CNG NG HA HC V NG DNG

DIN N BOOKGOL

LN 8
( thi c 4 trang)

THI TH TRUNG HC PH THNG QUC GIA

NM HC 2015- 2016
Mn: Ho Hc
Thi gian lm bi: 90 pht;

(50 cu trc nghim)

Ngy thi: 23/04/2016
Bin son: Thy V Nguyn

M thi 061
Cho bit nguyn t khi (theo vC) ca cc nguyn t: H = 1; He = 4; Li = 7; Be = 9; C = 12; N = 14; O = 16; F
= 19; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Ni = 59;
Co = 59; Cu = 64; Zn = 65; Br = 80; Rb = 85; Sr = 88; Ag = 108; Sn = 119; Cs = 133; Ba = 137; Pb = 207.
------------------------------------------------------------------------------------------------------------------------------------------Cu 1: Cho cc ion O2-, F-, Na+, Mg2+. Bit O (Z = 8) ; F (Z = 9) ; Na (Z = 11) ; Mg (Z = 12). Ion c bn knh ln
nht l
A. Na+.
B. Mg2+.
C. F.
D. O2.
Cu 2: t chy hon ton 24,64 gam mt este c tn gi vinyl metacrylat th cn bao nhiu lt O2 (ktc)?
A. 34,496 lt.
B. 29,568 lt.
C. 19,712 lt.
D. 27,104 lt.
Cu 3: Cho 50 gam dung dch axit axetic tc dng ht vi 50 gam dung dch NaOH 16% (dng d), dung dch sau
phn ng cha 14,3g cht tan. Nng phn trm ca dung dch axit axetic ban u l
A. 9,00%.
B. 20,93%.
C. 13,80%.
D. 18,00%.
Cu 4: T tm v t nilon 6,6 u
A. thuc loi t thin nhin.
B. cha cc loi nguyn t ging nhau trong phn t.
C. thuc loi t tng hp.
D. c phn ng mu biur.
Cu 5: Cho dy cc cht: NH4Cl, (NH4)2SO4, NaCl, MgCl2, FeCl3, Al2(SO4)3. S cht trong dy tc dng vi lng
d dung dch Ba(OH)2 to thnh kt ta l
A. 4.
B. 3.
C. 1.
D. 5.
Cu 6: Nung trong khng kh n khi lng khng i hn hp cha 0,2 mol CuS v 0,1 mol Ag2S, th thu c
bao nhiu gam cht rn mi?
A. 26,8 gam.
B. 40,8 gam.
C. 37,6 gam.
D. 39,2 gam.
Cu 7: Trong phng th nghim HR c iu ch t phn ng sau:
NaR(rn) + H2SO4 (c, nng) NaHSO4 (hoc Na2SO4) + HR (kh)
Hy cho bit phng php trn khng th dng iu ch c HR no sau y ?
A. HF.
B. HNO3.
C. HCl.
D. HBr.
Cu 8: H l mt este mch h, c phn t khi nh hn phn t khi ca propan-1,2-iol. S este H tha mn cc
tnh cht trn l
A. 2.
B. 3.
C. 4.
D. 5.
Cu 9: Cho kh CO d qua hn hp gm CuO, MgO, Al2O3 nung nng. Sau phn ng xy ra hon ton thu c
cht rn gm
A. Cu, Al2O3, Mg.
B. Cu, Al, MgO.
C. Cu, Al2O3 , MgO.
D. Cu, Mg, Al.
Cu 10: C ba cht hu c: H2NCH2COOH, CH3CH2COOH, CH3CH2NH2. nhn ra dung dch ca cc hp cht
trn, ch cn dng thuc th no sau y?
A. dung dch NaOH.
B. dung dch HCl.
C. CH3OH/HCl
D. qu tm.
Cu 11: Dung dch cha cht tan X c cc c im sau: phn t c nhiu nhm OH, c v ngt, ha tan Cu(OH)2
nhit thng, phn t c lin kt glicozit, khng lm mt mu nc brom. Cht X l
A. saccaroz.
B. mantoz.
C. glucoz.
D. xenluloz.
Cu 12: T lapsan thuc loi t..........., c iu ch t..........v...........
Chn nhng ng tng ng vi cc khong trng trn.
A. poliamit ; hexametyleniamin ; axit aipic.
B. polieste ; axit terephtalic ; glixerol.
C. poliamit ; axit aipic ; etilen glicol.
D. polieste ; axit terephtalic ; etilen glicol.
Cu 13: Cho phng trnh : Fe3O4 + H2SO4 Fe2(SO4)3 + SO2 + H2O.
Tng cc h s (cc s nguyn ti gin) ca cc cht tham gia phn ng l
A. 14.
B. 26.
C. 10.
D. 12.
Trang 1/4 - M thi 061

Cu 14: Thnh phn chnh ca phn amophot l

A. Ca(H2PO4)2 v CaSO4.
B. (NH2)2CO.
C. NH4H2PO4 v (NH4)2HPO4.
D. (NH4)2HPO4 v KNO3.
Cu 15: Trng hp no di y khng c kt ta sau khi phn ng xy ra hon ton?
A. Sc kh SO2 ti d vo dung dch KMnO4.
B. Sc kh etilen ti d vo dung dch KMnO4.
C. Sc kh H2S ti d vo dung dch Pb(NO3)2 long.
D. Cho dung dch Ba(OH)2 d vo dung dch Al2(SO4)3.
Cu 16: Cho dung dch Ca(OH)2 vo dung dch Ca(HCO3)2 s
A. c kt ta trng.
B. c bt kh thot ra.
C. c kt ta trng v bt kh.
D. khng c hin tng g.
2+
2 2
6
Cu 17: Cation R c cu hnh 1s 2s 2p . V tr ca R trong bng h thng tun hon l
A. 10, chu k 2, nhm VIA.
B. 12, chu k 3, nhm IIA.
C. 10, chu k 2, nhm VIIIA.
D. 8, chu k 2, nhm VIA.
Cu 18: Mt nguyn t ca nguyn t X c 35 electron v 45 ntron. K hiu nguyn t ca X l
A. 45
B. 115
C. 80
D. 80
35 X.
35 X.
35 X.
45 X.
Cu 19: Trong s cc cht: metyl axetat, tristearin, tinh bt, protein. S cht tham gia phn ng thy phn trong
mi trng kim l
A. 2.
B. 1.
C. 3.
D. 4.
Cu 20: Cht no sau y l hp cht c lin kt ion?
A. SO2.
B. HCl.
C. K2O.
D. CO2.
Cu 21: Tn gi cha chnh xc l
A. CH2=CH-CN: acrilonitrin.
B. H2NCH(CH3)COOH: axit 2-aminopropionic.
C. C6H5NH2: phenyl amin.
D. CH3COOH: axit etanoic.
Cu 22: Cht no sau y khng tham gia phn ng trng bc?
A. axit metanoic.
B. vinyl axetilen.
C. anlyl fomat.
D. etanal.
Cu 23: Cho dy cc cht: Na, CrO3, CaC2, SO3, BaO. S cht trong dy tc dng vi nc nhit thng to
thnh dung dch lm i mu phenolphtalein (khng mu) l
A. 4.
B. 2.
C. 5.
D. 3.
Cu 24: Cho 18,6 gam hn hp rn gm Na2CO3 v Ca tc dng ht vi dung dch HCl d, thu c 6,72 lt kh
(ktc). Phn trm khi lng ca Ca c trong hn hp l
A. 43,011%.
B. 64,516%.
C. 56,989%.
D. 66,667%.
Cu 25: nhit thng Cr ch tc dng vi
A. oxi.
B. flo.
C. nit.
D. lu hunh.
Cu 26: Dung dch H2SO4 long phn ng c vi tt c cc cht trong dy no sau y?
A. BaCl2, Na2CO3, FeS.
B. CuO, NaCl, CuS.
C. FeCl3, MgO, Cu.
D. Al2O3, Ba(OH)2, Ag.
Cu 27: Cht H thuc hp cht v c. Bit H lm mt mu nc Br2 v khng lm c nc vi trong. Cht H l
A. CH3OH.
B. H2S.
C. C2H4.
D. SO2.
Cu 28: Thy phn hon ton 37,96 gam mt ipeptit Ala-Gly trong dung dch KOH (va ), c cn dung dch
sau phn ng c m gam mui khan. Gi tr ca m l
A. 43,68.
B. 47,84.
C. 62,40.
D. 54,08.
Cu 29: Khi c nn p sut cao v lm lnh t ngt, cht X s ha thnh khi rn, mu trng gi l nc
kh. Nc kh khng nng chy m thng hoa, nn c dng to mi trng lnh v kh, rt tin li cho
bo qun thc phm. Cht X l
A. CO2.
B. C2H5OH.
C. CO.
D. H2O.
Cu 30: Cho FeCO3 tc dng ht vi dung dch HNO3 d. Tnh s mol kh thu c sau khi phn ng kt thc?
Bit s mol HNO3 phn ng l 0,6 mol v NO l sn phm kh duy nht ca N+5.
A. 0,06 mol.
B. 0,18 mol.
C. 0,24 mol.
D. 0,12 mol.
Cu 31: t chy ht 0,2 mol hn hp X gm C2H6, C2H4, C2H2, C4H4, C3H4 v CH4 cn va 0,61 mol O2, thu
c hiu khi lng CO2 v H2O l 10,84 gam. Dn hn hp H gm 11,44 gam X vi H2 qua Ni, un nng, sau
mt thi gian c hn hp Y (khng c but-1-in); t khi ca Y i vi H2 bng 14,875. Dn Y qua dung dch
AgNO3 trong NH3 d, thu c 3 kt ta c khi lng m gam v thot ra hn hp kh Z ch cha cc ankan v
anken; trong s mol ankan bng 2,6 ln s mol anken. t chy ht Z trong oxi d, thu c 0,71 mol CO 2 v
0,97 mol H2O. Gi tr ca m gn nht vi
A. 7,8.
B. 8,1.
C. 8,0.
D. 7,9.
Trang 2/4 - M thi 061

Cu 32: Thy phn hon ton dung dch cha 0,15 mol saccaroz v 0,25 mol vinyl fomat trong mi trng axit,
trung ha lng axit d bng lng va dung dch NaOH, cho vo dung dch sau phn ng lng d dung dch
AgNO3 trong NH3 th thu c ti a bao nhiu gam kt ta Ag?
A. 172,8.
B. 118,8.
C. 86,4.
D. 140,4.
Cu 33: Cho cc pht biu sau:
(1) Hin tng tri t nng ln do hiu ng nh knh nguyn nhn ch yu do kh cacbonic.
(2) Dung dch NaF long dng lm thuc chng su rng.
(3) Silic c dng trong k thut v tuyn v pin mt tri.
(4) Trong cng nghip sn xut H2SO4 ngi ta dng nc hp th SO3.
(5) Mui NaHCO3 c dng lm thuc tr au d dy do tha axit.
(6) Naphtalen tham gia phn ng th brom d hn so vi benzen.
(7) Cht gy nghin v gy ung th c trong thuc l l nicotin.
S pht biu ng l
A. 7.
B. 5.
C. 4.
D. 6.
Cu 34: t chy hai este X, Y (MX < MY) no, n chc, mch h thuc cng dy ng ng lin tip cn va
1,12 mol O2, thu c 0,88 mol CO2. Mt khc, thy phn hai este trn trong dung dch NaOH, c cn dung dch
sau phn ng thu c m gam rn H v 9,2 gam mt ancol. Nung H vi CaO th c 0,1 mol hn hp kh. Bit
cc phn ng xy ra hon ton. Phn trm khi lng ca mui c phn t khi nh hn trong H c gi tr gn
nht vi
A. 56%.
B. 36%.
C. 46%.
D. 47%.
Cu 35: Dn ton b 3,808 lt (ktc) kh SO2 vo V lt dung dch KOH 0,5M, c cn dung dch sau phn ng c
30,22 gam cht rn khan. Gi tr ca V l
A. 0,80.
B. 0,40.
C. 0,34.
D. 0,68.
Cu 36: Trn hn hp gm Fe2O3, CuO, Cr2O3 (2x mol), MgO vi bt Al (7x mol) c hn hp H. Nung hn hp
H mt thi gian c m gam hn hp X. Cho ton b X tc dng ht vi dung dch HNO3 (dng d 25% so vi
lng phn ng), thu c 4,48 lt kh NO (ktc) v dung dch Y. Nh t t dung dch NaOH (long) 2,14M vo Y
n khi khng cn phn ng xy ra th va ht 1,5 lt, sau phn ng thu c 0,03 mol kh v 33,88 gam kt ta.
Gi tr ca m l
A. 34,12.
B. 36,82.
C. 45,32.
D. 37,76.
Cu 37: Hn hp H gm hai cht hu c c cng thc phn t C3H12N2O3 v CH2O2 (t l mol tng ng 1 : 2).
Cho H tc dng ht vi 200 ml dung dch cha NaOH 2M v KOH 2,5M, c cn dung dch sau phn ng c m
gam rn khan v thot ra 0,2 mol kh lm xanh giy qu m. Gi tr ca m l
A. 43,7.
B. 64,2.
C. 60,4.
D. 52,2.
Cu 38: Cho 26,81 gam hn hp H gm Na2CO3, NaOH, Na2O, Na tc dng va vi dung dch HCl 10,95%,
thu c 273,16 gam dung dch X cha mt cht tan c nng phn trm l 16,0621% v hn hp kh Y. Bit t
khi ca Y i vi He bng

365
. Phn trm khi lng ca Na2O trong H c gi tr gn nht vi
58

A. 41%.
B. 42%.
C. 38%.
D. 25%.
Cu 39: Ha tan hon ton 13m gam hn hp H gm Al v Al2O3 trong dung dch NaOH (dng d 25% so vi
lng phn ng), sc kh CO2 ti d vo dung dch sau phn ng thy tch ra 31,2 gam kt ta v thu c dung
dch X c cha 35m gam cht tan. T l khi lng ca Al so vi Al2O3 c gi tr l
A. 1,89.
B. 0,26.
C. 0,53.
D. 0,18.
Cu 40: Hp cht X (cha C, H, O) c t khi hi so vi metan l 8,25, thuc loi hp cht a chc khi phn ng
vi NaOH to ra mui v ancol. S lng hp cht tha mn tnh cht ca X l
A. 5 cht
B. 4 cht.
C. 2 cht.
D. 3 cht.
Cu 41: Dn 22,4 lt kh CO qua m gam hn hp gm Al2O3, MgO, Fe3O4, Fe2O3, sau mt thi gian thu c hn
hp kh X v hn hp rn H. Cho H tc dng va vi 0,5 lt dung dch cha HCl 2,8M; H 2SO4 1,6M, c cn
dung dch sau phn ng c 180,54 gam mui khan v thot ra 0,5 mol kh. Bit t khi ca X i vi He bng
9,8. Gi tr ca m l
A. 70,04.
B. 63,24.
C. 52,04.
D. 81,24.
Cu 42: Dy cc dung dch no sau y, khi in phn (in cc tr, mng ngn) c s tng pH ca dung dch ?
A. KCl, KOH, HNO3.
B. CuSO4, HCl, NaNO3.
C. NaOH, KNO3, KCl.
D. NaOH, BaCl2, HCl.
Cu 43: X, Y (MX < MY) l hai amin no, h, c cng s nguyn t cacbon. t chy ht hn hp H gm X, Y
trong khng kh (va ), dn ht sn phm sau phn ng gm CO2, H2O (1,35 mol), N2 qua 550 ml dung dch
KOH 2M, thy thot ra 5,05 mol kh v dung dch sau phn ng cha 74,6g cht tan. Bit s mol X bng 1,5 ln s
mol Y. Khi lng ca Y l
A. 15,2 gam.
B. 9,2 gam.
C. 12,2 gam.
D. 9,0 gam.
Trang 3/4 - M thi 061

Cu 44: X, Y, Z (MX < MY < MZ) l ba ancol no, h, c s nguyn t cacbon lin tip nhau. t chy ht hn hp
H gm X, Y, Z (s mol X chim 48% s mol hn hp) cn ng 1,13 mol O2, thu c tng s mol CO2 v H2O l
2,26 mol. Nu cho H tc dng ht vi Na d th thu c 9,856 mol kh (ktc). Cho Z qua CuO d, un nng, kt
thc phn ng thu c mt cht hu c T (khng cha nhm chc cacboxyl). Cho T tc dng ht vi lng d
dung dch AgNO3 trong NH3 th thu c bao nhiu gam kt ta?
A. 77,76.
B. 25,92.
C. 58,32.
D. 51,84.
Cu 45: Hn hp H gm mt axit X v hai este Y, Z c to t axit X; bit X, Y, Z u mch h, phn t u
cha hai lin kt pi, u n chc. t chy H trong 1,62 mol O2 (va ), thu c 65,12 gam CO2. Mt khc,
un nng H trong (3,5m + 14,4) gam dung dch NaOH 12,5%, c cn dung dch sau phn ng c m gam rn
khan. Gi tr ca m l
A. 41,6.
B. 42,4.
C. 37,6.
D. 40,8.
Cu 46: Cho m gam dung dch H2SO4 long nng x% tc dng hon ton vi hn hp (dng d) hai kim loi
kali v st. Sau phn ng, khi lng hiro thot ra l 0,04694m gam. Gi tr ca x l
A. 24,51%
B. 70,75%
C. 24,81%
D. 15,51%
Cu 47: Tin hnh in phn 100 gam dung dch cha AlCl3 (7x mol) v FeCl2 (10x mol) (c mng ngn) vi
cng dng in 5A, khi lng dung dch trong qu trnh in phn thay i theo thi gian c biu din
bng th sau:

khoi lng dung dch (g)

100
89,84

m
thi gian ien phan (giay)
0

t1

2,5t1

17370

in phn ti thi im 2,5t1 giy khi kh bt u thot ra ti catot th tm dng in phn, sau in phn tip
ti thi im 17370 giy th kt thc qu trnh in phn, ly mng ngn ra; yn dung dch mt thi gian th khi
lng dung dch cn li m gam. Gi tr ca m l
A. 83,95
B. 52,37.
C. 58,55 .
D. 73,03.
Cu 48: X, Y, Z (MX < MY < MZ) l ba este no, h; X v Y thuc cng dy ng ng; Z khng phn nhnh v to
thnh t mt ancol. Thy phn ht 0,35 mol hn hp H gm X, Y, Z trong 350 ml dung dch KOH 1,08M, c cn
dung dch sau phn ng c m gam rn T ch cha cc mui v hn hp A gm 3 ancol thuc cng dy ng
ng, lin tip. Mt khc, t chy ht 36,52 gam H trong oxi, sau phn ng thu c 24,12 gam H2O. Bit tng s
nguyn t ca c X, Y, Z l 48; Z nhiu hn Y hai nguyn t cacbon. Trong T th t l khi lng ca mui to nn
Y so vi khi lng ca mui to nn Z c gi tr l
A. 0,699.
B. 1,075.
C. 0,973.
D. 0,831.
Cu 49: Ha tan 1180m gam hn hp H gm FeS2, FeS, FexOy, FeCO3 vo dung dch cha 2 mol HNO3, kt thc
phn ng thu c 549m gam hn hp kh T gm NO, NO2, CO2 v dung dch X. Cho X tc dng ti a vi 20,16
gam Cu, th ch c kh NO thot ra ng thi thu c dung dch Y; khi lng cht tan trong Y nhiu hn khi
lng cht tan trong X l 18,18 gam. Mt khc dung dch X cng phn ng ti a vi 500 ml dung dch Ba(OH) 2
1,74M, sau phn ng thu c 90,4 gam kt ta. Bit trong H oxi chim 24,407% v khi lng v sn phm kh
ca N+5 trong c qu trnh ch c NO v NO2. Phn trm khi lng ca NO2 trong T c gi tr gn nht vi
A. 30%.
B. 23%.
C. 55%.
D. 28%.
Cu 50: X, Y l hai este hai chc; Y cha vng benzen; X, Y u c to bi hai axit no thuc cng dy ng
ng lin tip, Z l mt peptit c to bi alanin v valin; X, Z mch h. un nng ht hn hp H gm X (9x
mol), Y (3x mol), Z (x mol) bng dung dch NaOH (va ), thu c dung dch A v 32,4 gam ch mt ancol T.
C cn dung dch A c 137,24 gam mui khan (cc mui khng cha nhm chc ancol v mui c phn t khi
ln nht chim 13,4655% v khi lng). t chy ht lng mui khan trn cn ng 4,71 mol O 2, thu c
148,72 gam CO2 v 56,88 gam H2O. Trong H c m N : mO 7 : 64. Hiu khi lng gia X v Z l
A. 34,76 gam.
B. 43,72 gam.
C. 44,84 gam.
D. 39,80 gam.
----------- HT ---------Trang 4/4 - M thi 061