n-butil asetat (1)

air (2)
Temp =
300
k

CH3CO - OCH2 - CH2 - CH2 - CH3

H2O
K
DATA UNIFAC
Rk
Qk
vk(1)

x-I
0.25
0.75

vk(2)

CH3-CH2CH3CO-CH2OH2O

1
2
19
26
17

0.9011
0.6744
1.6724
0.9183
0.92

0.848
0.54
1.488
0.78
1.4

1
2
1
1
0

0
0
0
0
1

main grp
k=1
1
9
13
7

CH3m=1
0
0
26.76
83.36
300

-CH21
0
0
26.76
83.36
300

-CH2CO9
476.4
476.4
0
52.38
-195.4

-OH
13
251.5
251.5
5.202
0
540.5

ri
qi

i=1
4.8406
4.196

i=2
0.92
1.4

tau-mk
k=1
1
9
13
7

m=1
1.0000
1.0000
0.9147
0.7574
0.3679

m=1
1.0000
1.0000
0.9147
0.7574
0.3679

m=9
0.2043
0.2043
1.0000
0.8398
1.9181

m=13
0.4324
0.4324
0.9828
1.0000
0.1650

m=7
0.0124
0.0124
0.2070
2.8548
1.0000

J-i
L-i

i=1
2.5475
1.9990

S-k
k=1
1
9
13
7

0.6461
0.6461
1.2617
0.4489
0.8050

CH3-CH2CH3CO-CH2OH2O
STEP I

STEP II
e-ki
k=1
1
9
13
7

0.2021
0.2574
0.3546
0.1859
0.0000

0.0000
0.0000
0.0000
0.0000
1.0000

STEP III
beta-ik
k=1
1
9
13
7

i=1
0.9246
0.9246
0.6046
0.7331
0.6098

i=2
0.3679
0.3679
1.9181
0.1650
1.0000

STEP IV
ln (gamma C)
ln (gamma R)
ln (gamma)
Gamma - i

i=1
0.0572
0.2132
0.2703
1.3104

i=2
0.1142
0.2257
0.3398
1.4047

H2O
7
1318
1318
472.5
-314.7
0

i=2
0.4842
0.6670

teta-k
k=1
1
9
13
7

0.1010
0.1286
0.1772
0.0929
0.5002

k
CH3
CH2
CH
C
OH
H2O
CH3CO

DATA
Rk
Qk
1
0.9011
2
0.6744
3
0.4469
4
0.2195
15
1
17
0.92
19
1.6724

i=1
ri
qi

beta-ik
i=1
i=2

ln(gamma C)
ln(gamma R)
ln gamma
gamma i

i=2
6.702
5.3

UNIFAC
vk(1)
0.848
0.54
0.228
0
1.2
1.4
1.488

vk(2)
1
2
3
2
1
0
1

tau-mk
0.92
1.4

1
1
1
1
5
7
9

0
0
0
0
0
1
0

1
1
1
1
1
1
1
1
1
1
0.593728 0.593728
0.367879 0.367879
0.914663 0.914663

1
1
1
1
5
7
0.884055 0.884055 0.884055 0.884055 0.302924 0.133898
0.367879 0.367879 0.367879 0.367879 2.146131
1

i=1
i=2
-0.010948 0.171319
-0.005195 -2.918515
-0.016143 -2.747195
0.983987 0.064107

CH3
m=1
CH3
CH2
CH
C
OH
H2O
CH3CO

0
0
0
0
156.4
300
26.76

CH2
m=1

CH
m=1

0
0
0
0
156.4
300
26.76

0
0
0
0
156.4
300
26.76

1
1
5
7
1
1 0.037316 0.012359
1
1 0.037316 0.012359
1
1 0.037316 0.012359
1
1 0.037316 0.012359
0.5937284 0.593728
1 0.307791
0.3678794 0.367879 2.146131
1
0.9146626 0.914663 0.207008 0.207008
9
0.5525775
1.9180966

teta-k

C
m=1

OH
H20
CH3CO
m=5
m=7
m=9
0
986.5
1318
476.4
0
986.5
1318
476.4
0
986.5
1318
476.4
0
986.5
1318
476.4
156.4
0
353.5
84
300
-229.1
0
-195.4
26.76
472.5
472.5
0

9
0.204334
0.204334
0.204334
0.204334
0.755784
1.918097
1

e-ki
1
1
1
1
5
7
9
S-k

1
1
1
1
5
7
9

0.147052
0.187283
0.118613
0
0.208092
0.080925
0.258035

i=1
0.16
0.203774
0.129057
0
0.226415
0
0.280755

1
1
0.842284 0.842284

Senyawa
A
B
Temperatur

i=2
0
0
0
0
0
1
0

Fraksi i
0.75
0.25
300

j-i
l-i

i=1
i=2
1.274993 0.175021
1.225434 0.323699

1
1
5
7
9
0.842284 0.8422836613 0.452085 0.203987 0.663082