Gi) State what would be observed atthe cathode after the electrochemical cell in Figore 1 has been ruaning for «few houte, Ui mark) Gi) _State the experimental conditions used in the preparation of the cell in Figure | ‘Temperature ‘Concentration of Solutions A and B [2 marks) (iv) Use the information in your Data Booklet to calculate the standard cell potential, Ey forthe electrochemical cel in Figure 1. [3 marks} “Total 15 marks GOON TO THE NEXT PAGE OP LDAPAICAPR.IO10MODULE 3 (CHEMISTRY OF THE ELEMENTS: 3. Ammonium vanadate(V), NH, VO, is an orange solid. Tests are performed on NH,VO, to show the variable oxidation states of vanadium, (2) Record in Table 1 the observation expected for EACH of the tests below: ‘TABLE 1; TESTS ON AMMONIUM VANADATECY) Test Observation Inference (A fewom’ oftench NOH | Colour: VO; formed is added to.¢ small amount of solid NH,VO,, followed by afew env of dine HO, Gi) ATitte granulated zinc is} Colour changes to ‘added tothe solution in (i) + | VO, and vor above, tent : vo" hento ye and finally vie [ S marks] (©) Calculate the oxidation numberof va jum in EACH of the following species: voso, (i) vos i) VO 13 marks} GO ON TO THE NEXT PAGE (02112020/CAPE 2010©) When concentrated HC! is adsed 0 8 pink solution of cobalt I) chloride, te solution ‘urs blue. Give an explanation forthe observation stated above ip terms of the stailty constant ‘of the complex ion formed, and write a balanced equation forthe reaction, Explanation ‘Equation [4 marks) (4) Complete Table 2 to show the acid/base character of the oxides of Group IV elements in the +2 oxidation state TABLE 2: OXIDES OF GROUP IV ELEMENTS, Group 1V Oxiees Acid Base Character co © co, » Sn0 Armphoterc Poo i) [ 3marks} ‘Total 1S marks GOON TO THE NEXT PAGE, 02172920/CAPE 2010,SECTION 8 Answer ALL questions. Write your answers inthe separate answer booklet provided MODULE 1 FUNDAMENTALS IN CHEMISTRY 4. G)__ Copy and complete Table 3, which provides information the properties of the simple subatomic particles. TABLE 5: ROPERTIES OF I MPLE SUBATOMIC PARTICLES Particle Relative Mass | Relative Charge Location Fleetron a wo —— 18a) Proton “ Nucleus —— 1 we Nucleus 1 4marks} my] Radicgotive emisions are affested by an lect le, MAME the type of radio. Rade at behaves inthe sae way asthe cksron, | Lar 1 ti) Me decays by emitng paces State he Prose! formed from the decay dik po by theemissionof ee pricks ane cau ratioof BOTH the reactant and product atoms {6 marks} Gi) Comment onthe effect Unt the decay hasan the sabiiy oF nacleus of BE, {dark } fo) Draw the smctres of the atomic cebitals of principal auankeny umber 2 Include x,y and 7.axes inthe drawing 1 2marks) Gi) Using sp. notation, write the elecvonie configuration ofr ft vark 1 “Total 15 marks GOON TOTHE NEXT PAGE 921120201 APE 2010MODULE 2 INETICS AND EQUILIBRIA [Astudent prepares an ethanoic acid solution of pl 5. He uses his solution to make a buffer (2) Define EACH ofthe following terms: oH [ 2 marks} Buler solution {2 marks) (b) The avid dissociation constant (K,) of ethanoie acid at 25 *C has « numerical value of 1.7 x 10°, The equilibrium equation forthe dissociation of ethanoic acid is CH,COOH(ag) — Hr (ag) +CH,COO Cas). (Write an expression forthe aeid dissociation constant (K,) of ethanoie wed [tmark } Gi) Calculate the equilibrium concentration of ethanoic aid in solution that has pH of. [4 marks) (©) Sttetheetfect, onthe equi of rium position of «butler solution, of adding small amounts Hea) [tmark } (i) OM Cax. (mark | (6) A buffer solution is made by adding 20.5 g of sodium ethanoate (CH,COONa) 0 ‘500 cm of 1-5 mol dm ethanoie acid, (K, = 1.7 x 10° at25 °C forethanoie seid), Calculate the pH of this buffer solution. { 4marks) (Relative atomie mass: H= 1, C= 12,0 = 16,Na=23) ‘Total 15 marks GO ON TO THE NEXTPAGE, 02112020/CAPE 2010-10 MODULE 3 (CHEMISTRY OF THE ELEMENTS. “The elements in Period 3 of the periodic table are given below. Nao Mg Alsi PS) Le fa) Account for EACH of the following vanations in propertics across the period Na to Ar ()_Electronegatvity increases across the period. [ 2 marks} ii) Melting point ofthe elements increases from Na 0 Si 1 2marks} (b) Describe the rend in the aid/base character ofthe oxides of the elements in Period 3 [3 marks} (©) When aluminium chloride dissolves in water, its solution is acidic, Account for the acidic nature of the aluminium chloride solution. [2 marks] (a) ‘Transition metas have higher melting points than metals such as calcium in the block ofthe periodic table. Suggest TWO reasons for this, {2 emarks] (e) PO yan PCI are the oxide and chloride of phosphorous in ts highest oxidation state ‘Write an equation to show bow EACH of the following reacts with water. © PO. [2 marks} Gi) Pa, [ 2marks} “Total 15 marks END OF TEST (02112020/CAPE 2010<2. SECTION A Answer ALL questions inthis section, Write your answers in the spaces provided in this booklet. MODULE. FUNDAMENTALS IN CHEMISTRY 1. (a) State the types of bonds (intra-molecular and inter-molecular) that exist in liquid (b) Ammonia can he produced by heating calcium oxide with sammy to other products sre caleium chloride and water. (Write ahatanced chemical equation forthe reaction between calcium oxide and ammonium ehoride (2 marks] ii) Calculate the mass of ammonium chloride needed to produce 1 cm’ of ammonia at RTP (room temperature and pressure), (Molar volume = 24 dm" at RTP) [ 2 marks} GO ON TO THE NEXT PAGE, 02112020/CAPE 2010(©) G_—_ Ammonia gas deviates from ideal behaviour. Under which of the following sets of conditions. I. I or II, would the deviation be LEAST? Conditions | Temperature (C) Pressure (kPa) 1 40 tor 0 130 so 20 500 Gi) State TWO assumptions ofthe kinetic theory ast pertains [2 marks) (Gil) Which assumption of the kinetic theory si pertains toil woses would MOST. likely account for your answer to (e) (i) abowe? [tmark | (4) Some ammonia gas is dissolved in water. The exact concentration of the solution is tunknown and has tobe determined. Describe an experiment that would determine the concentration of the aqueous amimoni [ Smarks) ‘Total 15 marks GOON TOTHE NEXT PAGE 02112020/CAPE 2010