w (2) GB) @) () (6) 0) Chapter-7 Surface Chemistry From the following which is not a surface phenomenon ? (A) Crystallisation (B) Heterogeneous catalysis (C) Corrosion (D) Water and its vapour in a closed vessel What is to be done in a solution of a dye to reduce the intensity of colour ? (A) to add Fe powder as a catalyst (B) to pass H, in solution (C) to add charcoal powder (D) to add sugar powder From the following which is ci lled absorption ? (A) phenomenon between silica gel and water (B) phenomenon between alumina gel and water (C) phenomenon between sugar and water (D) phenomenon between coloured water and dye Which is physical adsorption phenomenon ? (A) Adsorption of H, over charcoal (B) Catalysis of Fe metal in Haber's process (C) Catalysis by V,O, to obtain SO, from SO, and O, (D) Adsorption of NH, and Ni metal Which is the statement which is not Freundlich adsorption isotherom’s limitation 2 (A) at high pressure it shows deviation, (B) values of constants k and n change with temperature, (C) this isotherm has no theoretical basis. (D) absorbate gas possesses thickness of one molecule ‘At very low pressure, Langmuir adsorption isotherm is —___ +. ry @ oie ®) B= @ © >=% @) * = kh m m x The slope of graph of Jog > logP of Freundlich adsorption isotherm indicates which value ? (A) logK By ~ (A) log e x 1 (C) log @) m tn 052-CHEMISTRY 47@) Tyndal effect represents which property of a colloid ? (A) Optical property (B) Mechanical property (©) Colligative property (D) Electrical property (©) Which statement is not applicable to Langmuir adsorption isotherm ? (A) depends on kinetic theory of gases {B) adsorption of gaseous molecules on the surface of the solid adsorbent - condensation. (©) adsorption of gaseous molecules ftom the surface of the solid adsorbent - evaporation (D) equilibrium is not established when rate of condensation and evaporation become equal. (10) Which is correet for “adsorption taking place on adsorbent in chromatographic separation” ? (A) Concentration of adsorbate is considered instead of its equilibrium pressure. (B) Adsorption will increase with the increase in temperature at constant temperature. (©) Adsorption will increase with the decrease in temperature at constant pressure. (D) There must be only coloured impurities only in the solution to indicate adsorption on | charcoal (11) Which is not correct for catalysis ? (A) catalyst generally increases the rates of forward and reverse reactions (B) equally catalyst does not affect the equilibrium constant of the reaction. (C) catalyst increases the energy of activation of the reaction. (D) above statements a and b both are correct. (12) What type of catalyst is used in the manufacture of SO, gas by Lead Chamber's process (A) Homogeneous catalyst (B) Heterogeneous catalyst (©) Catalyst is not used (D)_ enzymes are used as catalysts (13) Catalysts used for the inversion of sucrose (A) 180, (B) activated charcoal (C)_ Raney Nickel (D) Vanadium Pentoxide (4) Which is the main product obtained on reacting hydrogen with carbon monoxide using Nickel as a catalyst ? (A) CH, 8) CH,COCH, (©) CHO (D) HCHO (15) Which catalyst becomes useful to obtain HCHO as a main product on reacting Hydrogen a8 052-CHEMISTRY(15) (16) a7) (18) «gy (20) (1) 23) Which catalyst becomes useful to obtain HCHO as a main product on reacting Hydrogen and carbon monoxide ? (A) Ni (B) Cu/Zn0-Cr0, © cu @) V,0, As we move from group five to group eleven metals in periodic table catalytic activity (A) Decreases gradually (B) Increases gradually (C) Catalytic attitude remains constant (D) There is a gradual decrease Animals like cows and buffaloes are able to digest cellulose containing food stuff because in them, there is homogeneous catalysis. (A) Enzyme maltose (B) Enzyme urease (C) Enzyme zymase @) Enzyme cellulase What is ZSM-5 ? (A) Shape selective catalyst (B) Only selective catalyst (©) Biological catalyst (D) Substance useful to prepare gas mask Which substance converts alcohol directly into gasoline by dehydration ? (A) Raney Nickel catalyst (B) Anhydrous CaCl, (©) ZSM-5 (D)_ None of these Which phenomenon is included in electrode reactions ? (A) Electrical phenomenon (B) Physical change (©) Electronics (D) Surface phenomenon From the following which phenomenon is indicated by intraface ? (A) Solubility (B) Distillation (C) Cooling (D) Corvsion of metals ‘The example in which solid and liquid dispersing phase are separate but remain in contact with each other is (A) Hair cream (B) Cloud (©) Foam rubber (D) Buter What is the colloidal system in cell fluid ? (A) dispersing phase solid, dispersion medium liquid. (B) dispersing phase solid, dispersion medium gas. (C) dispersing phase liquid, dispersion medium solid. (D) dispersing phase gas, dispersion medium liquid Heterogeneous catalysis is the example of which phenomenon ? (A) General phenomenon (B) Activated phenomenon (C) Surface phenomenon (D) Chemical phenomenon 052-CHEMISTRY 49(25) (26) (27) (28) How much vacuum is essential to get a completely pure and clean surface of metals ? (A) 10° to 10” pascal (B) 10% to 107 pascal (©) 104 to 107 pascal ——(D)._10* fo 10” pascat The pressure of a gas dissolved in water is measured in which unit ? (A) Neuton (B) Atmosphere (C) Bar (D) Pascal Whaat is the phenomenon called for the asorption of acetic acid on the surface of activated charcoal in a solution of acetic acid ? (A). Desorption (B) Chromatography (©) Adsorption (D) Absorption In adsorption of gas molecules on the surface of a solid (A) Condensation reaction takes place (B) Evaporation takes place (©) Absorption takes place ) Desorption takes place (29) Which is the adsorbate in the phenomenon of adsorption of N, over Nickel metal ? (A) Ni metal 8) Ny (©) Ni and N, both (D) Not a single from Ni and N, G0) Wdentify the hydrophobic sol (A) Gelatin (B) Gum (© Sugar (©) Sulphur G1) Which is the relation between adsorption of gaseous adsorbent on solid adsorbate at constant temperature for a gas ? =KP”" -m=K-P* (A) 0% = KP (8) x-m=K-P x ” x_K S=(K-P)* rs © a(KPy © 20 pe 2) Which adsorbent is used to remove the yellow colour of sugar ? (A) Activated charcoal (BY Gelatin (C) Zeolite (©) Alumina (33) What will be the nature of graph of Jon versus logP in Freundlich adsorption isotherm ? (A) Parabola (B) Straight line (©) Ellipse ®) Curve G4) To obiain stable colloidal sol. of Fe (OH), reaction of which substance is used ? (A) hydrolysis of FeCl, (B) adding HINO, in Fe (OH), (C) adding HCI in Fe(OH), (D) adding hot water in Fe(OH), 50 (052: CHEMISTRY@5) (36) 37) (38) @9) ay @ @) ay (3) (6) 7) (8) What will be the approximate value of enthalpy in physical adsorption ? (A) More than 20 kjoule mol (B) -30 kjoule mol* (C) -20 kjoule mol" (D) 20 kjoule mol Which catalyst is used in the production of acrylonitrile from propylene, NH, and O, (A) Mo VI complex {B) Bismuth molybdate (©) [Rh(CO), 1)" (D)_Ni, Pd. complex compound Which substance is used in isomerisation in petroleum industries ? (A) Silica gel (B) Activated charcoal (C) Zeolite (D) Sodium aluminium silicate Emulsion of asphalt used in construction of roads is prepared in which substance ? (A) in water (B) in oil (©) in petrol (D) in kerosene From the following which is not an emulsifier ? (A) Agar (B) Gum (C) Soap (D) Milk Answers D (9) D ay D @5) D G3) B c (0) BB ag) A 26) C G4) A c ay oc a9 Cc Qn Cc @5) C A (2 A Qo) D (28) A G6) B D (3) A Qb D QQ) B G67 B a4) A @Q2) D Go) iD G8) A D as) oc Q3) A GBD oA G9) =D A (16) B G4) G2) A 0S2-CHEMISTRY St