Nurul Ain Binti Manshor

Progress Meeting 1st April 2015

2nd Semester
Prof Jose Rajan

Perovskites

Synthesis of Perovskite
CH3NH
2

HI

0c, Stirring

PbI2
(AIN)

CH3NH3Pb
I3

CH3NH3I
Rotary Evaporator
(precipitate)

PbCI2
(Zainab)

Figure 1 : XRD measurement for

CH3NH3I

a)

b)

c)

Figure 2 :
a)
FTIR
for
CH3NH3PbI2
liquid
b)
FTIR
for
CH3NH3PbI2
Powder
c) FTIR for DMF only

b
)

Figure 3 : (a) Absorption of TiO2/

CH3NH3PbI2 [1]
(b) Absorption of TiO2/ CH3NH3PbI2
with different quantity of DMF
[1] G. Niu, W. Li, F. Meng, L. Wang, H.
Dong, Y. Qiu, Study on the stability of
CH3NH3PbI3 films and the effect of postmodification by aluminum oxide in all-

Figure 4 : Transmittance for

CH3NH3PbI2
with different quantity of DMF

a)

c)

b)

Figure 4 : a) Emission and

Excitation of CH3NH3PbI2 with
30 % DMF
Emission and Excitation
of CH3NH3PbI2 with 40 % DMF
b)

c) Emission and Excitation

of CH3NH3PbI2 with 60 % DMF

Compact
Layer
~Nb-TiO2
~TiCl4

How to prepare compact layer

200ml ice

22ml TiCl4
1M TiCl4

0.05M
TiCl4

0.1M
TiCl4

0.2M
TiCl4

1.0M
TiCl4

Absorbance of compact layer

Transmittance of compact layer

a
)

b
)

Figure 5 :

a) Transmittance of TiO2

b) Transmittance with compact

TiO2layers of various
thicknesses
[2]
[2] X. Wang, Y. Fang, L. He, Q.
Wang, T. Wu, Influence of compact
TiO2 layer on the photovoltaic
characteristics of the organometal
halide perovskite-based solar cells,
Materials Science in
Semiconductor Processing, 27
(2014) 569-576.

a)

b)

Figure 6: a)Transmittance of Nb-TiO2

b) Transmittance of Nb-TiO2 and TiO2[3]

[3] Y.G. Xiong Yin , Zhaosheng Xue , Peng Xu ,

Meng He , and Bin Liu Enhance the
Performance of Perovskite- Sensitized

XRD TiO2

a)

(110
)
(100
(111
)
)
(210

b)

(004)
(101)

(204)

c)

d)
(200)
(211)
(110)

(301
)

Figure 7 : a) XRD 0.1M TiO2 b) XRD 0.5M TiO2 c) XRD 1.0M TiO2
d) XRD pattern of an individual TiO2 nanosheet [4]
[4] L. Etgar, P. Gao, Z. Xue, Q. Peng, A.K. Chandiran, B. Liu, M.K. Nazeeruddin, M. Grtzel, Mesoscopic

Now
im
here

Synthesis
of
doped
blocking
layer (Nb-TiO2)
Characterization
of blocking layer

Fabrication of
devices

Complete
characterization
of blocking layer
and perovskite

Characterization
of blocking layer
(TiCl4)
Literature Review
Basic
understanding in
Perovskite solar
cell
Skills
development in
Perovskite solar
cell First

Nov
2014

Semeste
Jan r
2015

Synthesis of
perovskite solar
cell
Characterization
of perovskite

Second
Semeste
r
Feb
2015

April
2015

Mei
2015

Jun
2015

July
2015