Material Safety Data Sheet for Biosulphur Sludge 7 CHEMICAL PRODUCT AND COMPANY INFORMATION Product Name Bio-Sulphur Slury Chemical Formula 8°, NaHCO, Na,SO, mixture Company Name Paques B.V. Address T. de Boerstraat 24, Postbus 52, 8560 AB BALK Telephone +31(0) 514-608 500 Fax +31(0) 514-603 342 Emergency Number _ Telephone: +31(0) 514-608 759 Mobile: +31(0) 6-207 057 48 2.___ COMPOSITIONINFORMATION ON INGREDIENTS “An aqueous slurry containing Salts (e.g. NaHCO, Na,SO.), sulphur (solid) and sulphide oxidizing bacteria (e.g. Thiobacilus) 3._ POSSIBLE HAZARDS FIRE HAZARD © Direct fire hazard Non flammable © Indirect fre hazard: - TOXICITY HAZARD —_o irect toxicity hazard: None expected © Indirect toxicity hazard: - EXPLOSION HAZARD _ Direct explosion hazard : Non explosive © Indirect explosion hazard : - ‘4___ FIRST-AID MEASURES INHALATION © Immediately remove individual to fresh air SKIN © Wash exposed area with soap and water. EYES © Immediately rinse with plenty of clean water for 15 minutes. ORAL © Drink water or milk as soon as possible after intake, © Get medical assistance. GENERAL © Many symptoms persist, seek medical attention. 5._FIRE-FIGHTING MEASURES EXTINGUISHERS © Extinguishers at surrounding fire: All extinguishers allowed. EXTINGUISH © Not applicable INSTRUCTIONS ‘ACCIDENTAL RELEASE MEASURESPERSONAL © Protect eyes and skin with safety goggles and gloves, PROTECTION respectively. © Use portable personal H-S sensor. Note: Since some H-S may be present in the vapour space above the liquid container/sample shall be opened in properly vented areas only, ENVIRONMENTAL © Wash exposed surfaces with water. AND PRECAUTION MEASURES. CLEANING © No special disposal procedure required. The slurry can be PROCEDURE sprayed into the sewer system with water. HANDLING AND STORAGE ‘STORAGE 2 Keep in closed containers/tank in an open vented warehouse or shelter. © Avoid sub zero temperatures, © Apply to local rules. STORAGE © Suitable storage materials: Polyester, plastics, glass MATERIALS © Special demands to storage materials: Closable; Correctly marked; Apply to governmental rules EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS No data available EFFECT/SYMPTOMS —_o Inhalation: None expected; OF EXPOSURE Note: Under oxygen-free conditions HS can be formed and can be present in the vapour space above the liquid. © Skincontact : May cause some skin irritation, © Eye contact : May cause some eye irritation co lngestion : May cause some irritation SPECIAL General —_: Protect eyes with safety goggles and gloves PROTECTION respectively, INFORMATION © Use portable personal H-S sensor. Note: since some H,S may be present in the vapour space above the liquid container/sample shall be opened in proper- vented areas only. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL DATA © Aggregation: Liquid © Odour —_: Slight smell of rotten eggs. © Colour: White/yellow viscous liquid (solids in suspension). © Solubility —: Nil Toxicity: None.DATA PHYSICAL © Bolling point ‘Similar to water. PROPERTIES © Vapour Density Not applicable Acidity (pH): 7 to 10. BIOLOGICAL DATA —_o Pathogenic bacteria No E-coli or pathogenic organisms (those that can harm humans) are present. 10,__ STABILITY AND REACTIVITY STABILITY ‘Stable under normal circumstances. CHEMICAL Under oxygen-free conditions some H,S can be formed from the REACTIONS anaerobic conversion of sulphur components present in the solution CIRCUMSTANCES TO - AVOID 11, TOXICOLOGICAL INFORMATION Nor applicable 12, ECOLOGICAL INFORMATION ECOLOGICAL © Ecological information for water: Weakly polluting (surface COMPARTMENTS: water); * None bio-accumable; * DH shifting © Ecological information for soil: Biological degradable in the soil 13.__ DISPOSAL CONSIDERATIONS © No special disposal procedure required. The slurry can be sprayed into the sewer system with water. 14,__ TRANSPORT INFORMATION 2 ADR Free > ADNR Free © RID Free © IMDG Free © ICAO/IATA — : Free 15,_ LABELLING ‘Symbol None Risk Phrases - Safely Phrases - 16. OTHER INFORMATION@ Relevant changes in a revision will be marked with a vertical ine in the marginal line. © Above data apply only to the product mentioned in chapter 1 and under the circumstances as mentioned in this material safety data sheet. © These data do not apply with restriction if this product is used in combination with other materials and with restrictions if itis used in a process. © Although this material safety data sheet is composed with great care Paques B.V. cannot accept any liability for the use of this product. The user should convince himself before he starts using this product if the data is complete and the product is suitable for the process where it will be used in, Material Safety Data Sheet for Sodium Carbonate To be obtained from vendor. Material Safety Data Sheet for Sodium Bicarbonate To be obtained from vendor.