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Summary Concentration
Summary Concentration
: atom
.
.
: O Cu Hg .C
: Molecule
) ( .
:
( : Mono Atomic Molecules
.
: He Ne Ar .Kr
) :(He
.
( : Diatomic Molecules
. : H2
O2 N2 F2 Cl2 Br2
.I2
( : Polyatomic Molecules
.
: O3 S8 .P4
( : Molecules of Compounds
. : H2O .C6H12O6
Properties of Matter
: Physical Properties
.
:
.
: Chemical Properties
.
: .
Change of Matter
: Physical Change .
:
.
: Chemical Change
.
: .
1
75.4
24.6
= Aw Cl
35 +
37 = 35.49 u
100
100
Molecular Weight and Formula Weight
: Molecular Weight
.Mw
C6H12O6
: Formula Weight
.Fw
: ) ( .NaCl
)(
Mw :
N2, NO, C2H6, N2O4, C8H18O4N2S, CO2, H2O2, Ca(NO3)2, Al2(CO3)3, MgSO4.7H2O,
C8H10N4O2, C6H12O6, H2SO4, C2H5OH, Zn(NO3)2.
:
)(H = 1, C = 12, N = 14, O = 16, Mg = 24.3, Al = 27, S = 32.1, Ca = 40.1, Zn = 65.4
Mw N2 = ( 2 14 ) = 28 amu
Mw NO = (14 ) + (16 ) = 30 amu
Mw C2 H6 = ( 2 12 ) + ( 6 1) = 30 amu
Mw N2O4 = ( 2 14 ) + ( 4 16 ) = 92 amu
Mw C8H18O4 N2S = ( 8 12 ) + (18 1) + ( 4 16 ) + ( 2 14 ) + ( 32 ) = 238 amu
Mw CO2 = (12 ) + ( 2 16 ) = 44 amu
Mw H2O2 = ( 2 1) + ( 2 16 ) = 34 amu
The mole
: ) (NA
...
)(NA
) (..............
).(NA = 6.022 1023
N A = 6.022 10 23
.
:
23
) (O2 6.022 10 .
) (O 6.022 1023 .
.
Molar Mass
g/mol
) (amu
amu )
g/mol
( .
)(
Mw g/mol
N2, NO, C2H6, N2O4, C8H18O4N2S, CO2, H2O2, Ca(NO3)2, Al2(CO3)3,
MgSO4.7H2O, C8H10N4O2, C6H12O6, H2SO4, C2H5OH, Zn(NO3)2.
:
(H = 1, C = 12, N = 14, O = 16, Mg = 24.3, Al = 27, S = 32.1, Ca = 40.1,
)Zn = 65.4
Mw N 2 = ( 2 14 ) = 28 g/mol
Mw NO = (14 ) + (16 ) = 30 g/mol
Mw C2 H6 = ( 2 12 ) + ( 6 1) = 30 g/mol
Mw N 2O4 = ( 2 14 ) + ( 4 16 ) = 92 g/mol
Mw C8H18O4 N 2S = ( 8 12 ) + (18 1) + ( 4 16 ) + ( 2 14 ) + ( 32.1) = 238.1 g/mol
K2SO4
6.022 1023
2 6.022 1023
3 6.022 1023
2 6.022 1023
)2 (2 6.022 1023
)3 (2 6.022 1023
6.022 1023
)2 (6.022 1023
)2 (6.022 1023
O
4 6.022 1023
)2 (4 6.022 1023
)3 (4 6.022 1023
( = ) (g
)m (g
=n
)Mw (g/mol
:
: n
: m
: Mw g/mol
( = ) (
)N (atoms , molecules, ions
N
=
NA
6.022 10 23
=n
: N
=
N = n NA
( =
)n = M V(L
:
: M mol/L
: V
) (ml or cm3
1000 :
V
3
n = M ml or cm
1000
)(
NaHCO3 420 g
(H = 1, C = 12, O = 16, Na = 23) :
Mw NaHCO3 = 23 + 1 + 12 + ( 3 16 ) = 84 g/mol
m
420 g
=
= 5 mol
Mw
84 g mol-1
= n NaHCO3
)(
) (1500 molecules C12H22O11
N
1500
=
= 2.49 10-21 mol
23
NA
6.022 10
=n
)(
) (0.2 mol )(C8H10N4O2
(H = 1, C = 12, N = 14, O = 16) :
)(
) (O = 16
)(NA = 6.022 1023
:
N
1 atom
=
= 1.66 10-24 mol
N A 6.022 1023 atoms mol-1
:
m = n Aw
m = 1.66 10-24 mol 16 g mol-1
m = 2.66 10-23 g
2.66 10- 23 g
= 2.66 10-26 kg
1000 g Kg -1
=m
= nO
: solution
) (m1 ).( m2
:
.
:
) (diluted solution : .
) : (concentrated solution
.
:
( ) ( :
: ) (NaCl :
H2O
)NaCl(S
) Na + (aq) + Cl- (aq
( ) ( :
:
H2O
C 6 H12 O 6
) C 6 H12 O 6 (aq
:
( : .
( :
( : .
METHODS OF EXPRESSING CONCENTRATION
:
(
( ( ( (
:
(.
(
(
(
/ Weight Percentage
) 100 g (.
:
) (m 2
) (m s o l
m2
100
m sol
= W t % m2
) (m 1
) (m s o l
m1
100
m so l
100
100
= W t % m1
:
: m1 ) (msolvent
: m2 ) (msolute
: msol .
: Wt % m ).(solute
: Wt % m ).(solvent
) (msol ) (m2 ): (m1
msol = m1 + m2
2
:
m
d sol = sol
Vsol
10
)(
)) (NaCl ( )(43 g
) (108 g
:
m
= 2 100
msol
Wt %solute
m NaCl
100
mSol
NaCl
Wt %
43 g
100
) ( 43 g + 108 g
NaCl
Wt %
Wt % NaCl = 28.5 %
:
Wt%solvent = 100 - Wt%solute
Wt% solute = 100 - Wt%solvent
)(
1.25 g C2H5OH 11.6 g H2O
:
( .
( .
:
= ) + (H2O )(C2H5OH
10
11
( : C2H5OH
100
mC2 H5OH
msol
1.25
100 = 9.73%
12.85
( : H2O
100
m H2O
msol
= Wt%C2 H5OH
= Wt% C2H5OH
= Wt %H2O
11.6
100
12.85
Wt % H2O = 90.27 %
= Wt %H2O
:
Wt %solvent = 100 - Wt % solute
Wt %solvent = 100 - 9.73
Wt %solvent = 90.27 %
.
)(
HCl 5 cm3
) (1.19 g/cm3 37.23% . (H = 1, Cl = 35.5) :
:
m
d sol = sol
Vsol
msol = d sol Vsol
) (m2 :
m2
100
msol
= Wt %
Wt % msol
100
37.23 5.95
= m HCl
100
m HCl = 2.215g
= m2
11
12
: HCl
m HCl
Mw HCl
= n HCl
2.215
)(1 + 35.5
n HCl = 0.06 mol
= n HCl
/ ) (
Mole Fraction
:
) (n
).(nt
) (A, B, C ) (nA, nB, nC
:
nC
nt
= XC
nB
nt
= XB
nA
nt
= XA
X = 1
XA + XB + XC
n
n
nA
n
+ B + C = t =1
nt
nt
nt
nt
.
:
m
=n
Mw
Mw ) (molecular weight
g/mol .
)(
:
( Zn(NO3)2 :
).(Zn = 65.4, N =14, O =16
( 127 g .Zn(NO3)2
( : Zn(NO3)2
12
13
( :
m Zn(NO3 )2
Mw Zn(NO3 )2
= 0.67 mol
127g
189.4 g / mol
= n Zn(NO3 )2
= n Zn(NO3 )2
)(
) (H2O NaCl ) (0.735 mol
) (6 mol .
: nt
n t = n NaCl + n H2O
n t = 0.735 + 6
n t = 6.735 mol
6
= 0.89
6.735
n H2O
nt
= X H2O
n NaCl
0.735
=
= 0.11
nt
6.735
= X NaCl
NaCl :
X = 1
X H 2O + X NaCl = 1
X NaCl = 1 - X H 2O
X NaCl = 1 - 0.89
X NaCl = 0.11
)(
5 mol
) . .(H = 1, O = 16 :
13
14
m H2O
= n H2O
Mw H O
2
1000 g
1000 g
= n H2O
=
= 55.55 mol
(2 1 + 16) 18 g/mol
n t = n NaCl + n H2O
n t = 5 + 55.55 = 60.55 mol
:
n
= NaCl
nt
5
= 0.0826
60.55
X NaCl
= X NaCl
/ ) (
Molality
) (.
: .
:
) (n 2
=
(m1 ) Kg
n2
)m1(Kg
=m
) (molal mol/Kg
:
: m )(m
: n2
: m1 .
:
1 kg = 1000 g
:
) (n 2
=
(m1 ) g
1000
n2
1000
)m1 (g
14
=m
15
)(
) (2 mol 800 g
.
)(
n1
1000
m2
= molality
2
1000 = 2.5 molal
800
= molality
20 g NaCl 90 g
) . .(Na = 23, Cl = 35.5:
m 2 = 90 - 20 = 70 g
n1
1000
m2
= molality
0.34
1000 = 4.86 molal
70
= molality
15
16
/ ) (
Molarity
) (
: .
:
) (n 2
=
)Vsol (L
n2
)Vsol (L
= )Molarity ( M
: Vsol .
cm :
n2
= )Molarity ( M
1000
) Vsol (ml, cm3
) (molar ) (M ) mol/L )(/
mol/L (mol L-1) :
1 L = 1 dm3 1 mol L-1 = 1 mol dm-3 :
n2
)Vsol (L
= ) ( M :
16
17
n2
)Vsol (L
/
=M
)n 2 = M . Vsol(L
m2
= M .Vsol
Mw 2
m 2 = M . Vsol . Mw 2
number of moles
m = M. Vsol(L) . Mw :
.
Wt %
d 1000
100
=M
Mw
:
: Wt %
: d )(g/ml
: M mol /L
: Mw ).(g/mol
)(
3 mol ) (C6H12O6
750 ml
n
1000
V
3
=M
1000 = 4 mol/L
750
=M
)(
200 cm3 2 g ) (NaOH
. .(H = 1, O = 16, Na = 23) :
17
18
)(
) (mol/L 20 g C12H22O11
) (125 g 1.02 g/ml
.(H = 1, C = 12, O = 16) :
m
m
145
=V
=
= 142.157 ml
V
d
1.02
n
0.0585
=M
= 1000
1000 = 0.412 molar
V
142.157
=d
:
=
1000
100
Wt % d 1000
Mw 100
=M
) (d ) (g/cm3 ).(g/ml
/ ) (
Normality
: ) (Eq
).(Vsol
:
) (N
Eq 2
=
)Vsol (L
Eq 2
)Vsol (L
Eq 2
1000
)Vsol (cm3 , ml
) (Eq2 .
18
=N
= or N
19
) (Eq
) (Eq )(Ew
:
m2
Ew
= Eq
: Ew :
Mw
= Ew
)n (H , OH , e
-
: n ) (H+ ) (OH-
.
:
) .(H
+
:
) .(OH
-
:
.
:
).(H+
) (NaOH
).(OH-
Ca(OH)2 .
:
) (H2SO4 ) (2 moles
H2O
NaOH
Na + + OH- .................................... n OH- = 1
H2O
Ca(OH)2
Ca 2+ + 2OH- ................................n OH- = 2
H2O
HCl
H + + Cl- ...................................................n H+ = 1
H 2SO 4
2H + + SO 2-4 ..........................................n H+ = 2
MnO-4 + 8H + + 5e
Mn 2+ + 4H 2 O....................n e = 5
19
20
)(
:
( HCl( H2SO4( NaOH( Al(OH)3
(H= 1, O = 16, Na = 23, Al = 27, S = 32, Cl = 35.5) :
Mw
= Ew
) n (H+ ,OH-
HCl
36.5
HCl
H + + Cl-
)(H+ , OH-
36.5 g
H2SO4
98
H 2SO 4
2H + + SO 2-4
49 g
NaOH
40
NaOH
Na + + OH -
40 g
Al(OH)3
78
Al(OH)3
Al3+ + 3OH -
26 g
)(
:
( K2Cr2O7 Cr
( KMnO4 MnO2
Na2SO3 ( Na2SO4
Fe2O3( FeO
.(O = 16, K = 39, Cr = 52, Mn = 55, Na =23, S = 32, Fe =56) :
3+
K2Cr2O7
294 g/mol
)2(+3
3+
)7(-2
22
7
2(+1) 12
K 2 Cr O
2Cr
3+
2Cr
2Cr + 6e
+6
20
Mw
= Ew
ne
6e
49 g
KMnO4
158 g/mol
21
K Mn O 4
Mn O 2
3e
)+7 4(-2
)+ 4 2(-2
Na2SO3
/
Mw
= Ew
ne
+1
52.67 g
Mn +7 + 3e
Mn +4
)2(+1) +4 3(-2
)2(+1) +6 4(-2
Na 2 S O3
Na 2 S O 4
126 g/mol
+6
2e
63 g
+4
S
S + 2e
Fe2O3
+2 2
)+ 6 3(-2
Fe2 O3
2 Fe O
160 g/mol
2e
80 g
2F3+ + 2e
2Fe 2+
) (M )(N
)N = M n (H+ , OH- , e
) (Eq )(n
24
H3PO 4
3H + PO
+
Eq = n H3PO4 n H+
Eq= 3 3 = 9 eq
)(
NaOH 16 g NaOH 400 ml
.(Na = 23, O = 16, H = 1) :
21
22
Eq 2
1000
)Vsol (ml
=N
Eq NaOH
1000
)Vsol (ml
=N
m NaOH
Ew NaOH
=N
1000
)Vsol (ml
m NaOH
Mw NaOH
n
OH
1000
=N
)Vsol(ml
16
23+16+1
1000
=N
400
0.4
=N
) 1000 = 1 N (1 normal, 1 Eq/L
400
)(
) (Eq )(0.25 N
Eq 2
)Vsol (L
=N
)Eq 2 = N Vsol (L
Eq 2 = 0.25 0.5
Eq 2 = 0.125 eq
22
23
SI Units
.
Basic Units
m
Kg
s
K
mol
A
cd
Derived Units
:
m2
m3
m/s
kg/m3
kg/ m.s2
kg m2/s2
kg . m/s2
)(area
)(volume
)(velocity
)(density
* )(pressure
)(work and energy
)(force
d
Pa
J
N
* : :
-2
*F N m . g
) (kg) (m/s2 ) ( kg m s
= =
=
=
) = kg m-1 s-2 (or kg/m s 2
=P
2
2
A A
A
m
m
*
Symbol
d
c
m
n
p
f
k
M
G
T
23
Value
10-1
10-2
10-3
10-6
10-9
10-12
10-15
103
106
109
1012
24
: Length
1 km = 1 103 m
1 m = 10 dm = 100 cm = 1 103 mm = 1 106 m = 1 109 nm = 1 1010 A
: Volume
3
1 ml = 1 cm ,
: Mass
6
1 g = 1 10 mg = 1 10 g, 1 Kg = 1 10 g = 1 10 mg = 1 10 g
: Temperature
F - 32
1.8
Pressure
=C
K = C + 273,
24
25
)(
) (121.8 g Zn(NO3)2
) (1.107 g/ml ).(Zn = 65, N = 14, O = 16
:
( )( .
( .
(
(
(
(
( .
( .
]< <<V<`]<<l^
) (m2 (121.8 g) = (Zn(NO3)2
= 1 L = 1000 ml
dsol = 1.107 g/ml
( :
( :
121.8
= 0.64 mol
189
m Zn(NO3 )2
Mw Zn(NO3 )2
= n Zn(NO3 )2
(
msol
Vsol
= d sol
25
26
( )( :
( :
n 2 1000
m1 g
n Zn(NO3 )2 1000
m H2O
=m
=m
m Zn(NO3 )2
1000
Mw
Zn(NO
)
3 2
=m
m H2O
121.8
(65 + 2 (14 + 3 16) 1000
=m
985.2 g
121.8
1000
189
=m
985.2
) m = 0.65 molal (or 0.65 mol Kg -1
26
27
( :
:
121.8
= 0.64 mol
189
m Zn(NO 3 ) 2
Mw Zn(NO 3 ) 2
985.2
= 54.73 mol
18
= n Zn(NO 3 ) 2
m H 2O
Mw H 2 O
= n H 2O
n t = n Zn(NO 3 ) 2 + n H 2 O
n t = 0.64 + 54.73
n t = 55.37
)( )( :
nZn(NO3 )2
0.64
= XZn(NO3 )2
=
= 0.012
nt
55.37
54.73
= 0.988
55.37
nH2O
nt
= XH2O
Xt = XH2O + XZn(NO3 )2
Xt = 0.012 + 0.988 = 1
( :
n Zn(NO3 )2
VL
0.64
)= 0.64 molar (or 0.64 mol/L
1
27
=M
=M
: /
...................................... ................ .....(.....)..........................
.
) (n :
:
(
) (n :
:
(
m sol 100
= wt %
:
m2
n2
)( 1000 :
= m
m1 kg
:
(
.
n2
)( 1000 :
= m
m1 g
:
(
(
) (K = 39.1, S = 32, O = 16 K2SO4 :
( 87.1 g/mol
NA
) n = N (atoms, molecules, ions
m 2 100 :
= wt %
msol
:
(
.
:
(
.
NA
( 126.2 g/mol
( 135.1 g/mol
( 174.2 g/ mol
) (20 L :
(2 dm3
( 500 g/L
( 875 g/L
( 1400 g/L
( 20 dm3
( 200 dm3
( 2000 dm3
( 3.01 1024
( 2.41 1025
( 1.21 1026
( 0.909
( 10
( 90
( 8.3 g
( 67.5 g
( 675 g
: /
...................................... ................ .....(.....)..........................
.
( 120 g
( 55.56 m/s
( 18 m/s
( 720 m/s
( 1.6 g
( 520 g
( 120 ml
) (320 g ) (200 g :
( 0.625 g
( 241.75 ml
( 258.53 ml
( 1360 g/L
( 73.53 g/L
( 13600 g/L
1.539 g/cm H = 1) :
O = 16,
N= 14,
:
( 125 g/mol
.
) ( :
( 15.39 g
( 0.976
( 0.24
( 0.76
) ( :
( 0.64 molal
( 0.24
( 0.976
( 0.76
) ( )( :
( 0.024
( 1.69 mol
( 67.72 mol
( 72.67 mol
) ( )( :
( 0.024
( 1.69 mol
( 67.72 mol
( 72.67 mol
) ( )( :
( 3.39 mol
( 56.44 %
( 64.21 %
( 84.04 %
) ( ) ( :
( 3.39 mol
( 43.56 %
( 35.79 %
( 15.96 %
) ( )( :
( 79.21%
( 153.9 g
( 15.39 g
( 1219 g
) ( ) ( :
( 20.79 %
( 153.9 g
( 1219 g
( 1539 g
) ( )( :
( 1539 g
( 127 g/mol
( 175 g/mol
( 189 g/mol
( 0.65 molal
( 1.39 molal
( 1.69 molal
) ( :
( 0.64 molar
( 0.65 molar
( 1.39 molar
( 1.69 molar