Problema 1

A)

Q=
W=
U=
S=
T=
P=
V=
Presin constante

L . atm
Cp=5/2 (R) mol . k
L . atm

Cv=3/2 (R) mol . k

L . atm
=.205125 mol . k
L . atm

=.123075 mol . k

L . atm

R=0.08205 mol . k

W=-25atm(25L-5L)=-500atm.L

( 25 atm ) (5 L)
T= ( 1 mol ) (0.08205 L . atm ) =1523.461k-1
mol . k
( 25 L ) (1523.461 k 1 )
T2=
=7617.3105k-1
(5 L)
L . atm
U=(1mol)(. 123075 mol . k

)(7617.3105k-1 -1523.461k-1)=750.0005L.atm/k

Q=(750.0005L.atm/k)(-500atm))=250k

L . atm

mol)(. 205125 mol . k

)(6093.85k)=1250L.atm/k

L . atm
S=(.205125 mol . k

7617.3105 k
)(ln)( 1523.461 k 1

(0.08205 Lmol. atm. k ) (1523.461 k

P=

=25 atm

L . atm
(5 L)
mol . k
=.01641 L
(25 atm)

( 1 mol ) 0.08205
V=

) (1 mol)

5L

B)

Q=
W=
U=
S=
T=
P=
V=

Se expande a 25L a Presin constante

L . atm

Cp=5/2 (R) mol . k

L . atm

Cv=3/2 (R) mol . k

L . atm

R=0.08205 mol . k

L . atm

=.205125 mol . k

L . atm

=.123075 mol . k

L . atm

)=.330136 mol . k

( 25 atm ) (2 5 L)
T= ( 1 mol ) (0.08205 L . atm )
mol . k

= 7617.31 k-1

( 5 0 L ) (7617.3 1 k1)
1
T2=
= 15234.62 k
(25 L)

(0.08205 Lmol. atm. k ) (7617.3 1 k

P=

) (1 mol)

25 L

W=-25atm(50L-25L)=-625atm.L

= 25atm