Table of Recommended Rate Constants for Chemical Reactions Occurring in Combustion Francis Westley Chemical Kinetics Information Center National Measurement Laboratory National Bureau of Standards Washington, D.C. 20234 Sponsored by the Department of Energy ‘Washington, D.C. 20548 and Office of Standard Reference Data National Bureau of Standards Washington, D.C 20234 U.S. DEPARTMENT OF COMMERCE, Philip M. Klutznick, Secretary Luther H. Hodges, Jr., Deputy Secretary Jordan J. Baruch, Assistant Secretary for Producti /, Technology, and Innovation NATIONAL BUREAU OF STANDARDS, Ernest Ambler, Director Issued April 1980Library of Congress Cataloging in Publication Data Westley, Francis, ‘Table of recommended rate constants for chemical reactions occurring in combustion, 3 stand, ref, data ser, ; NSRDS.NBS 67) ‘National standard reference data system.” Supt. of Docs. no: C134867 1. Qhemical reaction, Rate of-Tables, ete 2. Combustion- Tables, ete I, Title, Tl. Series: United States. National Buresu of Standards. National standard reference data series ; NSRDS.NBS 67. QC100,U573 no. 67 {QDS02} 6021s [541.°61°0212} 79.607159 NSRDS-NBS 67 Nat, Stand, Ref. Data Ser., Nat. Bur. Stand. (U.S), 67, 119. pages (Apr. 1980) ‘CODEN: NSRDAP © 1980 by the Secretary of Commerce on Beha” ofthe United States Government US, GOVERNMENT PRINTING OFFICE WASHINGTON: 1980 For sale by the superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20802 Price $4.25Foreword The National Standard Reference Data System provides access to the quantitative data of phys- ical science, critically evaluated and compiled for convenience and readily accessible through a variety of distribution channels. The System was established in 1963 by action of the President's Office of Science and Technology and the Federal Council for Science and Technology, and responsibility to administer it was assigned to the National Bureau of Standards. NSRDS receives advice and planning assistance from a Review Committee of the National Research Council of the National Academy of Sciences-National Academy of Engineering, A num- ber of Advisory Panels, each concerned with a single technical area, meet regularly to examine major portions of the program, assign relative priorities, and identify specific key problems in need of further attention. For selected specific topics, the Advisory Panels sponsor subpanels which make detailed studies of users’ needs, the present state of knowledge, and existing data re- sources as a basis for recommending one or more dsta compilation activities. This assembly of advisory services contributes grestly to the guidance of NSRDS activities. ‘The System now includes a complex of data centers and other activities in academic inst tutions and other laboratories. Components of the NSRDS produce compilations of critically evaluated data, reviews of the state of quantitative knowledge in specialized areas, and computa tions of useful functions derived from standard reference data. The centers and projects !so establish criteria for evaluation and compilation of data and recommend improvements in ex- perimental techniques. They are normally associated with research in the relevant field. The technical scope of NSRDS is indicated by the categories of projects active or being planned: nuclear properties, atomic and molecular properties, solid state properties, thermody. namic and transport properties, chemical kinetics, and colloid and surface properti Reliable data on the properties of matter and materials are a major foundation of scientific and technical progress. Such important activities as basic scientific research, industrial quality con- trol, development of new materials for building and other technologies, measuring and correcting environmental pollution depend on quality reference data. In NSRDS, the Bureau's responsi to support American science, industry, and commerce is vitally fulfilled. A Hoobs. Ernest Amster, DirectorContents Table of Arrhenius parameters for chemical reactions occurring in combustion. Reactions of: 0 ... Cx compounds Ca compounds Cs compounds C4 compounds Cs compounds Cs compounds Cx compounds Cs compounds Co compounds Cro compounds 3. Sources of Recommended Rate Constants Appendix: Conversion Tables VvTable of Recommended Rate Constants for Chemical* Reactions Occurring in Combustion Francis Westley National Bureon of Standards, Chemical Kinetics Division, Centr for Thermodynamics and Molecular Science, Washington, [A tube of recommended rate constants for gas phase chemical reactions oovurring in combustion is presented. Specifically it gives in tabular form the values of the parameters fr the modified Arrhenis equation #= AT "exp (CE/RT). The table covers reactions occurring in the combustion, oxidation and decomposition af aliphatic saturated or unsaturated C; t0 Gio hydrocarbons, aleohols, akichydes, Ketones, thiols, ethers peroxides, amines, tamides and their fee radicals, a well atthe reactions of O, Os H, Ha, OH, HaO, HaOs, N, Na, NO, NeO, NOx, 1N204, Nas, S, Se, SH, SO, SOs, SOH, NS, with each other. The table includes 169 frst order reactions 782 second order reactions and 7 third order reactions, There are 1770 entries covering 1008 distinct chemical recommendations have been taken from eleven evaluations and critical reviews published between 1970 and 1976. The papers examined by the evaluators extend from the nineteen fifties up to and including 1975. reactions. Th Keywords: Arrhenive parameters chemical kinetics; combustion: decomposition; free radicals; gas phase: hydrocarbons: hydrogen: nitrogen; oxygen; rate of reaction; sulfur. De 20204 1. Introduction This publication consists of a table of recommended reaction rate constants for the combustion, oxidation, and decomposition reactions of aliphatic saturated and un- saturated hydrocarbons, their oxygenated sulfur and ami- no derivatives, as well as for the reactions of hydrogen, nitrogen, oxygen, sulfur and their inorganic derivatives with each other. The table is a compilation of recom- mended rate constants given in eleven critical reviews on the kinetics of combustion, oxidation and decomposition reactions, published between 1970 and 1976. Its purpose is to provide the kineticists and kinetic modelers with a comprehensive and easy-to-consult reference book on the kkinetic data for combustion and oxidation processes. The table gives 1008 recommended reaction rate constants from these eleven sources. A summary of the content of the'table is given in the following listing of quotations from each source. No. of Recommended Source Rate Constants Baulch et al. (1972) 40 Baulch et al. (1973) 64 Baulch et al. (1976) 36 Benson and O'Neal (1970) 167 Benson et al. (1975) 19 Sa sel he reo at yh i of San Engleman (1976) 123 Herron and Huie (1973) 46 Kerr and Parsonage (1972) 185 Kerr and Parsonage (1976) 181 Kondratiey (1970) 37 Lloyd (1974) 10 Total 1008 reactions included in the table are listed separately under cach reactant, so that a grouping of the reaction according to the first reactant is obtained. As a result, the total number of tabulated entries is 1770, although the real umber of distinct chemical reactions is 1008. ‘The presentation of kinetic data is standardized and simplified as much as possible. Rate constants are ex- pressed in the modified Arrhenius equation k=ATPexp (—E/RT). In general uncertainties are given only for the rate constant & itself and not for the individual param- ters in this equation. Sometimes an uncertainty is given for the value of £/R. This uncertainty is only of second- ary importance and has been included in the uncertainty stated for the value of the rate constant. Rate constants are expressed 4 in units of 57 cm*mol's"%, and em‘mol"%~? for reactions of first, second, and third order, respectively. For the readers who prefer other kinetic units than the standard ones, two conversion tables for equivalent sec- ond and third order rate constant units are appended at the end of this publication.‘The arrangement of the tables is described in detail below, in the “Guidelines for the User. Its hoped that this table of kinetic data will serve as a handy and easy to use reference book for all the kineti- cists and kinetic modelers interested in combustion and ‘oxidation processes. This publication is not the result of the effort of a single person, but of the whole staff of Chemical Kinetics Information Center. My thanks to all of them. In particular, I wish to thank Dr. David Garvin, Chief of the Chemical Thermodynamics Division, and Dr. Rob- ert F. Hampson, Jr., Director of the Chemical Kinetics Information Center, for their more than helpful sugges- tions and constant guidance; Dr. Wing Tsang, Chief of the Chemical Kinetics Division, for his encouragement in having this table published; Mr. James G. Koch, Super- visor, for putting the tables into a printable computer form; Mrs. Bettijoyce Molino and Mrs. Carla G. Messina from the Office of Standard Reference Data for applying the OMNIDATA and GPSDIC programs to the present tables; Mrs. Geraldine Zumwalt and Mrs. Janice L. Jones for punching and typing a difficult typescript, full of digits and numbers, with particular care. 2. Guidelines for the User General ‘As pointed out above, the presentation of the kinetic data in this publication is an attempt to simplify and standardize them. In that respect, the choice of standard units for rate constants was easy; it was found that the ‘most commonly used units for gas phase rate constants are the cubic centimeter, the mole and the second. The choice of a standard form for uncertainty limits is some- ‘what more complicated, but when a series of recommend. cd rate constants is to he presented in a tabular form, the uncertainty limits cannot be omitted, for an uncertainty assigned to the recommended value of a rate constant is an estimate by the evaluator of the absolute accuracy of the preferred value. It is to be emphasized that in the present tables the concern is with the overall uncertainty of a reaction rate constant and not with the expression of precision of a set of experimental measurements. Most of the uncertainty limits included in this table are uniform within the respective temperature range indicated. How- ever, for a limited number of reactions, the data warrant or require variable limits, In such cases, a note under the respective data indicates for which interval of the tem- perature range there is a change in the uncertainty limits, Tt is thought that the uncertainty limits expressed in the form of lower and upper k factors, f and F, respective- ly, are the most suitable for tabulation. Thus, if ke is the central value of a rate constant the limits of reliability for the rate constant ke are defined by the relationshij Sho 100%, the F factor is determined first, according to relationship (19) then, instead of relationship (18), one simply. sets: IF. Ego, for a 150% error, r: ‘and f=1/F=0.4. ‘The above given relationships: (3), (8) and (9), (14) and (15), (18) and (19) can be used in reverse by the reader who prefers other types of uncertainty limits than thestandard & factors, f and F. However a word of caution is necessary. In contrast with the standard uncertainty limits, other types of uncertainties for rate constants using a unique factor or algebraic addend have a con- straint imposed upon them. Thus, the uncertainties ex- pressed by a unique algebraic addend are required to be symmetrical with respect to the central value to which they are appended, while the uncertainty expressed by a unique factor, F, indicates in fact that the upper factor F and the lower factor f are required to be inverse to each other (f=1/F). No such constraints are imposed on the standard uncertainty limits used here and for that reason this type of uncertainty has been found most suitable for tabulation purposed. Why some evaluators prefer uncer- tainty limits with constraints in not clear. It would seem more logical if the lower and upper uncertainty limits were studied independently from each other, without imposing any constraints on them. Probably itis a matter of convenience to express an uncertainty in the form, say: logiok=C+D rather than by the —inequelity: Fho~* Following the reaction order, on the same line, the presence of an inert reaction partner “third body” is indicated by the letter M, followed by its chemical formula, e.g., M:Ar or M:COz. No indication is given if M is undefined, or if the reaction does not include M. In all, there are 112 reactions with M specified. For 124 reactions, no Arrhenius parameters are in cated. Instead, for each of these 124 reactions, the ratio of the rate constant with respect to the rate of a reference reaction, taken as unity, is given. This information follows the reaction order information, on the same line, and is indicated by the symbol k/kyg¢ followed by a number, €.g- k/ kre: 0.59.The last line of column 1, placed under the line including the short reference and reaction order informa- tion, begins with the heading Note. It is given only when necessary and might include information about the de- pendence of & factors on temperature range, or the reaction taken as reference when the ratio k/dre is given in the previous line, or other information pertinent to the reaction indicated above. The rate constant, fret, for the reference reaction indicated in the note (by the same author) can be found in the table in the proper place. For a certain number of reactions taken from Baulch et al. (1972, 1973, and 1976) the relationship 1 =Kk-1 in- cluded in the note indicates that the respective rate constant was calculated from the equilibrium constant K and the rate constant k-1 of the reverse reaction. In such ceases, the author usually gives the rate constant of the reverse reaction immediately after the data for the for- ward reaction, The arrangement of the present table (based on the standard order, as described below in the following paragraph) does not allow the forward rate constant of a reaction to be followed immediately by its reverse reaction data, The reader will have to locate the rate constant of a reverse reaction (by the same author) in its proper place in the table. Column 2, with the heeding T/K, indicates in elvins the temperature range of validity of the recom- mended rate parameters. For some reactions only one temperature is given, meaning thet the reaction was studied only at one temperature. If no temperature at all is indicated, it means that the kinetic parameters of the corresponding reaction are valid throughout the normal temperature range for combustion. The data estimated by Benson and Golden in their report “Estimating the Kinetics of Combustion” are in this category. The tem- peratures are alined with the short reference and the reaction order information, Column 3, with the heading 4, gives the value of 4 for the equation #=ATPexp (—E/RT) in short scientific notation, In other words, it appears as a number less than 10, followed by a parenthesis including an integer pre- ceded by the sign + or —. The number less than 10 is the coefficient of the A factor, while the integer inside the parenthesis is the exponent of 10. Therefore, e.g.» (414) should be read as 3.5% 10", The coefficient of the A factor has no more than one digit after the decimal point. The units of the 4 factor are the same as for the rate constant ky according to the order of the respective reaction, as shown above. For those cases when the recommended value is only for one temperature, the entry under this column is in fact the value of the rate constant at this temperature. As for the temperatures, the data for the A factor are alined with the short reference and reaction order information. If a dash appears in this ‘column, it means that no 4 factor value was reported by the evaluator for the corresponding reaction. Column 4, with the heading B, gives the value of B for the equation k=ATPexp (—E/RT). the value of B is usually low and varies from 0 to about 3 or 4. It may be negative or positive. The negative values of B are pre- ceded by the sign —, while the positive values are without sign. No more than one digit is given after the decimal dot. Ifin this column a dash appears instead of a figure, it means that no B value was reported by the evaluator for the corresponding reaction. As for the temperature and A factor, the data for B are alined the short reference and reaction order information. ‘Column 5, with the heading £/R, indicates the value of EIR for the equation k=AT®exp (—E/RT). Since E is the activation energy in cal mol! and R the gas constant with @ value of 1.987 cal mol K~, it follows that the units of £/R are kelvins. The values given in column 5 for E/R may vary from 0 to over 100000 kelvins. The E/R values may be positive or negative. The negative values are preceded by —, while the posi without sign. Some of the £/R values included in the table are followed by an uncertainty with plus or minus ign. As pointed out in the introduction, these uncertain- ties may be ignored, as being included in the lower and upper & factors indicatd in the right column of the table. If in this column a dash appears instead of a figure, it ‘means that no £/R value was reported by the evaluator. [As for the data from the previous columns, the values for the E/R factor are alined with the short reference and reaction order information. Golumn 6, with the heading “k factors” and two subheadings, “/” and “F”, indicates the two uncertainty k factors, the lower factor f in the left subcolumn and the upper factor F in the right subcolumn. To find the uncertainty limits of a reaction, its rate constant is to be multiplied by the two factors, as shown above in relation (I: floOH-+CHla- and, as such, is listed in the O system, The advantage of such a procedure is obvious: referring to the example just given the reader will find the reaction between methane and oxygen listed with CHs as first reactant if he is interested in the reactions of methane, or listed with O as first reactant, if he is interested in the reactions of oxygen atom. The bimolecu- Jar reactions are the largest group of reactions included in the table. There are about 750 reactions listed in the table, having as reactants two distinct chemical com- pounds. Since each of these reactions is inserted twice, the number of entries for them will amount to about 1500. Only small number of termolecular reactions has three distinct reactants. As an example, one of them is NO+NOz+O,—+N20s. This reaction will also be insert- ed under the forms: NOz+NO+02->N20s and Oa-+ NO+NO:—>N20s. A number of second and third order reactions includes a second and third body M, respec- tively. For this group of reactions, M will always be placed after all the other reactants, which means that the second order reactions with Mas reactant will be inserted in the table only once, while the third order reactions with M as reactant will be inserted only twice. E.g. reaction Os -+M—+0-+O2-+M is inserted in the table only once, while reaction NO-+0-+M->NO2 +M is inserted as such, and also under the form 0-+NO-+M—>NOs+M. Most of the chemical reactions included in the table are balanced. A number of reactions are only apparently unbalanced. For instance, reaction (CHsCHaCHsCHs + H—-CHsCHaCHsCHa-+ (CHsCHsCH()CHs + He 0) has a rate constant which is in fact the sum of the rate constants for the two reactions (CHsCHzCH.CHs +H—-CHsCHsCHeCHa--+He (21) and CHsCHsCH2CHs + H—»CHsCHsCH()CHs +H (22) ‘Since the Arrhenius parameters listed in the table refer to the total rate constant, the reaction is listed in the table under the form (20) rather than in two separate forms. In some instances, a reaction is balanced, but the alkyl radicals formed as products are not specified, .g.: (CHa--+-(CH)sCHCH (CHs)CH(CH)—+CH, + [CaHi7-] (23)‘The unspecified octyl radical inserted in square brack- ets as product in equation (23) represents all primary, secondary and tertiary octyl radicals that could be formed by abstraction of a H atom from the reactant 2,3,4 trimethyl-pentane. There are a number of reactions with the products totally unspecified. In such a case, the word “products” appears after the arrow: (CHs),C=CHCHs +N—products 4) Display of Chemical Reactions and Formulae ‘A chemical reaction equation should show as clearly as possible the formation of products from the reactants, For that reason, the reactions listed in the table are written on the basis of semi-structural formulas. Straight chain hydrocarbons. All saturated normal hydrocarbons up to, and including n-pentane, are written 30 as to show separately each methyl and methylene group in the chain: CHs, CHsCHs, CHsCHsCHs, CHsCHaCHaCHs, CHsCHsCHs CHa CH. ‘The higher hydrocarbons, from n-hexane to n-decane, are written in a more condensed form to facilitate the counting of the number of methylene groups in the chain: CHs(CH2)sCHs, CHa(CHs)sCHs, CHa(CHa)sCHs, (CH3(CHla))CHs, CHs(CHs)sCHs. ‘The unsaturated hydrocarbons are written so as to show the position of each double or triple bond in the molecule, ¢.g.: Ethyne (Acetylene) CH=CH 1,2-Propadiene (Allene) CHs—=C=CHls 1,3:Butadiyne CH=CC=CH is-2-Pentene cis-CHsCHaCH=CHCHa 1 -Heptene (CHs(CHs)CH=CHa Alkyl radicals. The unpaired electron of each alkyl radical is always indicated, e. Methyl free radical Cia. Ethyl, L-methyl, free radical (Isopropyl) (CHs)pCH- Methyl, hydroxy-, free radical -CHsOH If the unpaired electron of an alkyl radical belongs to carbon in the middle of the chain, it is indicated inside a parenthesis following the carbon atom, e.g.: Propyl, I-methyl,, free radical (sec-Butyl) (CHsCH,CH()CHs Butyl, 1,1-dimethyl, free radi- cal (2-Methyl-2-pentyl) (CHa CHsCHsC()(CHs): Methyl, oxo-, free radical (Formyl) is written: “CHO Ory free radicals. If the oxygen atom of an oxy radical is attached to the terminal carbon atom, the radical is written in the usual manner: CHO. Ifthe oxygen atom of the oxy radical is attached to aC atom in the middle of the chain, then the oxygen atom, together with the unpaired electron, are inside @ parenthesis following the € atom: (CHs)2C(0-)CHaCHs. Peroxo, and other free radicals. The rules for writing peroxo, and other free radicals are the same as for the oxy free radicals: CHsOx-, CHaS-. ‘Atoms, like O, H, S, N, and simple radicals like OH, ‘SH, NH, CH, CHo, are written without dot. Hydroperoxyl free radical is written HOz- (with dot).“Table of Arrhenius parameters for chemical reactions occurring in combustion—Continued ctlons 7 7 7 TR] & factors Gay fe F OFOrM = Oem oxvGeN Tow “76 BAU/ORY REACTION oRDER: 3. Mz Ar | 190-4000] 1.9(418) | 0 9002175 Joe 1.2 NOTE: k FACTORS CHANGING TO: 7 =-0.4; F = 1.6 AT 4000K, Msp | 190-400 | 2.o(sa | 0 720 05 15 ME 08 | 2000-10000 4:7(328) | -2.5 0 oa 28 NOTE: ky = Kk_,. k FACTORS CHANGING TO: f= 0.5; F's 270 hf = B000K, 040, = O40 oxfcen ard’ oxvcen wovecuLe ‘76 BEN/COL. REACTION ORDER: 2. 6.3Gn) | 0.8 ° 0+ 0p 4H Oy +H oxTcéN ATOM 4ORYGEN MOLECULE 76 BAU/DRY REACTION ORDER: 3. M: 02 | 300 22a) | - - fos 12 NOTE: Weff: 0,(1.5) Ms an | 300 rsciy |= - foe 1a NOTE: M eff: Ar(1.0) Ms Xe | 300 zai | - - fos 12 NOTE: M eff: Ng(1-4) 040g = 09 + 05 ‘oxicen at6e’+ dzone 76 BAU/DRY REACTION ORDER: 2. 200-500 | 5.2(s12) | 0 20002260 [0.5 1.5 NOTE: K'FACTORS CHANGING TD: f= 0.6; F = 5.0 AT = 1000K OFM ew = ow sw ‘OXYGEN + “HYDROGEN ATOMS. 76 ENG REACTION ORDER: 3. 1500-2500 | 7.9(415) | 0 ° on 10. 04 te = Oe HL OxfceN ATOMS HYDROGEN NOLECULE 72 BAU/DRY REACTION ORDE 400-2000] 1.8(+10) | 1.0 | s4sorso for 1.3 04 Dp = 004 ‘OxTGEN ATOM’ + DEUTERIUM NOLECULE 72 BAU/DRY REACTION ORDER: 2 416-968 | 2.0(:13) | 0 5800 05 20 0+ 08 = O56 H OXYGEN ATO’, HYDROXYL FREE RADICAL 72 BAU/DRY REACTION ORDER: 2. 300 2.33) | = - Jos 14 76 ENG 1500-2500 | 2:5¢413) | 0 ° 05 210 008 + OH ‘OXYGEN ATOM’ HYDROXYL FREE RADICAL 75 BEN/COL FACTION ORDER: 2. 6.3m) | 05 ° OF OH SM Hog 4 a OXYGEN ATOM + AYDROXYL FREE RADICAL 76 ENG REACTION ORDER: 3. 1500-2500] 1.0(417) | 0 ° 0.01 100. OF OH = Of +o OXYGEN ATOM NYDROXYL, FREE. RADICAL "78 BEN/COL REACTION ORDER: 2. 6.3) | 0.8 | 4000 0+ Heo OW + OF oxicen aro + paren 72 BAL/ORY REACTION ORDER: 2. 00-2000] 6.8(113) | 0 s2so:200 Jo.7 1.5 04S. = S048. ‘otTceN sTow’ + SULFUR DINER 75 BEN/COL. REACTION ORDER: 2. 6.31) | 0.5 ° 0480 = O48 ‘OXYGEN 4TOW + SULFUR MONOXIDE 75 BEN/GOL REACTION ORDE 20+) | 05 | 2770 0+ 90 = 040 ‘OXYGEN. ATON + SULFUR MONOXIDE. 75 BEN/COL. REACTION ORDER: 2. 630m) | 0.5 ° 0+ 802M 50, 4 OXYGEN ATOW 4 SULFUR WONOXIDE 76 BAL/ORY 3. Mar | 298 4716) | - - for isa REACTION ORDER:‘Table of Arrhenivs parameters for chemical reactions occurring in combustion —Continued Chenical reactions TK a 3 Fit] factors Gan |e 048, = 0, + $0 OXYGEN ATOR + SULFUR DIOXIDE 76 BAL/ORY REACTION ORDER: 4ao-2100| 1.3(414) | -0.5 | 9980 os 4a NOTE: ky = Kk OF SH = Hy so OXYGEN ATON NERCAPTO FREE RADICAL 75 BEN/COL REACTION ORDER: 6.sGn) | 0s ° OF SH» Ones OXYGEN ATOM’ NERCAPTO FREE. RADICAL 75 BEN/COL REACTION ORDER: 6.31) | 0 4000 OF NEM NO em OXYGEN ATO 4 NITROGEN ATOM, 73. BAU/DRY REACTION ORDER: 200-400 | 6.4(416) | -0.5 ° One = MOE ‘OXTGEN ATOM + NITROGEN MOLECULE 73 BAUIDRY REACTION ORDER: 2000-5000 | 7.6(418) | 0 seng0+iso 0.5 2.0 Nove: ky = Rhy OFM EN = NO FM OXTCEN ATOM 4*NITROGEN MOLECULE 73 BAU/DRY REACTION ORDER: 3. MW: Ar | 1300-2500} 1.4(+18) | 0 rosoosiso0 }o.7 1.5 0+ 04 N ‘OXYGEN ATOM! NITROGEN OXIDEANO) 73 BAUDRY REACTION ORDER: 1090-3000] 1.5¢¢ 9) | 1.0 | r95008150 Jo. 1.3. NOTE: ky = Kk. k FACTORS CHANGING To: 1750.57'F © 2.0 AT 3000K OFM = NOLO, [OXYGEN ATOM NITROGEN OX1DE(¥0) 75 HEN/GOL REACTION ORDER: 6.311) | 0.8 ° O40 EN = No eM ‘OXYGEN ATOM + STTROGEN OXIDEGNO) 73 BAU/DRY REACTION ORDER: 3. mM: 0, | 200-800 | 1.1(+35) | 0 08 12 NOTE: Weff: 0,(1.0) AT 297K us Ae | 200-500 | 1.1G04) | 0 oa 12 Ar(0.1) AT 297 Me 200-50 | 6.7¢:15) | 0 08 12 H0(6.1) AT 297K Me 200-500 | 5.5(+15) | 0 08 12 D,0(5.0) AT 297K Ms 200-500 | 2.9(+15) | 0 08 12 SFg(2.6) AT 297K 2o0-soo | 1.515) | 0 08 12 Ng(1.4) AT 297k 200-500 | 2.3(415) | 0 0.8 12 N0(2.1) AT 207K 200-500 | 2.3(+15) | 0 og 12 0,(2.1) AT 297K 2o0-so | 2.4(415) | 0 08 12 (2.2) AT 207K 200-500 | 2.415) | 0 oe 12 (2.2) AT 297K 0+ Nog = Og + 80 OXYGEN” ATO + NITROGEN OXIDE(NOQ) 73 BAU/DRY REACHION ORDER: 300-580 | 1.0(+13) | 0 soor100 fo.8 1.3 05 Noe + Os + 80 OxYGen ATOM + NITROGEN OXIDE(OR) 76 ING EACHION ORDER: 1500-2500] 1.0(13) | 0 500250 [0.5 2.0 04 Op eM NOe sw OXYGEN ATOM + NITHOGEN OXIDE(NO,) 78 BAU/DRY REACHION ORDER: 295 2.3(416) | - - 04 2.5 NOTE: ky (LOW PRESSURE). REACTION ORDER: 295, rag) |= - fos 25 Nome: AMITING HIGH PRESSURE‘able of Arrhenius pa smeters for chemical reactions occurring in combustion—Contnued Cheaical reactions TK 7 a Tt | factors Gag [fF 07 m0 = 0 ovfeen ano | Nrnoces oxtpe(n,0) 73 BaU/ORY REACTION ORDER: 2. 1200-2000 | 1.0(414) | 0 4100-2000 |0.4 2.5, 0+ NO NO + No OXTGEN ATOM + NITROGEN OXIDE(N0) 73 BAU/DRY REACTION ORDER: 2. 1200-2000] 1.0¢:14) | 0 ra100:1s00 |0.5 2.0 OFM ons ‘OXYGEN ATOM’ + INIDOGEN FREE, RADICAL 75 BEN/COL REACTION ORDER: 2. 63g | 0.5 | 4000 OFM = Nore ‘OXYGEN ATOM INIDOGEN FREE, RADICAL 75 BEN/COL REACTION ORDER: 2. 6.3m | 0.5 o 04 MH SM — HNO sw OXTGEN ATOM + INIDOGEN FREE RADICAL 76 ENG REACTION ORDER: 3. 1500-2500] 1.0(:16) | -0.5 o:2500 fo.s 3.2 Nig OH + Nie OxYGeN ATOM ¢ Aionta 73 BAL/ORY [REACTION ORDER: 2. 300-1000 | 1.5(412) Jo 30002300 P.5 1.5 0+ HNO = OW + NO ‘OXYGEN ATOM + NITROSYL HYDRIDE 76 ENG REACTION ORDER: 2. 1500-2500] s.0(:11) | 0.5 o:2500 |0.8 3.2 04 WO + Og + aH oxyeen avod 1 Mirnost. avon 76 ENG REACTION ORDER: 2 1500-2500] 1.0(:11) | 0.5 | 3500:2500 |o.3 3.2 HNO + Np + OXYGEN ATON"S"NITROSYL HYDRIDE. 76 ENG REACTION ORDER: 2. 1500-2500 | 5.0(410) | 0.5 022500 |o.8 3.2 04s - son ‘OXYGEN ATON’ + NITROGEN SULFIDE(NS) 75 BEN/COL REACTION ORDER: 2. 6.3¢11) | 0.8 | 4000 04S = MES. ‘OXYGEN. ATOM + NITROGEN SULFIDE(NS) 75 BEN/COL REACTION ORDER: 2 6.3¢1) | 0.5 ° Orca = ae oXyGeN aTow Gatton aTow To BAUDRY REACTION ORDER: 3. 7000-1500 3.3(:26) | 3.1 | 2114 os 18 NOTE: W= Ar, ORO ky = Kk O41 OXToEN aT cao wovoxtDE 75 BEN/COL REACTION ORDER: 2. 1.0012) | 0.5 — |69s00 0:0 ~ oso OXYGEN ATOM’ CARBON MONOXIDE 75 BEN/COL REACTION ORDER: 2. eau) | 05 ° 0+ 00 eM Ong ontcEN aon ¢'éxtsov vowoxDE 76 BAU/DRY REACTION oRpER: 3. w= co | 250-500 | 2.415) | 0 auwa200 fos 1.2 NOTE: K FACTORS CHANGING TO: f= 0.5; F = 1.2 AT SOOK. 0+ Cy = 0, + 00 ‘oxvGEN” ATO + CARBON DIOXIDE 76 BAU/DRY REACTION ORDER: 2 1500-3000] 1.7(413) | 0 2650012500 0.5 2.0 NOTE: k FACTORS CHANGING TO: f= 0.5; F = 1.5 AT 3000K, kek, orm ore (OXYGEN, ATOM METHYLIDYNE FREE RADICAL 75 BEN/COL REACTION ORDER: 2. ean | 08 | 4000 10‘able of Arshenius parameters for chemical reactions occurring in combustion—Continued Ghenical reactions 77k + 7] Tt] factors Gay [er Ord ~ Ore OXYGEN ATOW + NETAYLIDYNE FREE RADICAL 75 BEN/COL REACTION ORDER: 2. es¢an) | 08 ° OF Hs w Ho sw ‘OXYGEN ATOM + METSYLIDYNE FREE RADICAL, 76 ENG REACTION ORDER: 3. 1500-2500 | 1.0(416) | -0.5 022500 [0.3 3.2 04 cai = Hs clo ‘OWVGEN ATOM + WETHYLENE FREE, RADICAL 76 ENG REACTION ORDER: 2. 1500-2500] 5.0111) | 0.5 | 200012500 0.3 3.2, + CH, = oll + at (OwvGEN ATOM + METHYLENE FREE. RADICAL 76 ENG REACTION ORDER: 2. 1500-2500] 2.0(:11) | 0.7 | 1s100:2500 Jo.8 3.2, 04d. = H+ HCHO OXYGEN ATOM + WETHYL FREE RADICAL 76 ENG REACTION ORDER: 2. 1300-2500 } 5.0418) | 0 ° 0.5 2.0 0+ Gi, = on + cH, ‘oxvGen ATOM > MetiiANE 73 HER/HUT REACTION ORDER: 2. 350-1000 | 2.1¢418) | 0 4550 07 13 76 1500-2500 | 2:0(+13) | 0 45308500 }0.6 1.6 0+ cH = H+ 00, OXYGEN ATOM + METHYL, OXO-, FREE RADICAL 76 ENG REACTION ORDER: 2. 1500-250 3.2(11) | 0 NOTE: ke ESTIMATED. 0+ co = of + 00 ‘OXYGEN ATOM + METHYL, OX0-, REE RADICAL 76 ENG REACTION ORDER: 2. 1500-2500 | 3.2¢+11) | 1.0 | 25021500 NOTE: k ESTIMATED, 0+ HoH = om + Ho OXYGEN ATOM +” FORWALDERYD 76 EN 2 1500-2500] 1.0(:11) | 1.0 | 175021000 fos 1.2, 0+ ACH = products OXYGEN ATOM FORMALDERYDE 73 HER/HUT REACTION ORDER: 2. 300 9.0(s10) | ~ - for 1s 0+ HOD = products OXYGEN ATOM FORMALDERYDE- 1-PROPENE, 3:NETHVI- 72 KER/PAR REACTION ORDER: 2. 298 13GM) - NOTE: CALCULATED ON THE BASIS OF 0.5% NON-TERNINAL ADDITION OF H TD (Gly) CCH. le + (CHa)aC. +, (Cig) CHC EN avow ¢ a-PROPENE, “2 METH 72 KERIPAR CTION ORDER: 2. k/kyee: 2.52 | 300 : e NOTE: kya? Hl H+ CHyCHACHACH, ily 4 CHCHCH(.)GK, + ClyCg CaCl. ‘avokocen Aro + BUTiNE 72 KON REACTION ORDER: 2. 320-980 | 4.14412) 2estss20 ]0.5 2.0 H+ (Ca)gCH = Ha, + (Cllg)sC- + (Cy aC. 'AYDROGEN TON + PROPANE, "2-METHYL” 72 KON REACTION ORDER: 2. 300-800 | 1.9(418) rooras fos 1.2 H+ CHCl, CH,CH-CH, + Ci, Cty Cig CIN), 4 GlscligcHa ci cis ‘avndocEN Ato +7i-PeyTENE 72 KERIPAR, REACTION ORDER: 2. 298 8.3(¢11) Ki, g¢2 0.89] 300 E NOTE: poe! H+ Clg 21‘Table of Arrhenius parameters for chemical reactions occurring in combustin—Continued Trent reactors 7 7 TT es day [F TEACTION ORDER: 2. ae | s.sumy Jizee: 0.29 | 50 : : i ICs = CHlgCHaCH(. )CHCHy ca 000 | tPane-2-eTENE 72 Ea TEACTION ORDER: 2 we | saan Wzegs 0.46] 300 B hee A+ coh. Hp CLC Cl, = yCHLC Giada | Garchced as, woes {rots E-poexe, 2_weniyL— 72 Kaka REACTION omen: 2. we | onan | - - D+ CHGEHACCCH) Ch, + CHAE. )(CH CHD | Sotacicta te oe atenfin crBu i-avrese, 2x. 72 KEN/PAR ENCTION one: 2 ae | noc) | - ‘H+ (Cita) CHC lo + (Cy) 9CHCH(.)CHy. 1 Ge strana. ioe aru? Lares, sera 2 KER PAR REACTION onR: 2. we | tam | - - Ds (CH,2sCHCICL, + (Cy) gCHCHC pad 2 (Gi) trator. ive rtor's -auTeNe, .aenstL- 72 KEVEAR ENCTON omen: 2. we | roy | - : Hs (Qig)sCsOlGl, + (Cy) CHEN, 1 Gee eay ep ito 2rexe, 2-xenm.— "kein REACTOR omen 2 we | ona | Wkgags 1.08 | 300 a : WOTE: Byars + Oy Cy H+ (CHS) gC=C(CHS) 2° = (CHS) CHC( .) (C3) sfonog Aton "2-aurihes So3-bieenit = 32 KER PAR EACTION ODER: 2, ae | 7.801) - Wigcg: 0.06] 300 é = NOTE: bree! + GOH, Hs (aby, GE(Ob ch, + (Cy gCCCI NC, 5 ae cet ae toRSCE Aidh #FoeeN, 2, 3.9, -TRIWETI 2 KEUPAR ibichiON ome 2. we | roi | - vores TENTITIVE ALLE BASED oN REACTION Teaco to = Ws oF fronoten wiugee + onvcen aro 2 BLUDRY ERCTION ono: 2. 40-2000} 1.00010) | 1.0 | sseoeso |o7 1.3 B40 = Dio devrehiut dotbous + oxveen snow Te BAU/ORY ERCTION onDR: 2. aise | 2.033 | 0 | sso Jos 2.0 Ye $05 = He Hp, info Woizcé oxvcen vourctz 2 BOK ENGIN omer: 2. avoso0 | s.sisiay | 0 | anreoss0 os 2.5 Me bo = OF on ifocén Novel + oxveen youscine ec EAGHON omen; 2. rsoo-2s00| 2.si12) | 0 | rseaossooo fo.1 10, Hat = Hot A fnteoce wdusBuue + vonocen rou 1 BCL TEACTION ORDER: 2 ese) | 0.8 | 4000Table of Arrhenius parameters for chemical reactions occurring in combustion —Continved Ta 7 7 Te i) hid tw fvbnoten Wines + neuen sTo4 72 KO ENCTION ORDER: 2. seo-100| sos | 0 | aemito fo 1a De t= 0s detest ottcute + mvoroces sou TEN TENCTON one: 2 roo | acts) | 0 | atesi2s0 0.6 1.6 Be bok = ns 0 fvonocEy Wott + wnonox. ree maorea 2 B/D ETON ONDE; 2 soo2s0} 2.a¢s1) | 0 | aswos100 Joe 1.2 ror: EFACTORS cANGING To: fe D.Se Fes FOR T 300K 5200 by = Ot D+ oo detenion WEE: + wvOROTL, REE RADICAL TN TEACTON ORIEN 2, seo-se3 | 1.9% | 0 | asotiz fos 20 He 5H the indices wuEcltE?, svororeon, rae, otc 2 BUOY tection tate soo.200 | rain |o | vumas0 fos 2.0 eis 2 ininoces wougtae 4 suri aro fo mr Arion one: 2. me | ae | - - fos 1s vores 53 weve 2sci2) | 0s |is6o Behe He Inrocey wouBeoe + simmocey 704 1S BEWUDL TEATION ORDER: 2. 2.52) | 0.8 | 870 Bees We ot inode WoLECLe + canoow ago "3 BEreoL ENCTION onnen: 2. .s12) | 0.5 | si00 Be £0, = 0s inbnboay woos canoo oroxane baad RENCHON omen: 2. rsoo.2sa0] 1.0089) | os | rssotasoo fo.s 3.2 Bee Gh ne om ivohboey OLE weravLe, REE trcaL aed TEACHON ORDER 2 1500-2500 | 3.a¢si2) | 0 | asesi1so0 sore: asthe. Sy. =e at inter wohetule*S wenn. FREE OIC KPA BEACON One 2 sro-700 | s.sinn | 0 a7 1s et. = cnt Annex wokecue werin.-p FREE mADTCAL 72 KN icriOn ORDER 2. wos | racy |o | sesmzas [os 1.2 DHS Gig. = a chub fevtdivo stotube wer. ene: suprca, TeREVAR HEkcron oti: 2. wo-700 | 24eiy | 0 | seasiso0 fos 15 Ob. = dc JARI OLDE wen. Paes CAL Te KEV TAR ECON Oi: 2. 00-700 | 2.100 | 0 os 15 be $y. = Ds chp dein Lic" wer, re naotca, Tote Pa Ener OnE: 2 soo-700 | zany | 0 | sowoiaso for 1 he = He ty inbtocgy Hoistite cYasoce8 FREE auDICAL Tee TENCTON ORDER: 2. 1500-2500] 3.2¢s12) | 0 | 2s0ns1s00 vore; {esthureo, We {ObGyn ivondeet woiectué ETH. mee mores. 12 ON TEACHON ORDER: 2. waa | scam |o | sass‘Table of Arshenivs parameters for chemical reactions oosurting in combustion—Continued Chenical reactions 7 7 a TR] & factors inky | 68 iw Was HYDROGEN MOLECULE 72 BAU/DRY REACTION ORDER: 2. M: Ar |2500-s000| 2.2(:14) | 0 48300:2000 |0.5 2.0 Nove: ky = Rk OH 0 = 04 of HYDROXYL FREE RADICAL + OXYGEN aTOW "75 BEN/COL. [REACTION ORDER: 2. 6.34 | 0.5 | 4000 OHO. Hs 0 HYDROLYL PREERADICAL + OXYGEN ATOM “72 BAU/DRY HEACTION ORDER: 2. NOTE: ky CALCULATED FROW k_,K IS: 1.3 X 10"ce.nole’ 840 Hs Og HVDROLYL PREE"RADICAL + OXYGEN ATOM 76 ENG REACTION ORDER: 2. 1500-2500] 2.5(+18) | 0 ° 0.5 2.0 OHS 04M = Hos +H HDROXYL FREE RAbICAL + oxvG 76 ENG ft 300 2.3(418) | - = foe 1a 3. 1500-2500] 1.017) | 0 ° 0.01 100. OH 4 Oy = Hoe. + thx. rréi taba + ozone 76 BAU/DRY REACTION ORDER: 2 300 soc) | - - fos 1s OH LH 0s Re AYORORYL, FREE RADICAL. 5 Tow 2 BAL/ORY EACTION ORDER: 2 490-2000} 8.914 9) | 1.0 7 13 OK as OF fois rie orca. + wore aro 75 BEN REACTION ORDER: 2 sau | os | o Ohne 0H HvbnOc Fee abi + wvonooey aro 72 BROT REACTION OmeR: 3. a H,0 [1000-3000] 1.44420) | -2.0 | 0 for 1s nore: Wet H00.0). ky = Key x: ar | 1000-3000} s.su2n | 20 | 0 fos 20 4100.06) us [r00-s000} 2.202) | 20 | 0 Jos 20 44(0.16) Ost HOF inbox fe ntorca + avonoces souscite 2 Uron REXCTION ORDER: 2. soo-asoo] 2.2418) | 0 | assosi00 fo.s 1.2 rove: CHHCIONS cUNcING To: FOS Pes for Satoe 8 sD, mmo +0 fivbfowi, FREE "RbIca + oevreuww wouscuLe 72 KN TENCTION OnE 2, 300-603 | 1.91013 | 0 | amoez00 fos 2.0 OH: OF Hop +t boxy aes ntorcu. 32 BAUR rection ome: 2 20.20 | 1.213 | 0 | 2020350 |0.5 2.0 OH + of = a0 + 0 ivonori. rite etotca, 2 BOAT REACTION ORDER: 2 aeo.2000 | 6.a(n2) | 0 ssoi200 lor 1s OF FOF ew = hoy fu fnbtokvt rice Eb BAL/ORY "REACTION ORDER: 3. Ws -Ne | 700-1800] 9.10414) | 0 | assosi000 Jo.8 1.3 nore: CHHCIORS cuNcING To: Ce OlSy Fe 20 A ISON OF + thos, = 0 + fvbRORuLreb ehoteh. + voce pero 72 BAY TENCTON ORDER: 2. 200-200 | 1.0018) | 0 swouso fos 1s obs s 04 st ivbnowwu rise tabicaL + suLEER ow 73 BECO REACTION ORDER: 2 r.aina) | 0s | r2t00‘Table of Arrhenius parameters for chemical reactions occurring in combustion—Continued Ghenical reactions 7K 7 7 oe (inky OLS = Ha 90 HYDROXYL, FREE RADICAL + SULFUR ATOM 75, BEN/GOL REACTION ORDER: 2. 6.aGny | 0.5 ° OW + HS = Hg0 + HS fivoROXYL FREE RADICAL + HYDROGEN SULFIDE 76 BAU/DRY REACTION ORDER: 2. 298-900] 6.3(+12) | 0 2010 0.7 1.3 NOTE: K FACTORS INCREASING TO: f= 0.5; F = 1.5 AT 900K. OWEN = 04 HH AYOROXYL, FREE. RADICAL + NITROGEN ATOM 75, BEN/GOL REACTION ORDER: 2. 1.3412) | 0.5 [17765 OWEN Hs NO. ‘HYDROXYL, FREE RADICAL + NITROGEN ATOM 75, BEN/COL. [REACTION ORDER: 2. acm) | os ° OW FNM BNO GW FRYDROXYL FREE RADICAL + NITROGEN ATOM 76 ENG REACTION ORDER: 3. 1500-2500] 1.0(+15) | -0.5 ° OH Ng + M+ HNOg + HYDROXYL FREE RADTCAL + NITROGEN OXIDE(NO,) 73 BAUDRY REACTION ORDER?” 300 soar) |= - fos 16 OWE NO Hog + 8 ‘iypROXYL FREE RADECAL + NITROGEN OXIDE(NO) 76 ENG. REACTION ORDER: 2. 1500-2500 } 3.213) | 0 7550 Nove: ke ESTIMATED, OW FM = Hos 8 [HYDROXYL FHEE RADICAL AND IMIDOGEN FREE RADI 76 ENG REACTION ORDER: 2. 5.01111) | 0.5 | 10002500 |0.3 3.2 OW 4 HNO + 0 + 0 YDRONYL FREE RADICAL + NETROSYL HYDRIDE 73 BAU/DRY REACTION ORDER: 2. 2000 s.(13) | - - fos as OW 4 HNO, HO. + NO, HYDRORYL FREE RADICKL + NITRIC ACID 73 BAU/DRY REACTION ORDER: 2. 300 s.o(10) | - - [os 20 Osc = 04 cH HYDROXYL, PREE RADICAL + CARBON ATOM 5 BEN/GOL REACTION ORDER: 2. 7.9) | 0.8 | 14800 OH YC = Hy AYDRONYL, PREE RADICAL + CARBON ATOM 7 BEN/COL REACTION ORDER: 2. 6s) | 05 ° OH sO + Hs coe AVDRONTL FREE RADICAL + CARBON NONOKIDE: 76 BAU/DRY REACTION ORDER: 2. 250-2000] 1.5(¢7) | 1.8 |- 38s 08 12 NOTE: k FACTORS OVER 1000K: f= 0.53 F = 1.5. ARECINWENDED FOR 250-2500K: Tog(k)eeuol~*s-* = 10.83 4 3.97 OWS GH Hs cH HYDROXYL FREE" RADICAL AND METEVLIDYNE, FREE RADICAL 76 ENG REACTION ORDER: 2. s.o(s11) | 0.5 | sooos2500 jos 3.2 08s Oh = 0.5 Gy AvonOxvL, FREE RABICAL AND METHYLENE FREE, RADICAL 76 ENG REACTION ORDER: 2. 1500-2500] s.0(:11) | 0.5 | s000:2500 Jos 3.2, OW + Gig +H HHO AVOROXYL FREE RADICAL AND NETHVLENE FREE. RADICAL, 76 ENG REACTION ORDER: 2. 1500-2500 | 1.0(+13) | 0 asi NOTE: k ESTIMATED. 08s Gh, = HO + OH HyoROXYL FREE RADICAL AND METHYLENE FREE RADICAL 1500-2500] 5.0(+11) | 0.5 | s000:2500 |o.3 3.2, 76 ENG REACTION ORDER: 2. 25‘Table of Arthenius parameters for chemical reactions occurring in combustion—Continued Ghenical reactions TK 7 Tit | & factors Gnk) OF Gi + Cho. HYDROXYL FREE RADICAL AND METHYL FREE RADICAL 76 ENG [REACTION ORDER: 2. 1500-2500 | 6.3(+12) o OH Gia. = He 4 Ce AVORORYL FREE RADICKL AND METHYL, REE RADICAL, 76 ENG REACTION ORDER: 2. 1500-2500 | 6.3(+10) 100012500 3.2 OH 4 Gly = Heo + cH yOROXYL FREE RADICAL + METHANE 76 ENG REACTION ORDER: 2. 1500-2500 | 8.2(418), 2soor250 }0.5 2.0 OF 4 .cH0 0 4 co AYORONYL FREE RADICAL + METHYL. OX0-. FREE RADICAL 76 ENG REACTION ORDER: 2. 1500-2500 | 3.2(+10) 01500 Nove: ESTIMATED. OW 4 G40. HO + HeHO FDRONYL, FREE"RADICAL + METHOXY FREE. RADICAL 76 ENG. REACTION ORDER: 2 1500-2500 | 8.2(418) 021500 Nove: ESTIMATED. Of + HCHO = HO 4. cho FAYDROXYL FREE RADICAL + FORMALDEHYDE 76 ENG TREACTION ORDER: 2 1500-2500 | 8.2(+10) 2.0 OF sO + 0 5 HON ‘AVORONYL FREE RADICAL + CYANOGEN FREE RADICAL 76 ENG ACTION ORDER: 2 1500-2500 | 3.2(+12) 150041500 OW} HON = Hao + cx HVOROWYL FREE RADICAL + HYDROCYANEC AciD 76 ENG REACTION ORDER: 2. 1500-2500 | 2.0(411) 25002500 3.2 0 + GieG = 80 + ceca. HYDROXYL, FREE RADICAL + ETHYNE 72 KON REACTION ORDER: 2 300-2000 | 7.6(+12) 23352400 2a OF 4 ClgnGly = MeO + Cl HvDRORYL REE RADICAL F EBTEXE 72 KON REACTION ORDER: 2. 3500-1400 | 1.6(18) 2asisHs 24 OW + GiyaCs + -CHgCHLOH HyOROXYL FREE RADICAL + ETHENE 72. KERIPAR REACTION ORDER: 2. 300 11g) E 13 Os CyOly HO + Cle. wvoROXYE FREE RADICAL’ s ErHANE 72 KON REACTION ORDER: 2. 302-798 | 1.3¢414) 1998 OF 4 CgCHCle + CHACH(.)CH,OH + caCHC ON) CH HYDROXYL FitEE RADICAL + 1-PROPENE 72 KER/PAR REACTION ORDER: 2. 300 6.6(412) - NOTE: ADDITION TO TERMINAL CARBON OF DOUBLE BOND 1S PROBABLY 95% Hog. + 05 = OH + O24 02 ‘wvondrenoxvL FREE RaDEcAL. + OZONE 76 BAU/ORY [REACTION ORDER: 2 298 9.14 8) = 1s HO tH = Og +H HYDROPERONTL FREE RADICAL + HYDROGEN ATOM 72. BAD/DRY REACTION ORDER: 2. 200-800 | 2.5(+13) 3502350 25 76 ENG 1500-2500 | 2'5(113) 3303500 20 Ho, tH 0 10 HYDROPERONTL, FREE RADICAL + HYDROGEN aTOW 74 Lo. REACTION ORDER: 2 300-1000 | 5. (413) 500 3.2 Nore: E ESTIMATED, Hog, 4 H+ OW + OW HHYOROPERONYL FREE RADICAL + HYDROGEN ATOW 72 BAU/DRY [REACTION ORDER: 2 200-800 | 2.5(18) 0.5 2.0 76 ENG 1500-2500 | 25:18) 0:5 20 26‘Table of Arrhenius parameters for chemical reactions occurring in combustion—Continved Ghenical reactions TK 4 7 Tk | factors Gan fee WO, +H = Hho +0 WYOROPEROXTL FREE RADICAL + RYDROGEN ATON 76 ENG REACTION ORDER: 2. 1500-2500 | 1.0(+13) | 0 on 1. Hg, + He = a0, + TWOROPEROKYE FREE RADICAL. + HYDROGEN YOLECULE 72 BAL/ORY REACTION ORDER: 2. 300-800 | 7.3(411) | 0 sanoi250 0.5 2.0 Hy, + HO = Hap + 0» ‘wioKOPEROXYL FREE RADICAL 74 LD. REACTION ORDER: 2. 00-1000] 1.0(:13) | 0 500 05 2.0 NOTE: E ESTIMATED. k FACTORS ARE LARGER AT T)300K. Hog + HO a0, + 08 ‘WYDROPEROXYL FREE RADICAL + ATER 72 BAL/DRY REACTION ORDER: 2 300-800 | 2.8(413) | 0 res00:500 |o.5 1.5 Hg + S0g + OH + 50g "HYDKOPEROKVL FREE RADICAL. + SULFUR DIOXIDE 74 LO REACTION ORDER: 2. 300 s.2ia) | - - foo 12 Hg, +N = Og + i ‘WYDROPEROXTL FREE RADICAL. + NITROGEN ATOM 76 ENG REACTION ORDER: 2. 1500-2500} 1.0(421) | 0 02500 Jos 3.2 Hg, + Oo 4 00g "WYDROPEROXYL FREE RADICAL + CARBON MONOXIDE 76 BAL/DRY TEACTION ORDER: 2. 700-1000] 1.5(:14) | 0 1190041000 }0.8 3.0 Hy, ¢ Gh = 05 + Cy 'WYDROPEROXYE FREE'RADICAL AND METHYLIDYNE FREE RADICAL. 76 ENG REACTION ORDER: 2. 1500-2500 | 1.0(s10) | 0.5 | 755022500 0.3 3.2 HO, + GH = Os cho 'WYDROPEROXYL FREE RADICAL AND METHYLIDYNE FREE. RADICAL 76 ENG REACTION ORDER: 2 1500-2500 | 5.0(+11) | 0.8 | 30002500 [0.3 3.2 Wy + Gig. > Og + Cle ‘nvoROPERONYL FRRE RADICAL AND METHYL FREE RADICAL 76 ENG REACTION ORDER: 2. 1500-2500] 1.0(41) | 0.5 | sooo:2s00 [0.3 3.2 Hos + CWO = Og + HOHO AYDROPERONYL FREE RADICAL + NETHVL, ONO, FREE RADICAL 76 ENG. REACTION ORDER: 2. 1500-2500] 1.0(414) | 0 150041500 NOTE: k ESTIMATED. Hog, 4 HCHO tad + cto TWYDROPEROXYL Fre RADICAL + FORMALDENYDE 74 0. [REACTION ORDER: 2. 300-900 | 1.0(112) | 0 4000 07 18 NOTE: K FACTORS ARE: f= 0.1; P= 10, AT 300 K. le + Cg-CHle ~products wvonoPenOgyL ABE RADICAL +, ETHENE 78 UD. [REACTION ORDER: 2. 300 10 |= - for ve. NOTE: RATIO DATA VERSUS kref FOR HO, + GO ON 1 00 KVFACTORS MIGHT BE" HIGHER Hg, + ClyOly = Hag + Cig nyokoPerdxve nabréa. + Eruike. 74 LD REACTION ORDER: 2 300-1000] 1.0(412) | 0 7000 O10. NOTE: E ESTIMATED, UPPER LINIT RECOMMENDED. keer IS FOR HO, + 00 OH + Og Wg + ClgCUsCH + Has + (cits) Ci ‘HYDROPEROXUEL FREE AABICAL 4 PROPANE 74 110 [REACTION ORDER: 2 300-1000} 2.0421) | 0 5300 O11. NOTE: UPPER LIMIT RECOAMENDED. RATIO DATA. VERSIS Kye FOR WO. + HO, ~ a0, + O2 Hg, + (Ca) CoC = products WYDROPEROXYL FREE RADICAL + 1-PROPENE, 2-METEYL 74 Lo REACTION ODER: 2. 300 1048) |= - for wo. NOTE: SUGGESTED k VALUE. QT‘Table of Arrhenius parameters for chemical rections occurring in combustion—Continued Chemical reactions 7K 7 z Tk] & factors Gay [fF iC ch = ania, “wvonoPexdxvE hee wbicae athe “4 110 ‘REACTION ORDER: 2 300-1000] 5.0(+11) | 0 5285 0.1 10. sore; UPPER LINTT RECOMMENDED. HATIO DATA VERSUS keet FOR HO,’ + Hg. HD, + Og + (G0) CH = Hae + (Cla) 6 w saiohoretdNTL PREE*RIDIAL > Propave,. 2-werane ‘74 LL REACTION’ ORDER: 2 300-1000] 1.0(+11) | 0 3500 0.1 10. NOTE: UPPER LINIT RECOMMENDED. RATIO DATA VERSUS by FOR HO, + HO, = HO, + Op Hoy tM = H+ Op ‘AYOROPERONYL FREE RADICAL 72. BAU/DKY REACTION ORDER: 2. 300-2000] 2.11415) | 0 2sooos2s0 fos 1.5 NOTE: We AR, OR He. ky = Kk, HO +0 = OH + Om WATER + ONYGEN ATOM 72 BAL/DRY REACTION ORDER: 2. 300-2000 6.8118) | 0 07 18 HOt = te 4 on inex 7 HibaGces ATOM 72 BAL/DRY REACTION ORDER: 2. 300-2500] 9.3(13) | 0 05 15 NOTE: GIVEN k FACTORS ARE FOR HIGH T H,0.+ HO, = 08 + Hee WATER" fivROPERORYE FREE RADICAL 72 BAU/DRY REACTION ORDER: 2 300-800 | 2.8(+13) | 0 05 15 0.4 AH = Hy + HNO VATE + BOGEN FREE RADICAL 76 ENG REACTION ORDER: 2. 1500-2500] 1.0(:11) | 0.5 os 3.2 Gia. OH sO, WATER") METHYL, FREE RADICAL, 76 NER/PAR ‘REACTION ORDER: 2 rzrsims| 7.1¢12) | 0 1290021000 | 0.5 2.0 NOTE: TENTATIVE k VALUE Woe w= Hy OHM vATER 72 BAU/DRY REACTION ORDER: 2. M: 10 | 2000-6000} 2.2(+16) | 0 ot NOTE: Weft: HyO(1.0). ky = Kk Ys ar | 2000-6000] 1.3(415) | 0 0.5 2.0 Ax(0.06) Ms Ng | 2000-6000] 3.5(+15) | 0 0.5 2.0 Na(0.16) Hag, +H» ie vindoss venSutoe?s avonocey sow 72 BAU/DRY REACTION ORDER: 2. so0-s0 | 1.7(412) | 0 roo0i2s0 [0.5 2.0 Og. + 08 Hg + HO AiybROGEN PERORIDE 7 HYDROXYL FREE RADICAL 72 BAU/DRY REACTION ORDER: 2. 300-800 | 1.0(:18) | 0 s1siso fos 1.5 HO, 2M +O +O + "HYDROGEN PEROXIDE "2, BAU/DRY REACTION ORDER: 2. Ms Nz | 700-1500 1.20(+17) | 0 22000-1000 J0.8 1.8 NOTE: k PACTORS CHANGING TO: f= 0.5; F = 2.0 AT 1500K. S40, = 90+ 0 SUEFUR ATON 4 OXYGEN woLECULE 76 BAU/DRY REACTION ORDER: 2. 20-450 | 1.a(s12) | 0 os 1s S tiie > Sis Ht SUErUR TOW s wYOROGEN WoLECULE 76 BAL/DRY REACTION ORDER: 2. 298 Lacy | - - Jos as NOTE: ky = Kk 78 wens 2.s(s12) | 0.5 | 13640 SOK = so SULFUR ATOM + HYDROXYL FREE. RADICAL 75, BEN/GOL REACTION ORDER: 2. 6.a(41) | 0.5 °Table of Arrhenius parameters for chemical reections occurring combustion—Continued Chesical reactions 7K 7 3 Fk] & factors Gan [fF Ss oh. SHs0 SULFUR ATOM WYDROXYL FREE, RADICAL. 75 BEN/GOL REACTION ORDER: 2. 1.3(+12) | 0.5 | 12700 StS. = S48 sUfrua aTéu . “SvLUR DIVER 75 BEN/GOL REACTION ORDER: 2. 6.) | 0.5 ° 0+ S40 SULFUR_ATON' SULFUR WoNOxIDE 75. BEN/GOL REACTION ORDER: 2. 6.3(¢11) | 0.5 | 11500 0. 804s ‘SULFUR ATOM + SULFUR NONOKIDE 75: BEN/GOL [REACTION ORDER: 2. 6.3(m) | 0.5 ° StH» SpeH ‘SULFUR ATOM’ ERCAPTO FREE. RADICAL 75 BEN/COl REACTION ORDER: 2 6.341) | 0.8 o St SH» shes SULFUR ATOM NERCAPTO FREE, RADIC 75 BEN/GOL REACTION ORDER: 2. 6.) | 0.5 | 4000 Shp = NS 4K SUfrUR ATOW's NITROGEN NOLECULE "75: REN/COL REACTION ORDER: 2 4.0(412) | 0.5 | 5200 S440 $048 ‘SULFUR, ATOM NITROGEN OXIDE. (NO) 75. BEN/GOL REACTION ORDER: 2. 4.01 | 05 | 17260 S40 + A840 'SULEUK_ATOM + NITROGEN OXIDE, (NO) 75: BEN/GOL. REACTION ORDER: 2. aog2) | 0.5 | 17465, Sim shen SULFUR ATOW's TNIDOGEN FREE. RADICAL, 75 BEN/COL ‘REACTION ORDER: 2. 6.30) | 0.5 | 4000 S 4M XS 4H SULFUR ATOM s IMIDOGEN FREE RADICAL, ‘75 BEN/COl. REACTION ORDER: 2. 6.3m) | 0.5 ° SHS = Spt SULFUR ATOM NITROGEN SULFIDE(XS) 75: BEN/G REACTION Roe 2.0(41) | 0.8} 10870 + IS = 38.4.8 SULFUR ATOM} NITROGEN SULFIDE(NS) "78. BEN/CO. REACTION ORDER: 2 6.agn) | os ° 75: BEN/COL [REACTION ORDER: 2. 4.0(+12) | 0.5 | 66530 Sim = +0 ‘SULFUR. ATOM + CARBON NONOXIDE 75 BEX/COl. REACTION ORDER: 2 1.3412) | 0.5 | 37600 Sta = sic SULFUR ATOM WETHYLIDYNE FREE RADICAL 75 BEN/COl. REACTION ORDER: 2. 6.31) | 0.5 | 4000 Sich = 4H SULFUR ATOM y+ NETHYLIDYNE FREE RADICAL 75 BEN/COL REACTION ORDER: 2. 6.30) | 0.5 o S408 = s+ SULFUR_ATON's CARBON NONOSULEIDE. FREE. RADIC rez) | os | 046s "75: BEN/GOL. REACTION ORDER: 2.‘Table of Arrhenius parameters for chemical rections occu ined Ghesical reactions 7% a z Tt] & factors Gay [VF SiG - Ors ‘SULFUR, ATOM’ CARBON NONOSULFIDE. FREE. RADICAL 75 BENG REACTION ORDER: 2. 63cm) | 0.5 ° SHS eM = Oe ‘SULFUR ATOM - EARBON NONOSULFIDE FREE RADICAL 76. BAL/DRY REACTION ORDER: 3. 1800-8700] 8.7(418)] 0 ao fos 1.5 NOTE: ky = Kk S4Sp = Ses 68 ‘SULFUR ATOM + CARBON DISULFIDE 76 BAUIORY REACTION ORDER: 2. 208 scm} = - fos 1s S 4005 = Ss. + oo ‘SULFUR ATOM + CARBON OXIDE SULELDE 76 BALIORY REACTION ORDER: 2 230-2600] 1.7(412) 2osor230 | 0.3 3.0 SiO S46 ‘SULFUR, ATOM + CYANOGEN FREE, RADICAL, 75-BEN/COL REACTION ORDER: 2 2.0412) | 0.5 | 32010 St ~ aN ‘SULFUR ATOM + CYANOGEN FREE RADICAL 78 BEN/COL REACTION ORDER: 2. 6.aGn) | 0.5 ° SiG - +e ‘SUEUR ATOM's “CARBON DINER 75 BENIGOL REACTION ORDER: 2. 6.3(411) 5 ° S 4 Cllecl — ey=claces ‘SULFUR ATOM” ETHYNE 2 KER/PAR REACTION ORDER: 2. 28 nen |= - S 4g ey-CHgCHS ‘sulfur drow. ETHeNe "72 KER/PAR REACTION ORDER: 2. 298 sagen) | - = S 4 igCoCH — ey-(Cll)CsCiS SULFUR ATOM 4“ T-PROPINE 72 KER/PAR REACTION ORDER: 2. 298 naga) | = S + yCHeClly = cy (Cg) CHCH,S SULFUR aTOu + 1SPROPERE 2 KER/PAR REACTION ORDER: 2. 298 5.8(412) Kk,oe: 6.9 | 298 a NOTE: eae? S + Clig=CHly S*CD) sc = ey-(CH,)CICH,S stein afow (5) + .“peopede 72. KER/PAR, REACTION ORDER: 2. k/kyee: 1.7 | 300 : = : NOTE: kewe? SCD) + ClgsClly + C=0Hy = y=(CH)C=C(CHIS SULFUR ATO ¢ 2°BiTyNt 72 KER/PAR REACTION ORDER: 2. 208 rsensy |= - S 4 GiprcHaNc, e-(GlacHnCHCH,S suufur avow + 1,3-BUTADIENE, 72 KER/PAR REACTION ORDER: 2. 208 6.o(s13) |= - S GL Gcllcl, + ey-(Citcit) CHS SULFUR ATOM 2 1-BUTENE 72. KER/PAR REACTION ORDER: 2. 298 9.3(412) Kkgge? 10.0) 298 E NOTE: kege? S + Clay S + cie-CHgCH-ClcH, ~ ey-(Cit,)CHCH(CHg)S SULFUR ATOM + cls-2-BL TEN 72. KER/PAR REACTION ORDER: 2. 298 1.413) Kk,oe? 16.0) 298 Sy NOTE: kag! S + Cipla‘Table of Arrhenius parameters for chemical reactions occurring in combuston—Continued Ghesical reactions —————~—~S*~S:SR 7 a Fit | factors dinky | fF S + trans CH,GH-GHCH, = _ey= (Cig) CIOH(AI,)S SULFUR ATOM + trans-2-UTENE ‘2 KER Pak REACTION ORDER: 2 zoe | nacstsy |= Wier: 20.0 290 e 5 5 NOTE: keer? S + g=Cly S 4 (ClgdaC-Oe cy (Gly) COGS SULFER?ATON”s 1-PROPENE? 3-WEFiYL 72 KEPAR REACTION ORDER: 2 298 003) |= Kk, ge: 50.0 298 ei NOTE: koe? S + Clase SCD) (Cla) aCeCll, = ey (CHa) 00H, SULFUR ATON'('0)"+ 1-PROPENES 3-4 72 KER/PAR REACTION ORDER:"2. K/k,ge: 3.5. | 300 S - - NOTE: kyae? SD) + GlyoClly S + Ciy(CHa) OFC = ey-CH (Clg) CHOH,S SULFUR ton > 1-PexrENE 7 KERUPAR REACTION ORDER: 2. 298 aagiy | - = 8 FGCU) Oy yO, cH CCG) CHS tutte -lurine”a-uBmnfc 72 KPA REACTION one: 2 we | ray | - - S + (Cle) sC-CHCH, = cy =(CH) ,CCH CHR) SUCRUR?ATON = 2-BUTENE, 2-4ETHYL 72 KER/PAR REACTION ORDER: 2 298 6.50418) 56. | 298 ” NOTE: kyge S + Cllg=Clty S + (GilraC=C(CHig)a = cy~ (Cll) a0Ci CH) 2S ‘SULEURATON +“2=BUTENE, 2,3-DIMETHYL 72 XER/PAR REACTION ORDER: 2. 298 5413) | - - Se £0 + $4 80 ‘SULFUR DIVER + OXYGEN ATO 75, BEN/COL REACTION ORDER: 2. oan | 05 0 Sp tH = $2 SH ‘SULFUR DINER HYDROGEN ATOM 75 BEN/GOL REACTION ORDER: 2. 7.91212) | 0.5 | 8355 SptS = S45, SULFUR DIMER? SULFUR ATON 75 BENCOL, [REACTION ORDER: 2. 6am | 05 ° Sp iN Sins SULFUR DIVER = NITROGEN ATOM 5 BEN/GOL REACTION ORDER: 2, 6.340) | 0.5 | 4000 Eo = S$ scs SULFUR DIMER > CARBON ATO "75 EN/COI. REACTION ORDER: 2. es) | 0, S040» 0% so SULFUR NONOXTDE: + OXYGEN ATOM 75 BEN/COL, REACTION ORDER: 2. 6.3m) | 0, S040 - S40, SULFUR NONOXIBE + OXYGEN ATON 75 BEN/COL REACTION ORDER: 2. 2.0m) | os | 2770 S04 02M = StH SULFUR WONOXTDE + OXYGEN ATO 76 BAUIORY REACTION ORDER: 3, 298 6.70413) |= - for 1a S040, 80. +0 SULFUR WONOSIDE + OXYGEN WOLECULE 76 BAL/DRY REACTION ORDER: 2. soar 4.5411) | 0 32508590 0.3 1.7 S024 = 04 SH SULFUR NONOXIDE + HYDROGEN ATOM 75, BEN/COL REACTION ORDER: 2. 6.341) | 0.5 | 19930 31‘Table of Arthenius parameters for chemical rections occuring in combuttion—Continued Tt | & factore Gam [tr Chemical reactions 7K 4 o SPR = SoH SULFUR MONOXIDE. + HYDROGEN ATOM 75 BER/COL REACTION ORDER: 2. 4.0(12) | 0.5 | 11200 S048 = 045, SULFUR MONOXIBE + SULFUR ATOM "75: BEN/COL. REACTION ORDER: 2. 6.31) | 0.5 | 11500 S048 = 8450 SULFUIL MONOXIDE. + SULFUR ATOM "75: BEN/COL. REACTION ORDER: 2 6.) | 0.5 ° SO4N = 02 ns SULFUR MONOXIDE. + NITROGEN ATOM 75 BEN/COL REACTION ORDER: 2. roca) | 0.5 | 8256 SEN = S480 ‘SULFUR MONOKIDE + NITROGEN ATOM 75, BEN/COL. REACTION ORDER: 2. 6.31) | 0.8 | 4000 EC = 0468 ‘SULFUR YONOXIDE. + CARBON ATOM 75 BEN/COL REACTION ORDER: 2 6.3m) | 05 ° Sec. sso SULFUR MONOXIDE. + CARBON ATOM 75 BEN/COL REACTION ORDER: 2. 63cm) | 05 ° +0 = 904 *siufun onourbe ? oxvcen aTow 76 BAU/ORY REACTION ORDER: 2. 4o-a10g 1.3¢+14) | -0.5 | 9900 O38 17 NOTE: ky = Kk S05 4 HM = S02 ‘SULFUR DIOXIDE +#YDROGEN ATOM 76 BAU/ORY REACTION ORDER: 3. 1660-2124 5.11415) | — - 05 15 0g 4 We = SOq + Ol slum ofoxtDe } Mororetowy. Ree nupicat 74 10 REACTION ORDER: 2. 300 8.248) | - - joo re NOTE: RATIO DATA VERSUS kref FOR REACTION Hog + WO, = Hats + 0, SH sO + $4 Of WERCAPTO FREE RADICAL + OXYGEN ATON 75; BEN/GOL REACTION ORDER: 2. 6.341) | 0.5 | $000 SH +0 + 804 i WERCAPTO FREE RADICAL + OXYGEN ATOM 75 BEN/GOL REACTION ORDER: 2. 6.3m) | 0.5 ° SHH = 84 te NERCAPTO FREE"RADICAL + HYDROGEN ATOM "76 BAU/DRY REACTION ORDER: 2. 298 asia) |= = fos as Shy Ho Hy SH MeRcaPTO FREE RADICAL + HYDROGEN 4TOMW 75 BEN/COL REACTION ORDER: 2. 6.31) | 05 ° Hes shy ichcaPro Ree eantcaL + suuguR_ATOW 7S BEN/COL REACTION ORDER: 2. 6.31) | 0.5 ° SH 4S 2S 4 si NERCAPTO FREE RADICAL + SULFUR ATOM 75, BEN/COl REACTION ORDER: 2. 6.9¢n) | 0.5 | 4000 SH 4 SH aS +5 fiencarro Fie” RADicaL 76 BAU/DRY REACTION ORDER: 2. 295 7.00812) | - - fos 1s SHAN = HENS. WERCAPTO FREE RADICAL + NITROGEN ATOW 75 BEN/CO. REACTION ORDER: 2. 6.) | 08 | 408 32.‘Table of Archenius parameters for chemical reactions occurring in combustion —Continued Treleal reactions ™ Ta Ti tore wo [ft ways sm fckero rit manta. + wrrocen Tow DNL TEACHON Oe: 2. sau | 0s | ovo sic iG fro rie manta + cans aTow SNe ctTON wet: 2. saum | os | o siic sia icfcaro rie nuoiea. + campy arow Not ectION oom: 2 socom | 0s | a0 HS tty = eo Sufotdoeh sited ozone Me nn reaction onan: 2 we | sone | - - for HS tH = sy wotocds Sud + moroce sou euro ction omen: 2 wos | 1.802) | 0 won os is HS. 0H = ss 0 onto siLpioe mmpro, FREE ADL, ve HURT AEITION ODER 2 eso | sauna) | 0 ono for as nore: KRIS cmncinc 0: FE OLBe FT 0K. He Gly. = St wontlin Suftog Sera. MEE motca, Me Rea TEACHING: 2. soo-«ao} acon) | 0 | a0essiso fos 2.5 sore; TENEAHVE ALE, Widen 04 ric st $ Savcen stow nS na eacrion ome: 2. a % | 200-40 | oan | os | 0 fos as Neg = 040 faa non + oxvoen vouecaLe is muon ENN mgt 2 soo-soo] 6.19) | 1.0 | signs for as nore: L'rRtORS cmncrnc 0: Corse Fee A S00K. Nea Mn rho tt$ Fomocen ano pia REACTION OER: 3. 1300-2500 2.51 | 0s | oso Ne = Mt ‘athroGe tri svonocey woscue moO ACTION ont: 2. asin) | os {700 8401 = N08 inode 04" woRoX, FEE ROICAL Saco EACH a ssa | os | o Net = seo aoe N+ RORONTL FREE RADICAL eB REACTION Omen: 2. rae | os fares WO A NO fade snot" NNOXL FEE RADICAL Tea REACTION Oko: 3. rxoo-2s00| 1.00615) | os | 0 Ny = Ms Op ftfocén Mou Srvonoretor. FREE auotcaL "0B eter ono rs0n-2500| 1.0001) | 0 ois00 Jos 3.2 Whgy = as vifaoden andy + son oie Te ae feactiow oer: 2 esa | os | 500 Neg was tuoi nda + usu vox 1S BOL Erion nen: 2 eau) | 0s | a0 W480 = Mg 40 staan + suum vooxtpe toon Merton owner: 2 ruta) | 0s | ase 33‘Table of Archeniue parameters for chemical reactions oocurring in combustion—Continued Ghenical reactions 7K 4 a Tt | factors Gnky |e F Nest = Ms NITROGEN ATOW + MERCAPTO FREE RADICAL, 75, BEN/COL REACTION ORDER: 2. 6.3 | 0.8 | 9060 St NS pt NITROGEN ATON + MERCAPTO FREE, RADICAL "75 BEN/GOL. REACTION ORDER: 2. 6. | 05 | aos Nene w= nem NITROGEN ATO 73 BAL/DRY REACTION ORDER: 3. Mz Nz | 100-600] 3.0(:14) | 0 = 50050 Jos 1.5 NOTE: K FACTORS RANGE: 200-600K, BUT NIGHT INCREASE AT LORER T'S, NaN = Ne aN NITROGEN ATO + NITROGEN MOLECULE 75, BEN/COL REACTION ORDER: 2 6.34 | 0.5 | 4000 NANO = Ne 40. NITROGEN ATOM + NITROGEN OXIDE(¥O) 73 BAU/ORY REACTION ORDER: 2. 300-5000} 1.6(+13) | 0 0 fos 12 NOTE: K FACTORS CHANGE TO: ¢ = 0.5; F = 2.0 ABOVE 2000K. NaN = NON [NITROGEN ATOM + NITROGEN OX1DE(N0) 75 BEN/COL REACTION ORDER: 2. 6.91) | 0.5 | 4000 N+ Mg = No + 09 itilocen Afot +*iTROGEN OXIDE(NO9) 76 EXC REACTION ORDER: 2. 1300-2500 | 1.0(+12) | 0 021500 N+ Nop = NO + NO NITROGEN ATOW + NITROGEN OXIDE(NO.) 76 ENG REACTION ORDER: 2 1500-2500 | 4.0(+12) | 0 o:1500 }0.2 5.0 N eNO = N00 NITROGEN AFON’+ NITROGEN OXIDE(NO,) 76 ENG REACTION ORDER: 2 1500-2500 | 5.0(+12) } 0 021500 |0.5 2.0 NEMO = NOY Ny NTFROGEN ATOM + "NITROGEN OX1DE(N_0) 16 ING REACTION ORDER: 2. 1500-2500] s.0(+ 8) | 0 50002500 0.3 3.2 NM Ne tl NETROGEN ATOM + INIDOGEN FREE RADICAL. 75 BEN/COL REACTION ORDER: 2 63am | 05 ° NAME NN NETROGEN ATOM + TNIDGEN FREE, RADICAL. 75 BEN/COL REACTION ORDER: 2. 6.31) | 0.5 | 4000 N+ HNO = Ht m0 [NITROGEN ATOW 7 NITROSYL HYDRIDE. 76 ENG REACTION ORDER: 2, 1300-2500] 5.0(:10) | 0.5 | 15002500 N4ANO Nis No NETROGEN ATOM + NITROSYL HYDRIDE 76 ENG REACTION ORDER: 2. 1500-2500] 1.00411) | 0.8 | 10002500 NaNS = Ne 4s. [NITROGEN TOW" NITROGEN SULFIDE(NS) "75, BEN/COL. REACTION ORDER: 2. 6.3m) | 05 ° N ANS = 85 4 NITROGEN ATOM + NITROGEN SULFIDE(NS) 78 EN/COL, REACTION ORDER: 2. 6.3(01) 4000 Ni . ne NITROGEN ATOM + CARBON MONOXIDE. 75 BEN/GOL REACTION ORDER: 2. s.o(12) | 0.8 | 57300 Neco. 40 IKITROGEN ATOM + CARBON MONOXIDE, "75 BEN/GOL, REACTION ORDER: 2. 3.2012) | 0.5 | 38800‘Table of Arrhesive parameters for chemical reactions oocurting in combustion—Continued ‘Ghenical reactions 7k 4 e Ft | & factors dinky | t Ney = N0: NITHOGEN ATOM + CARBON DIOXIDE 76 ENG REACTION ORDER: 2. 1500-2800 | 2.00(:11) | 0.5 | 1800810000 Jo.1 10. Nek. Mc NITROGEN ATON + METEYLIDYNE, FREE. RADICAL 75 BEN/GOL ‘REACTION ORDER: 2. 1.01412) | 0.5 | 6995 Neck = eH [NITROGEN ATOM + METRYLIDYNE, FREE RADICAL, 75 BEN/GO ‘REACTION ORDER: 2. 6.30) | 0.5 ° Ns iy = Nas at NETROGEN ATOM + METHYLIDYNE. FREE RADICAL 76 ENG ‘REACTION ORDER: 2. 1500-2500 | 6.8¢:11) | 067 | 2040022500 |o.3 3.2 N+ co = 04 HCY NITROGEN ATOM = FORNYL FREE RADICAL, 76 ENG ‘REACTION ORDER: 2. 1500-2500] 1.0(414) | 0 ° Nove: k ESTIMATED. N+ cl Ni + 00 NITROGEN ATON’ + FORNYL, FREE, RADICAL, 76 ENG REACTION ORDER: 2. 1500-2500 } 2.0(111) | 0.5 | 100022500 N 4 cho. = Ni + weno NITROGEN ATOM + METHOXY FREE. RADICAL 76 ENG REACTION ORDER: 2. 1500-2500 | 1.0(+14) | 0 01500 Neo = css NITROGEN ATOM + CARBON MONOSULFIDE FREE RADICAL 75 BEN/COL REACTION ORDER: 2. 4.0(412) | 0.5 | 37200 NEG = iS NETROGEN’ATON + CARBON WONOSULFLDE.PREE RADICAL 75 BEN/COL REACTION ORDER: 2. a.a(12) | 0.5 | 160 NEG = Ne NITROGEN ATON + CYANOGEN FREE, RADICAL, 75 BEN/GOL REACTION ORDER: 2. 3) | 0.5 ° N4G = ic NEFROGEN ATON + CARBON DIMER 75 BEN/GOL REACTION ORDER: 2. 6.341) | 0.5 ° N+ GHecth = calla NITROGEN ATO} ETHYNE 72. KER/PAR REACTION ORDER: 2. “0 2069) | - - Nove: UPPER LIMIT. N Gigi, ~ products NITMOGER aTow” + ETHENE "72 KER/PAR REACTION ORDER: 2. 320-850 | 2.0(+10) | 0 353 N 4 CHgCaC products NITROGEN aTON? | 1-PROPYRE 72 KER/PAR REACTION ORDER: 2. 320-550 | 6.9(+10) | 0 145 Tigge: 6.5 | 485 S - Z N+ chech N+ GhyGtecH = products NITROGEN AoW +"1-PROPENE "72 KER/PAR REACTION ORDER: 2. 320-550] 1.2(+11)| 0 655 Whzge? 2.8 | 435 5 a 2 NOTE: kee? N+ Cy*Cly N + CgCHACeCH + products NITROGEN ATOW + T-BUTHNE. "72 KER/PAR REACTION ORDER: 2 szo-sso | 3.s(s11) | 0 us ‘Wh,ee? 13.0 435 = - a NOTE: get N+ Clic‘Table of Archenius parameters for chemical reactions occurring in combustion—Continued Gheaical reactions TH 4 2 TR | & factors Gan | ft Ny ciigonock, — products NITROGEN drow ="2°BUTINE 72 KER/PAR REACTION ORDER: 2. szo-sso | 1.9¢611) | 0 926 Wig: 12.0] 435 * = - NOTE: ge? N+ CHach Ne ow. products sttdocen sto 1 SERA teNe 72 KER/PAR ‘REACTION ORDER: 2. 340 3.5(s10) | - 2 N+ ClycHeclecl, = products witocEx arom + a-Kireve 72 KERIPAR REACTION ORDER: 2. sz0-sso | 1.6411) | 0 660 Whig 435 = a NOTE: Kyag? N+ CpG, N+ cia-ciGecich, ~ products INITHOGER ATOM oie-2°BUTENE 72 KER/PAR REACTION ORDER: 2 sz0-sso | 2.3411) | 0 995 as a - . NOTE: koe? N+ Cllg-Oly N+ trans-CH,CH-CHGH, + products NITROGEN ATOM + tfans-2°BUTENE. 72 KER/PAR ReAcTION omen: 2, | | g30-so0 | s.acsan) | 0 1055 NOTE: byoe? N+ Clea an N+ (Gi),CeGa = products niTROGEN aTou + .PHOPENE, 2-ETINL 72 KERIPAR AEACTION onDen:. 2 szo-sso | 7.810) | 0 aT Wines: 41 | 85 ei - - NOTE: Kjgg? N+ Ca=Cy N+ CyCHLCHACeCH + products nitiiociN frow + 1-rENTYNE ‘12 KER/PAR REACTION ORDER: 2. s20-ss0 | 3.011) | 0 10s Kikee 14.0] 485 5 - NOTE: poet Ne + CHaCH N+ (Ciig)_C-CHCH, + products iTaGcEN stows 2-nbTENE, 2-NETHYL- 72 KERIPAR REACTION ORDER: 2 s20-sso | 9.8(+10) | 0 483 Wh,ee! 3.5 | 35 e e z NOTE: Kygg? N+ Clly-Cy N+ CCH. cHacHaCaCH products naviocEN roi + 1-wexvie 72 KER/PAR REACTION oRDE s20-s5 | 4.1) fo 1233 14.0] 435 5 S = NOTE: kygg? N+ CHsCH Ce00,C, = products SRTOGEN aro sx ‘72 KER/PAR REACTION ORDER: 2. szosso | sacs) | 0 1102, K/k,ge: 14.0) 435 e a . NOTE: koe! N+ CHa N+ (Gia)eCeCiClia)s, = products NITROGEN” ATON's72-BUTENE, "2, 3-DINETAYL— 72 KER/PAR REACTION ORDER: 2. 320-550 | 1.740) | 0 0 Kkge: 3.5 | 435 es 2 - NOTE: kee! N+ Cl MeO = 4 N0 ETROGEN MOLECULE + OXYGEN ATOM 73 BAU/ORY REACTION onDER: 2. 2000-5000] 7.6(+13) | 0 se000e150 0.8 2.0 Nove: ky = Kk Mas O¢N ~ NOs Hntaockn iousttni + oxvcen «Tou 73 BAU/DRY REACTION oRDER: 3. Mz Ar {1300-2500 1.4(s13) | 0 roso0:1500 }0.7 1.5Teble of Arthenius parameters for chemical reactions occuring in combuntion—Continued Ghenical reactions 7 7 2 Fk] k factora (Gan [ft X20 + 0 WOLECULE + OXYGEN MOLECULE ‘Ta BAU/DRY REACTION ORDER: 2. 1200-2000 | 6.8(+13) | 0 5200:2000 ]0.4 2.5 Nove: ky = Kk Ne tH Ne nh [NITROGEN WOLECULE + HYDROGEN ATOM 75, BEN/GOL REACTION ORDER: 2. 2.013) | 0.8 | 75945 Met S = NG NS NITROGEN WOLECULE + SULFUR ATOM 75 BEN/COL REACTION ORDER: 2. 4.0(412) | 0.5 | 55200 th = NG NITROGEN MOLECULE + NITROGEN ATOM 5 BEN/COL REACTION ORDER: 2, 6.3) | 0.5 | 4000 c+ Ns ay ‘NITROGEN WOLECULE + CARBON ATOM 75 BEN/GOL REACTION ORDER: 2 1.3012) | 0.5 | 22750 No + cH =X + HON NITWOGEN MOLECULE + METHYLIDYNE FREE naDical, 76 ENG. REACTION ORDER: 2. 1500-2500 | 1.0(:11) | 0 9360 NOTE: REVISED ESTIMATE. No 4 GH = Ms cv NETROGEN MOLECULE + METHYLIDYNE PREE RADICAL 76 ENG. REACTION ORDER: 2. 1500-2500] 3.2(+14) | 0 46300410000 Nove: k ESTIMATED. No + Ci NH 4 HN NITROGEN MOLECULE + METHYLENE FREE RADICAL 76 ENG. REACTION ORDER: 2 1500-2500] 1.0(114) | 0 35280410000 Nore: k ESTIMATED. Nes M os NaN aw NETROGEN WOLEGLE 76 ENG. REACTION ORDER: 2 1500-2500] 4.0(421) | 1.6 | 132404500 73 BAL/DRY 6000-1500 3:7(421) | “1.6 f1s200:500 |o.3 3.0 W040 = 04 10 NITROGEN OXIDE(NO) + OXYGEN ATO 75 BEN/COL [REACTION ORDER: 2 6.34) | 0s ° Ns = N40, NITROGEN OXIDE(NO) + OXYGEN ATOM 73. BAU/DRY [REACTION ORDER: 2. 1000-8000] 1.5(+ 9) | 1.0 | 195008150 Jo.7 1.3 NOTE: k FACTORS INCREASING TO: f= 0.5; F = 2.0°AT 3000K. Kye ik NOLO EM = NOs sw NITROGEN OXIDEGNO) + OXYGEN ATOW 73 BAU/DRY REACTION ORDER: 8. M: 02 | 200-800 | 1.1(415) | 0 940250 }0.8 1.2 NOTE: Weff: 0g(1.0) AT 297K as ar | 200-500 | raga | 0 -swrs0 foe 12 (0.1) AT 297K 200-500 | 6.7(:15) | 0 -ows0 }0.8 1.2 H0(6.1) AT 297K 200-500 | 5.5(+15) | 0 ows ]0.8 1.2 1,0(5.0) aT 297% 200-500 | 2.9(115) | 0 -owss0 fos 1.2 SF,(2.6) AT 297K 200-500 | 1.5(+15) | 0 ows [oe 12 Ng(1.4) AT 297K 200-50 | 2.34415) | 0 owis0 Joe 1.2 N0(2.1) AT 297K 200-500 | 2.8(:15) | 0 -swosso foe 1.2 (09(2-1) AT 297K 2o0-soo | 2.4(115) | 0 900250 0.8 1.2 g(2.2) AT 297% 200-500 | 2.4(+15) | 0 -owss0 0.8 1.2 (2.2) aT 297K 37‘Table of Arsheniue parameters for chemical reactions occurring in combustion—Continued Ghenical reactions 7k 7 7 Tk | & factors Gam [fF No +0, +0. fntiocds Utfokdtoy + oxen vouscuns 73 BAU/DRY [REACTION ORDER: 2. soo-sso } 1.7412) | 0 23400 08 13 NOTES ky = Kk NO 4 09 irtfoci Oxfod8) + ozone 73. BAU/DRY REACTION ORDER: 2. 200-350 | 8.9¢:1) | 0 rssoris0 [os 1.5 NOH = 05 NH NITROGEN OXIDE(NO) + HYDROGEN ATOM 75 BEN/GOL REACTION ORDER: 2. s.0(412) | 0.5 | 38200 NOH NG ivTocer’oabteso) + mvonocsn sTou 75 BEN/GOL ‘REACTION ORDER: 2. 2.5(s12) | 0.5 | 2460 NO HEM = HNO GH NITROGEN OXIDE(NO) + HYDROGEN ATOM 73 BAL/ORY REACTION ORDER: 3. 5.4(215) | 0 -soor100 Jos 1.5 76 ENG sc) | 0 “so08is0 Jos 20 Noes = 04K NITROGEN OLIDE(NO) + SULFUR ATOM 75 BEN/COL IEACTION ORDER: 2. 1.02) | 0.8 | 17465 Noes - Ny s0 NITROGEN OXIDE(NO) + SULFUR ATOM 75 BEN/COL REACTION ORDER: 2. 4.oqn | 0s | 17260 NOdN = 08 N, NITROGEN oX1DE(NO) + NITROGEN ATOM 78 BAU/ORY REACTION nDER: 2. 300-5000] 1.6(+18) | - = fos 12 NOTE: FACTORS CHANGING TO: f= 0.5; F ABOVE. 2000K NOG N = Ns NO NITROGEN OXIDE(NO) + NITROGEN ATOM 75 BEN/COL TEACTION ORDER: 2. 6.311) | 0.5 | 4000 NO 4 NO srtagcn ia) + OXYGEN MOLECULE 72, KO REACTION ORDER: 2. 1870-4800) 1.3(414) | 0 seocorm20 o.7 1.5 NO 4 NO N04 0 IMITROGEN OKIDE (v0) 73 BAU/DRY, REACTION ORDER: 2. 1200-2000] 1.3(412) | 0 sat00si500 Jos 2.0 N04 N04 Og irttodehoxioetn6)*, Stvcen vouscuue 73 BAU/DRY [REACTION ORDER: 3. 213-660 | 1.2049) | 0 -ssor00 Jos 1.5. NO 4X 0 + 2 OXDDE(ADY + NITROGEN OXIDECNOA) 6 ENG ‘REACTION ORDER: 2. 1500-2500 | 1.0 (412) | 0 30200 0.01 100, 0 = 8, + 1 Antnbcks°dudeo§ + Nrocen oxroE«so,) oY NOLES 73 BAU/DRY REACTION ORDE 300-500 | 2.91+ 7) | 0 4001500 [0.8 2.5 NO NO, N0, varadeat ott" "+ NITROGEN OXIDE(NO,) ‘REACTION ORDER: 2. 290-se7 | 1.5414) | 0 meses [0.7 1.4 NO No = Artfboek oXtBa(ndf + wemocey oxsoey, 0) 76 BNC reaction ofoea ORDeR: 2. 1500-2500] 2.0(:14) | 0 25000 oO. 10 N04 HNO sao tein + NITROSTL sYORIDE REACTION ORDER: 2. 1500-2500] 2.0412) | 0 1300022500 J0.5 2.0‘Table of Arthenius parameters for chemical reactions occurring in combustion —Contnued Chenical reactions 77k 7 3. | factors Guy | f Noe C Oy cy NITROGEN OXIDE(NO) + CARBON ATOM 75 BEN/GOL, [REACTION ORDER: 2. 6.3) | 05 ° Nore + Ny oD [NITROGEN OXIDE(NO) + CARBON ATOM 75 BEN/GOL, REACTION ORDER: 2. 6.341) | 0.5 | 4000 NO + cH = 0.4 Hey NITROGEN OXIDE(NO) + METHYLEDYNE. FREE, RADICAL. 76 ENG ‘REACTION ORDER: 2 1500-2500 | 2.0(+12) | 0 £1000 NOTE: KESTIATED. NO + cH = Ns cho NITROGEN OXIDE(NO) + METHYLLDYNE FREE. RADICAL 76 ENG REACTION ORDER: 2. 1500-2500 | 1.6(:13) | 0 500018000 NOTE: i ESTIVATED. NO Cle N+ HCHO NITROGEN OXIDE(NO) + METHYLENE FREE RADICAL 76 NG REACTION ORDER: 2. 1900-2500] 1.6(412) | 0 3500:2000 Nove: ke ESTIMATED. NOs CHO + BNO + co NITHOGEN OXIDECHO) + FORMYL, FREE RADICAL, 76 NG REACTION ORDER: 2. 1500-2500] 2.00111) | 0.5 | 10002500 |0.3 3.2 NOs ON + 00 NITROGEN ORIDE(NO) + CYANOGEN FREE RADICAL. 76 ENG REACTION ORDER: 2. 1500-2500 | 3.2411) | 0 012500 [0.3 3.2 NO+M = Ns Ow NITROGEN OXIDE(N0) 76 ENG REACTION ORDER: 2 1500-2500 | 4.0(420) | -1.5 | 7550022500 Jo.3 3.2 NOTE: Ms Ar, OR No OR Op. GIVEN FITH CAUTION, 72 KON w: Ar | 3000-8000] 8.00(+ 2) | -1.5 | 75500 NOg, #0. NO + Oo ‘NITROGEN OXIDECOg) + OXYGEN ATOM 73 BAU/DRY REACTION ORDER: 2. 300-850 | 1.013) | 0 so0:100 |o.8 1.5 76 ENG 1500-2500] 1.0413) | 0 So0:250 0:5 2:0 NOs +04 Ko NOy 4H NITROGEN OXIDECROg) + OXYGEN ATOR 73. BAU/DRY REACTION ORDER: 2. Ms Np | 295 aga) | - : o4 25 NOTE: LIMITING HUGH PRESSURE k REACTION ORDER: 3. 295 2.8G16) | - - 04 25 ky (LOW PRESSURE) Nog 405 ~ NOs + Og ‘wiTRdcen oxiBE(NOS) + OZONE 73, BAU/DRY REACTION ORDER: 2. 286-302 | 5.90412) | 0 3500 05 2.0 Nog 4 = NO + o8 "NITROGEN OXIDE(NO,) + HYDROGEN ATOW ‘73 BAU/DRY REACTION ORDER: 2, 298-630 | 3.5(414) | 0 140500 0.5 1.5 NOTE: ke FACTORS CHANGING TD: f = 0.5; F = 2.0 AT 638K, 76 ENG 1500-2500 | 3.2(:14) | 0 750:500 |0.5 2.0 Nop. + OH 4M > HNO, + M ‘NITROGEN OXIDE(NOg) + BYDROXYL FREE RADICAL 73 BAU/DRY REACTION ORDER: 3. M: He | 00 s.0u17) |= - jos 16 Nog 28 2 0 + Nao 'NITROGEN OXIDEGNO.) + NITROGEN ATOM 76 ENG REACTION ORDER: 2. 1500-2500} 5.0(112) | 0 05 2.0 Nog +N + Oa + Na NITROGEN O€1DECHOg) + NITROGEN ATOX 76 ENG REACTION ORDER: 2. 1500-2500 | 1.0(412) | 0 021500 ]0.5 2.0 Noa, 48 -» NOs NO NITROGEN OKIDE(NOg) + NITROGEN ATO 76 ENG REACTION ORDER: 2. 1500-2500 | 4.0(:12) | 0 os1s00 [0.2 5.0 39‘Table of Arthenius parameters for chemical reactions occurring in combustion—Continued Ghesicel reactions TK 7 7 Tt] x factors dag | M0, 5 80 — 05 + Hao “wimoces oxoeexday + nrTaaces oxtne«¥o, 76 NG HEACTION ORDER: 2, 100-2500} 1.00412) | 0 | 3020 fo.o1 100. Nog + NO 05 NO + NOs NITROGEN @x1DE(N02) "+ NETROGEN Ox1DE(NO) TOXWGEN MOLEGLLE 73 BAUADRY REACTION ORDER: 3, 300.500 | 2.97) | 0 1002500 Jos 2.5 Nog 4 Mg N04 NO + 0p NITROGEN OXIDE.) 73 BAU/ORY REACTION ORDER: 2 00-2000} 2.0(412) | 0 o7 13 Note: K FACTORS INCREASING SLIGHTLY ABOVE, 1000 Nog 4 Og 4 a *ximmoteh Oxtaedbes * 73. BAU/ORT REACTION onoen: 3 2s0-350 | 111s) |o fom Jor 1.3 NOTE: CORRECTED i VALUE (PERSONAL cOMMLNTCATION HON DE. BAULCH TO\DR: RANPSON)s y= Kk Nd. Ny, = N04 NO nimoten ‘oxides + Nrwooen oxtnec¥0,) 73 BAU/ORY TEACTION ORDER: 2, sooeso | raat | 0 woios00 fos 2.5 Nog 4 Ny 4M nimotek Oxxoecd6oS £ Armnocen oxt0e(0,) 73 BAU/DRY HEACTION ONDER: 2. 300, 2.2) | - 04 25 ores LIMITING HGR PRESSURE ¥ WIS A Nag + NO MIXTURE REACTION ORDER: 9, 300 Lowey |= - fos 20 o(LOF PRESSURE). 1S A'NQ0y + NO MIRTLE. Ng | ME 20.» HNO NITROGEN OXIDE(NO,) + THTDOGEN FREE RADICAL 76 ING TEACTION ORDER: 2 1500-2500] 2.0(s11) | 0.5 | 25002500 [os 3.2 Ng $00 + 0 + on NITROCEK OX1DE(S0) + caRDON wonoxtDE 72 108 REACTION CROER: 2, sos00 | i912) | 0 — fasrasia85 Jos 1.9 76 ING 300-2500 | 2.00(:12) | 0 | 1s000=is00 |0:3 2.0 Nn X= 0 405 NITROGEN GkuDE( 0) 73 BAU/DRY evcrion onpen: 2. a: Ar [1400-2400] 1.1¢+16 | 0 | ss000¢750 Joe 1.3 M4 NO Np + NO ‘NITROGEN OXIBE(NO,) + NITROGEN OX1DE(NO) 72 HON EACTION ORDER: 2 ase-set | 1.50418) | 0 ues Jor 14 Nog + 0 +80 + 0, xlrtodia” axing) + Nfrmocex ox1pE(so,) 73 BAU/DRY REACTION ORDER: 2. 300-850 | 1.4¢+1) | 0 6001500 }0.4 2.5 Ng, 0 uimoden tuube(Mded { MrTROceN OxtDE(NO—) "72 BAU/DRY TEACTION ORDER: 2 300 zac | - - fos 2s Nome: LIMITING HIGH-PRESSURE Ky WIS A°N,0, + NO MIXTURE eke REACTION ORDER: 3. 300 rots) | - jos 20 Ko (WOR PRESSURE). WIS A'NGOg + NO MOAT. 1M. 1040, 4H 'nkmRocEN ox1de (Roy) 72 108 Reaction onoeR: 2, a: m0, | 500-1100] 1.9081) | 0 wosor110 foe 1.3 M040 Me imtocen babettoy + onreey stow 73 BRU/ORT REACTION ORDER: 2, 1200-2000} 1.0(316) | 0 | rsto0:2000 Jos 2.5 M040 30 4 N0 ‘NETHOGEN OXIDE(NO) + OKYOEN aTOW 73 BAU/DRT TEACTION omDER: 2 1200-2000} 1.0(:14) | 0 | r4ocoeis00 Jo.s 2.0 72 10 900-2300 | 3:6(113) | 0 | 13700 40“Table of Arshenivs parameters for chemical reactions occurring in combustion—Contnued Grenical reactions Tk 7 7 Tk | factors dup | NOW = Ny on NiTHocEN OFNDEC0) + HYDROGEN aTOW 73 BAU/INY EACTION ORDER: 2 100-2500 | 7.6(+18) | 0 re002500 |o.5 1.5 NOs NO $M NITROGEN OXTDE(N0) + HYDROGEN ATOM To ENG TEACTION ORDER: 2. 1500-2500] 1.0(611) | 0.5 | asto0s2500 Jos 3.2 NO 4 OF = Ne 4 Hog NITROGEN ORFOE(N,6) + HYORONYL FREE RADICAL 76 ENG REACTION ORDER: 2. 1500-2500 3.20418) | 0 1580 vores K ESTIMATED. NON = Ne 5 80 Niraocex OfnDECN,o) + NrTHOGEN xTOW To ENG REACTION ORDER: 2. 1500-2500] s.0(+ 8) | 0 so00s2so0 | 0.3 3.2 N04 NO Ne + Ng wirategoMfoi 8) + strane onpe,y0) 6 ENC TEACTION ORDER: 2 1soo-2500] 2.0(:14) | 0 [asi fo. 0, AO 4 0D hey sinloces otfoé 6) + cunow woxoxine 76 ENG REACTION ORDER: 2. 1500-2500] 1.0(611) | 0 | ro00081500 |o.s 2.0 MO tH Me OEM tocen Ofunecnz0) 78 BAU/DRY REACTION ORDER: 2. 1300-2500] s.0(+14) | 0 | 2900081500 }o.7 1.5 Nag 0g + NOp ‘Srrocen“ox1DEGN.04) 70° BEN/OTN REACTION ORDER: 1. 2ss.so | 1.0116) [0 00 Nags Mm Mg 4 Ng + Srinocen ottbe(s,0%) 73 BAU/ORY REACTION onDeR: 2. Mi Xy } 250-350] 2.5(417) | 0 sss0is00 0.7 1.3 Maly Mo Ny + NO, rintcss ottbe" (8,5 73 BAU/ORY EACTION ORDER: so-so | s.7¢1 | 0 [10600 Jos 2.5 Nove: LINETING HIGH-PRESSURE Ken ISA Nabe 1 80 MIXTURE ReACTION onde: 2 1.34419) | 0 9700 05 2.0 o(LOF PRESSURE). 15 A°NG0, + NO AIXTURE, M40 + Hs No Tntvocen’ ier RaDtcaL + OXYGEN ATOM 75 BENG EACTION ORDER: 2 6g) | 0. ° Ns 0 Ns of iipocey Fie naDIcAL + oxYGEN TOW 75 BEN/CO REACTION ORDER: 2. 6c) | 0.5 | 4000 Mis 0 4M 1N0 6 TtpOcen FREE RADICAL + OXYGEN ATO 76 BN TEACTION oaDeR: 2. 1300-2500] 1.0¢416) | 0.5 or2s00 [0.3 3.2 Mem wa a Fvtboce FREE RADICAL + wYOROGEN ATOM 75 BENVOOL REACTION ORDER: 2. sscmy | 0.5 ° Md Ne ty Futboce FREE"RADICAL + wvOHoGeN ATOM 5 BEN/COL ENCTION ORDER: 2 63cm) | 05 | 00 MES 0H Ny intboces Pads" ibrca. + wvotont, ete trea, 76 TEACTION ORDER: 2 1500-2500] 5.0(:11) | 0.5 | 00082500 [0.3 9.2 MS 0 — HNO + He Ttboces rate tabicat « waren 1500-2500] 1.0(s11) | 0.8 | 15002500 [0.3 3.2 76 ENG REACTION ORDER: 2 a‘Table of Arthenius parameters for chemical reactions occurring in combustion—Continued Ghesical reactions 7 a e Fk] & factors Gan jeer Mes Has INIDOGEN FREE RADICAL + SULFUR ATOM 75 BEN/COL REACTION ORDER: 2. 6.3Gm) | 0.5 o MESS = NG SH IMTDOGEN FREE RADICAL + SULFUR ATON 75 BEN/COL REACTION ORDER: 2 6.341) | 0.8 | 4000 NEN He Ne TMIDOGEN FREE-RADICAL, + NITROGEN ATON 75 BEN/COL REACTION ORDER: 2. 6.34) | 0.5 ° NEN Ne ML TWIDOGEN FREE RADICAL + NITROGEN ATO 175 BEN/COl REACTION ORDER: 2. 6.3¢11) | 0.5 | 4000 NH 4 NOs TMIDBGEN FRE NITOGEN ORIEN) 76 ENG REACTION ORDER? 2, 1500-2500] 2.0(411) | 0.5 | 250022500 [0.3 3.2 NH MH ty intbocin Fed, orca, 76 ENG REACTION ORDER: 2. 1500-2500 | 1.0(:18) | 0 ° 0.1. MC. Hy ov INIDOGEN FREE RADICAL + CARBON ATOM 75 BEN/COL REACTION 0 6.a(4) | 0.5 ° Misc = Ny GH {nIDOGEN' FREE RADICAL + CARBON ATOM 75, BEN/GOL REACTION ORDER: 2. 6.31) | 05 | 4000 NHL ON +N 4 HN INIDOGEN FREE RADICAL + CYANOGEN FREE. RADICAL, 76 ENG REACTION ORDER: 2. 1500-2500] 1.0¢:11) | 0.5 | 1000#25000 Nig 4 We Mo Ny AMIDOGEN FREE RADICAL, + RYDROGEN ATON 78 BAU/DRY REACTION ORDER: 3. M: Ar | 2000. 4-14) | 0 830022500 2.0 NOTE: ky = Rk Ny. $0 + Nip + OH ‘AIWONLA. + OFYGEN ATOM 78 BAU/DRY REACTION ORDER: 2. 300-1000 | 1.5(+12) | 0 30208300 0.5 1.5 4. Mle + Cl “ANWONTA¢ WETHTL FREE RADICAL "76 KER/PAR REACTION ORDER: 2. 350-650 | 1.0(:11) | 0 s100:500 Jos 1.8 NDg Gil. = Ng 4 GD ‘swoNTi-0, Envi FREE RADICAL, "76 KERIPAR REACTION ORDER: 2 350-500 | 1.0011) | 0 55351500 ]0.3 1.3 Ny Mo Ht Mig + nO 73 BAL/DRY REACTION ORDER: 2. M: Ar | 2000-3000] 9.2115) | 0 4210012500 [0.5 2.0 NiMg + H+ MN. 4 Be NeMvBniziNe + WVBROGEN Ao 78. BAU/DRY REACTION ORDER: 2 250-soo | 1.3(413) | 0 1260100 0.5 2.0 NUM + Clip. = NILNH. + Clty inbnicine’ 5 veri Fisk Sabrcat 76 KER/PAR REACTION ORDER: 2 so-so | 1.0(:11) | 0 asisss00 [0.5 2.0 NDGNDg. + Clip. = NDGND. + Ci eiVBRAZINE°os + WEPIVL FREE RADICAL 76 KER/PAR, [REACTION ORDER: 2. so-so | 7.2¢:10) | 0 sa00sson jo.s 2.0 NUgNilp + M+ Mig. + My. + M ‘WYORAZINE 73. BAL/DRY REACTION ORDER: 2M: Ar [1250-1400] a.0(s13) | 0 2170051000 0.8 3.0 NOTE: LIMITING HIGH PRESSURE k.‘Table of Arthenius parameters for chemical reactions occurring in combustion—Continued ‘Ghenical reactions 7K 7 7 Zk |X factors inky fF NWN + Mo Nig. 4 Mg. AYBRAZINE 73. BAL/DRY REACTION ORDER: 2. M: ar | 1250-1400} 4.0(+15) | 0 2060081000 |0.3 3.0 NOTE: Kg(LOW PRESSURE) cr *onaborc”scaB" "wet, eREE_aADucAa, 76 KER/PAR REACTION ORDER: 2. 300-400 | 1.0¢:11) | 0 ayooss00 0.5 2.0 NOTE: TENTATIVE k VALUE HNO $0 = Ht Np NITROSYL HYERIDE 4 OXYGEN ATOM 76 ENG [REACTION ORDER: 2. 1300-2500] 5.0(:10) | 0.5 o:2500 }0.3 3.2 HNO + 0 = NO + oH TNITROSYL HYDRIDE + OXYGEN ATOM 76 ENG REACTION ORDER: 2 1500-2500 | 5.0(+11) | 0.5 or2500 }0.8 3.2 HO £0 = NY Op INITHOSYL HYDRIDE + OXYGEN ATOM 76 ENG REACTION ORDER: 2 1500-2500] 1.0(411) | 0.5 | 35002500 [0.3 3.2 ANOS Hs NOs He NETHOSYL HYDRIDE + RYOROGEN ATOM "73 BAU/DRY REACTION ORDER: 2 2000 4c) | - - fos 1s HOS Hs NH 4 on NETROSYL HYDRIDE + HYDROGEN ATOM 76 ENG REACTION ORDER: 2. 1500-2500] 2.0(:11) | 0.5 | 1160012500 Jo.3 3.2 HNO + OW = NO + Ho 'NITHOSYL HYDRIDE” + HYDROXYL FREE RADICAL. 73. BAU/ORY REACTION ORDER: 2. 2000 3.613) | - - fos is HNO $ N= NO + Ni NITROSYL HYDRIDE + NITROGEN ATOM 76 ENG TREACTION ORDER: 2. 1500-2500 1.0(:11) | 0.5 | 10002500 |o.3 3.2, HNO | No XO intosic baioe + virrocen snow 76 ENG [REACTION ORDER: 2. 1500-2500] 5.0(+10) | 0.5 | 1500:2800 |0.3 3.2, RO + KO = OB + N20 [NITKOSYL HYDRIDE” + NITROGEN OXIDE{NO) 76 ENG [REACTION ORDER: 2. 1500-2500 | 2.0(:12) | 0 131002500 }0.5 2.0 HNO 5 CD + MH 4 Og NITROSYL, HYDRIDE. + CARBON WONOXIDE 76 ENG TREACTION ORDER: 2. 1500-2500] 1.0¢:11) | 0.5 | 8002500 |o.3 3.2, HNO + CL + 10 + Gi NITROSYL HYDRIDE 7 WETHYLIDYNE FREE RADICA 76 ENG [REACTION ORDER: 2. 1500-2500] 6.3¢411) | 0.5 o:2500 }0.8 3.2 HNO 4 Gig = ND + Cy ‘NITROSYL HYDRIDE +"WETHYLENE FREE RADICAL 76 ENG [REACTION ORDER: 2. 1500-2500] 6.3(-11) | 0. o:2500 Jos 3.2 HNO + Ci. NO. Ch NITROSYL HYDRIDE + ETHYL FREE RADICAL 76 ENG TEACTION ORDER: 2. 1500-2500] 5.0(:11) | 0.5 o:2500 |0.3 3.2 HNO 4 cH No 4 HCHO 'NITHOSYL HYDRIDE + METHYL, 0X0, FREE RADICA 76 ENG TEACTTON ORDER: 2. 1500-2500) 3.2(1) | 0.8 o:zs00 Jos 3.2 BNO + CX NO + HN NITHOSYL HYDRIDE + CYANOGEN FREE. RADICAL 76 ENG [REACTION ORDER: 2. 1500-2500 | 4.00(:11) | 0.5 012500 J0.3 3.2 HNO, + OH + ND, + He AVTRIC ACK «HYDROXYL FREE, RADICAL 73 BAL/DRY ‘REACTION ORDER: 2. 300 8.(s10) | ~ - fos 20‘Table of Arrhenius parameters for chemical reactions occurring in combustion—Continued Chemical reactions 7k 7 z Zk] k factors Gay | t ANOg |W NO + OH sw Sitar Aca 73 BAL/DRY REACTION ORDER: 2. Mz Ar | 00-1200] 1.6(:15) | 0 04 25 NS 40 = S4n0 NITROGEN SULFIDE(NS) + OXYGEN ATOM 75 BEN/GOL REACTION ORDER: 2. 6. | 08 o NS40 N+ so NITROGEN SULFIDE(NS) + OXYGEN ATOM 75 BEN/GOL TREACTION ORDER: 2. 6.3m) | 0.5 | 4000 NS ss ML NITROGEN SULFIDE(NS) + HYDROGEN ATOW "75 BEN/COL REACTION ORDER: 2. 2.5(412) 20735, NSH. Ns si NITROGEN SULETDE(NS) + HYDROGEN ATOM 75 BEN/COL REACTION ORDER: 2 2.5(412) | 0.8 | 18700 Mas Rata + SULFUR ATOM 75 BEN/GOL REACTION ORDER: 2 6.a(4) | 0.8 ° N48. Nes, Artnogen stLFiDE(Ns) + SULFUR ATOM 75 BEN/COL REACTION ORDER: 2. 2.0011) | 0.5 | 10870 NS4N Sony NrTnoceN suuFipe(xs) + NITROGEN sTO "75 BEN/COl REACTION ORDER: 2. 6.0) | 05 ° NSN = NG NS NITROGEN SULFIDE(NS) + NITROGEN ATOM 75 BEN/GOL REACTION ORDER: 2. 6.361) | 0.5 | 4000 Nic 2 84 cn NITROGEN SULFIDE(NS) 4 CARBON ATOM 75 BEN/GOL REACTION ORDER: 2. 6.3m | os ° N41 = NES NITROGEN SULFIDE(NS) + CARBON ATOM 75 BEN/GOL TREACTION ORDER: 2. 6.3G1) | 0.5 | 4000 Cros. oa ‘CARBON ATOw + O4YGEN aTOW 76 BAL/DRY REACTION ORDER: 3. 7000-1400 3.3(:26) | 3.1 | -2118 03 18 NOTE: Ws Ar, OR OD ky = Ki CHO. core ‘cao’ ATOW's OXYGEN MOLECULE 75 BEN/GO. REACTION ORDER: 2. 6.sGny | os o Chie» chad ‘ARRON ATOM HYDROGEN NOLECULE 5 BEN/Gol TREACTION ORDER: 2. 1612) | 0.5 | 15700 C+ on co yw (CARBON ATOM} HYDROXYL FREE RADICAL 75 BEN/COL REACTION ORDER: 2. 6am | 08 ° Cron. ciso ‘CARBON. ATOM’: HYDROXYL FREE, RADICAL 75 BEN/GOL REACTION ORDER: 2 7.9) | 0.8 | 14800 CHSe = 348 catBoN ATOW') "SULFUR DIMER 75 BEN/CO. REACTION ORDER: 2. eau | os o CHS. 4s ‘CARBON ATOW's SULFUR MONOXIDE 75 BEN/COL 2 6.3(41) ° REACTION ORDERTable of Arrhenius parameters for chemical reactions occurring in combustion—Continued Chenical reactions 7k 4 3 Tk | & factors Gag [tPF 0 = S40 CARBON ATOW + SULFUR MONOXIDE "5 BEN/GOI REACTION ORDER: 2 6.3m | 0.8 ° cHst chy s (CARBON ATOM NERCAPTO FREE. RADICAL, 5 BEN/GOL REACTION ORDER: 2. 4.04) | 0.5 | 6000 Cet - aH ‘CARBON ATOM MERCAPTO FREE. RADICAL, 75 BEN/COL [REACTION ORDER: 2. 6.3) | 0.5 o Ma = EN CcatboN ATOM" NITROGEN NOLECLLE 75 BEN/GOL REACTION ORDER: 2. 1.322) | 0.5 | 22750 CHM. aN CARBON _ATOW + NITROGEN OX1DE(NO) 75: BEN/GOL REACTION ORDER: 2. 6.311) | 0.5 | 4000 CEM. tO ‘CARBON. ATOM + NITROGEN OXIDE(NO) 75, BEN/COL REACTION ORDER: 2, 6.) | 08 ° CHM = ote N ‘CARBON, ATOM" INIDOGEN FREE, RADICAL 75 BEN/COL REACTION ORDER: 2 34) | 08 | 4000 CHM. Os ‘CARBON, ATOM TMIDOGEN FREE, RADICAL, 75 BEN/GOL REACTION ORDER: 2. 6.a¢n) | 0.5 ° cons 2 aN ‘CARBON ATOM ATOM + NITRIC SULFIDE. 75 BEN/COL REACTION ORDER: 2. 6.3¢m) | 0.5 | 4000 NS + ches ‘CARBON ATOM NITRIC SULFIDE 75 BEN/GOL REACTION ORDER: 2. 63m) | 0.5 ° © - Gio ‘CARBOY_ATEW' + CARBOW MONOXIDE 75 BEN/COl REACTION ORDER: 2. 1.0012) | 0.5 | ss025 cra. arc ‘CARBON ATOW + WETHYLIDYNE FREE RADICAL 75 BEN/COL REACTION ORDER: 2. 6.311) | 0.8 | 4000 CHO. Gad ‘CARBON ATM's NETHYLIDYNE FREE RADICAL 75 BEN/COL REACTION ORDER: 2. 63g) | 0.8 ° csc ARBOR ATOM’ + “CARBON MONOSULFIDE. FREE RADICAL, 75 BEN/GOL REACTION ORDER: 2, 6.3) | 08 ° CHO» Ges attyos_ ATEN CARBON MONOSULFIDE. FREE. RADICAL, 75 BEN/Col. REACTION ORDER: 2. 5.0011) | 0.5 | 20835 CH. ee ‘CRBow ATOM + CYANOGEN FREE, RADICAL, 75, BEN/COL ‘REACTION ORDER: 2. 6.30) | os ° CHO Gen ‘CARBON. ATOW’+ CYANOGEN FREE, RADICAL 75 BEN/COL ‘REACTION ORDER: 2. 2.5¢:11) | 0.5 | 19300 CHG. Gi ‘cafaon ATOM’ CARBON DINER 75 BEN/COL REACTION ORDER: 2. 6.3¢11) | 0.5 °‘Table of Archenius parameters for chemical reactions occurring in combustion —Continued Ghenleal resctlons 7 7 7 Tt] & factors Gen [et Oi Cao MONOXIDE + oxyceN aTON 75 BEN/COL, REACTION ORDER: 2 scm | os ° 404K oy eH Ca wowoxt8 © Oxxcen sto 76 BAU/DRY HEACTION omoeR: 3. Ms cp | aso-soo | 2.ac45) | 0 aiasz0 Joe 1.2 Nove: KFACTORS CHANGING TO: f°='-5, Fo 2:0 AT BOOK so cro, CARBON MONOKTBE + OXYGEN ATOM 75 BEN/COL REACTION ORDER: 2 roi» | 0.5 | 65000 4 0 oy 60 Carbon WoNORIDE + OXYGEN MOLECULE 76 BAU/DRY REACTION ORDER: 2 00-3000] 2.5(:12) | 0 | asoonszs00 fos 2.0 Note: KFACTORS CHANGING TO: f'=-5; F = 1-3 AF 3000K. Oem. os at CARBO MONOXIDE + nyOROGeEN ATOM 75 BEN/ COL, REACTION onoeR: 2 2scis) | 0.5 | anno OH = cs of CARBON MONOXIDE + wYOROCeN sTOH 75 BEN/COL REACTION omen: 2 2.013) | os | 7755 Osten. aoe K aRaoN woNOXiDE + ‘HYOROGEN sto 76 AUORY RENCTION onosR: 2. ws ay | 298-778 | 7.2cx18) | 0 asossoo fo? 1.8 note: K°FACTORS CHANGING TOs f= 04S; Fe 200 AT TTHK. © snew cw + Gano wowoxibe"nYoROCEN sTOu 70 REACTION onoER: 3, 100-2500] 1.64420) | -1.5 ojos a2 Ce alton wroube+ wvorox ee pte, 76 BAU/DRY REACTION ORDER: 2 250-2000 1.57) | 13 | a foe 12 NOTE: LFACTORS OVER 1000K: f= 0.5, F © 1:5. RECOMENDED LOR, 250-2500 Tog k(en®aole""s"!) = 10,83 + 3.98 x 10“ Os HO, = o, Galt oyttioe S"avonorexoxy. FREE RADHA. 76: BAU/DRY REACTION ORDERS 2 200-1000} 1.50414) | 0 | 1900:1000 Jo.3 3.0 Hes. oF cs CaRboN wOwdnTDE + SULFUR «TOW 75 aL REACTION ORDER: 2 ray | 0.5 | sr600 2s cs s0 CaRDON windIDE + SULFUR ATOM 75 BN/COL, REACTION ORDER: 2. 4.012) | 0.5 |ossso MEN oF ey CARDO vONOATDE + NITROGEN ATON 75 BEN/COL, REACTION onDeR: 2. s.2¢12) | 0.5 | see00 ek CHM CARBON MONOXIDE + NITROGEN ATOM "5 BEN/COL REACTION owen: 2. 5.012) | 0.5 | 7300 © + Nog 4 ¥0 uttdn dowoxtod * simocey oxve,to,) 72 10 REACIONOnpeR: 2. soo-800 | 1.9(s127 | o | rsrasiaas os 1.9 6 iN xgon-2s00 | 2'00312) | 0 130001500 |0:3 2:0 OD $M = 00, + My tatfow wosbtind srmmocen ox10e(N,0) 76 EACTIO® OnoeR: 2, 1500-2500| 1.0(411) | © | 1000011500 |o.s 2.0 © 80 O05 Gabon fovoktod "srr. spaune 76 REACTION onpex: 2. 1500-2500] 1.0¢11) | 0.5 | ssonzs00 fos 3.2 6‘Table of Arthenius parameters for chemical rections occuring in combustion —Continued Ghesical reactions 7K 7 @ Ft] i factors Gay [er sc o% CARBON WONOXIBE + CARBON ATOM 75, BEN/GOL. EACTION ORDER: 2. Loci2) | 0.8 | saoes © + Gi. CAC(O), Campi wovoxTDE + ETHYL FREE RADICAL, 72 KON REACTION ORDER: 2. 273400 | 3.84 8) | 0 1965 iM crosw CARBON WONOXIDE 76 BAL/DRY REACTION ORDER: 2. 7000-15009 0.8(429) | 3.5 f2s70osi800 Jos 1.8 NOTE: k FACTORS CHANGING 0: f= 0.5; P= 1.3. OVER 10000K. = Ar OR GD Os 40 = co + 0, “CARBON DIOXIDE? OXYGEN ATOM 76 BAU/DRY REACTION ORDER: 2. 1500-3000] 1.7018) | 0 2650022500 ]0.5 2.0 NOTE: k FACTORS HANGING 10: f= 0.5; F = 1.3 AT 000K kai Os 4H = co + ‘CARBON DIOXIDE + HYDROGEN TOW "76 BALU/ORY TEACTION ORDER: 2. 000-3000 | 1.5¢414) | 0 1s300:150 fog 1.2 ys He + cD + 0 ‘chwadN DIOXIDE yuvorocen NoLecuLs 76 ENG REACTION ORDER: 2. 1500-2500] 1.0(+ 9) | 0.5 | 7550:2500 |0.3 3.2 Oye N + oD 4 NO ‘CARBON DIOXIDE’ + NITROGEN ATO 76 ENG TEACTION ORDER: 2. 1500-2500] 2.0(411) | 0.5 | 15000210000 0.11.0. + cH = cD + .cHo ‘CARBON DIOXIDE } NETHYLIDYE_ FREE RADICAL 76 ENG TEACTION ORDER: 2. 1500-2500] 1.0(s10) | 0.5 | s000:2500 Jos 3.2 Oe) N= CEO EM ‘CARBON DIOXIDE 76 ENG REACTION ORDER: 2 1500-2500] 1.015) | 0 50000:2500 }0.5 2.0 he 0 = Hy NETHYLIDYNE FREE RADICAL + OXYGEN ATOW 75 BER/GOL REACTION ORDER: 2. ean) | 0s o ho = cs on WETIYLIDYNE FREE RADICAL + OXYGEN ATON 75 BEN/GOL ACTION ORDER: 2. sum | 08 | 4000 Gs oN «cu su METIYLIDYNE FREE RADICAL + OXYGEN TOW 76 ENG REACTION ORDER: 3. 1500-2500 | 1.0(416) | -0.5 o:2500 |0.8 3.2 hs Og HO + 0 WETHYLIDYNE FREE RADICAL + OXYGEN MOLECULE 76 ENG REACTION ORDER: 2 1500-2500] 5.0411) | 0.8 | 300022500 Jo.3 3.2 Creer) METHYLLDYVE FREE RADICAL + HYDROGEN ATOM 75. BEN/GOL. REACTION ORDER: 2. 6.3) | 0s o Chem Ch te NETHYLLDYNE FREE RADICAL, + HYDROGEN ATOM 75 BEW/GOL REACTION ORDER: 2. 6.3 | 08 | 4000 Che Het = Cie aw METHVLIDYNE FREE RADICAL, + HYDROGEN ATOM 76 ENG REACTION ORDER: 3. 1500-2500 | 1.00(419) | -1.0 ° 0.3 32 Hs OW cH 4 METHYLIDYWE FREE RADICAL + HYDROPEROXYL FREE RADICAL 1500-2500 | 5.0(:11) | 0.5 | s000:2500 Jo.3 3.2 76 ENG REACTION ORDER! 2 a7‘Table of Archenius parameters for chemical reactions occurring in combustion—Costinued Ghenical reactions — 7k 4 3 ZR (in) Cs We cue + 0, beatae FRc RanreaL + syoROPEROKYL FREE RADICAL 76 ING REACTION ORDER: 2, 1300-2500] 1.0(;10) | 0.5 | 738022500 |o.s 3.2, CH Hs = C0 + OH WeTHLIDYNE FREE RADICAL + HYOROPEROXYL FREE RADICAL 76 NG REACTION ORDER: 2. 1500-2500] 5.0(+11) | 0.5 | 300022500 |o.3 3.2, hes. Hees NETHYLIDYNE FREE RADICAL + SULFUR ATOM 75 BEN/COl. REACTION ORDER: 2. 6.3) | 05 ° ches = C3 SH METWYLIDYNE FREE RADICAL + SULFUR ATOM 75 BEN/COL REACTION ORDER: 2. 6.3m) | 05 | 4000 CHEN Hy ETWYLIDYNE FREE RADICAL + NITROGEN ATOM 75 BEN/COL REACTION ORDER: 2. osc | os ° CHEN CaN NETHYLIDYNE FREE RADICAL + NITROGEN ATOM 75 BENIGOL. REACTION ORDER: 2. 1012) | 0.8 | 6905 CY Ne = ON 5 METHYLIDYNE FREE RADICAL + NITROGEN wOLBCULE 76 ENG REACTION ORDER: 2. 1500-2500] 3.2414) | 0 46300210000 NOTE: k ESTIMATED. Hs Na = HN 4X NETAYLIDYNE FREE RADICAL + NITROGEN WOLE 76 ENG REACTION ORDER: 2. Lowy | 0 9360 Nove: REVISED ESTIMATE. Hs NO + cH 4H NETHYLIDYNE FREE RADICAL + NITROGEN OXIDE(NO) 76 ENG REACTION ORDER: 2. 1500-2500 | 1.6(418) | 0 50003000 NOTE: ke ESTIMATED. CH ND + HW 4 0 METHVE-TOYNE FREE RADICAL + NITROGEN OXIDE (NO) 76 ENG REACTION ORDER: 2. 1500-2500 | 2.0(+12) | 0 ‘0£1000 Nowe: K ESTIMATED, CHS HNO + Cle + 80 METHYLIDYNE FREE RADICAL + NITROSYL HYDRIDE 76 ENG REACTION ORDER: 2. 1500-2500] 6.3¢411) | 0.5 012500 |0.3 3.2 ee We NETHYLIDINE SEE RADICAL + CARBON ATOM 75 BEN/GOL REACTION ORDER: 2 ean) | 05 ° dic. cra METHYLIDYNE FREE RADICAL + CARBON ATOM 75. BEN/COL REACTION ORDER: 2. 6.¢1) | 0.5 | 4000 GH} Oy = .cH0 + co METINLIDYNE FREE RADICAL + CARBON DIOXIDE To ING REACTION ORDER: 2. 1500-2500] 1.0(+10) | 0.5 | so00s2500 |o.3 3.2 GH Cy = cia + dy, WETILIDYNE Fake RADICAL + METHANE 76 NC REACTION ORDER: 2 1500-2500] 2.5¢411) | 0.7 | s00nsas00 |o.3 3.2 CH CHO Gl, + 00. BTHYLIDYNE FREE RADICAL + METHYL, OX0-,_ FREE RADICAL, 76 ING REACTUON ORDER: 2 1500-2500] 3.2(+10) | 0.7} soot2soo Jos 3.2 CH HCHO + Gis + .cH0 METHYLIDYNE FEE HADICAL + FORMALDENYDE 76 ING REACTION ORDER: 2 1500-2500] 1.0(411) | 0.7 | 20002500 Jo.3 3.2‘Table of Arrhenius parameters for chemical reactions occurring in combustion —Continued Ghenical reactions 7 7 a | & factors (aw ft TF Gi, 0 Gs OF ‘ETHYLENE FREE RADICAL + OXYGEN ATOM 76 ENG REACTION ORDER: 2. 1500-2500] 2.0(:11) | 0.7 | 13000:2500 ]o.3 3.2 Gi, 0 = CHO + H “METHYLENE FREE RADICAL + OXYGEN ATOM 76 ENG REACTION ORDER: 2 1500-2500] 5.0(+11) | 0.5 | 200012500 J0.3 3.2 le Oe = HCHO + 0 'WETINLENE FREE RADICAL + OXYGEN ATOM 76 ENG REACTION ORDER: 2. 1500-2500] s.0(:11) | 0.5 03 32 CH hy ‘METHYLENE FREE RADICAL + HYDROGEN ATOM 76 ENG REACTION ORDER: 2. 1s00-2500/ 3.2(411) | 0.7 | 250022500 Jo.3 3.2 Chae He a. wer iene Feb L + HYDROGEN MOLECULE REACTION ORDER? 2. 1500-2500} 3.2(+12) | 0 352521500 Nove: ke ESTIMATED. 0H = GH s HO “METHYLENE FREE RADICAL + HYDROXYL FREE RADICAL, 76 ENG REACTION ORDER: 2. 1sc0-2500| 5.0(411) | 0.5 | s000:2s00 ]o.3 3.2 la 4 OW layirmmusne PHBE RADICAL + WYDROWYL FREE RADICAL 76 ENG REACTION ORDER: 2. 1500-2500] 5.0(411) | 0.5 | s000:2500 Jo.3 3.2 soll NoHo + H “METHYLENE FREE RADICAL + HYDROXYL FREE RADICAL 76 ENG REACTION ORDER: 2. 1500-2500 | 1.0(:18) | 0 2500 Nove: ke ESTIMATED. 2X + Ne “METHYLENE FREE RADICAL + NITROGEN sTOu 76 EMG REACTION ORDER: 2. 1500-2500 | 6.3(411) | 0.67 | 2040022500 Jo.3 3.2 HCN +N leysotfuese PE'HADICAL + NITIOGEN vOLECULE 76 ENG REACTION ORDER: 2. 1500-2500] 1.0(+14) | 0 35230410000 NOTE: k ESTIMATED. fats paty BS 48, “METHYLENE FREE RADICAL + NITROGEN OX4DE(NO) 76 ENG [REACTION ORDER: 2. 1500-2500] 16412) | 0 350042000 NOTE: k ESTIMATED. Gy, { HNO = ly. NO 'WETHYLENE FREE RADICAL + NITROSYL HYDRIDE To ENG [REACTION ORDER: 2. 1500-2500] 6.34411) | 0.5 oa 32 Gy + Ol, + cH + Cy. WETHYEENE FREE RADICAL, 76 ENG REACTION ORDER: 2. 1500-2500] 5.04411) | 0.5 03 32 ct, + at wcrntent eee wore. + weruane 76 ENG REACTION ORDER: 2. 1500-2500 | 1.3(+12) | 0.7 | 10000:2500 Jo.3 3.2, G10 + Cy. + 00 ueTiVLENe FREE'HADICAL + METHYL, Ot0-, FREE RADICAL 76 ENC REAGHLON ORDER: 2 1500-2500 3.2(+10) | 0.7 | soos2so0 Jo.3 3.2, Ce, «HCHO + cH iain Hee RDLEAL + FORWALDEHYDE 76 NC REACTION ORDER: 2. 1500-2500] 2.0(411) | 0 827081500 NOTE: k ESTIMATED, Gi CN GH HN WETINLENE FREE RADICAL + CYANOGEN FREE RADICAL 76. ENG [REACTION ORDER: 2. 1500-2500] 3.21412) | 0 250021500 NOTE: k ESTIMATED.‘Table of Archenins parameters for chemical reactions occurting in combustion—Continued Chenical reactions 7 4 F aR Gnw factors f "Oly + GHyGI-Gl, = products Gietavuie Frés nan¥cat + 1-PRoPENE 72 KER/PAR REACTION ORDER: 2. Krk, NOTE: yee? ily + Cly-Ciy at + oducts friutLBNe rade Rakes T-pnopene 72. KER/PAR REACTION ORDER: 2. Kk, NOTE: Kyee! iy + Cy 'Gi + ClgCl,Cl-Cl products ierayLine’ race Rapical’s 1-atrexe 72 KER/PAR REACTION ORDER: 2. k/k, NOTE: kyee? iy + Cyl dlls + CHpClCi-Gl, products eh Fe boreal" eos Stren ‘72 KER/EAR REACTION ORDER: 2. Krk, NOTE: keee? lly + Cy Ol + eis-ci, products WenWLENe Pate Bitte #Pctec3'sureNe ‘72 KER/PAR REACTION ORDER: 2. rk, NOTE: joe? "lly + Clg Pdlg: | cis CACHACHCH, + products ETHYLENE FREE RADICAL + €is~2-BUTENE 72. KER/PAR REACTION ORDER: NOTE: yep! Ulla + Cai AG, + trans’ IC, + products ietiYLENe Fae maDICh. 2 cpans=2-BUTENE 72. KER/PAR REACTION ORDER: 2. k/k, NOTE: Kyee? 'Ci + ClyeCl dlls + trane-ClhCH-CHCH, + producte ‘HETHYLENE PuEE RADICAL + Fans-2-BUTENE 72 KEV/EAR REACTION ORDER: 2. k/kyggt 0.89 NOTE: Krag? lly + ly=Cll Nag +, (Cla) oducts ‘ietnYce%e* Paes RADICAL 1-PnorENE, 2-werHYL— 72 KER/PAR REACTION ORDER: 2. Kit, NOTE: krgg? ly + C=C rot? 1:96 Pcl + (Clad oducts ieruYLete" Pere’ RaDIchl. + L-PROPENE, 2-METHYL "72 KER/PAR REACTION ORDER: 2. K/kyog: 2.86 NOTE: egg? "Oly + Cg NOs + (Cia) aC-CHOH, = products IETWYLERE"FREE RADICAL’ + 2-BUTENE, 2-NETHYL- "72 KER/PAR REACTION ORDER: 2. K7k,, NOTE: Kyer! 'Cig + Ciy-Ca 12 = (Ca) products efaNceNPFnue Rhorca?(°2"abteve,. 2-wer- 72 REWVPAR REACTION ORDER: 2. KTkyag: 1.88 NOTE: koe! *Cla + CaCl Nag + (tld Products eiu\CARE’ re Wlcal,s"SAUTENE, 2. 5-onnerINL- 72 KEIVPAR REACTION O#DER: 2. K/h, NOTE: Kye?! + ClgsCly "dil + (Ciiy)aC-C(Clig)s + products fiemycete"rnee nibfcat "2-BUTENE, 2,3-pivenivi— 72 KER/PAR REACTION ORDER: 2. K/k,.: 2.74 NOTE: Krag? "Cy + ClgeCly iy. +0 = HCHO SH “ETHYL, FREE RADICAL + OXYGEN ATOM 76 ENG REACTION ORDER: 2. 207 : 207 = 207 : 207 : 201 = 207 : 201 - 1500-2500) 5.0(413) 50 05 20‘Table of Arsheniva parameters for chemical reactions occurring in combustion —Continued Ghesical reactions ™ | 4 7 FR] k factore Gok | ft at, he + HO Piet eee MokcAt?, oxveey wouscane 76 2NG REACTION ORDER: 2. 1300-2500] 3.2(412) | 0 497521500 NOTE: ke ESTINATED. Oh 4 Og = HCHO Om ‘werivé, FREE RADICAL + OXYGEN NOLECULE 16 NG REACTION ORDER: 2. 1300-2500 | 3.2(13) | 0 r00c0:5000 }0.3 3.2 Gly. + 0p = G0. + 0 SwernvE. rice RADICAL + oxyceN ovrcute 76 NG REACTION ORDER: 2. 1500-2500] 3.2(412) | 0 1510041500 Nove: k ESTINATED. Gis. 4 Hp = Che “were, rae RADICAL, + WYOROGEN MOLECULE 2 KER/PAR REACTION ORDER: 2. 370-700 | 8.5(411) | 0 s500s500 0.7 1.3 Gi + HD aD 4 HL “ETHYL, FREE RADICAL + DEUTERIUM HYDRIDE 76 KER/PAR TREACTION ORDER: 2. 400-700 | 2.4¢11) | 0 50352500 |0.5 1.5 Cy. + HD Gly + D. ETHYL FREE RADICAL y DELTERIUM WYDRID 16 KER/PAR REACTION ORDER: 2. 400-700 | 2.1¢s11) | 0 os 15 lng 4 Dp = GUD + D. ‘octave, ree RADICAL DEUTERIUN WOLEOULE 76 KER/PAR REACTION ORDER: 2. 300-700 } 7.10401) | 0 soooi2so 0.7 1.3 ae rts isin, ened RioIGAL + wvonocen wowecute 72 Kot REACTION ORDER: 2. 400-570 | 7.4(411) | 0 sesoiz3s 0.6 1.7 Cy. + OH Ce + 120 “WETHYL FREE RADICAL + HYDROXYL FREE RADICAL 76 ENG REACTION ORDER: 2 1500-2500] 6.3(+10) | 07 | 100012500 |o.3 3.2 Ce ee “WETHVL FREE RADICAL + HYDROXYL FREE RADICAL 76 ING REACTION ORDER: 2. 1500-2500 | 6.8(412) | 0 ° Nove: ie ESTIMATED. Gis. + HOg = Che ¢ Oe WweTAVL FREE RABLCAL HYOROPEROXYL, FREE RADICAL 76 ING REACTION ORDER: 2, 1500-2500] 1.0(+11) | 0.5 | 30002500 [0.3 3.2 Oly. 4 HO = Cy 0H Weta rae Rabreai + waren 76 KER/PAR ‘REACTION ORDER: 2. ars | 7.1¢42) | 0 1290021000 | 0.5 2.0 NTE: TENTATIVE k VALUE ly. 4 HS + Che 4 SH wet enex AABICAL + HYDROGEN SULFIDE 76 KER/PAR REACTION ORDER: 2. 300-600 | 2.0(s11) | 0 2oess750 los 2.5 NOTE: TENTATIVE k VALLE. Clg + My > Clg + Na eT enee naBLCAL ? amwoxta 16 KER/PAR REACTION ORDER: 2. 350-650 | 1.0(+11) | 0 os 18 Gy, + MDs CD + ND SWETHYL FREE RABICAL +“AWMONIAA<, 16 KER/PAR REACTION ORDER: 2. 350-500 | 1.0(+11) | 0 55352500 [0.3 1.8 iy. + ML = Cl + GN WeTavL FREE match. y wfpRAZINE 76 KER/PAR FACTION ORDER: 2. 350-500 | 1.0(s11) | 0 25003500 |0.5 2.0 Gly + NDANDg Cad + NDRND. “ETHYL FREE RADICAL. + HYBRAZINEWd 76 KER/PAR REACTION ORDER: 2. 350-500 | 7.2(s10) | 0 2008500 J 0.5 2.0 51‘Table of Arrhenius parameters for chemical reactions occurring in combustion —Continued Ghenical reactions TK 7 a FR] ¥ factors Gay | Cg, 4 HNa Cla 4 Ny WieTuYL'rREE HABICAL’ + nvORAZOIC ACID "16 KER/PAR REACTION ORDER: 2 300-400 | 1.0(;11) | 0 21003500 0.5 2.0 NOTE: TENTATIVE k YAUIE. Clg. 4 HNO Che + 10 WWETWVL FREE RADICAL + NETROSYL HYDRIDE 16 KER/PAR REACTION ORDER: 2 1500-2500] 5.0(:11) | 0.5 o:2500 }0.3 3.2 Gy. +00 CHACO) WWETHYL, FREE RADICAL + CARBON MONOXIDE 72 KON REACTION ORDER: 2. 273-400 | 3.8(:8) | 0 1968, Cy. + ly + Cle + CH WeTuYL "ene RABICAL 2 METHANE 76 KER/PAR REACTION ORDER: 2. 450-800 | 4.0(:11) | 0 or 1a Cy. + CHD = lly + D5. ‘WETHYL, PREE RADICAL + WETHANE=dy 716 KER/PAR 'REACTION ORDER: 2. 00-650 | a.1¢a | 0 coose250 0.7 1.3 NOTE: TENTATIVE k VALUE, Gig, + Dg Had + Ca, WWeTHYL"enEe RABICAL + WETHANE-d 76 KER/PAR REACTION ORDER: 2. 400-650} 2.5¢:11) | 0 rr00s500 0.51.5, y+ CHD + Dy + Gly. "TaVI=d_-FREE. RADICAL” + METHANE=d 76 KeA/PAR REACTION ORDER: 2. 400-650 | 5.0(+10) | 0 OS 15 NOTE: TENTATIVE k VALUE. (y+ (Dy + Dy + Dy, “ietuyi“a,-FHEE"RADICKL, + NETHANE=dy 72 KOR REACTION ORDER: 2. 473-623 | 4.1(+12) | 0 Cy. + CHO» chy + 0 ‘iit, FREE RADECAL + NETHVL, OXO—, FREE RADICAL 76 ENG REACTION ORDER: 2 1500-2500] 3.2(:11) | 0.5 0:2500 }o.3 3.2 Cy. + HCHO cay + .cH0 “WETHYL FREE. RADICAL + FORMALDEHYDE 76 KER/PAR [REACTION ORDER: 2. 300-500 | 1.1¢1) | 0 05 Gly. + HCHO cy + .cH0 ‘WeTHyL FREE aADEcAL"+ FoRUALDERYDE 76 ENG REACTION ORDER: 2. 1500-2500] 1.0(:10) | 0.5 os 32 CH. + DDO aD } C00 "WETHYL FREE RADICAL} FORMALDERYDE=d 76 KER/PAR REACTION ORDER: 2. soo-soo | 1.4011) | 0 3075500 |0.8 1.5 Gy. + CHAO = Cay + CHAO. ‘Wernyi rage wabidaL + METHANOL 16 KER/PAR REACTION ORDER: 2 sso-sso | 6.2¢:10) | 0 4900:500 0.6 1.4 Gy. + H,0H = Ce 4 C08 WETHYL "FREE RADICAL + WETHANOL, 16 KER/PAR REACTION ORDER: 2. 50-500 | 1.911) | 0 06 La Oy. + CH,OH = Cle + cth0. + .cH,0 WETHYL FREE RADICAL + METHANOL, 16 KER/PAR REACTION ORDER: 2. sso-sso | 2.3¢:11) | 0 49003500 }0.6 14 Gy. + CDAOH = CHAD + .cO,0H WWETHYL, FREE RADICAL 4 WETHAN-a,-0L "76 KER/PAR REAETION ORDR: 2. 370-550 | 2.04511) | 0 soaoisoo |0.6 1.4 Qs. + CDSOH = Cle + CD40. ‘WETHYL'FREE RADICAL + METHAN-d4OL 76 KER/PAR REACTION ORDER: 2. 370-850 | 6.2(:10) | 0 4900:500 0.6 1.4 Dy. + HOD = CDall + .cH,00 envied, FREE RADICAL + METHANOL 400-500 | 1.911) | 0 05 20 16 KER/PAR ‘REACTION ORDER: 2.“Table of Arshenius parameters for chemical reactions occurring in combustion—Continued Tented Teeeone 77 7 Tito iatey | EF GN) — oho, eh vane MichL veo“ To hiea TENTION noe: 2. soosio | a.2i0 | 0 | sroo:1000 fos 2.0 vore: Ever TAE caurion ay, 4 SI — chy 4 as. + can chiro: wbttad, tulnatay Te KaiPAh ECHON onoen: 2 ws | iaee | - - fos 20 ay, | 8h ole 0,8. ie Ton Pah osm | iam |o — | a0sosoo fos 20 + c0,81 «oho + co,st eee thes SEINE TH Toga Pat MEGAN onoen: 2. 6019) | 0 os 20 Gh. $x = abe HA eh rice Hot’, cvnoces re motca pin chon OEE vson-2500/ 1.00 | 0.7 os 3a cat ata Eto onan: 2. sesorr | satay | o | seatsoo fos 3.0 Oh, CM — Ol, + OHNE. + Gl et de facts Wins pea ENCTON nUER: 2 soo | 2rcay | o | assoisoo for 1s hy, CHD = he + ep ieh de Gaon AER dy pi RECHT omen 2 asoaso | rain | 0 | assossoo for 1.3 i, + CHD, = OD + Ohno ic ade jaorell | MERNNe-a Toe eNO oer: 2. asoaso | 2ociy | o | sisssio0 fos 1 vore: Feat va Oh, COM, = + CaN. iN Pe Gaon SUN ano TO PAR stitON noe: 2. wos | zo |o | assorso fos 2.0 sore: Feat va hy CDM = aD + cDaMe iota jared, {AEH au pi iON om: 2 wos | z.210) | 0 | stoossoo fos 15 Clg. CHAIN, = Gly + CUgN INS + GN ania UPR mato + woHAzINe. METI To uENEa RENCHON aban: 2 a | ose] - . vores TENN au iy, 4 HOON, = y+ HONE. + CR, cit ibe janet’ "ela To eh/EAt ETION onveR: 2. ssosw | socio) |o | soso fos 15 iy 4 MEDD, = hy + cont, cat ate fants’. SoubunEy. To aah Fat Ec foe: 2. asosoo | s.scio | o | asrsisoo fos 2.0 Cy, + HOON, = GD + oN, rit ree Gane, | FORMMIDES,\- Toth Ea MaNGN fuer: 2. ssosw | 200 | o | asmsoo fos 2.0 vores TENTATIVE k VALLE, Gg, | CIN ~ hy + hed, ctl hae, woes WRG, nao aaa eicHON oe: 2. aoo-so | soci | o — | stonirso fos 25 yore, RAN, va fy. 4 cH0p = cy + clon. ich reg wont | AVONLAUNE, oer. Te eR PAR ETO of sooso | s.oi0) | 0 | a2esis00 fos 1s‘Table of Arrheniua parameters for chemical rections occu 6 in combustion—Contnued ‘Ghenical reaction 7K 7 z Fk] & factors Gon [fF Oy. 4 CH,OND, = CiD + GH,OND wet FREE naDicat, +" WYDROKYLANINE-N,N-dg, O-WETHYL- 76 KER/PAR REACTION ORDER? 2. 300-500 | 3.5(+10) 29703500 }0.5 1.5. Gy. + Hac — che + CHC. WeeTuYL, FREE maDIGsl, + ETHNNE 76 KER/PAR REACTION ORDER: 2. aaa | - — | m0 Nove: GIVEN 81TH CAUTION iy, + Cec cHCt-CH. ‘WETHYL FREE RADICAL + ETHYNE 2 KEN/PAR REACTION ORDER: 2. sms | 2.5¢411) 3900 Gy. + ClgeCl = Cll, + Cllp-CH. WweTuYL FREE aapicat + ETHENE 16 KER/PAR REACTION ORDER: 2. 350-650 | 4.2(411) 36002500 [0.5 1.5 Cy. ChaCha Ce "wetuyL Ree apical, + ETAENE 72 KER/PAR REACTION ORDER: 2. asaas3 | 3.3(411) 3900 Cy. + Cha=Cly = CHeCACHa. + (Cy) Cl. “wetuvi-rneé napieal 1 ETHENE 72 KON REACTION ORDER: 2. 350705 | 2.0(211) asrss10s fog 1.3 Gy. + CHaCy = Olly + Clg. Twetuyi FRE aapick ETHAN 16 KER/PAR REACTION ORDER: 2. 400-900 | 5.6(411) or 13 Gy. + CDgCDy = Cad + CDaCDg. WietuyL"FnBe aaptchL. $ ETHANEde 76 KER/PAR REACTION ORDER: 2. 500-900 | 5.64411) o7 13 4 HCH, = Cyl + Clie. ‘weTHYi=“d, FREE RADICAL +*ETHANE 72 kOe REACTION ORDER: 2. 390-800 | 1.0(+12) 05:65 }0.7 1 Dy, GigCDy = Cook + COC werivicd, Free eapicaL + Erviie-1 1,14 76 KER/PAR REACTION ORDER: 2. 500-750 | 3.0(+11) sooo2s0 |0.7 1.3 Oy, + CDs = Cy + CD, ‘ieravicd,"raee tabrcaL + ehuane-1., 1,124, 76 KER/PAR REACTION’ ORDER: 2 500-750 | 4.3(411) 245.250 0.7 1.3 (Dy. + CDgCDy Dy + CDgODs. ‘wernvi=a,rnee RabicaL + eine. 72 KOR REACTION ORDER: 2. 550-760 | 4.6(411) 6405 Gy. + CHACHO = Cy + CHACLO). WWETHYL FREE HADI.’ + ACETALDENYDE 76 KER/PAR REACTION ORDER: 2. 300-525 | 8.5(+10) 30001250 0.4 1.6 Gig. 4 CHACDO = CigD + ciiyc(O) WETHYL FREE RADICAL + ACETALDEHYDE-1-a 6 KER/PAR TREACTION ORDER: 2. 300-500 } 1.0(411) so75:500 [0.5 1.5 Cy, 4 eyCh.CH,0. Clg + ey=ciic8(.)0 WwetuvE, PREE fADICAL + “OXIRANE To KER/PAR REACTION ORDER: 2. 50-500 | 2.5(+11) 05 20 NOTE: TENTATIVE k VALUE, Cg. + HODOCH Gly + .C00CH, ‘ETHYL, FREE RADICAL + PORMIC" ACID NETHYL ESTER 76 KER/PAR REACTION ORDER: 2. 350-sso | 2.0(+11) 900500 [0.5 1.5 Cy. + HODOGH, cat, + HoDoCH. ‘WETHYL, FREE RADICAL + FORWIC'ACID WETHYL ESTER 76 KER/PAR REACTION ORDER: 2. 350-550 | 1.6(+11) sossss00 |0.5 1.5, Gy. + HONIG, = Cll, + COO, + HODOCH ‘WETHYL FREE RADICAL + FORMIC’ACIO WETHTL ESTER 76 KER/PAR REACTION ORDER: 2. 350-550 | 3.0(+11) 49005500 [0.5 1.5Table of Arthenius parameters for chemical rections occurring in combustion—Contnued Chenical reactions 7k 4 3 ZR | factors Gan | ft Oly. + DCDOGH, cD +, COUCH “WeTHYL, FREE RADICAT. + FORMIC=d ACID METHYL ESTER 76 KER/PAR REACTION ORDER: 2: 350-550 | 2.5(411) | 0 59001500 0.5 1.5 Gis. + NCOOG, = cll, + DCOOG "Wet FREE nADICAL + FORWIC=d ACID NETHYL ESTER 76 KER/PAR REACTION ORDER: 2. ss0-sso | 1.6(s11) | 0 5352500 0.5 1.5 NOTE: TENTATIVE k YALE GH, 4 1,000 = ci, + .ci,c000 ‘weTHYL FREE RaDteAL, + ACERIC ACID~a 6 KER/PAR REACTION ORDER: 2. 300-600 | 1.011) | 0 sissts00 Joe 1.4 Gy. + CHACHLOM cll, + cllsc,0. ‘WETHYL "FREE RADICAL" | ETHANOL 76 KER/PAR REACTION ORDER: 2. 400-025 | 7.9(:10) | 0 47301500 J0.6 1.4 Gia. § CHyCHLON chy + cH. CHK DOH TweTHYL FREE naDrcAL*." ETHANOL 76 KER/PAR REACTION ORDER: 2. 400-625 | 4.00(+11) | 0 49001500 0.6 1.4 Gig. 4 GUgcl0H - CH, + CHctl0. + CH,CH.)OH $ GigCH08 ETHEL FREE RADICAL + ENIANOL 76 KER/PAR TREACTION ORDER: 2. 400-025 | s.1(s1) | 0 9002500 0.6 1.4 Gly, 4 CHCD,0H = Ci + ClgCD,0. + Cig C0,08 WwerayL FREE RapncaL*s EMIAN-L, ica “0L, 76 KER/PAR REACTION ORDER: 2. 400-850 | 7.1(¢10) | 0 06 Lt Gly. + cHlgcD,0H = cD + CigCD(. 08 ETHYL FREE RADICAL™+ ETHARCL i-dy—OL 16 KERIPAR ‘REACTION ORDER: 2. 400-550 | 4.1¢:11) | 0 06 14 0, aad ak + CH )00 = -ccHgp0 Weer FREE RADICAL + ERWANOL Gly + C100, WWeTUNL FREE RaptCat > METHANE, oxvers— 16 KER/PAR REACTION ORDER: 2. soo-sso | 4.2¢s11) | 0 50351500 |0.5 1.5 Cy. + CH00CI, + Gy + Cl, l0Cy \WeTUYL "PREE RADICAL"; PEROXIDE, DINETHYL 16 KER/PAR REACTION ORDER: 2. so-so | 4.2¢411) | 0 500011000 |0.3 3.0 NOTE: TENTATIVE k VALUE, yf cy AS = CDsH + ey -CHGHIS etal -a, mde napncal. «Tad ARE 16 KER/PAR REACTION ORDER: 2. 00-500 | 2.2(611) | 0 48003500 0.5 2.0 Gy. + CCHS ~ CH, + CHAOS. + CHCHT.)SH + dics WeTatL FREE RADICAL + ETHANETHIOL, 76, KER/PAR [REACTION ORDER: 2. 308 3.57 | - - fos 20 NOTE: TENTATIVE: k VALLE, Gly, 4 sc = Cla + CCX ietayL "FREE RADICAL } ACETONITRILE 76 KER/PAR REACTION ORDER: 2. 50-600 | s.s¢-11) | 0 si00:s00 [0.5 1.5 Chg. + UCL, = Cll, + CUACUANH. + GHyCH.)Ny cu WETHiL, FREE RADICAL + ETHAMMINE 76 KER/PAR REACTION ORDER: 2. s0-soo | 2.9(:11) | 0 2001500 0.5 2.0 Cig. + CCM Cll, + CHCHLNI. ‘eravLsRe avteat ¢ eniakawine 16 KER/PAR REACTION ORDER: 2 50-500 | 2.0¢:11) | 0 46001500 |o.s 2.0 NOTE: TENTATIVE k VALUE.i occuring in combustion—Continued Grea = ™ 7? 4 | 8 Fk | i factors Guy [er Gly. + CDACHEN, Gil, + GRAD + CDQCHC.)NiL, + .CD,Ci, Ml ‘wera REE RaptcaL + EvHaN2,2,9°4,-AMINE ‘76 KER/PAR REACTION’ ORDER: 2. 350-500 | 2.9¢s11) | 0 200500 [0.5 2.0 Gy, + CDQCHEN + Cie + CaCl Wweruye "FREE apical t ErHaN-2°2,2-dy-AMINE 76, KER/PAR ‘REACTION ORDER: 2 a3 4005) | - E NOTE: TENTATIVE k VALUE. Gig, + (CHAN Ole + (GiadaN. 4 CCH, Weetw, FREE nabtoaL.*s"weTeANANiNe, “Neri 76 KER/PAR REACTION ORDER: 2. 350-650 | 1.6(+11) | 0 35002500 0.5 2.0 Gly, + (Ci) ANY = Oa + (Ca). WWETWYL, BREE RADICAL.“+'WETHRNAMINE, N-METHYL 76 KER/PAR REACTION ORDER: 2. 350-650 | 6.5(+10) | 0 2002500 |o.s 2.0 $(Gig) ND = Gh, + cH NOCH TWETHYL, PRE RADICAL + WETHANAMINE=d, N-METHYL 6 KER/PAR REACTION ORDER: 2 aso-soo | 2.9¢s11) | 0 4001500 Jos 1.5 $ (Gig) ND — GigD + (ata) 3h ictal REE Mica» METAR 4, -weninL- a 76 KER/PAR REACTION ORDER: 2. 30-soo | 1.0¢411) | 0 4300500 0.5 1.5 Gy. + CHyNeNCH, = CH, + .CllaN=NCHR SWETHYL FREE Rapteat. + buizefe, DilerwyL— 16 KER/PAR REACTION ORDER: 2. 300-500 | 1.1411) | 0 375,250 [0.71.3 Gy, + CyA=NCH, (CH) NN.) ‘weTWYL REE RavicaL +"Diazeie, Biweravi— 72 KON REACTION ORDER: 2. 300-450 | s.0(410) | 0 04 26 Dy. + CDgN=NCDg Cy + CDANeNDy ETHYL, FREE RADICAL” + DEAZENE? DI (WETHL—4g)~ 76 KEL/PAR REACTION ORDER: 2 300-500 | 6.6(410) | 0 aizssso0 fo.s 1.5 Gy. + MaCHeCligNia = Cll, + .NICIACHNH, Pisani METHYL, PREERABLCAL + 1,2-ETHANEDIAWINE. 16 KER/PAR ‘REACTION ORDER: 2. s0-soo | 3.a(411) | 0 42002500 |0.5 2.0 NOTE: TENTATIVE k VALUE. Oly, + McL a6 + NACHO ichuni2rnde fabhcal, ¢-2'eRUANEBTAGTAE 1e KER/PAR HEACTION ORDER: 2. ss0-s00 | 2.061 | 0 ass0:s00 0.5 2.0 ove: TENTATIVE VALUE. Gy, + NDRCHRCHANDS, > Ci +N CHD oH De ‘ietuyL- Fale fapicat, + 1'2éerutneDi awineca,) 76 KER/PAR ‘REACTION ORDER: 2. 350-500 | 2.0(+11) | 0 40008500 0.5 2.0 Gig. 4 NDC CH ND + CiaD + NDCH-CHND, ichunterade EaotcaL +°122-dnianand RINE 4,) 76 KER/PAR ‘REACTION ORDER: 2. s0-soo | 3.2¢+11) | 0 0.5 2.0 NOTE: TENTATIVE k VALUE. CH (cig) AN “ictal REE WiorcaL +'woMUzINE 1 1-o1NETHYL- 76 KER/PAR TREACTION ORDER: 2. ss0-soo | 1.711) | 0 os 15 + (Cig)aNMie = Gy + (Cla) aNN. + CHiN (Cl Nip “eet. FRE. whoicaL + wvonaziNé,1-1-pinetat- 76 KER/PAR REACTION ORDER: 2. 350-soo | 2.4(411) | 0 29703500 0.5 1.5 4 (Gig)aNNDy. + Gly + CHEN(CH IND. cht PEE Rhorea, VniniezlNed 1:1 -onerIL ‘76. KER/PAR REACTION ORDER: 2 880-500 | 3.2¢y11) | 0 sizsit50 |0.5 2.0 NOTE: TENTATIVE k VALUE. Gig, + (Cla) NNDs yD +. (Cia) aNND. TieTaL FREE RADICAL + HvORAZINE=dy, 1 DIMETHYL 76 KER/PAR REACTION ORDER: 2. 3s0-s00 | 2.10411) | 0 3400:500 [0.5 1.5‘Table of Arrhenius parameters for chemical reactions occurring in combustion —Contnued Ghenieal reactions 7k 7 z Tit] factors Gay | ft Gig. + CHANNNHCH, Ci, + HN. )NHC, + CHANING, ETHYL 'EREE RADICAL + “HYDRAZINE, 1, 2°DIwErH'T 16 KER/PAR REACTION ORDER: 2. 3s0-soo | 2.5(:11) | 0 2400:250 0.5 2.0 Nove: TENTATIVE k VALUE Gy. + CU,NDNDCH, = CHD 4. CaN )NDCH, WETWYL "FREE RADICAL °RYDRAZINE-1,2-42,_1,2-DIMETHYL- 76 KER/PAR REACTION ORDER: 2. s0-so0 | 2.0(:11) | 0 21008500 0.5 2.0 NOTE: TENTATIVE k VALUE Gly. 4 CONCH, = Cl, + .CONHCH, + HCON(. i, Tucows ‘METHYL, FREE RADICAL + FORMAMIDE, N-NETEYL- 76 KER/PAR REACTION ORDER: 2 400-600 | 7.9(110) | 0 sa00ss00 |0.5 1.5 Gy. + CCD, = Ci + CHOON. + C,CON, "WeTHYL’PREE "RADICAL ACETAMIDE 16 KER/PAR REACTION ORDER: 2. 50-600 | 2.10611) | 0 52352500 |o.5 1.5 Gly. + CHACON = Cll, + .CHECONE, TWeTHYLPREE “RADICAL” ACETAWIDE? 16 KER/PAR REACTION ORDER: 2. 50-600 | 1.00411) | 0 s200ss00 0.8 1.5, Dy, + CDsCOMy, > CD,t + Co_coNt. WETHYL FREE RADICAL" ACETRMIDE-2,2,2-4 76 KER/PAR REACTION’ ORDER: 2. 350-600 | 1.1(411) | 0 s2asis00 |0.5 1.5 Dy, + COSCON, > CD, + -CD,C0Ni AETHYL "FREE: RADICAL} ACETANIDES2,2,2-<, 76 KER/PAR REACTION” ORDER: 2 350-600 | 1.4(411) | 0 seoo:soo 0.5 1.5 Gly. + CH,CHCH + (ly) CCH. + CHAC()=CHCH, ETHYL FREE RADICAL ';“1-PROPINE. 72. KER/PAR REACTION ORDER: 2 319-465 | s.0(s11) | 0 00 NOTE: TENTATIVE. k VALUE. Clg ADDITION OCCURS’ PREDOMNANTL AT TERMINAL C ATO Og, asCaC, + Cyc C(.) cH “weTHYL FREE faDtcaL 7 1;2-PROPABLENE 72 KER/PAR [REACTION ORDER: 2. 373483 | 2.0(411) | 0 4100 Gis. 4 CHsCH=Cp + Gly + CHAC(.)=Cllp WETHYL FREE Rapicat ¢ L-PROPENE 16 KER/PAR REACTION ORDER: 2. 50-600 | 1.4011) | 0 4301500 0.6 14 CH. + CHyCHRGHe = Cle + [Call] ETHYL" FREE RapicaL, + 1-PROPENE 72:40" REACTION ORDER: 2. sso-se0 | 3.2(+10) | 0 si7sis00 |0.5 2.0 Gig, + Hise + CigCigOH(. )OHy + (Cy) CHC WWeTHYL FREE Raia. + 1ZPROPENE! 72. KER/PAR REACTION ORDER: 2 asz453 | 1.7¢4) | 0 3700 Whege 0.72 453 2 a NOTE: Keg? Gly. + Ola=Clly Gy. $ CHSC, + Cy (Cla) "wetuy'FREE RaptcaL 7 PROPANE’ 76 KER/PAR REACTION ORDER: 2 sso-7so | 2.0¢:11) | 0 on 13 Dy, + CCDaCy » Dall + CeCDgCh,. “wetuyicd, Fake aptcht. + PROPARE-3:2-a,, 76. KER/PAR REACTION ORDER: 2. 530-750 | 4.acsun) | 0 o7 18 Dy + CHyaGy = cdg + (Clg) 0, ‘wenivEady itee nabidal, + PROPANE-2,2-4, 76 KER/PAR REACTION ORDER: 2. ss0-750 | 2.561) | 0 s7asi250 0.7 1.8 Gly. + CHAGHLCHO + Gy + CHLCHCKO WETHYL FREE RADICAL + PROPaNAt 76 KER/PAR REACTION ORDER: 2. 350-500 | 1.0(:11) | 0 29% 04 16 NOTE: TENTATIVE k VALUE. s7‘Table of Arthenius parameters for chemical reactions occursing in combustion —Continaed Ghenical reactions 7K 4 a Fit | k factors (an | Gi, (GH) Gly + CHACOVG ‘weTnyL, FREE RapicaL.*+ 2-PRoPaNoxE: 6 KER/PAR REACTION ORDER: 2. sso) | 0 49002250 [0.8 1.3 ©. + (CDy)00 = Dy + CDAC(OVCD,. WeTWYL-d, FREE RADICAL + 3-PROPARONE-1,1,1,3,3,3-dg 16 KER/PAR REACTION ORDER: 2 350-000 | 4.9¢:11) | 0 s7asi250 |0.8 1.3 Gl, + HODOCHCHy + CH, +, .CO0CHC, + HODOCH(. dCs WeTuve, FREE RADICAL +“rORiNC ACID EnivL. ESTER’ . 76 KER/PAR REACTION ORDER: 2 3so-soo | 2.511) | 0 00:50 |0.5 2.0 NOTE: TENTATIVE k VALUE, iy. + CHACOOGH, + CH + .ClLz0000R, + ClL,COOC,. WETHYL FREE RaptcaL + ACETHC AciD"weTHyE ESTER 76 KER/PAR REACTION ORDER: 2. 350-600 | 2.1¢:11) | 0 5035500 |0.5 1.5. Gig. 4 CACO, Ci + .cHL,c000, ‘WETHYL FREE RADICAL + ACETIE ACID'WETHYL-d, ESTER 76 KER/PAR REACTION ORDER: 2. 350-650 | 1.9¢:11) | 0 s03s+500 [0.8 1.6 Gy, + cDscw0H, — cH, = eDgconcs ‘wera, FREE RaotcaL ? AckriC-d, AC10 wen ESTER "76 KER/PAR REACTION ORDER: 2 400-60 | 1.711) | 0 soo0ts00 |o.5 1.5 GH,. + cHl,0000CH, + cll, +. .CH,000008, ‘WeTuYL"PREE RADICAL + “chnBoNiC ACTD"DIVETHVL ESTER 16 KER/PAR FACTION ORDER: 2. ss0-so0 | 3.2(11) | 0 5800:750 0.5 2.0 NOTE: TENTATIVE k VALUE. Gig. + (Clg) COOH + CHD + (Cy) g0C-)OH TwetuyL, PRE RADICAL +"2-PROPAN-2-a-O1, 76 KER/PAR REACTION ORDER: 2. 4o0-s2s | 1.9(:11) | 0 49003500 |0.6 1.4 Cy, + (Clg) CHD. CD5H 4 (Ca) aC(.)OD + CH, CHC) OD ‘wetuyL_a, "Pure apical +'2-pabpanoi-a 76 KER/PAR REACTION ORDER: 2. 400-525 | 1.51411) | 0 39752500 |0.6 L.4 Gy. + ey-CHgCHgCLS = Cll, + ey-CHLGN.)CH,S uetuvi, FREE Rafat + TufeTaN 76 KER/PAR REACTION ORDER: 2. 3o0sso | 3.2¢s11) | 0 asg01750 0.5 2.0 NOTE: TENTATIVE k VALUE Gy. + (Gis) gCHSH + Cll, + (CH) HS. + (Gy) ACC. )SH ¥ ca.cHch si wetaiL, PREE RADICAL + 2-PROPANETHTOL, 76 KER/PAR FACTION ORDER: 2. 308 sen |= - fos 20 NOTE: TENTATIVE k VALUE, Oy, + CaCO = CDall 4 CEACHC.)ON + ccc ‘WETHYL=aly FREE RADICAL + PROPANENITRILE 76 KER/PAR 'REACTION ORDER: 2. 400-600 | 3.6(:11) | 0 4330500 |o.5 1.5 Gy. + (Cy) aN Cll, + CAN (Cll) TwetuvL BREE naprcad, + iceviANAMENE,N,xpiweTuVL— 76 KER/PAR REACTION ORDER: 2. 50-600 | 4.7(:11) | 0 eo0:500 |0.7 1.9 Gig. + HOON(GHS) sll, CONCH) + HOD (CH, )NCH. ‘WeTHYL_FREE"RADICAL + FORMAMIDE, “N=N-DINETHYL= 76 KER/PAR [REACTION ORDER: 2. 400-600 | 6.3(:10) | 0 36002500 }0.8 1.5 NOTE: TENTATIVE k VALUE. Gly. + CHACHRCACH cll, 4 CHAE. yC=CH T° GiaCH CECH + Giga Cec. woniL, FREE RADICAL + 1-BurYNE 76 KER/PAR REACTION ORDER: 2. 456-020 | 1.94412) | 0 06 14 NoTE: TENTATIVE k VALUE. Gy. + ChyCaCCHy + Ch, + CxCeOCt,. ‘wera FHeE HaptaL, + 2-BUtYNE 76 KER/PAR REACTION ORDER: 2. 496-619 | 1.1(:12) | 0 9001500 ]0.6 1.6 NOTE: TENTATIVE k VALLE,Table of Artheniue parameters for chemical reactions occurring in combustion —Continued Chenical reactions 7K 4 a Ft | & factors fap ft Gy, + Gly CHCH-CH ClCH. CHC ‘weTnyL FREE RADICAL + 1,3-BUTADIENE 72 KER/PAR REACTION ORDER: 2. 353-458 | 8.1110) 2065, Gly. + Cla=CHCH=CHy CHC, )CHHC, Y caec(cH,) cit weruG FREE RADICKL + 1,3-BUTADLENE 72 KER/PAR REACTION ORDER: 2. k/kyae: 12.0 458 = 2 : NOTE: keer? (lly + CH-C Gly. + CCH CH-CH, cll, 4 CRACK. )I-Ghy wetav"PuEe wapfoaL + 1“avTENE 76 KER/PAR REACTION ORDER: 2. 350050 | 2.5(+11) 42008500 foe 14 Gig. 4 CHyCllsCeCll, ~ CH,CHSCH. JOH, T aicascHt ct) wer FReE RADIGAL 4 1-BUTENE 72 KER/PAR REACTION ORDER: 2 353-453 | 1.0(411) 3600 Kiger: 0.7 | 453 5 - - NOTE: keugt ly + ChyaCy Gly. + cis CHyOI-CHCH, = cll, + ciiyclcHal WWeTHYL PRE RADICAL + ‘ci=-3-BUTERE "16 KER/PAR REACTION ORDER: 2. 30-650 | 1.3411) 100:500 Joe 1.4 Gy. + eisCHyCIACHCH, + (City) CHDK. ly ETHYL FREE RADICAL + eis-2°BC TENE "72 KER/PAR REACTION ORDER: 2 353-453 | 4.5(410) 3675 Kiger! 0.2 | 453 5 e Z NOTE: kyee! Cll» + Cy=Cly Gly. + tranecCH-CHCH, + Cl, + cHlscH-CHCH, ‘ietwvt Fae RADICAL + erane-3-BUTENE 76 KER/PAR REACTION ORDER: 2. 350-500 | 1.0(:12) 49n0s500 0.6 1.4 Cy. + trans Cli, = (Cy) CHER. Vay Wweravi FREE RADICAL } ceans—2°BCTENE 72 KER/PAR REACTION ORDER: 2. 353-453 | 1.s(a1) 4075 What 0.4 | 458 = = NOTE: poet Cy Cy. + (Cig) C-Cly = Cy + CHR C (Cy ietaYL FREE aaBican + t-paoprse, 2°uerifL— 76 KER/PAR REACTION ORDEX: 2. 350-600 | 3.0(:11) 06 1a lg. f (Clg) CHCl = (Cy) OL. + (ig) (CHC, ETHYL FREE RADICAL + I2PROPENE, ‘2_weFRiL— 72 KER/PAK REACTION ORDER: 2. 358-458 | 1.4(411) 3475, Kikyge: at | 483 7 Z NOTE: yoo? Cy + ClaeCa Gy ¢ CLaCUaGleC = Cy + CLC CH ‘evi, FREE RADICAL + BUTANE "76 KER/PAR REACTION ORDER: 2. 350-750 | 4.0(+11) asaorzso 0.7 1.3 Cy. + CigCHaCHCly Cll, + CHSC hy ¥ ccc METHYL FREE SADICAL + BUTANE 72 KON REACTION ORDER: 2 350-500 | 1.6411) asweiso Jo7 14 Dy. + CHyCDCD4CHy Cyl + CH CDC, WETHYL=dy FREE RADICAL + BUTANEW2,2,58,324,. 76 KER/PAR REACTION ORDER? 2 600-750 | 4.8511) siasizs0 Jor 1.8 (Dy. + CHyCDgCD5CHy = Cy + CigCDAOD Jey Wwetuvid, Fade RaprcaL + BUTANE-2,2.3,5-d, 76 KEL/PAR REACTION’ ORDER? 2. 600-750 uy o7 18 Gg. + (Clg) CH Cy + (Cl) C+ (Gig) aC. ‘wera PRE RaprcaL*y PROPANE, “2-wenwti= 76 KER/PAR 300-500 | #.3(s10) 40003500 0.5 2.0 REACTION ORUER: 2.Table of Arthenis ps meters for chemical reactions occurring in combustion—Continued Chenical reactions TK 4 # eK K factors dak | £ iy. + ~ Gig +, (Cla). etal REE ante "ohoPRRE 2 wer 76 KER/PAR REACTION ORDER: 2. 850-750 | 9.6(+10) | 0 9975:250 ]0.7 1.3 yz + (Chg) gD CDall + (City) CDC, iekatody Mex elt ROMMPSA, aera prey eacrio Gaiae 2 sso.as0 | oem | o | srasiaso for a Oy, 0) (Cad. ital? Mee abt, SPW 2-4, 2 no ea er ssoro | racy | o | sowaso for as 4, ¢ Cyc ly» cA CI-HEO). init Fee tanict, 3 SoTL Tokina REACTION ORR: 2. so-so | oui |o | sus for 2 vores TENTATIVE. Cg + Hy C00GH, + 5 cenit ita eo Mca. YoSa ante Teun Pat EACION Oem: 2. soo.s00 | 22cm | o os 1s Gg + (2050. ch, + cem00% ful itt tnica"t Acetic a tenon TERR elt DE. soos00 | acy | | ansoo foe 4 4 emgc40, + C8060) ict MBE fate, Mina pata cro. omen: 2. aso | roca | o | asso Jos 16 sore: TREAT ae. Hy. + (Clg) CHCHO GH, + (CiL,) .CHC(O). kal MEE tc, cea seine escrow OUR: 2. asosoo | oun | o | armsoo fos 16 sore: TTP ALE Oy OsCgcH, = ch, + Hye, + co, “ERE iyorca, + 2-svrgone oneal Aithov omer: 2. son-s00 | s.2ci0) | 0 | srmsoo fos 1s + ooo cc iat ok anita” ova ORE esx aN elctto ona sass | sein | o | ses sect, oy mR, wooocH (eit + as woe, 1gCH(.)CHy 1 Heal eke vn APE inca « ronwrc acto enor, esx Tone elcttn oma aso-soo | asc | 0 | smsoo 20 NOTE: TENTATIVE k VALUE Gis. + HODOCH CH) > Ci 4 .COOCH Clg) F ubooc(.) (CHa. coo CH, yc. ETHYL FREE MABICAL + FORMIG ACTD 1-WETHYLETHYL ESTER 76 KER/PAR REACTION ORDER: 2. 50-500 | 2.s¢s11) | 0 s9a0:500 |0.5 2.0 NOTE: TENTATIVE k VALUE. Gy. + CHACHLOCH.CH, ~ Cl + CHACHLOCH(.)C cals METHYL FREE RADICAL + ETEANE, 1,1°-oxvBIS- 76 KER/PAR EACHION ORDER: 2 400-500 } 2.5¢:11) | 0 42001750 |0.5 2.0 NOTE: TENTATIVE k VALUE. Gly, 4 (Cad sCSH + Ci + (Clha)sCS.. + CC (Cia) SH ‘weTHYL FREE RADICAL + 2-PROBANETIINOL, “2=METHTL= 16 KER/PAR REACTION ORDER: 2. 308 s.o¢7) | - = jos 20 NOTE: TENTATIVE k VALUE. Gly. 4 ObCHENNCHCH, = Gl, + CHO.) =AVSCHC, 7 ih vETHRL FE ADTCAL + ACETALDEHYDE erm. tDENERYDRAZONE 76 KER/PAR REACTION ORDER: 2. 350-600 | 2.5(+11) | 0 0751500 0.5 2.0ions accuring in combustion—Continued Grevical voactione 7 7 TR] a tore iy | er Gi. + GaHCHCIN, — Gly = OCH,CH cM. + CHLCHSORCH. Mi + CHC CHC N ETI Fy RADICAL T-AUTANINE Te KERR AEACTION ORDER: 2 ws | s20 - fos 20 sore: TEMITIME k VALE. Cy. «(GLC ANK = Cy + (CLIN. Fanci lc ch NHC, vr pee adoteaL rfageuind, eri ToYak ENCTioN ORES 2 so-so | 2.2(-11) sssossoo fo.s 2.0 vores TEMITIVE K MALLE, CHhy. + CHhyCHHaN(CH,)2 = Ci,» CH CHC DN(CH da aed. araiNal ETI PAE Moicat"s ETmNWWINE 9-prveri To-AEN/Pak EtcrioN ORDERS = wo | 266 - fos 20 Nove: TENTATIVE L VALE. Gly = CHOON )2 = Oy + CHOON * Gadn(en nee, METI AED RicaL sceTAMDOE, §,.-D1UETINL Tova EXGHTON onMER 2 sso-cn | 2.0(:11) sams00 |o.s Gig, | CLOONGH), + Gly + CHACON Chae ein MEL ARTcal <“Hdstvetdey 4 kb TO KER/PAR REAGi1ON ORD 2 aso-cm | 1.0¢11) sisis00 |o.s nove: TENTATIVE KALLE Oy. | OI (Gb,)-alal, - aby» cigaljan Ch, via fare unica. Pere 7 AER/FAR THAETION OWOER: 2. sso-es0 | 4.51) 4500:500 Jo.6 1.4 Cy, + eis CC CHEN, + CLC CHC)OH Ce itd HMDHCAL = esc-o-reNTE aenvean TEACTION ORDER: 2 8 - 0 Oy, + cincCCLLOH ONL, Cy GHRCHCCH JOH 1, iin Fa RIAL eic-o-PiSTEE TE Mak EACTON ORDER: 2 Eo ; as Chg, 4 (CHDACHCIGL, (Ca QHERC DOH, vino Pee munch. © SatiSbe ssibrte TE AEN Eat ENGTION OnE 2. 28 - 300 Ga § (Olly — Ce + (Cy gSl pCHeCy ei fais aotch 2 Shrink sSthitee Te KEN/Pat Agron OM: 2. sso-c00 | aac weassts00 fos 1.5 Gig. 4 (Gh) CO101, = ky + (Clg)aC-CH CH, seneteht “crak IHL HEE MICA. « 2-muTENE, 2-verint— To KH Pad Hadnion OWE. 2 00-500 | 4.9¢:10 ssv0:500 Jos 1.5 nove: TESTATIE ALLE Gilg. = (Clg) aC=CHCR, = (Cy) OCH) 2 con abt Sema)» WONL?HEE MOLE + 2-onene, 2-weninL- Aba REACTION ORDERS 2. K/kyags 0.4 | 458 - - NITE: Keer ly. + OO sos.ass | 1.4010) 070 TENTATIVE k SALE Gig « CHOLCHCLCHy = Che + GA GH,G, Cy vio tre EAL» rektiN To KENPAR REACTION ORDER: 2 50-800 | 4a¢411) 0713 NOTE, TENTATIVE & VALUE. a, + cuckaLael oh + cuckcaKCG ‘-obomaemo WETHYL FREE RADICAL ~ PENTANE. 350-800] 6.0(+11) Ge TO KER/PAR REACTION nex; 2. sort: TENIATIE VALE 61‘Table of Arthenive parameters for chemical reactions occurring in combustion —Contnued eal Fenton 77 7 co re a (in k) f F Gs (OG AEICGL, Ol lac ea eta RE abc. + soe, SARA” rae ba WiscTiON Oe: 2 asoi0 | 9.610) | 0 | sorsiaso for 1.3 vores TATE YALE hy, 4 (chy) OH CL, + + (Gg HEHE VCH, chal PREPAC | ete SUMAN - pa isGTION OER: 2 } noun |o | assis Jor 1.3 woe, TESTE VALE, Cy. + (Ch gCHCLCh, = ay + (pCO daentiacae veri hed RABTCL + won, 2-aptI— Tene Acne: 2 sor | rau | o on 1s sore: TEXTE, va lg, (Ch4C + hy + (p08 ef "FRE aioe | ARORAES'2 owen. EN eA ction OEE sooo | asciy | o — | soinsso foe 14 a4, | aaLCciaN «al, + cigaHzccH,0(0) cha Pe Bibi, «ret TenaPAe rion ous: 2 asosoo | soci | o | suss00 fos 1.6 sore; FEMAT IE van Cy, CHARON CHO = ae + eI ICC0 ial MEE COREA, Bet: Sat pay ica onan: 2. ssos00 | roc | o | seo fos 20 nore: TEMTATHGE vat CHa. + (CHa) aCHCH ACH GH, + (Cis) 2CHCH, eft PRE eine. + pny RE eenad ction Ow: 2 asosoo | rom | o | aurossoo fos 1.6 vores TESTE YALE hy, 4 (cb gcEMO ch + (Cha) ial PES Mca rik 22 vera Toe eat Iiscr168 Mtn sss | roc) | o | sis fos 20 vores TENTATIVE VALE, hy. $ (C409 = + CCH IDOE, 'y falco vinta Boa, + s.rearawne Tea THNcHow one: 2 soos | r.9ny | o os 15 a, + (aeH,),00 — ly + alycecne,ca- ict PED Rica. 4. pestines Sina, prea riser oii’ sm-o00 | 2.00 | 0 — | ssssssw los 20 4 (cH0,),00 cleo + clcascoen pal, ich ED Rica, Poin oe, Teenie acti iin sm-o00 | 1.2011) | 0 os 20 A 4 HOD(CHsCl = Oly + HOLE cH, women SBA + Relcason Sean omen chart pos + Neue ETM AMECUACAL | onde 49 Bera, sex TE ea eactIon ek sono | esc ]o — | soos fos 20 vores FEAT YALE. Cy. 4 CHOC, + ay + Ged VaWEN, Cy | ei geen “ea eanelsth, + Seon iE fou, + porsyore acto eran. esex aah Ea rio bln: aoosso | 2.sciy fo | anasisoo fos 1s Cp. + (CHCHAN = y + CORO, dane ia can AG: virile Reta eau eiyy-n-veL- Teena itction omar 2 wo | sen] - - fos 20 NOTE: TENTATIVE k VALUE 62‘Table of Arrhenius parameters for chemical reactions occurring in combustion—Continued Chesical reactions 7K 4 z k factors dinky | £ (His, + (CHa )eNCON(CHy)2 Cl, + CaN CH, OON( CHa.» ‘veruvL Fae RADICAL” UREA TeTRANERHL 76 KER/PAR REACTION ORDER; 2. 50-550 | 2.0(s11) | 0 39752500 }0.5 1.5, CHis. + cis-CHaCHACHCH-CHCHL, ~ Citi CHaCH .)CH(CHa)» VWETUYL FREE RADIEAL + cis-2-uEXE! 72 KER/PAR REACTION ORDER: 2. 298 - - 4060 His, + cis-CClgCHCH-CHCHly -_ Cll,CH,CHlaCH (Cils)CH(.)Cl, METHYL FREE RADICAL + cis-2—uEXENE 72 KERIPAR REACTION ORDER: 2. 298 - - 4150 Cis. + CHyClaCHRC(Cits)=CHlp = CliyCHgCHlaC() (Cis) Clay ETHYL FREE RADICAL + T-PENTENE, S-METHVL~ 72 KER/PAR REACTION ORDER: 2 208, - = 3450, City. + ei e-(Clly)aCHCH=CHCly > (CH) CCH. YOK)» ETHYL FREE RADICAL + cis-2-PENTENE, 4 N@THYL- 72 KERIPAR REACTION ORDER: 2 298, = - 4390 CHiy. + (Cll) aC=C(CHlg)> = Clty +. (Cily aC (Cll )CCH Wwetavt, REE RADICAL » 2-BUTENE, 2-3-oiMeTityL— 76 KER/PAR REACTION ORDER: 2 403-614 | 7.80411) | 0 41002500 }0.6 1.6 Gils. + (Glad C-C(CHla)2 = (Cy) CCL) (Cad Wwetuvi, PREE RADIGAE + 2-BOTERE, 2-3-o1iefHYL~ 72 KER/PAR REACTION ORDER: 2 403-453 | 1.01410) | 0 3400 NOTE: TENTATIVE k VALE. Wh peet 453 5 E = NOTE: yee? il. + CHla=CHly iy, (Aha) ly Cla + CHa (He) i WwernYL FREE fabicaL + HEXANE. 76 KER/PAR REACTION ORDER: 2 350-800 | 4.8(s11) | 0 58002250 | 0.7 1.3 NOTE: TENTATIVE k VALUE, Giz. + Cy (Gia) Clty ~ Cy + CHfyCHLCH(. )CHg CHC, P aigcscH Cia. yc, werllyL"FREE RADICAL 2 HEXANE. 76 KER/PAR REACTION ORDER: 2. 50-800 | 7.9¢-11) | 0 4830:250 0.71.3 NOTE: TENTATIVE k VALUE, ily. + (CHa) aCHCH(Cily)s Cll +, Cia CH(CHy)CH (CH) 2 Tweruye PRbE napeckis purané, 2,3-Bineni— 76, KER/PAR REACTION ORDER: 350-750 ° 8002250 0.7 1.3 NOTE: TENTATIVE k VALUE Os, Ata) UCN)» hs 4 (hac JCH(Cs)2 TweTavL FREE RADICKL”+ BUTANE, '2,3-DIETIVL 76 KER/PAR REACTION ORDER: 2. 350-750 | 1.9011) | 0 s975:250 [0.7 1.3, NOTE: TENTATIVE k VALUE. CH, + (Cia gCHCH(CAy)» = CB 4 (Ci) CHCK)(Cls) 2 GtgGHUC OHCs ETHYL FREE RADICKL”s BUTANE, 2,3-DIMETHYL- 72 KON REACTION ORDERS” 2 5.0610) | 0 345 Ds. + (Clad -CHCH(Clyd2 > CDgH + (Clly aC ICH (CH) 2 Y scacHi CHC) WETHYL-d, FREE RADICAL + BUTANE, 2,3-DINETHYL 72 KOR REACTION ORDER: 2 439.566 | 4.7011) | 0 4525 Gilg. + (Clla)gCHOCH(CH)2 = CH, + (CHly)aC(. OCH Cy) -CiCH (CH) OCH (Cli) METHYL FREE RADICAT, + PROPANE, 2,2°—OXYBIS— 76 KERIPAR REACTION ORDER: 2 00-600 | 2.1cay | 0 41002500 }0.5 2.0 (Hy. + (City) aCHOOCH(CHly)y + Cll, + (Clis)6C - )OOCH( CH)» 2 cil,Ci( cil, yo0cil (Gis) METHYL, FREE RADICAL’ + PEROXIDE, BIS(1-NETHYLETHYL)~ 300-450 | 2.3G11) | 0 4100:500 0.5 1.5, "76 KER/PAR REACTION ORDER: 2‘Table of Arsheniue parameters for chemical reactions occurring in combustion —Continued Ghesical reaction= 7 7 2 Fh | & factors Gow [tor Gig. CHRGHRNC(CISD e+ GCE )=AC(GI)s 4 eCHeNC( Chg? GigcieNc( Cis} ci, weTuiL FREE RADICAL "PROPANTMINE, N-ETHVLIDENE-2-METHYL- 76 KER/PAR REACTION ORDER: 2 aso-soo | 8.010) | 0 30254500 [0.5 1.5 Chg. 4 (Cl) gCHNHOH CH) > Cy + (Cy) CAN )CHUCH ¥en). NICH(C) 2 WETHNL: FREE RADICAL + 2-PnopANAMINE,,V_(1-METAYLETAYL)-| 76 REN/PAR TEACTION’ ORDER: 2 | sso-soo | 2.0¢11) | 0 ssz0e750 Jos 2.0 Nove: TENTATIVE k VALLE. Oy. A (GEN, > Ol + CGC INCH) (GH cH), *yérnit BREE RAOTGL + enaanauine y,y-o1ETAML- 16 KER/PAR [REACTION ORDER: 2. 50-600 | s.0(321) | 0 ao00:s00 [0.8 2.0 NOTE: TENTATIVE VALUE. Cg. + (ChyHla) CH = Clg + (CHdgC ‘wera, FREE HaDICAL + BeNrAne® sett 70 KEL/PAR REACTION OnDER: 2 350-750 | 9.5(410) | 0 sorsi250 [0.71.8 Nove: TENTATIVE k VALUE Oy. + (Cla) CH + Clk + (CHCl) CHER) WweTavt, FREE RADICAL + Penranes 32 efaVL— 16 KER/PAR REACTION ORDER: 2 350-750 | 6.0011) | 0 or Ls NOTE: TENTATIVE k VALUE Cy, + (igi) gC + Che + (CH) CHOC WweTaYt FREE HaDicaL ¢ PeNTaNEs 37EfHYL~ 76 KER/PAR REACTION ORDER: 2. 50-750 | 7.10411) | 0 5002250 [0.7 1.3 NOTE: TENTATIVE k VALUE Gy + Cl (Hladg Cla + Ce + CHO) “et AER Sabie, «Bern 7 KER/PAR REACTION ORDER: 2. sso-s00 | 4.811) | 0 58001250 [0.7 1.8 Nove: TENTATIVE k VALUE Gy. thy (GhareOy + ky + Cy Cg) CHC. CHAM, * ch cil) EHC yetacly “cl (Cha) CH Ci, were faée nabiCAL + ocrate 76 KER/PAR REACTION ORDER: 2. so-so | 1.2(s12) | 0 4302250 [0.7 1.8 NOTE: TENTATIVE k VALUE Cy. + (CHa) gCCHCHL CR), + Cl, + (Cy) CC HICH) Wwetu, FREE RADICAL S"peNtANE® 2.2.421RIMETHYL- To KEN/PAR REACTION ORDER: 2. 350-750 o O71 Nove: TENTATIVE k YALE. Gy. + (CH) OCHACH( Cl)» > CRs 4 (Gla) gCCHCl) (Cl) wera, FREE RADICAL" "PeNTaNE® 2.2, 4°rIMeHYi— 76 KER/PAR REACTION ORDER: 2. 350-750 | 9.5(+10) | 0 sovsi250 0.71.8 NOTE: TENTATIVE k VALUE. iy. § (Cla) sCCHCHCCH)g > Cy + (Cy) CCC, 21 c(Ciy) aac (cil) ‘BeNTANE, 2.2.4-TRINETHYL— necriow onper: 2. 350. 1.2012) | 0 58002250 0.7 1.3 NOTE: TENTATIVE k VALLE Gy. + (CH) CHO (CHO)CH(GH,) = Cy 2 -GieciG cu GIO) CHS) = WwoTaGL, FREE RADICAL + PENTANE, 2.3, 4—TRIMETHYL- 76 KER/PAR REACTION ORDER: 2. aso-750 | 1.2012) | 0 seooizs0 fo.7 1.8 Nove: TENTATIVE k YALE. Oy. 4 (Ci) CHANG )CH(CH,) 2 > Cll ¥ (ta) EHEC) (CHL DOH CH} "4 (Cy) EL -)H( Cia }CH( CHa) ETHYL FREE RADICAL + PENTANE, 203.4-TRIMETIIYL- 70 KER/PAR REACTION ORDER: 2. 350-750 | 2.9¢411) | 0 aorsi250 [0.7 1.8 NOTE: TENTATIVE k VALLEing in combustion—Contnued ‘Table of Arrhenius parameters for chemical reactions occu Thetcal Veaetions 77 Ta Ce dy [EMF Th + (Gy HONIG, + ial BED abel Pty 203 hn IEichigs ont aes | aren fo | ast Ch, (CH g ECAC = | aL gla irk HEE EAB" abe; 2 Sete reauuat Wisciton oats 2 soa | racy fo | sn2so for 1.3 nore; TENTATIVE VALLE Cy + (Cy }gC0CICHa)s = cy + -Cigerce 0c ich ER HAOTeR, Fenotta, BEL bMaeM EL) Teal Ear ibat ssosw | recy | o | soars fos 3.0 Oh =. +H iui BON neacrioy owen: 1 rave-iaio} 2.05) | 0 | soso 40 ay +08 vinand «ict tou 2 kt escrow one: 2 ssormo} rei |o | aso for as Oh, 0» ly, + of yn Dic row TN reaction one: 2 ssao-2si0| a.ocis) | 0 | asanisoo foo 1.6 Oh eH Gly te vy «Mind stow Tee rection nner: 2 rso0-2500{ 6.31 | 0 | spose fos 2.0 cheb ah sm vy Uhinattn aro al escrow nme: 2, sexe | esi) |o | sto lO Oh ed nite, ioc Feee santa, TN ETON owner: 2. rsoo-2s00| 201s) | 0 | soos os 2.0 he $k ay 4 cate nines SEtndsGMME nes onc Te ECT nner: 2. vsio-2500| 2.sc1 | 0.7 [sous Jos 3.2 Oh chy = cl, + ch vive 7 AERA Fis saptea TONE Resttion one: 2 vsoo-2500 | 1.312) | 0.7 | roo902500 Jo. 3.2 1 Ohy, = Oy, + Ol, nie ued net orca Te Pa Atacrion one: 2 aso | soci | o | rssias0 for 1.9 OND +. = Oy, + Oy Nerantta within‘ fee motca, iS ba BU omen: 2 oo. | s.0c10) | 0 | raamsoo fos vore; FEAT Ya Cl 4 Oly. Ody, + Oy uth" Win, Fite maotea, To Karan ESCH owDER: 2. woo | uae | o | ossiase for 1 wore: FEST YALE, ht ye Oy tai Win PE nape nated ttHon noe: 2 srosio | asciy | o | caso fos 1.5 i Cy. = Cys + Oy iia ini Sy‘ree onca. oe ACTOS owen: 2 was] sacin | 0 | osm cs ck = HOt man's CHSC FREE aDICAL ray TEETIOW noe: 2 rso-2s00| s.2cn | 0.7 | 2500200 Jos 3.2 tw = Oy. He vata Tee ieacrios onan: 2 rsma500| 2.00 | 0 — awsssio fos 2.0 65‘able of Arthenius parameters for chemical resetions accuring i combustion—Continved Chenical reactions TK a 7 TR] & factors Ging [ft clo =) + METHYL, ONO-. FREE. RADICAL 10 BEN/O"N REACTION ORDER: 1 298 5.0418) | 0 9560 HO +0 = Cp 4H METHYL, OOH. FREE RADICAL + OXYGEN aTON 76 iNG REACTION ORDER: 2 1500-2500] 3.2¢401) | 0 041300 Nove: ESTIMATED. HO 40 = C0 + of METHYL, OX0-, FREE RADICAL + OXYGEN ATOM 70 ING REACTION ORDER: 2. 1500-2500] 8.2) | 1.0 | 25081500 Nove: ESTIMATED. Hs = CD + Hy WETUVE, OX0-, FREE“RADICAL + OXYGEN MOLECULE 76 iNG REACTION ORDER: 2. 1.6¢+12) | 0 350051500 Nove: k ESTINATED.. alo so + ETAL, Ox, FRE RADICAL. + HYDROGEN TOW 76 ENG REACTION ORDER: 2 1500-2500] 1.6(412) | 0.5 012500 }0.8 3.2 ato + on = co + H,0. TIL, 0, HEE RADICAL 4 HYORORYL, FRE AOICAL REACTION ORDER: 2 1500-2500] 3.24310) | 1.0 11500 sore: U eSttMareD G0 + HO, = HOH + 08 METWYL: ON0-, FREE RADICAL + HYDROPEROXYL FREE RADICAL 76 ING. REACTION ORDER: 2 1500-2500} 1.0(+14) | 0 150081500 Nove: k ESTIMATED. 0K = HCN + 0 METHYL, OX0-, FREE RADICAL = NITROGEN ATOM To iN REACTION ORDER: 2. 1500-2500 | 1.0(+18) | 0 :1000 Nove: ie ESTIMATED. HO N= oo + MH METHYL, OX0-, FREE RADICAL + NITROGEN ATO 76 iNt REACTION ORDER: 2. 1500-2500] 2.0(411) | 0.5 | 10002500 Jos 3.2, cH +80 = cD HNO METHYL, OX0-, FREE RADICAL. + NITROGEN OXIDE(O) 76 ING REACTION ORDER: 2 1500-2500} 2.0011) | 0.5 | 100022500 fo.s 3.2 HO 4 HNO = HCHO + No METHYL, ON0-, FREE RADICAL + NITROSYL, AYORIDE 76 ENG REACTION GADER: 2. 1500-2500] 3.2¢411) | 0.5 02500 0.8 3.2 -GH4 GH = 00 + Oly METHYL, OXO-, FREE”RADICAL + NETHYLIDYNE. PREE RADICAL. 76 ING [REACTION ORDER: 2 1500-2500] 3.2(410) | 0.7 | s0os2500 Jos 3.2 C10 + Ce = OD + Cy METHYL: ON0-, FREE RADICAL + ETHYLENE FREE RADICAL 76 ENG REACTION OADER: 2. 1500-2500] 3.2210) | 0.7 | sooszs00 Jo.s 3.2 CHO Cll. = OD + Ce ETWYL,"ox0-, FREE RADICAL « METHVL FREE RADICAL 76 ING REACTION ORDER: 2. 1500-2500} 3.2G11) | 0.5 0:2500 [0.3 3.2 CHO + CHO HCH. + 00 METHYL, ONG-, PREE RADICAL 76 BN REACTION ORDER: 2. 1500-2500] 16:11) | 0.5 12500 Jos 3.2 cH 5 CN = HON 4 0D WETHYL, OX0-, PRES RADICAL 4 CYANOGEN FREE RADICAL 76 ENG REACTION ORDER: 2. 1500-2500] 2.00411) | 0.5 o:2s00 [0.3 3.2 HCHO sO CHO + on FORWALDEAVDE + OXYGEN ATOM 1500-2500 | 1.0(411) | 1.0 | 1750:1000 Jo.5 2.0 76 ENG REACTION ORDER: 2 66‘Table of Arthenius parameters for chemical reactions occurring in combustion —Continued Chenical reactions Tk 7 a Fit | factors Gan |e HOH 5 0 = products ORMALDERYDE. + OXYGEN ATOM 73. HER/HUT REACTION ORDER: 2. 300 s.o(s10) |= - for as HCD0 4.0. = products FomwsLoenvbeed OXYGEN ATOM 73: HER/HUT REACTION ORDER: 2. 300 4.910) | - - for 13 HCHO HCHO + He FORMALDENYDE + HYDROGEN ATOM 76 ENG REACTION ORDER: 2. 1500-2500] 1.3¢:10) | 1.0 | 1600 0.8 a2 HHO + OF = -cHO + Ha0 FORMALDEHYDE + HYDROXYL FREE, RADICAL 76 ENG REACTION ORDER: 2. 1300-2500 | 3.20510) | 1.0 ox1so0 }0.5 2.0 HCHO + HO = CHO + #0 Poruatewvoe’¢ wvbRoPEROXYL FREE RADICAL 74 LO REACTION ORDER: 2. 300-s00 | 1.0112) | 0 4000 on Ls NOTE: k FACTORS ARE: f= 0.1; F= 10, AT 300K HHO + CH .H0 + Oy PORNALOENYDE ~ METHYEIDYNE. FREE, RADICAL "76 ENG REACTION ORDER: 2. 1500-2500] 1.0(:11) | 0.7 | 200022500 Jo.3 3.2 HCHO «Ce = CHO + Cha. FORMALOEHVDE’+ METHYLENE FREE, RADICAL, REACTION ORDER: 2. 1500-2500 | 2.0(-11) | 0 sevoniseo | =~ NOTE HCHO, + Cis. CHO + Ci PORNALDEHYDE. + METHYL FREE RADICAL 6 KEK/PAR EACTION ORDER: 2. raguy | o 0.5 1.8 76 ENG LoGio) | 6.5 08 32 DODO 4 cily. = .c00 + tio FORMALSENDE-d + NETIVE FREE RADICAL 76 XERUPAR REACTION ORDER: 2. 300-500 | 1.41) | 0 os 15 HCHO + CN = .cH0 + HN FORIALDENYDE + CYANOGEN FREE RADICAL 76 ENG REACTION ORDER: 2 1500-2500] 1.3¢:11) | 0.7 | 1500:2500 Jo.8 3.2 HoH Ms cH + Ha FORWALDERYDE. 76 3G REACTION ORDER: 2. 1500-2500 | 3.2017) | 0 4300022500 |0.3 3.2 Chon cw EMH, HVOROKY-, FREE RADICAL, 70 BENIO"N REACTION ORDER: 2. or.773 | Lacs) | 0 14600 G0. +0 = HHO = METHOXY FREE RADICAL + OXYGEN ATOW 76 ING REACTION ORDER: 2. 1300-2500 } 1.014) | 0 01500 Nove: ke ESTIWATED. Clg. + Op HCHO 4 Hoy “WeniOXT FREE RADICAL 2 OXYGEN WoLECULE 76 ENG REACTION ORDER: 2. 1500-2500 | 1.0(:12) | 0 300021500 Nore: b ESTIMATED. GO. ¢ H+ HaHO + Ry METHOXY FREE RADICAL + HYDROGEN ATOM To ENG [REACTION ORDER: 2. 1500-2500 | 1.014) | 0 021500 NOTE: ke ESTINATED.. yO. + OH HCHO + H50 METHOXY FREE RADICAL'+ HYDROXY FREE RADICAL 76 ENG REACTION ORDER: 2. 1500-2500 | 3.2(+13) | 0 01500 Nove: k ESTIVATED.. CHO. +N = HCHO. «NH METHOXY FREE RADICAL + NITROGEN ATOM 1300-2500 } 1.00114) | 0 021500 76 ENG REACTION ORDER: 2 or‘able of Acthenivs parameters for chemical reactions occursing in combustion —Continued Ghenieal FenctTons 77 7 7] 1 factors dey [EEF Gig = Wao W sony FREE RADICAL a ACTION oRDER: 2 vso0-2s00 | soo) | 5 | uszssis00 some: E'estiuren. CH + Gly. = salon + cH nial eit ek fbrea To KEP TEACTION ORDER: 2 so-so | roc | 0 | sossisoo foe 14 GAO Gh. = a0. + Oly nial”. erin ade Rlotcy, Te KERPat REXcri0y ooeR: 2 ea | 0 | avo0ssoo fo.6 a8 GOH 5 ch. = cho. + aon ETiANIE's wine mAbTeAL To REAP REICTION ORDER: 2 aso-sso | 2am | o | amossoo fos 1.4 400 + e,. = 0100 + coy AbriavoLa + vinifteay HABE eaptca 76 KER/PAR REACTION ORDER: 2. wos | roc | 0 — | sooosse fos 2.0 1,00 + @,. = yO. + cy ‘weriaNolcd + werivi-d, ‘FREE RADICAL To KEP AEACHION ORDER: 2 so-so | a.acno) | 0 | sroos1000 Jo.s 2.0 nome: GIVEN TEM CUTION, 10H | chy. = 0,08 + cH, WWETHAN=d-OL "NEFIVL FREE RADICAL a MERCHIOw omen 2. stesso | 2.0 | 0 | soiorsoo 0H. ch. + co. + ly io «tind, Fae: eapica, Tehri REACTION ome: 2 svosso | orc) | 0 | spoossoo fo.s a. CHg00H co. 4 8 Hoenn, ete. “or BN BACTION one: ses.osi | roc | o fare Novi: TATE CONSTANTS MAY ae SLIGATLE Loe S10. si 0 abot onosttrtoe ries: eapicu. « oxycey arow bya eaGrion ORDERS 2 ao | ras) |= - fos 1s 10 - s+ @ fatbos sonstteror rau mabicaL, + oxygex arow 75 WENOL aeacriow ea 2 ssa fos | o G40. src fatbos ooSutrioe mee mapIeA + oxen "5 BENCOL EAGT OnDER: 2. sci) | 0s | aso Sit. seat Catuoy wONISELEIDE FREE RuDIcAL, + sroROGEN aTOU 38 BENOL Cio OnDEK: 2 racis | os | soos in. Hee xtuos ubsuLerog meee suDIcaL. + wvoRocen 4Tow SS MEV COL TeAcrioN OER: 2 2.0113) | 0.5 | a0 Bis = $1 ‘aRtoN WONSUIDE PEE RADICAL + sULgUR ATOW 8 BEWCOL REACTION ORDERS 2 esau | os | o is. Cis akuos uote me RADICAL « SULFUR ATON 5 BEML HEACrion ‘kn 2. roca» | 0s | sous Se oso ‘atuon woosttFLDE ex saotea, « suuzun srow BA HAGrioN Omen! 3: 100-2700] v.70 | | aso fos as nome: ty # Key‘Table of Arshenive parameters for chemical reactions occurring in combustion—Continued Theaeal TectTons 7 7 TT teres dey [t Salsa Gal osu FREE aaniea» nerogen ou eat eAcrion Oe: nsci | os | aso cen = cans aod wowsttrioe es MoIcaL + tmmo6e sTou eh ecrion vies soca) | 0.8 | sr200 sic. s3c aod wbdsKfrioe REE eoIcaL + campo aTou setae eer oan s.owy | 0.8 {2s ic. cies so MSIL FREE AADC + cao ATO "aan etrdos oi ssa | os | o 10 = 3 +9 ‘lato ‘Sufi 4 oxen aTow ent oY hcrios one: 2 a00-1000 2.2¢213 | 0 ro for 1s 40. css chabo"otttrind oxen ston se ail cro owen: 2. we | nau | - fos 1s 48 ~ O84 cabot 5 suusve stow etal oY TBlcriow one 2 we | agua | - fos 1s yi = ys 4M chibov nng tase ail reveriow omer: 2. x: an |im-s700| 2.0018) | 0 | seesose00 |o.s 1.8 cs +0 = oo + 39 cinbov one sitrne + oxveen arom elt on EAETOs owe: 2, ron.i200} roc | 0 | sasoo Jos 1s vore; {'rRcrOts cuncrneo. ord Fe 5 ADV oo ous = ob + 88 cag oxtn'slrine re auran ection one: 2 we | asa | - fos 1s ons 4s = ob 4S cub ‘ooe'sttrne + suru stow ton TEA onuet: 2 nozao] iri |o | ass fos 3.0 as, + ole = cy soc rig fi FREE HOTOAL ena 72 KER/PAR ‘REACTION ORDER: 2. 298-333 7.9(4 7) - a AS, | GaSe = ch hac inlaid ate? hue: Kae Teton ost: 2. re ; aS, GHC, eH SCHDCH aH, rin HO REP aac Se Tee Erion onoen: 2 easy | roe 9 | - : Nore: Glestrane BUILINIUN ~ HEIGHT ct ay, + st ‘ruin 10 0X nection one: 1 rons-nie2| s.2qasy | 0 [sesso CS 4 Gly = chs. + cht + cy rigor, ein age ove 0 Pak ECHO onoet: 2 ws | ace] - - Jos 20 C4 Gly, = 38. Tia, Taney wETE FREE sant Parca TEACHON Oar: 2. sooo | aun | o | amsisoo fos 2.0 O,514 ch. = nest + aD rig, Fyn MeN PRE ayoIcA, soos | ran | o | saoeiase fos 2.0 76 KERTPAR REACTION ORDER: 2.Table of Arrhenius parameters for chemical resctions occurring in combustion Continued Gionieal eactione 7 7 7] Ta factors Gain | a0 CvinoGer Fi aca» oxvees aTow "eine REACTION on 1s00-2500] 1.012) | 0 aso fos 3.2 Wo - wc vtnocer Fe antcal « oxveey anow 3S BENCOL ENCTION ORDER: 2 Laci | os |assis C1 jo, no 5 0 GrNfocen FREE RADTCAL onvGeN wousmuLE ob REXCTION ORDER: 2 1500-2500] 3.2¢411) | 0 xso00 Jo. 3.2 On = Kt Gxkvocan es toa 75 RENO 2 osc) | 0.5 [ors On Mc vk Fe ecu + wvonoaey aroe 75 BEN RENCTION ORDER: 2 roc | os | sens New = HON ow vince FA abt + svonooen «Tox Ye iN REACTION ORDER: 3 1so0-2500| a.2c16 | -0.s | osssoo fos 2.2 Oh sty = HON + Gviocéy FRE" eotcu. + mvonocen vouscuLe "BN REACTION ORDER: 2 1500-2500] a.2012) | 0 25001500 sore: esti, 4 of HX + 0 voce PRE RDC + anoRONY, FREE RADICAL "6B REACTION ORDERS 2 1500-2500] 3.2012) | 0 10021500 yore: 1 eStiwreD, is = ny vivoien rieF maton, + suru, stoe 2 BENOL EICTION ORDER: 2. esti | 08 ° Wis = cos ivinocin Fick maotea. + sure stow BENCOL REACTION ORDER: 2 2.012) | 0.5 | s2010 in com ‘rhxoGen FREE“tatea + vtTHoney aTou 1S BNO TRACTION ORDER: 2. eauay | 05 o CVs M = OM xMocda Fee RlorcaL + arraocEn oxtDE%0) tebe REACTION ORDER: 2 1500-2500] 3.20011) | 0 c:aso0 Jo. 3.2 hem = nox s rktocdy Fate eAorea, + wugo%ey rRte eaptea Nore REACTION ORDERS 2 100-2500 1.0(:11) | 0.5 | r000:2500 Jo.s 3.2 0 HOV 4X0 viNdoes tet Rabtou. + stngoste. roe tone REACTION ORDER: 2 rsoo.2500 | soc) | 0.5 casoo fo. 8.2 Wie = NG ivfnoden Fie" taorea. + cao Tow 7 BECO EACTION ORDER: 2. 2.sciy | 0.5 |19900 Wicca rknoden FREE RADLEAL + cnwos ATO BEN OL EACTION ORDER: 2. osc | 05 ° © Ako FREE ADT FREE a4DICaL vce) ARE Gato. + weraNLeNE. FRE "76.80 ENCTION ORNS 2 1500-2500] 3.20.12) | 0 250021500 Nove: L oStinnren © hacen PRE RADI (1, FREE RADICAL pa wach « wena , cutis REACTION ORDERS 2 1se0-2500] s.ocv11) | 0.7 | 15002500 70‘Table of Arrhenius parameters for chemical rections oceurring in combustion—Continued Chenical reactions TK 7 a Fk | factors Gay fF Cs hy = HON + CH CYANOGEN FREE RADICAL 4 METHANE 76 ENG REACTION ORDER: 2. 1500-2500] 3.2(11) | 0.7 | 250022500 Jo.3 3.2 OF + clo oo + HEN CCVANOGEN FREE RADICAL + METHYL, OX0-,, FREE RADICAL 76 ENG REACTION ORDER: 2 1300-2500] 2.04511) | 0.5 022500 Jos 3.2 Ch HCHO + HON + cho (CYANOGEN FREE RADICAL + FORMALDEHYDE 76 ENG REACTION ORDER: 2. 1500-2500] 1.3(411) | 0.7 | 150082500 Jo.3 3.2 CONOg)4 = CINOg a + Na WEttane, TETRARTTRON 70 BEN/O"N REACTION ORDER: 1 ass-sos | 3.a(s17) | 0 20875 HON § OH + CW 4 HO HYDROCYANIC ACID"+ HYDROXYL FREE RADICAL 76 ENG REACTION ORDER: 2 1500-2500} 2.0411) | 0.6 | 2500:2500 Jo.3 3.2 GUM, ¢ Cle. > CHAN. + CleN + Cll, wetHANAMNE ¢ WETAVL FREE RADICAL 76 KER/PAR REACTION ORDER 2 350-650 | 2.10411) | 0 3302500 Jo.7 1.3 CUM | Clg. + HRN + WWEtwAnawlve ¢ wirHiL Pree Rapica. 72 KON REACTION ORDER: 2 seso17 | 5.4(s11) | 0 so20s500 [0.8 3.0 GyNdy + Cl. + GLyND. + Cad WEfHAMANNE-d + METIVL, FREE. RADICAL 16 KERIPAR [REACTION ORDER: 2. 350-450 | 2.0(+11) | 0 s13ss100 }o.5 1.5 Nove: TENTATIVE k VALUE GUND, + Cle. > .ClNDe + Clg WETHARANINE-d + WETHTL FREE RADICAL 16 RERIPAR REACTION ORDER: 2. as0450 | 1.4011) | 0 07 18 CDgNip jC. = CD5NI. | gD ‘wefwandy-auine’; ETHYL FREE RADICAL 72 KERTPAR REACTION ORDER: 2. 400-so0 | 7.2(110) | 0 s1o0:so Jo.s 1.5 Ny, + Cl. DAN + Cy Wefan ds-avINE 4 WETHL lEE RADICAL 76 KERTPAR REACTION ORDER: 2. 400-500 | 2.011) | 0 asaoiso Jos 2.0 NOTE: TENTATIVE k VALUE. lyeMaN + Gls Ny ‘WeTiANE, Duiz0- “10 BiN/O'N REACTION ORDER: 1. 498-728 | 1.0(:18) | 0 17600 HNN CNH. + My ‘uvpKAzaNe, wbTwi~ 70 BENIO"N REACTION ORDER: 1 746-262 | s.o16 | - | 22600 NOTE: SUSPECT ARRHENIUS FACTORS. CHNIMy + lye 2 CNC. Mla + GINA TCHNHVEa | Gy WWDRAZINE, NETHTL-, + METHVL FREE RADICAL 76 KERIPAR REACTION ORDER: 2. 420 6.98) | - - NTE: TENTATIVE’ k VALUE. CHyNO_ Cg =10H 'WerHANE, RiITHOSD- 70 biNz0'N REACTION ORDER 633-608 | 7.912) | 0 19800 HOON, $ Cia. = HCONH. + .CONHs + Gl PORMAWIDE’ + METHYL FREE RaDIChL 76 KER/PAR REACTION ORDER: 2. 350-500 | s.6(s10) | 0 330015000 0.5 1.5 HCOND, + Cte. COND. CHD FORMAMIDE, Nd + WETHVL FREE RADICAL "76 KER/PAR REACTION ORDER: 2. 350-500 | 2.04411) | 0 s900:500 }0.5 2.0 NTE: TENTATIVE k VALUE 1‘Table of Arrhenius parameters for chemical rections occurring in combustion —Contnued Ghesical reactions TK 7 z ma Gin ky factors ee HOOND, + Gly. COND, 4 Gy PORMANIDEN. Ad, + ETHYL FREE RADICAL "76 KER/PAR REACTION ORDER: 2. CH,ONO = CHAO. NO ‘nrTROUS ACID” METHYL ESTER 70 BEN/O'N REACTION ORDE CUNO = CHa. + NOg Wefuane, Nitwo. 70 BINION EACTION ORDER GHNe + Cas + .CliNO, + Cl Wefuine, “inrko-"+ ferivL FREE RADICAL 76 Xin /PAR REACTION ORDER: 2. NOTE: TENTATIVE k VALUE, CHONO, + CO. 4 NOs ‘ivi acto 'werivL EsreR 70 BEN/O'N REACTION ORDER: 1. O1,0%e 4 Oly. + CLO. + Gy HYDROXYLAMINE, O-NETHYL-, + METHYL, FREE, RADICAL, To KEY PAR REACTION ORDER: 2 CH,OND, 4 Gy. CHOSND. + CHAD VOROXYLAMINE=N,N-dg, O-AETHL, + wera 76 KERIPAR REACTION ORDER: G40. cso CARBON DIMER + OXYGEN ATOW 75, BEN/GOL. REACTION ORDER: 2. tH cy aH CawoN DIMER + HYDROGEN ATO 75 BER/COL REACTION ORDER: 2. GtS = Cr ako DIwéR + SULFUR ATOM "75 BEN/GOI. REACTION ODER: 2 Gin con CARBON DIVER + NITROGEN ATOM 75 BEN/GOL REACTION ORDER: 2. iC = CG, CanBow lvn ? cansow aTow 75 BEN/COL. REACTION ORDER CoD + cect = products ‘CARBON Ox1DE(E;O) + ETHYNE 72 KERIPAR REACTION ORDER: 2. k/keo NOTE: bree? 000 + CllsChy OCD} CHACHECHL, — O + chgC ‘CARBON OxIDE(c20) + 1-PROPENE 72 KERIPAR REACTION ORDER: 2. Krk, Kor! OOD + GlgsClly No 000 + CigCctt, + products ‘caRBoY OUIDE(C,0)" + 2-BUTYNE 72 KER/PAR REACTION ORDER: 2. k/keor NOTE: Kae? COD + Cly=Cly 000 } Cy=CHCH-Cly + OD + Cl-C-CHCH-GH, ‘CARBON OXEDE(C{O) + 1,3-BUTADTENE "72 KER/PAR REACTION ORDER: 2. /kyog NOTE: Kyee! OCD + Cly=Clly co + chau ciect, + crcmcHocai, va cinpat‘atineyeZy + (eBore KER Pas TEACTON ORDER: 2. 7k wore: fear REE RADICAL 2. 0.8 8.7 85 210, 1.0 350-500 453-515 300-500 403-513 300-500 300-500 306 207 308 298 298 2 5.5(410) 4.0(415) 4.0(415) L0G) 8.2(415) 5.0(410) 3.5(+10) 6.3(411) 1.60413) 6.3¢-) 6.3411) 6.811) 0.8 35752500 20700 29700 51002750 20030 22652500 20703500 04 25, 05 15 os 15Teble of Archenius parameters for chemical reactions occurring in cambustion—Contnued Gesical reactions 7K 7 a Fit] factors Gok) | er Gy cie-OhgaIcl, =o + eiecoyca-cccn, ‘cluihOUH (Cos ioc AUTEN Pa arION OER: 2. Ar, wore: Lett EDD + Cys 000 + trans-CiyCH-CUCH, + 00 + trans-CisCH-C=CHCH, (CARBON OXIDE(C0) +" trans-2-BUTENE REACTION ORDER: 2. Krk, 9a | 207 e - - 10.6 | 297 2 2 - 000 + (is) + OD + (Gia) 6. cinkin Otro) 4°t-tnGreAee asa "72 KER/PAR REACTION ORDER: 2. k/k, 9: 50.0} 297 e = = ewe! COD + CHla=Ciy 000 + (Gg) ,C2AIG1, + 00 + (Cl, ,CHCCHO, ‘aboN OLDE CB) + 2-BUTENE,“2°NETIVL- 72 KER/PAR TEACTION ORDER: 2. k/k NOTE: Kyog? 000 + Ciera 000 + (Gta) gC

You might also like

• Fear: Trump in the White House

  

  From Everand

  Fear: Trump in the White House

  Bob Woodward

  Rating: 3.5 out of 5 stars

  3.5/5 (738)
• Devil in the Grove: Thurgood Marshall, the Groveland Boys, and the Dawn of a New America

  

  From Everand

  Devil in the Grove: Thurgood Marshall, the Groveland Boys, and the Dawn of a New America

  Gilbert King

  Rating: 4.5 out of 5 stars

  4.5/5 (266)
• A Man Called Ove: A Novel

  

  From Everand

  A Man Called Ove: A Novel

  Fredrik Backman

  Rating: 4.5 out of 5 stars

  4.5/5 (4611)
• • Magazines
  • Podcasts
  • Sheet music
• A Heartbreaking Work Of Staggering Genius: A Memoir Based on a True Story

  

  From Everand

  A Heartbreaking Work Of Staggering Genius: A Memoir Based on a True Story

  Dave Eggers

  Rating: 3.5 out of 5 stars

  3.5/5 (231)
• The Sympathizer: A Novel (Pulitzer Prize for Fiction)

  

  From Everand

  The Sympathizer: A Novel (Pulitzer Prize for Fiction)

  Viet Thanh Nguyen

  Rating: 4.5 out of 5 stars

  4.5/5 (122)
• Grit: The Power of Passion and Perseverance

  

  From Everand

  Grit: The Power of Passion and Perseverance

  Angela Duckworth

  Rating: 4 out of 5 stars

  4/5 (590)
• The World Is Flat 3.0: A Brief History of the Twenty-first Century

  

  From Everand

  The World Is Flat 3.0: A Brief History of the Twenty-first Century

  Thomas L. Friedman

  Rating: 3.5 out of 5 stars

  3.5/5 (2259)
• Shoe Dog: A Memoir by the Creator of Nike

  

  From Everand

  Shoe Dog: A Memoir by the Creator of Nike

  Phil Knight

  Rating: 4.5 out of 5 stars

  4.5/5 (540)
• Principles: Life and Work

  

  From Everand

  Principles: Life and Work

  Ray Dalio

  Rating: 4 out of 5 stars

  4/5 (608)
• The Little Book of Hygge: Danish Secrets to Happy Living

  

  From Everand

  The Little Book of Hygge: Danish Secrets to Happy Living

  Meik Wiking

  Rating: 3.5 out of 5 stars

  3.5/5 (401)
• The Subtle Art of Not Giving a F*ck: A Counterintuitive Approach to Living a Good Life

  

  From Everand

  The Subtle Art of Not Giving a F*ck: A Counterintuitive Approach to Living a Good Life

  Mark Manson

  Rating: 4 out of 5 stars

  4/5 (5813)
• Never Split the Difference: Negotiating As If Your Life Depended On It

  

  From Everand

  Never Split the Difference: Negotiating As If Your Life Depended On It

  Chris Voss

  Rating: 4.5 out of 5 stars

  4.5/5 (844)
• Her Body and Other Parties: Stories

  

  From Everand

  Her Body and Other Parties: Stories

  Carmen Maria Machado

  Rating: 4 out of 5 stars

  4/5 (822)
• Team of Rivals: The Political Genius of Abraham Lincoln

  

  From Everand

  Team of Rivals: The Political Genius of Abraham Lincoln

  Doris Kearns Goodwin

  Rating: 4.5 out of 5 stars

  4.5/5 (234)
• John Adams

  

  From Everand

  John Adams

  David McCullough

  Rating: 4.5 out of 5 stars

  4.5/5 (2409)
• The Emperor of All Maladies: A Biography of Cancer

  

  From Everand

  The Emperor of All Maladies: A Biography of Cancer

  Siddhartha Mukherjee

  Rating: 4.5 out of 5 stars

  4.5/5 (271)
• A Tree Grows in Brooklyn

  

  From Everand

  A Tree Grows in Brooklyn

  Betty Smith

  Rating: 4.5 out of 5 stars

  4.5/5 (1929)
• The Glass Castle: A Memoir

  

  From Everand

  The Glass Castle: A Memoir

  Jeannette Walls

  Rating: 4.5 out of 5 stars

  4.5/5 (1716)
• Hidden Figures: The American Dream and the Untold Story of the Black Women Mathematicians Who Helped Win the Space Race

  

  From Everand

  Hidden Figures: The American Dream and the Untold Story of the Black Women Mathematicians Who Helped Win the Space Race

  Margot Lee Shetterly

  Rating: 4 out of 5 stars

  4/5 (897)
• Yes Please

  

  From Everand

  Yes Please

  Amy Poehler

  Rating: 4 out of 5 stars

  4/5 (1898)
• Rise of ISIS: A Threat We Can't Ignore

  

  From Everand

  Rise of ISIS: A Threat We Can't Ignore

  Jay Sekulow

  Rating: 3.5 out of 5 stars

  3.5/5 (137)
• Elon Musk: Tesla, SpaceX, and the Quest for a Fantastic Future

  

  From Everand

  Elon Musk: Tesla, SpaceX, and the Quest for a Fantastic Future

  Ashlee Vance

  Rating: 4.5 out of 5 stars

  4.5/5 (474)
• The Hard Thing About Hard Things: Building a Business When There Are No Easy Answers

  

  From Everand

  The Hard Thing About Hard Things: Building a Business When There Are No Easy Answers

  Ben Horowitz

  Rating: 4.5 out of 5 stars

  4.5/5 (348)
• The Gifts of Imperfection: Let Go of Who You Think You're Supposed to Be and Embrace Who You Are

  

  From Everand

  The Gifts of Imperfection: Let Go of Who You Think You're Supposed to Be and Embrace Who You Are

  Brené Brown

  Rating: 4 out of 5 stars

  4/5 (1092)
• Angela's Ashes: A Memoir

  

  From Everand

  Angela's Ashes: A Memoir

  Frank McCourt

  Rating: 4.5 out of 5 stars

  4.5/5 (441)
• The Constant Gardener: A Novel

  

  From Everand

  The Constant Gardener: A Novel

  John le Carré

  Rating: 3.5 out of 5 stars

  3.5/5 (104)
• The Perks of Being a Wallflower

  

  From Everand

  The Perks of Being a Wallflower

  Stephen Chbosky

  Rating: 4.5 out of 5 stars

  4.5/5 (2104)
• Wolf Hall: A Novel

  

  From Everand

  Wolf Hall: A Novel

  Hilary Mantel

  Rating: 4 out of 5 stars

  4/5 (3811)
• On Fire: The (Burning) Case for a Green New Deal

  

  From Everand

  On Fire: The (Burning) Case for a Green New Deal

  Naomi Klein

  Rating: 4 out of 5 stars

  4/5 (74)
• The Woman in Cabin 10

  

  From Everand

  The Woman in Cabin 10

  Ruth Ware

  Rating: 3.5 out of 5 stars

  3.5/5 (2522)
• The Art of Racing in the Rain: A Novel

  

  From Everand

  The Art of Racing in the Rain: A Novel

  Garth Stein

  Rating: 4 out of 5 stars

  4/5 (4203)
• The Light Between Oceans: A Novel

  

  From Everand

  The Light Between Oceans: A Novel

  M.L. Stedman

  Rating: 4.5 out of 5 stars

  4.5/5 (789)
• The Yellow House: A Memoir (2019 National Book Award Winner)

  

  From Everand

  The Yellow House: A Memoir (2019 National Book Award Winner)

  Sarah M. Broom

  Rating: 4 out of 5 stars

  4/5 (98)
• The Outsider: A Novel

  

  From Everand

  The Outsider: A Novel

  Stephen King

  Rating: 4 out of 5 stars

  4/5 (1850)
• Sing, Unburied, Sing: A Novel

  

  From Everand

  Sing, Unburied, Sing: A Novel

  Jesmyn Ward

  Rating: 4 out of 5 stars

  4/5 (1104)
• The Unwinding: An Inner History of the New America

  

  From Everand

  The Unwinding: An Inner History of the New America

  George Packer

  Rating: 4 out of 5 stars

  4/5 (45)
• Little Women

  

  From Everand

  Little Women

  Louisa May Alcott

  Rating: 4 out of 5 stars

  4/5 (104)
• Brooklyn: A Novel

  

  From Everand

  Brooklyn: A Novel

  Colm Toibin

  Rating: 3.5 out of 5 stars

  3.5/5 (1947)
• Bad Feminist: Essays

  

  From Everand

  Bad Feminist: Essays

  Roxane Gay

  Rating: 4 out of 5 stars

  4/5 (1018)
• Manhattan Beach: A Novel

  

  From Everand

  Manhattan Beach: A Novel

  Jennifer Egan

  Rating: 3.5 out of 5 stars

  3.5/5 (792)
• Steve Jobs

  

  From Everand

  Steve Jobs

  Walter Isaacson

  Rating: 4.5 out of 5 stars

  4.5/5 (807)