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Bestchoice > CHEM 110 2016 > 3 Kinetics > Page 11

Thetablebelowshowstheconcentrationsandvolumesofthesolutionsmixedforsixruns.
Usethesetocalculateconcentrationofthesolutesbeforereactionoccursand[I2]duringtimet.

Run

(NH4)2S2O8

KI

0.150molL1

1
2

2.50mL0.150molL1

0.100molL1

2.50mL

0.050molL1

3
0.150molL1

4
5

Na2S2O3

starch

2.50mL

0.100molL1

1.00mL
0.5mL

0.0100molL1

2.50ml0.200molL1

0.050molL1

Enternumbersasdecimalsusingallofthedigitsingivendata.
Toavoidearlyroundingerrorsforcalculatedanswersenteralldigitsonyourcalculatororasmanyaswillfitinthebox.
First:ForRun2:
Second:Forruns4,5and6
1
0.0025L0.150molL
0.0025L0.200molL1
c(S2O82)=
c(I)=
0.0065
0.0065L
L
Calculate the concentration (calculator in Resources) Enter c(S O 2) for Runs 46 and then deduce c(I) and
2 8
and enter this in the table below for any run using this
2
c(S2O8 ) for all runs from those already entered. c(I) and
combinationofvolumeandconcentration.
c(S O 2)areusedintheplotstodeterminetheratelaw.
2 8

Run
1

c(I)

c(S2O82)

c(S2O32)

[I2]

reactionrate

molL1

molL1

molL1

molL1

molL1s1

0.0577

0.057692

0.00153846

0.000769

0.057692

0.038461

0.057692

0.019231

0.057692

0.076923

0.038461

0.076923

0.019231

0.076923

Beforehandingthisin,circlethegroupofrunsthatyoudid:123456
Third:ForALLRuns
c(S2O32)=

Fourth:ForALLRuns

0.0010L0.0100molL1
0.0065L

[I2]=0.000769
molL1
(thechangeinconcentrationI2duringthetime(t)
beforethereactionmixtureturnsblue)

Usethecalculated[I2]forRuns16tocalculatereaction
Enter the calculated concentration. Once you have entered a
rateforeachrun.
correctanswer,itcanbeselectedusingyourmouse,copied(Ctrl
Print this page and take it with you to your lab
c)andpasted(Ctrlv)intotheotherboxes.
session.
THENgoforwardtothenextpagetosaveyourmarks.

22/
19
22 = 100% (no mistakes: /22 = 86%)

DrSheilaWoodgate
TheUniversityofAuckland2002

BestchoiceUser:rche622,FullName:Cheerala,Rohan,ID:854970352
http://www.bestchoice.net.nz/?c=163#cs=14180&p=11029

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