Nama : Apriza Marfina

NIM

: 4311413029

Prodi : Kimia 01/2013

Tugas Dinamika Kimia

3. The hydrolysis of t-butil iodide follows first-order kinetic at 26 C
ButI + H2O ButOH + HI
The conductivity of the solution was measured with time as follows
Time
Time/min
0
6
10 x conductivity 5,5

2
13

4
20

6
26

8
31

10
36

17
46

22
51,5

28
56

65

Calculate the rate constant of the reaction

Answer :

5. The optical rotation for the mutarotation of -glucose at 20C are as follows
20,26
10

/degrees
Time/min

18,92
20

16,82
40

15,22
60

14,02
80

13,18
100

10,60
equilibri
um

Show that the reaction is first order and calculate the rate constant
Answer :
7. Reaction of diacetone alcohol with alkali to give acetone produces a volume change ,
which is measured on a cathetometer as the reaction proceeds. From the following data
obtained with 5 per cent diacetone alcohol by volume in a KOH solution og concentration 2
mol dm-3 , calculate the order and the rate constant.
Time/s

Cathetometer
reading

24,
4
20

35

48

64,8

24

28

32

75,
8
34

89,4
36

106,
6
38

133,
4
40

183,
6
42,

43,3