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Ethanol As Biofuel and Chemical Feed Stock: Course: Chemical Technology (Organic) Module V
Ethanol As Biofuel and Chemical Feed Stock: Course: Chemical Technology (Organic) Module V
Module V
Lecture 2
LECTURE 2
ETHANOL AS BIOFUEL AND CHEMICAL FEED
STOCK
INTRODUCTION
Alcohol is a key feedstock for the manufacture of basic chemicals. Alcohol based chemical
industry occupies an important place in the Indian chemical industry and is a key contributor to
the growth of the sector. The current size of alcohol based chemical industry is $1.1 billion
(Rs.4850 crores) [Indian chemical industry Five year plan 2012-17, Indian Chemical IndustryXII Five Year plan, Govt of India]
165
2,483
2,265
1,830
1,670
1,194
5% EBP 1,040
Industrial use
1,000
35%
33%
32%
Potable Use 1,100
ETHANOL AS BIOFUEL
India is now going an unprecedented energy crisis due to dwindling energy resources. The
present import of crudes which is around 180 million tones per annum, is expected to exceed 240
million tones per annum in the next 5 years, if the GDP growth of around 6 to 7percent were to
be sustained [Venkataraman, 2012]. India is also importing 80 million tones per annum of coal.
166
Global crude oil prices are also surging unbated as global crude oil is finite and depleting, there
is continuously searching all over the world to go for alternative energy sources. World demand
for energy is expected to double by 2050 and this demand cannot be satisfied with conventional
fuel resources like, crude oil, natural gas and coal [Tuli & Gupta, 2010]. In order to meet the
rising demand of energy and increasing population, alternate energy resources will play a
important role and biofuels based on ethanol are expected to grow rapidly. Biofuels
developments are primarily driven by three fundamental policy considerations: rural
development, energy independence, reduced carbon footprint.
Alcohol has been globally accepted as an alternative to gasoline and alcohol blend gasoline are
being used in many countries in varying proportion ranging from 5-20percent as ethanol. Brazil
which is one of the major sugar producing industry introduced commercial gasoline with ethanol
content of about 25percent. Even ethanol is being sold in Brazil pure ethanol as E-100 fuel.
Ethanol accounts for about 40percent of the fuel consumed by passenger vehicles [Sehagal,
2006]. Brazil and U.S. together account for about 70percent of worlds ethanol production.
Blending characteristics of fuel oxygenates are presented in Table M-V 2.1 [Brockwell et al.,
1991]. US the largest user of gasoline introduced gasoline with 10percent ethanol content.
Similar trend has been observed in several countries [Tuli& Gupta, 2010].
Blending
RVP
(Kg/cm2)
Average
Octane
(R+M)/2
Oxygen
content
(wt.%)
Blending limits
(Percentage)
O2
O2
(vol.%)
(wt.%)
131
161
187
8
4
1
110
111
106
18
16
16
15
16
17
2.7
2.0
2.0
148
173
145/180
60
18
31
120
115
108
50
35
35
10
9.5
3.7
3.7
181
12
100
21
16
3.7
Source: Brockwell, H.L., P.R. Sarathy, R. Trotta, Synthesize ethers, Hydrocarbon Processing, Volume
70, No. 7, 1991, p. 133.
167
India is currently has a mandate for 5% blending of ethanol in petrol and is being implemented
Through the nationwide Ethanol Blending Program (EBP). About 3.5 billion liters of ethanol are
being produced in about 320 distilleries in India which is enough to cater to the 800 million liters
requirement for 5% blending. However, the national average blending in 2008-09 was only about
2% [Sarangi, 2011].
Gashol is new ecofriendly fuel containing blend of gasoline with 5-10% ethanol from molasses.
Gashol can be also made by blending gasoline and methanol. gashol has higher octaneor
antiknock properties than gasoline and burns more slwly, cooly and completely resulting in
reduced emission [Lawson, 2004]. The octane number of gasoline increases with blending of
5% ethanol by 1.3-3.4 times. blending of ethanol increases the reid vapour pressure and vapour
lock index. ethanol increases the oxygen content of the blend [Raje et al. 2002]
168
169
Alco-chemical
Downstream Product
Major application of
downstream product
Styrene
ABS Resins
ABS Products
Styrene
SAN Resins
SAN Products
Styrene
Ion-Exchange Resins
Ethylene
LDPE
LDPE Products
MEG
Polyester Films
Packaging
Vinyl Acetate
EVA/VAE Polymer
Styrene
SBR
Acetic Anhydride/Acid
Cellulose Acetate
Styrene
Poly-Styrene
PS Products
10
Styrene
PS Foam
Packaging
11
Vinyl Acetate
Emulsions
Adhesives
B. Chemicals
12
Styrene
Styrenated Phenol
Rubber Chemical
13
Acetic Acid
PTA
Polyester Feedstock
14
Acetic Acid
Di-methyl-Acetamide
15
Acetic Acid
Aceto Acetates
16
Acetic Acid
Aceto Acetanilide
17
Acetic Acid
AcetoAcetanides
18
Acetic Anhydride
Paracetamol
Pharmaceuticals
19
Acetic Anhydride
Aspirin
- do -
20
Acetaldehyde
Vinyl Sulphone
Dyestuff Intermediate
170
21
Acetic Anhydride
Acetanilide
Dyestuff Intermediate
22
Pentaerithritol
Emulsions/Dispersions
Paint Industry
23
Pentaerithritol
PETN
Explosives Industry
24
Glyoxal
Pharma
25
Glyoxal
26
Ethyl Acrylate
Emulsions/Dispersions
Paint Industry
27
Ethyl Vanillin
Flavouring- Formulations
28
DDT
Formulations
Pesticide
29
2,4-D
Formulations
Pesticide
30
Ethylene Oxide
Condensates
Various Industries
Textiles
C. Synthetic Fibres
Textiles, Tyre Cord/ Yarn,
31
MEG
Polyester Fibres
32
CMC
33
Adhesives/Polymers
34
Acetanilide
Sulpha Drugs
35
Acetanilide
Intermediate
Dyestuffs
Industrial Yarn
Sources: Alcohol based industry marching into the 21st century, Ashok Kadakia, Chemical Business,
January 2000, p.39., Chemical Industry News, match 2003, p.69
171
172
REFERENCES
1. Brockwell, H.L., Sarathy, P.R. , Trotta, R., Synthesize ethers, Hydrocarbon Processing,
Vol. 70, No. 7, 1991, p. 133.
2. Indian chemical industry Five year plan 2012-17, Indian Chemical Industry-XII Five Year
plan, Govt of India
3. Kadakia A., Alcohol based industry marching into the 21st century, Chemical Business,
January 2000, p.39.
4. Lawson,B. Gashol again Oil and gas journal Jan19,2004,p.15
5. Mall I.D. Waste utilization and management in sugar and distillery plants, Chemical
Engineering World vol. 30 (1)1995 pp. 51.
6. Mall, I.D Waste management in sugar and distillery plant for Resource generation SGAT
bulletin Volume 13, No.2 December, 2012, p.25
7. Raje, N.R. Indian experiences with the use of ethanol gasoline and ethanol diesel blend
ISAF XIV Technical papers 2002-GS-02
8. Sarangi, S.K. Feb 17-19, 2011 Compendium 16th Refinery technology Meet organized by
Centre for high technology & Indian oil corporation, p.161
9. Sehagal, J. M. Emergence of ethanol as global alternative to gasoline, Chemical Weekly
September 26, 2006, and p.193
10. Tuli, D.K., Gupta, R.P. Indian oil alternate and renewable Energy initiatives for sustainable
development, Chemical industry digest August 2010, p.83
11. Venkataraman N.S., Algae biofuel could be India savior, Chemical News, July 2012, p.40.
173