TRNG I HC VINH

TRNG THPT CHUYN

THI TH THPT QUC GIA, LN 2 NM 2016

Mn: HA HC (Thi gian lm bi: 90 pht)
M thi 132

H, tn th sinh:............................................................................................ S bo danh: .............................................

Cho bit nguyn t khi ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32;
Cl = 35,5; K = 39; Ca = 40; Fe = 56; Cu = 64; Ag = 108; Ba = 137.
Cu 1: Cho 8,8 gam CH3COOC2H5 tc dng ht vi 200 ml dung dch NaOH 1,5M un nng. C cn dung dch
sau phn ng thu c m gam cht rn khan. Gi tr ca m l
A. 17,6.
B. 9,2.
C. 8,2.
D. 16,2.
Cu 2: Kh hon ton mt lng Fe2O3 bng CO d nhit cao thu c m gam Fe v 6,72 lt CO2 ( ktc).
Gi tr ca m l
A. 5,60.
B. 2,80.
C. 16,8.
D. 11,2.
Cu 3: in phn dung dch cha 23,4 gam mui n (vi in cc tr, mng ngn xp) thu c 2,5 lt dung dch
c pH = 13. Phn trm mui n b in phn l
A. 65%.
B. 70%.
C. 80%.
D. 62,5%.
Cu 4: Tng hp polietilen t etilen bng phn ng
A. thy phn.
B. trng hp.
C. trng ngng.
D. crackinh.
Cu 5: Oxit no sau y tc dng vi H2O to ra hn hp axit?
A. SO2.
B. CrO3.
C. SO3.
D. P2O5.
Cu 6: Ha tan hon ton 5,4 gam Al bng dung dch H2SO4 long, thu c V lt H2 ( ktc). Gi tr ca V l
A. 3,36.
B. 2,24.
C. 6,72.
D. 4,48.
Cu 7: Thuc th dng phn bit cc dung dch ring bit, mt nhn: NaCl, HCl, NaHSO4, Na2CO3 l
A. NH4Cl.
B. NaOH.
C. KNO3.
D. BaCl2.
Cu 8: Cho cc cht: Al, AlCl3, Zn(OH)2, NH4HCO3, KHSO4, NaHS, Fe(NO3)2. S cht va phn ng vi dung
dch NaOH va phn ng vi dung dch HCl l
A. 5.
B. 4.
C. 3.
D. 6.
Cu 9: Cho 13,5 gam hn hp gm 3 amin no, n chc, mch h tc dng va vi 300 ml dung dch HCl
xM, thu c dung dch cha 24,45 gam hn hp mui. Gi tr ca x l
A. 1,0.
B. 0,5.
C. 2,0.
D. 1,4.
Cu 10: C cc pht biu:
(1) Protein b thy phn khi un nng vi dung dch axit, dung dch baz hoc nh xc tc ca enzim.
(2) Nh vi git dung dch axit nitric c vo ng nghim ng dung dch lng trng trng (anbumin) th c
kt ta vng.
(3) Hemoglobin ca mu l protein c dng hnh cu.
(4) Dung dch protein c phn ng mu biure.
(5) Protein ng t khi cho axit, baz vo hoc khi un nng.
S pht biu ng l
A. 5.
B. 4.
C. 3.
D. 2.
Cu 11: Cho cn bng ha hc (trong bnh kn) sau: N2 (kh) + 3H2 (kh) 2NH3 (kh); H 92KJ / mol .
Trong cc yu t:
(1) Thm mt lng N2 hoc H2.
(2) Thm mt lng NH3.
(3) Tng nhit ca phn ng.
(4) Tng p sut ca phn ng.
(5) Dng thm cht xc tc.
C bao nhiu yu t lm cho t khi ca hn hp kh trong bnh so vi H2 tng ln?
A. 4.
B. 5.
C. 3.
D. 2.
o
Cu 12: sn xut 10 lt C2H5OH 46 (d = 0,8 gam/ml) cn bao nhiu kg tinh bt bit hiu sut ca c qu trnh
sn xut l 80% ?
A. 8,1 kg.
B. 16,2 kg.
C. 10,125 kg.
D. 8,62 kg.
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Cu 13: Este no, n chc, mch h c cng thc phn t chung l

A. CnH2nO (n 3).
B. CnH2n+2O (n 3).
C. CnH2nO2 (n 2).
D. CnH2n+2O2 (n 2).
Cu 14: Trong nhm halogen theo chiu tng ca in tch ht nhn t flo n iot th
A. m in tng dn.
B. bn knh nguyn t gim dn.
C. tnh oxi ha gim dn.
D. tnh kh gim dn.
Cu 15: Cht no trong cc cht sau y c lc baz ln nht?
A. Anilin.
B. imetylamin.
C. Etylamin.
D. Amoniac.
Cu 16: Cp cht c xy ra phn ng oxi ha - kh l
A. Br2 + dung dch FeCl2.
B. KHSO4 + dung dch BaCl2.
C. Fe2O3 + dung dch HNO3 c, nng.
D. Al(OH)3 + dung dch H2SO4 c, ngui.
Cu 17: Ancol etylic v phenol u c phn ng vi
A. CH3COOH (xc tc H2SO4 c, un nng).
B. Nc brom.
C. Na.
D. NaOH.
Cu 18: Hiro ha hon ton 47,6 gam anehit acrylic bng H2 d (c Ni xc tc, un nng) thu c m gam
ancol. Gi tr ca m l
A. 50,6.
B. 72,8.
C. 51,0.
D. 72,4.
Cu 19: sn xut nhm trong cng nghip ngi ta thng
A. in phn dung dch AlCl3.
B. in phn Al2O3 nng chy c mt criolit.
C. cho CO d i qua Al2O3 nung nng.
D. cho Mg vo dung dch Al2(SO4)3.
Cu 20: T ba -amino axit: glyxin, alanin, valin c th to ra my tripepit mch h trong c c ba -amino
axit?
A. 3.
B. 2.
C. 6.
D. 4.
Cu 21: Polime no sau y l polime tng hp?
A. Thy tinh hu c plexiglas.
B. Tinh bt.
C. T visco.
D. T tm.
Cu 22: Cho t t dung dch NH3 n d vo dung dch cha cht no sau y th thu c kt ta?
A. AlCl3.
B. HCl.
C. CuCl2.
D. NaCl.
Cu 23: Trong cc gluxit: glucoz, fructoz, mantoz, saccaroz c bao nhiu cht va c phn ng trng bc
va c kh nng lm mt mu nc brom?
A. 4.
B. 2.
C. 1.
D. 3.
Cu 24: Hp cht X c cc tnh cht sau:
(1) L cht c tnh lng tnh.
(2) B phn hy khi un nng.
(3) Tc dng vi dung dch NaHSO4 cho sn phm c cht kt ta v cht kh.
Vy cht X l
A. NaHS.
B. KHCO3.
C. Al(OH)3.
D. Ba(HCO3)2.
Cu 25: Loi thuc no sau y gy nghin cho con ngi?
A. Thuc cm pamin.
B. Moocphin.
C. Vitamin C.
D. Penixilin.
Cu 26: Trong cc hp kim sau y, hp kim no khi tip xc vi dung dch cht in li th st khng b n mn
in ha hc?
A. Cu-Fe.
B. Zn-Fe.
C. Fe-C.
D. Ni-Fe.
Cu 27: Cho cc phng trnh phn ng sau ( X, Y, Z, T l k hiu ca cc cht):

Y + Z
X + NaOH
CaO, t 0

Y(rn) + 2NaOH(rn) T + 2Na2CO3

0

Ni, t
C2H6
C2H4 + T

Cht X l
A. HCOOCH3.
B. HCOOH.
C. (COOH)2.
D. HOOC-COONa.
Cu 28: Ha tan hon ton 8,5 gam hn hp gm 2 kim loi kim X, Y ( 2 chu k k tip, MX < MY) vo nc
thu c 3,36 lt H2 ( ktc). Phn trm khi lng ca X trong hn hp ban u l
A. 54,12%.
B. 45,89%.
C. 27,05%.
D. 72,95%.
Cu 29: Cho cc cht: C2H5OH, CH3COOC2H3, CH3COOH, C2H2, C2H4. C bao nhiu cht sinh ra t CH3CHO
bng mt phn ng?
A. 4.
B. 3.
C. 2.
D. 5.
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Cu 30: Tin hnh cc th nghim:

(1) Cho kh NH3 tc dng vi CuO un nng.
(2) Sc kh O3 vo dung dch KI.
(3) Cho Na vo dung dch CuSO4.
(4) un nng dung dch bo ha ca NaNO2 v NH4Cl.
(5) Sc kh Cl2 vo dung dch H2S.
S th nghim to ra n cht l
A. 4.
B. 3.
C. 2.
D. 5.
Cu 31: Cho 18 gam hn hp X gm R2CO3 v NaHCO3 (c s mol bng nhau) vo dung dch cha HCl d, sau
khi cc phn ng kt thc thu c 4,48 lt CO2 ( ktc). Mt khc nung nng 9 gam X n khi lng khng i
thu c m gam cht rn. Gi tr ca m l
A. 7,45.
B. 2,65.
C. 3,45.
D. 6,25.
Cu 32: C cc pht biu sau:
(1) Hp cht hu c nht thit phi c cacbon v hiro.
(2) Cc hirocacbon thm u c cng thc chung l CnH2n-6 vi (n 6).
(3) Penta-1,3-ien c ng phn hnh hc cis-trans.
(4) Isobutan tc dng vi Cl2 c chiu sng theo t l mol 1 : 1 ch thu c 1 sn phm hu c.
(5) Hirocacbon c cng thc phn t C4H8 c 5 ng phn cu to.
S pht biu ng l
A. 4.
B. 3.
C. 2.
D. 5.
Cu 33: Nhit phn hon ton hn hp X gm a mol KNO3 v b mol Fe(NO3)2 trong bnh chn khng thu c
cht rn Y v hn hp kh Z. Cho ton b Z vo nc th thu c dung dch HNO3 v khng c kh thot ra.
Biu thc lin h gia a v b l
A. b = 4a.
B. b = 2a.
C. a = 3b.
D. a = 2b.
Cu 34: C 5 hn hp, mi hn hp gm 2 cht rn c s mol bng nhau: Na2O v Al2O3; Cu v Fe2(SO4)3;
KHSO4 v KHCO3; BaCl2 v CuSO4; Fe(NO3)2 v AgNO3. S hn hp c th tan hon ton trong nc (d) ch
to ra cc cht tan tt trong nc l
A. 5.
B. 3.
C. 4.
D. 2.
Cu 35: X, Y l hai hp cht hu c n chc phn t ch cha C, H, O. Khi t chy X, Y vi s mol bng nhau
hoc khi lng bng nhau u thu c CO2 vi t l mol tng ng 2 : 3 v H2O vi t l mol tng ng 1 : 2.
S cp cht X, Y tha mn l
A. 3.
B. 5.
C. 4.
D. 6.
Cu 36: Cu hnh electron trng thi c bn ca nguyn t nguyn t R c tng s electron trong cc phn lp p
l 10. Nhn xt no sau y khng ng?
A. Hp cht kh ca R vi hiro c tnh kh mnh.
B. S oxi ha cao nht ca R trong hp cht l +6.
C. R chu k 2 nhm VIA.
D. Khi tham gia phn ng R va c tnh oxi ha va c tnh kh.
Cu 37: Nung 20,8 gam hn hp X gm bt st v lu hunh trong bnh chn khng thu c hn hp Y. Cho
ton b Y tc dng vi dung dch HCl d, thu c m gam cht rn khng tan v 4,48 lt ( ktc) hn hp kh Z
c t khi so vi H2 bng 9. Gi tr ca m l
A. 6,4.
B. 16,8.
C. 4,8.
D. 3,2.
Cu 38: Hp th ht 0,3 mol kh CO2 vo 2 lt dung dch hn hp Ba(OH)2 0,05M v NaOH 0,1M. Sau khi cc
phn ng xy ra hon ton thu c m gam kt ta v dung dch X. C cn dung dch X thu c m1 gam cht rn
khan. Gi tr ca m v m1 ln lt l
A. 19,7 v 10,6.
B. 39,4 v 16,8.
C. 13,64 v 8,4.
D. 39,8 v 8,4.
Cu 39: Hn hp X gm hai anehit Y v Z k tip nhau trong dy ng ng, MY < MZ. Oxi ha 10,2 gam X thu
c hn hp hai axit cacboxylic no, n chc tng ng. trung ha hn hp axit ny cn va 200 ml dung
dch NaOH 1M. Phn trm khi lng ca Z trong X l
A. 56,86%.
B. 43,1%.
C. 40,0%.
D. 54,6%.
Cu 40: Mt loi supephotphat kp c cha 87,75% mui canxi ihirophotphat cn li l cc cht khng cha
photpho. dinh dng ca loi phn bn ny l
A. 53,25%.
B. 14,625%.
C. 50,25%.
D. 48,75%.
Cu 41: t chy hon ton 4,03 gam triglixerit X bng mt lng oxi va cho ton b sn phm chy hp th
ht vo bnh ng nc vi trong d thu c 25,5 gam kt ta v khi lng dung dch thu c gim 9,87 gam
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so vi khi lng nc vi trong ban u. Mt khc, khi thy phn hon ton 8,06 gam X trong dung dch NaOH
(d) un nng, thu c dung dch cha a gam mui. Gi tr ca a l
A. 9,74.
B. 4,87.
C. 7,63.
D. 8,34.
Cu 42: Ha tan hon ton 7,5 gam hn hp gm Mg v Al bng lng va V lt dung dch HNO3 1M. Sau
khi cc phn ng kt thc, thu c 0,672 lt N2 ( ktc) duy nht v dung dch cha 54,9 gam mui. Gi tr ca
V l
A. 0,72.
B. 0,65.
C. 0,86.
D. 0,70.
Cu 43: Cho hn hp M gm hai axit cacboxylic X, Y (cng dy ng ng, c s mol bng nhau, MX < MY) v
mt amino axit Z (phn t c mt nhm -NH2). t chy hon ton 0,4 mol hn hp M thu c kh N2; 14,56 lt
CO2 ( ktc) v 12,6 gam H2O. Cho 0,3 mol M phn ng va vi dung dch cha x mol HCl. Nhn xt no sau
y khng ng?
A. Phn trm khi lng ca Z trong M l 32,05%.
B. Phn trm s mol ca Y trong M l 50%.
C. X c phn ng trng bc.
D. Gi tr ca x l 0,075.
Cu 44: un nng hn hp X gm 0,1 mol etilen; 0,1 mol vinylaxetilen v 0,3 mol hiro vi xc tc Ni mt thi
gian, thu c hn hp Y c t khi so vi hiro bng 10,75. Cho ton b Y vo dung dch brom d thy c ti a
a mol brom phn ng. Gi tr ca a l
A. 0,2.
B. 0,3.
C. 0,4.
D. 0,05.
Cu 45: Cho m gam bt st vo dung dch X cha AgNO3 v Cu(NO3)2 n khi cc phn ng kt thc thu c
cht rn Y v dung dch Z. Cho dung dch Z tc dng ht vi dung dch NaOH d, thu c a gam kt ta T gm
hai hiroxit kim loi. Nung T trong khng kh n khi lng khng i thu c b gam cht rn. Biu thc lin
h gia m, a, b c th l
A. m = 9b 6,5a.
B. m = 8,4 3a.
C. m = 8,225b 7a.
D. m = 8,575b 7a.
Cu 46: t chy hon ton mt lng hn hp X gm ba ancol n chc cng dy ng ng cn va V lt
O2 ( ktc) thu c 22 gam CO2 v 14,4 gam H2O. Nu un nng cng lng hn hp X trn vi H2SO4 c
nhit thch hp chuyn ht thnh ete th thu c m gam hn hp ete. Gi tr ca V v m ln lt l
A. 20,16 v 7,0 .
B. 15,68 v 12,7.
C. 16,80 v 9,7.
D. 13,44 v 9,7.
Cu 47: Hn hp X gm glyxin v tyrosin. Cho m gam X tc dng hon ton vi dung dch NaOH d, thu c
dung dch Y cha (m + 8,8) gam mui. Mt khc nu cho m gam X tc dng hon ton vi dung dch HCl, thu
c dung dch Z cha (m + 10,95) gam mui. Gi tr ca m l
A. 33,1.
B. 46,3.
C. 28,4.
D. 31,7.
Cu 48: Ha tan hon ton 19,4 gam hn hp X gm Fe v Cu trong dung dch cha 1,2 mol HNO3, sau khi cc kim
loi tan ht thu c dung dch Y (khng cha NH 4 ) v V lt ( ktc) hn hp kh Z gm hai kh c t l mol 1 : 2. Cho
500 ml dung dch KOH 1,7 M vo Y thu c kt ta D v dung dch E. Nung D trong khng kh n khi lng khng
i, thu c 26 gam cht rn F. C cn cn thn E thu c cht rn G. Nung G n khi lng khng i, thu c
69,35 gam cht rn khan. Bit cc phn ng u xy ra hon ton. Gi tr ca V l
A. 10,08.
B. 11,20.
C. 13,44.
D. 11,20.
Cu 49: Thc hin phn ng nhit nhm m gam hn hp X gm Al v Fe3O4 n khi phn ng hon ton thu c
hn hp Y (bit Fe3O4 ch b kh v Fe). Chia Y thnh 2 phn:
- Phn 1 cho tc dng vi dung dch NaOH d thu c 0,15 mol H2, dung dch Z v phn khng tan T. Cho ton
b phn khng tan T tc dng vi dung dch HCl d thu c 0,45 mol H2.
- Phn 2 cho tc dng vi dung dch HCl d thu c 1,2 mol H2.
Gi tr ca m l
A. 144,9.
B. 135,4.
C. 164,6.
D. 173,8.
Cu 50: Cho hn hp A gm 2 cht hu c mch h X, Y (ch cha C, H, O v MX< MY) tc dng va vi
200 ml dung dch NaOH 1M, thu c 0,2 mol mt ancol n chc v 2 mui ca hai axit hu c n chc, k
tip nhau trong dy ng ng. Mt khc t chy 20,56 gam A cn 1,26 mol O2 thu c CO2 v 0,84 mol H2O.
Phn trm s mol ca X trong A l
A. 80%.
B. 20%.
C. 75%.
D. 40%.
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