroxide

Sulfuric acid

Highly toxic cyanide gas

Highly toxic hydrogen
sulfide gas
Highly toxic chlorine gas

21



4
Class

2.1

2.2

3.1

3.2
3.3
3.4
FS
SG
NA

4.1

4.2

4.3

5.1

5.2

6.1

2.1 NA NA FS
FS PR FS PR PR FS FS SG
2.2 NA NA SG
SG FS SG SG FS SG SG SG
3.1 FS SG NA
FS FS FS PR PR FS SG SG
3.2
3.3 FS SG NA NA SG FS FS PR PR FS SG SG
3.4
4.1 FS SG FS SG NA FS FS PR PR FS SG SG
4.2 PR FS FS FS FS NA FS PR PR FS SG SG
4.3 FS SG FS FS FS FS NA PR PR FS FS SG
5.1 PR SG PR PR PR PR PR NA FS FS FS FS
5.2 PR FS PR PR PR PR PR FS NA PR FS FS
6.1 FS SG FS FS FS FS FS FS PR NA SG SG
8
FS SG SG SG SG SG FS FS FS SG NA SG
9
SG SG SG SG SG SG SG FS FS SG SG NA
: NA ; SG
3
FS
PR 10

22

23

3.3.

3.1



-

3.2

24

2
3.3

25

3.4


60
1

-

15 6 23
9
30 12

26

3.5

3.6


-

27




2%

3.7

28

 5
3.8
-

29

 6
3.9

30

3.10

3.11

31

32

3.12
-

-

3.13
3.13.1
1.

6 1 ABC
12 1 200 50
2

33

2.

3.

4.

5.
(Class A)

(Class B)


(Class C)
(Class D)

6.

34

()
ABC
BC

Aqueous Film Forming

Foam (AFFF)

(Class A)

(Class B)
(Class C)

(Class D)

35

 9
3.13.2
1. (Water Sprinkling System)

(In-rack sprinkle)
2
2. (Water Hydrant)

50
3. (Hose)

36

4.
2
100 2,500
200
4,000
5.

10

3.14

60

37

4.4.

4.1
-
- - (first in-first out)

- 3

11

38

4.2

MSDS

200

39

 12
5.5.

5.1

5.1.1




(firstin-firstout)

40

-

- MSDS

-
5.1.2

(bill of lading)
MSDS

41

5.1.3

42

- 2

13

43

5.1.4

44

5.1.5





MSDS

-
-
-
-
-
-
-
-
-

45









MSDS

14

46

 15

5.1.6

MSDS

47

5.2

5.2.1
5.2.2
5.2.3
5.2.4
5.2.5
5.2.6

MSDS

MSDS MSDS

48

 16

(1)

(2)
15
(3)

(4)
MSDS
(5)

(6)

49

5.3

1.
1.1)


850
3
1.2) 424
358

1

50

 17
2.

18
3.

3.1)

51

3.1)

3.3)

19
4.

(Blower)
150

1-2

52

5. 2
5.1) (Ear plug)
, ,

15 ()

20 (Ear plug)
5.2) (Ear muffs)


25 ()

21 (Ear muffs)

53

6.

22
7.

23

54

5.4



/









5.4.1
. 635 1

55

-
-

(1)

-
-
-
- ( , ,
,
- , ,
(2)
-
-
-
-
-
-
-
-
-

(1)

(2)

56

50

5.4.2

5.4.2.1
4

5.4.2.2

5.4.2.3

57

:
:

-
35

-
:
50
:

:

:
:

-
50

:
:

-
50

58

5.4.3

5.4.3.1

5.4.3.2

5.4.3.3
-
10
-

5.4.3.4

8

59

5.4.4

(a) (b)
75
60
5.0
100
80
6.6
150
120
10.0
225
180
15.0
300
240
20.0
600
480
40.0
750
600
50.0
900
720
60.0
1200
960
80.0

60

5.4.5

5.4.6

1.


(1.1)

61

(1.2)

2.
1
(2.1)
2

62

63

(2.2)

64

(2.3)

65

3.

66

5.5. (Chemical Safety)

1.

MSDS (Material
Safety Data Sheet) SG (Specific Gravity)

2.

-
MSDS (Material Safety Data Sheet) SG (Specific Gravity)

- /

-
MSDS
(Material Safety Data Sheet) SG (Specific Gravity)

67

1.

2. MSDS SG
MSDS SG

3.

68


6. 6.

6.1
6.1.1

.. 2542 6

6.1.1.1 1.1 (Mass-Detonating)

6.1.1.2 1.2
(Non Mass-Detonating, Fragment Producing)

6.1.1.3 1.3 (Mass Fire)

6.1.1.4 1.4
(Moderate Fire, No Blast)

69

6.1.1.5 1.5
1.1 (Very Insensitive
Substances Which have a Mass Explosion Hazard)

6.1.1.6 1.6
(Extremely Insensitive Articles
Which do not have a Mass Explosion Hazard)

6.1.2

6.1.2.1 37
21 2519
6.1.2.2 .. 2530
6.1.2.3
.. 2490
6.1.2.4

6.1.2.5

..2542

70

6.2
6.2.1
6.2.1.1

2 (TP II)

6.2.1.2
2 1

6.2.1.3
6.2.1.4

6.2.1.5

6.2.1.6
6.2.1.7
-
6.2.1.8
2
6.2.1.9
( )

71

6.2.1.10
()

6.3 (3A 6.2)

6.3.1
6.3.2

6.3.2.1
90
6.3.2.2
180
6.3.2.3
0.30

6.3.3 90
10
6.3.4
5 1

6.3.5
6.3.5.1

72

6.3.5.2 100

6.3.5.3
6.3.5.4

6.3.5.5

6.3.5.6
1%

6.4
6.4.1

6.4.2
90 1 0.50
6.4.3

73


1. . .
[]. : http://www.diw.go.th/diw/news/haz/
presentation. ( : 16 2553).
2. . 2551.
.
3. Moody International Certification. .
[]. : http://www.moodythai.com/new/article/
iso14001/14001_chemical%20store.htm.
( : 18 2553).
4. ().
. []. :
http://www.shawpat.or.th/news/news_detail.php?news.
( : 22 2553).
5. Chem Track .
. []. :
http://chemsafe.chula.ac.th/ chemtrack/index.php .
( : 25 2553).
6. . 2545. .
25 2.
7. . .
http://pcdv1.pcd.go.th.

74

8. .. [].
: http://www.fisheries.go.th/train-gr/003/S_Lap01.doc.
( : 16 2554).
9. MSA The Safety Company. . [].
: http://www.safetythai.com/products/helmet.htm.
( : 25 2554).

75