Resonance Educating for better tomorrow DATE : 26-05-2013 TARGET : JEE (ADVANCED) 2013 JEE PREPARATORY TEST-3 (JPT-3) (JEE ADVANCE) COURSE : JP, JF, JR, JCC HINTS & SOLUTIONS PAPER-1 PAR: PHYSICS: 1 © 2 Sol. “must be dimensionless putting down all the dimensions x wil get x= MLTS 2 (c) Sol. Path AC is y=; thus dW =F dr We (exisy*).(oxi+6y)) j Ty2ay = [22a + fy’ 1 = faxydx + [yay = fartax+ [yay <2 toy Jposer|ver= [ater [vor Fey 2 Sol. atthe comer mg = WN, +p a N= 1Np @ and torque oat = HNGR + NER 2 aR? MRT =uR(N+Na) (NN) from equation (3) = 2mR? 0? ~0? = 200 hence caleuate 9" 4) Sol. The frequency heard by the observer is tt aa | w= ucest from the figure its clear that cose = 4 v ence -PNResonence 5 SOL. T= a ¥p# ay) ~~ sy = a [4 1 = 4 (249) 4 2y, “2ay “1 6 @ 7 @ 8% «) Ol. pat = Aly C08? $/2 75% of max means 3p = Al cos? 9/2 BB "6° 6d hence 9. (AD) Sol. I the colison is perfectly inelastic, then Oo ® > Oy 10. Sol X= sinagt y=2sinongt eliminating Sinagt > x= 'SOLIPTSPAPER260613 -11". 2 Sol. 2 4, +6. sol, 6 Sol. 1”. Sol. TX equation of etaight tine thus | ABE muy a8 its sinosodual function hence peridic and simple harmonic 0) (ago) ‘Sol. A ~ ony true if the mirror is at rest R—atays tue @ @- 1 ©) Conserving the angular nomentum about the pont of contact Vs _ Ns me? Sol A — Away teas Ve = 5 09 = oy +R Vp Ne ee fas uy = oR) 20. Ans. (A) ant ; (B)- as 5 (C)- ast; (0)- art 1 aa) Pat = pv=c sau) Pat lester process, Hone Au =0 (C.D) ‘2s the process is isothermal hence Specific Heat is infinite. a0 (@) As TCherce uO and 2rd 2 Bh Sk 5 process is laocherie hence C 1s = D 2 2 (C) P=C isobaric hence AT +0 (B,C) ‘Thus Au +0. a oo Acceleration f= a—b\ a_pvy hb p-2v fa (0) as cyclic process hence AU = O , as dQ is non zero hence ceo f oo ~ 3 ke-2vyy PARTAL: (CHEMISTRY) 2. @) se $0. Cyn =O, +R accelraton = f= 6 =21.686+10°T +8.314 = (30+10°7) (ec) 400 (ay MH=fnc,aT = 1 (30+10°T)dT = 30350 tom e fre 4 sind = 22. (C) mu, ) os aM QB Sol. ty = (tua tn] 1 0683 las, tence sing = “(48e) ® ° ry Tine spent = AS Henath us © Sevag mple i ays equal to change in mmentan ee oo yt ty 3), Mua 8 muy ty 0802” (hyaye mes) 2) 4 a 2qBo . _ s8 [muooe 5 ) ma2T 1 aT sol > Ogi > 4% = 3.647 mu, ‘Since freezing point undergoes a depression, hence freezing point is 3.647%, Resonance SOLIPTSPAPER260613 -2 mm24 Sol. 2. Sol. 28 Sol. 23, 30. 31 Sol. 2, 2. 4 IW Resonance @ Octahedral void is present atthe center of cube while tetrahedral 1 void is present at (0 distance along each or 7 9 Ba F body diagonal So distance betwen bot AB = 3a AB distance between octanesal & taranedal vad > = peueete CO -CaI-OD 3 Due to tinear movement of electron by hyper conjugation of -CH, @ In compoun I: F* and 4 carbon atom have cis configuration. In compoun it: and 4" carbon atem have tans configuration (aec) meting of iron In a blast furnace does nek involve sublimation (acy (eco) Anode: Pb(s) Cathode : Pb0.(s) H,SO,(cone.) about 36% solution of H,SO, fs taken. Anode : Pb(s) —> Pb* (aq) + 26" Pb*(aq) + SOJ (aq) > PDSO,(s) ois) + SOF (aa) > PDSO, +26 most of the PbSO,(s) ppt sticks to the lead rod Cathode : 2+ 4H + PbO.{s) —> Pb?(aq) + 2H,0(0) poi(aq) + SOF (aa) +4H* + 2e- PESOYS) + 2H,0(4) PbSO,(s) sticks to cathode rod Over ail reaction : Pb(s) + PBO, (8) + 24,80, (2a) > 2PDS0(s) + 2H,0(0), Egy = 208 V (a0) (aco) (8c) Sol, Ambident nucleophiles have more than one site of attack. 35. (A) Sol. Electrophiles are @ deficient species 36. (©) ‘Sol Ihave maximum partial postive centre, 37.) Sol. Due to 2 nto groups at o~ & p- postion carbon directly attach to chlorine have max positive charge 38. (0) 39. (8) 40. A-p.qt:B-prntiC-patiD-s Sol. (8) Beckmann rearrangement (8) Pinacol-pinacolone rearrangement (©) Dlenone-phenol rearrangement (©) Oxymercuretion demercuration PART-II : (MATHEMATICS) 4. 8) Product of ralonal & rational is integer only if rational is zero Hence a = 0 is only possibe. 42. (0) Acranging siopes in decreasing order. = A=n-tan'7 “This fs largest ange as tis obtuse 43. (A) Chord AB subtend 90° at center 6x 1.95~11.70 v (oe Oy SOLIPTSPAPER260513 -3 mmPO, +PO, =f fp =5-124 ©, =(0,0),0, 4 for unit vectors ie = 8, B.C are mutually perpendicuiar a =x(bx6) + (xa) +2(@«b) Toking dot wth & t=x[abé] > x=-1 Taking dot win B&G are we get y = 0 46. (8) sieagtn te a’b’e'd’e MAP. asbicidte arbictdee arbsctdte = a an) © arbre+d+e arbsctdve . are inp, d e bictd+e arc+d+e arbidte a b © atb+c+e arbic+d - arenAP d e 47. 8) EEE %G,. 40, 5C,= number of ways of se Perec’ lection of 3 persons out of 12 =", = 220 48, (A) Let P, denotes the number of ways in wich '’ persons can be repeated 2s per conaiton, then P, =P 4 +Ph2 since P,=1,P,=2,P,;=3P,-5P,-8.. t is 2 fibonacei sequence. Total number of ways = 120 49. (8,C.0) sin? A +sin?B +sin?C =2 = 3-cos2A~cos2B- cos20 = 4 = c0s2A +.cos2B + cos20.41=0 = 2c0s(A +B)cos(A ~B) + 2cos*C = 0 cosAcosBeosC = 0 =A=5 50. (B.C) st 52. 53. 2 [aw sw? [iw iw? A iw? iw [ez | = (04 2W)1= 4 VSD1 0 342] = (1-2w?) I (ec) secx sec? x + cot xcos ecx| A(x) =|cos*x cos? x 1 cos?x osx cosec?x cos? x G96, costxC, secx 0 — sec?x+cotxcosecx| =|cos?x cos?x cosec?x 1 0 cos? x 2 sin? x{ 2g 008K) = cos? xsin’ x| cosx~sec? x - 98 \ ‘sin? x = 005" x sin? x-sin® x—c0s* x = —cos® x- sin? x 1 A(x) +cos® — 9) ‘ 4 = ¢ 2 maco aor D, =R- % nel} J cotx cosec*x (x)= sec? x + -cosec*x)=0 tanx.sec”x > x) is constant (i f(a) =1vxe RF nel} (c.0) IW Resonance SOLIPTSPAPER260513 -4 mmmffcesceeemesn Sn Kx (24+ 3c0sx) “J 3+2008% ox Be deosxjF™ GN 8, wih Scosec’ (2cosecx + 3cotx)* + 2oosecxcotx iv -dt,t = 2cosecx + 3cotx z 1 sinx °° ~243cosx sinx 5, ¢ _ sinx-4~6cosx = SK +c 243cosx 2+ 300sx sink 4g SNK +2+3c08% | 5 24 3cosx 24+ 3cosx 54. (B.D) 21, 4th 4ty 41? =-8t (ast 40) swet-2 f(t) = 1-2 (t-2) = -219 4 41? A(t) = -61? + 8t = -2t@t-4) 55. (0) ul £2) (2) ® == g(t) * g(2) 58. (a) arg{ N44 ® \ny=i (rey Bi) 4 OA 4 Consider the function yo) = Fs) +g). Applying LMVT to yb) In {1 , 2] wo get y(c) = 3 for atleast one in (1 2) ‘But the first condition implies that y'() is strictly decreasing. Therefore the number of solutions Is exactly one 57. (A) A(x) x Ths) Puay imaginary. Thus Hs) = 5 This oer} function has one maxima and no minima 58. (A) Statement 2 is tue atb+c=1,a? +b? +c? —ab+be+ca=-4 a +b? 40% Babe =1.(9.+4) 1-abe = 13 abe ab+-be +ea ‘abe 59. (8) Putx=y=0, then (0) + (0) +2011 2013 => — {@-=b = Statement 2is true ( by substituting x = 2013 and y = 0) f(x +h) =f) h f= r= iy 2013) 0 =f) sing the given relation = 1) =aK+D Anes 60. (A~H) :(8-@) (C3) (0-p) (A) Foot of 1 from @ (1, 1, 1) tothe ne of intersection of (1 P, Pais Al | as paral vector ofthe ine is ij hoa q=2 } -1 4] Required plane sx + 4y + (8) requied plane through @ has to be paral to angle bisec- tor planes. [Angle bisector planes are tat 9 Resonance SOLIPTSPAPER260513 -5 mmrequiced plane sx + 2=2ory=1 (©) Plane trough Aline of P,P is (xy 42-2)+)x4y+2)=0 is | toxnyor #2 14a (AFA) 4142.20 34h=0 3 = 2x4dy+2242=0 ©) P(MA1)=3 Pa (Mad required bisector plane is yaz 8 teed PAPER-2 PART-1: (PHYSICS) 1. (0) Bol. Fra peretycaecting sutae the change in mama fr 2h the iit rays AP = $"c08(90-8) 2h. ap = sino 2. rence F = —sin6 (uhere is power he = SIN8 where P is power) 2P fore 6 a, Pressure = = 2 sin? (ea) Ac sind Power as = Intensi ‘Area a 2 (0) 2nR sot, T= ” a (C) Sol. 15in 45° = 0=30° at fist refraction Sol. Sol sol. Sol. Sol. 8, = 45°—30° = 15° and at second refraction by = 45°- 30° = 15° thus Spy = 15° 415° = 30° (0) [As 'K| moves down by %! the spring get extended by Ng? Max = 2K’ I,ox= 5) the bock ‘8! would get ited if KX = Mgg A Meg ) ie i Bg fl = a) sohing 1A The ie aan by eau tat emay 6 = 5g at any height Y the thrust force aching on the container is va(Y2ay)° = aay ‘This force accelerates the container thus pa(2ay) = (PA) via a he aca a= 2 (29) A Bh a tmus v= 0+ FQ) rg = ¥=2V20h o) a N=mgcos0+BiLsin® for balancing mgsind = BiL.cos0 +N BiLsine mg hence B= ™tan(a— ant 9) es p=tand © Ay= Ae" A = Age" iviaing 9 Resonance SOLIPTSPAPER260513 -6 mmm(mgucoso)t at (: at Ap -Ae Hh) 2 = Ay T x aL hence “Gr 9. (AB.C.0) Sol. The potential inside the outer shells same throughout hence (A) The pd between the shell decreases hence (8) a Eearting alas ' zero potential hence (C) yucosé sewers 7 L=mgucoso [ tdt = Maucosd| 9 RC . Kx _KQ o i the charge on ier epee then Et = a 298m? Hence (0) 64g 10. (8) Ans. x28 Sol. 8y the weins law iq,T = constant a ts, x=acos=(t41) A 37 i= 7aT body comes to rest atthe ampite hence tee 1 x 1, sol, fF ity fR@2al 1 4 Sol. = OB wm |[2, 2; amy or Hee == f 4 ans. 9 foro = Sm _ By 2q8 9B 18, The net resistence can be calculate by apping Krchots lw neuton remains undevated eth 13.) ; A Sol, 8, The bots woud not colle at the midpoint but at the centre O(i-i)+3H)-V=O Fy of mass Smee 9i-6i,=V “0 5, The momentum is @ vector quently thus the étecton of from loop (2) maton can be diffeceant S,£As kinetic energy before and afer the clisin is conserved and not during the collision. 3i, +3(2i,-i) -9(1-4,) =0 +24 -1-31+3i, =0 14. (C) Sol. 8,: True only if wate fs filed up tothe brim in the vessel 6i,=4i 8,1 Vaid as pyAyyy = p2A2Ve a 8,: Theo @ 84: Theory 418. The torque acting to the particle about the point of projection at any time would be SOLIPTSPAPER260513 -7 mm 9 Resonance1, si=V Ans. 18 x=50+4t-1 the particle stops wien its velocity is zero. x 4-2t=0 at t=2s at 25 the x coordinate of particle is x=50+4(2)—(2)° = 54m at t=0 x=50 hence displacement is 4m Ans. 4 foe chamber (1) equating number of moles Fo(10)(A) _ Pxx(A) R@lo) RT 0 rR PR 2 a fine for chamber (2) Po (20)(A)_P(30-x)A 7 RT, 2 PBR TA ot Frat dtving (1) by 2) = 30-K=4x 5x =30 Thus piston moves by 4cm RT-Il : (CHEMISTRY) 21. (0) Sol. P, = 200 «05 + 30005 100 + 180 = 250 tor. It P,, > 250, no vapour exist WFP, = 250, vapour ext, 2. (8) 23. (8) no Sot. ntecor= [3-55 ]x0:9=0.7 > equt = @ 07 m4. (a) Sol. for (16 9) nitiela Saute > = Woe 973) 16 9 Simiany for LP (= 1), {5 3 (189) \zue2) so,rato= (169) => -2)"2 Us 3] 25. (A) so. A+B—>C+D r= k(t-x)?(1—x)® SOLIPTSPAPER260613 -8 mmm x=6m Ans. 4 a =k(t-xy) 3 % eK Ka-x)= Genk) 2303107 (0.01 9 Resonance26. () ° = 100xd,, =V,x1.6+(100-Y)2.42 Sol. Na,CO, + HCI > NaHCO, Intatmm 11.25 > Vi=60 => 0, = 60% After reaction 00254 36. (03) NaHCO, + HC! > H.CO, 01, HCHO = C,H,,0, Inatmm 10250 c 0 iter reacton 075.0 025 Sue” ca =) ‘etal nase = [0(1-)]30+( 2180 Its an acidic butter PH = pKa, + lo . or Teal moles = C(1- a) + 2 (0.75) = 644109575) - ( [et1-a)}204( 180 2. (0) = mean molar mass = Ca = 180 Sol. carbon do nat form 5 bonds tae's 150 28. (c) Reported answer is = “gy Sol. i -dketone have higher enol contant eee ar. (60) A) Sol. X(OH), —>X(OH); +OH Sol, Sef understos ; (OH); —>x(OH)" +0H 31. (ABCD) ° Boi Sy an cscten = taaoHr= (410° +3) 32. (ABCD) pH=1178 = pOH=222 Sol, Sef understood = [OH]=6*109M => 4x10 +a=6x10° 33. (A) > a=2x10° = 3 desocistion is 50% ° ° i CHMg8r | 38. (a4) Sol. CHs—~C—OBt -— i Sol. Volume strength = 11.2 x Moaty one > 12=11.20M DIBAL-H i > M=10 tp cB on, I of solution contain 10moles HO, sone AA 1 mole of H,O, = 349m — a tet = 1000me Homi g 1000m® -> 340gm CIN Seton EIOH+ CH, -C-OH s00me-» 24gm a ay so 34%(w/v) 36, (60) . (10) Sol, Let us suppose total 100 volume of azonised oxygen out of X shows geometrical, fnisation ard Enkege isomers. si of gone NO-NO, es-rans. ;10,= 1007, NO,-ONO — cis.rans. Ta fee" Vpn 18+ (00-Vp 242 ‘ONO-ONO clstrans. NO,-NO, — cis-trans. vi220 _ [dy NO-NO, clesrans "7200 \'d, > don = 1-88 gmn1 it “al number of eomers = 10 9 Resonance SOLIPTSPAPER250513 8 mm40. (20) SOL, AG%yy = AHP ayy -TAS®agy = AHP 55 -20— = 16Kj/mol AH, = AH, + AC, (T,-T,) Putting the values, we get: AC, = 20 Jimol PART-II: (MATHEMATICS) 41. 0) vtk=t-1 t Ayk=2 h Locus: xy 2x+ Which isa rectangular hyperbola 42. (A) 43. (A) -2sin'|e? | -28in asin'[e! ng Ind= => a-t6 44, (a) aa +bp+¢=0 bu+ch+a=0 cu. +af+b=0 is consistent la b of bc al-0 cab = a+b+C=0 a8 abe are distinct ax +by +62 =0 passes through (0,00) ang (40). ‘Thus Wt contain the line, x = 45. WV ie rea for any 2,,2),2) { 2% 4 = 224 21s pucty imaginary 48. (8) fo - fF HoKHa xs bx+2, xot 2+a=b ond § = > at 4b? =34 47. (a) cotdered triplets = 197 = 133 43. (A) Let E, > event that C's are separated E, > event that all S's are separated Pe 1) ee) PE, x PEE) rete) i 8 48. @0) 2x] +64 = 3[x]-192 9 Resonance SOLJPTSPAPER260513 10 mm[x]=256 => pe (256,257) © gin3%. in? asin sin 2%... sin 18°18 "48 2 © gin? 3% gin? SR cine = sin? % sin? = sin? 2 sin? 18 18 18 18 ae m6 BC 50. (A,8.0) Solutons are y = mx +m? whete m is an arbitrary constant Its singular soon is. y = 2 ye Ans. 8,6. 51. (A.C) A y-a(x,)2c=4 AC 2, Jiyee xenef =[lejor+ J [got ( ot Tat 53. (0) 2 lines are concurrent 5a, 55. > System have infinitely many solutions other than (0.0.0), hence True ‘8, If ciagonal elements are zero the malik is need not be skew symmetric, c) SS, :de of 2° degree curves is of order S as numberof indepen- dent arbitrary constants fs 5 8, : Between any two irrationals there are infinitely many rationals, sc ptgrt «Od : ©, = PP fim MRD. (M— C=) Hy 4) noe fi nf 21-2) af =2) 2-4) me a er a) sana 8,:Fortetuneton f(x) =x° (0°) ara (0 ) bam cose ot exis, bu Fs continuous at 0 4) Consider cole with OP as dlameter x(x-6)+y(y-8)=0 Let bets centre & 6) be angle hence CF,F; is equilateral tiangle Thus 2 F,OF,= 30 9 Resonance SOLJPTSPAPER260513 11 mmv7. TX Ni = eta 49 14, Hence sum of all possible values of ais (25) 2x—y=5 is tangent to cicle at (2,~1) S=(-2,1) Number of terms = 21 (00) F's continuous every where Therefore fof is also continuous every where Resonance x€(0,1] 0. (x) i increasing in (0, 4] = F()> FO) = sin ae xe (0,1] x sin 2 ts even function go statement is also true for x 1.0) sin'x | sin'y | sin tz x SOLIPTSPAPER260513 12 mm