2011 2012

) ( )(

7) :(

13) : (
 3 ) : 1(
 4,5 ) : 2 (
 : 3 ) 5,5 (

6 1 z

2012/2011

   

2012/2011

: pH8
. pH =8
O

:
AH ) A (
-

AH A- .

OH

.
:

= 8 = 2 ; pH pKa (H2O/HO )= 14 pKa (AH / A) = 3,5 pH

M(AH)=180g.mol-1 ; pKa(H3O+/H2O) =0 ; pKa(CH3COOH/CH3COO- )=4,75

C
CH3

m(AH) =500mg : m (AH) = 500mg : pH8

.......
.........
(1
(11 AH . AH
(12 AH A- .
(13 pH8
(2
(12 . .
. :
(2 " :" 500mg
1

10ml cB = 1,0 mol.L
100ml .
20

10ml . cA = 5,0 10 2 mol.L1

VAE = 8,4 ml
:

coo

+ CH3COO + H2O

OH

OH

2 HO

)(1

O
C

CH3
H3O+(aq) + HO (aq) = 2 H2O

(12
(22 ) ni (HO .

6 2 z

)(2


  
(32 HO aq .
(42 ) (1 m .

2012/2011

(3 :
(23 / .
(33 H3O+
(43 H3O+ HO- .
: ) (8,2-10 BBT ) . (6 -7,6.
:
50% .
.
1 F : 9,65.104 C.mol-1
. M(Zn) : 65,4 g.mol-1) . ). Zn2+(aq) / Zn(s) ; H+(aq) / H2(g) ; O2(g) / H2O(l
(1 :
(11
(12 .
(13
( 2 U=3,5V . I =80kA
(21 .
.
(31 80% :
.24 L.mol-1 .
) : (1



:
Do

Si

La

Sol

Fa

Mi

Do R

261 294 330 349 392 440 466 494

:

)(Hz

2 .
.

=v

= 0,073 N.m = 1,0103 kg.m3

(1 f1 = 440 Hz 1 = 1,33 mm V1
.

6 3 z

 2012/2011

  
(2 ) (1 t1 AB

(12 t2
(22 M3 M 4 M3 . M5
(3 f2 2 = 1,62 mm v2 f 2
.
1
(4 f3 = 0,038 N.m :
3 = 1,30 mm

)(2

1
G R C =2200F .
K ) (1 t1 ) (2 ) (1
G1 ) (2 G2 .
(1 :
(11 uc : uR uG
k )(1
(12 ) (1 .
.
(2 ) : (1 )(1
R 91
(12 E G1

(22 t1 t2 =1,6s
t

(32 uc ] [0; t1 ) U C (t ) = E (1 e RC
) uc(t1 ) 10-3 (
(42 ) i(t ][1,28s;2,4s
(3 ) (2 I0 = 22mA .
(13
(23 Umax =16 V
.

6 4 z

 2012/2011

  
N R =5k L

(1 ) (1 UR Ub ) . UR
)( Ub )( (
(2 ) ( Inv . ) )( (2

(3 UR Ub
(4 L

L dU R
.
R dt

= Ub

. .
M m F = kV k T
N T=f.N f . . ) k =0.5 (SI ) f=0.8(SI )m = 75 (SI

= cos = sin
(1

k. f

(2

M ) (ox; oy

(12 NT
(22 v M :

dv v
+ =A
dt

A.

(23 . 74,8m.h-1
t

dx
(3 v(t ) = vL (1 e ) :
dt

=v

(13
(23 t 1
(4 t1 T=2f.N : D =13 m )
(

6 5 z

   

2012/2011

) (2
L=10cm ) ( O .
C
= C

M = 0,1Kg

). (

=10 );Z

(o .

) + ( . . .
(1

(2

(3

L
:
)g ( 1

(4

t =10s C . g =9,81 m.s-2

(5

. O .
2

6 6 z

= (1

T0 = 2 . C Mg

. cos =0