Potencial est Ag

Ca
T

779
0.9
19

Conc
FI
Conc
Conc
Conc

Ag
ClNH3
I-

OBTENCION CONSTANTES Y E REF

k ref
E ref
421.024161 241.959732

Inicio
ClNH3
NH3
NH3
iI-

OBTENCION CONCENTRACION Ag
V Total (mL) M ligante
E celda
100
110
0.01
120
0.01
130
0.01
140
0.01
150
0.01

(mV) Conc Ag
247
0.001
117 5.74026E-006
40 2.70103E-007
10 8.21033E-008
-4 4.70993E-008
-196 2.30743E-011

Cl-

OBTENCION KPS AgCl

V Total (mL) M ligante
E celda (mV) Conc Ag
Conc Cl110
0.01
117 0.000000574

I-

OBTENCION KPS Agl

V Total (mL) M ligante
E celda (mV) Conc Ag
Kps AgI
150
0.01
-196 2.30743E-012 2.3074345784E-018

NH3
NH3
NH3

0.009

OBTENCION Kf complejo plata y p

V Total (mL) M ligante
E celda (mV) Conc Ag
Conc AgNH3p
120
0.01
40 0.000000027
0.0121
130
0.01
10 8.21033E-009
0.0131
140
0.01
-4 4.70993E-009
0.0141

NH3
NH3
NH3

V Total (mL) M ligante

E celda (mV)
120
0.01
130
0.01
140
0.01

40
10
-4

0.001
0.01
0.01
0.01
0.01

Kps AgCl lite

Kps AgI literatura

Kps AgCl
%Error
5.16624E-012 96.6883091

% Error
98.461710281

Conc NH3
Y
Log conc NH3
0.0009090909 4.65125538
-3.0413926852
0.0013043478 5.20291087
-2.8846065813
0.0016666667 5.47620449
-2.7781512504

p
log Kf

Kf suponiendo p=3
6257E+013
9003E+013
46634E+013
3964E+013

3.1627
14.286
193196831701693

1.56E-010
1.5E-016

Y vs Log Kt
f(x) = 3.1626664397x + 14.286231823
R = 0.9932152892

-3.1

-3.05

-3

-2.95

-2.9
LogNH3

-2.85

-2.8

g Kt
6
5.5

823

H3

5
4.5

-2.9

-2.85

-2.8

4
-2.75