CNG N TP HE LP 11

MN HA KHI 11
********
Dng 1: ng Phn Danh Php
Bi 1:
a) Vit ng phn v gi tn ankan c CTPT C4H10, C5H12
b) Vit ng phn cu to, ng phn hnh hc v gi tn ca anken c CTPT C4H8 ,C5H10 ;C6H12
Bi 2: Vit ng phn cu to v gi tn ca ankin c CTPT C5H8; C6H10
Bi 3: Vit ng phn cu to v gi tn ca hirocacbon thm c CTPT C8H10; C8H8
Bi 4: Vit ng phn cu to ca hp cht thm c CTPT C7H8O (5 ng phn)
Bi 5: Vit ng phn cu to v gi tn ca ancol c CTPT C4H10O; C5H12O
Bi 6: : Vit ng phn v gi tn cc anehit v axit cacboxylic c CTPT C4H8O, C5H10O, C4H8O2, C5H10O2
Dng 2: Vit PTHH
Bi 1: Hon thnh cc PTHH v gi tn sn phm:
a. isopentan + clo (1:1)
b. vinyl axetilen + H2 (Ni)
c. 3-metyl but-1-in + dd Br2
d. toluen + Cl2 (Fe, to)
e. propilen + dd KMnO4
f. toluen + dd KMnnO4 (to)
g. butan-2-ol + CuO (to)
h. propan-1-ol + H2SO4 c (180oC) i. stiren + dd Br2
j. andehit fomic + dd AgNO3/NH3 k. axit propionic + canxi cacbonat
Bi 2: Vit cc PTP theo s chuyn ha sau:
PE

a. C2H5OH C2H4 C2H5Cl C2H5OH

1,2-dibrom etan
b. C2H5COONa C2H6 C2H4 C2H4(OH)2

C2H5Cl C2H5OH
c. tinh bt glucozo ancol etylic etylen ancol etylic etyl clorua ancol etylic andehit axetic
Bi 3: Vit PTP theo s chuyn ha:
O
KOH
/ ancol
Cl 2 , 600 C
P, xt
a. C2H6 C2H5Cl
A
B
polime
b. C4H10 CH4 C2H2 C6H6 6.6.6

Vinyl clorua P.V.C

c.
Bc axetilua axetilen

CaCO3 CaO CaC2 C2H2 etilen PE

vinyl clorua PVC

d. pentan C2H4 etanol CH3COOH canxi axetat axeton propan-2- ol C3H6 alyl clorua
ancol alylic 2,3-dibrom propen 1-ol glixerol ng (II) glixerat
Bi 4: iu ch cht hu c
a/ T vi, than v cc cht v c cn thit khc, hy vit cc PTHH iu ch: P.E, P.P, cao su Buna, thuc
tr su 6.6.6.
b/ T metan v cc cht v c cn thit khc, hy vit PTHH iu ch: ancol etylic, anehit axetic, axit axetic,
P.V.C.
c.T metan v cc ha cht v c cn thit khc c th iu ch c axit fomic v axit axetic. Vit PTHH ca
cc phn ng xy ra.

Dng 3: Nhn bit Tch cht

Bi 5: Bng phng php ha hc hy nhn bit cc l mt nhn:
a. benzen, hex 1 en, hex 1 in
b. benzen, ancol etylic, dung dch phenol, dung dch CH3COOH.
c. axetilen, but-2-in, butan, kh sufuro
d. phenol (lng), ancol etylic, andehit axetic, axit axetic v glixerol
Bi 6: Tch ri tng cht sau ra khi hn hp:
a. metan, etilen, axetylen
b. Benzen khi hn hp vi toluen v stiren
c. phenol, etanol, benzen
Bi 7. Nhn bit cc cht sau bng phng php ha hc:
a. Andehit axetic, axit axetic, glixerol v etanol.
b. Axit fomic, andehit axetic, axit axetic, ancol etylic
c. Propan-1-ol, propan-1,2-iol, andehit axetic, axit axetic.
CHUYN : ANDEHIT AXIT CACBOXYLIC - ESTE
A- ANDEHIT
CC DNG BI THNG GP
Dng 1: L thuyt tng hp.
Dng 2: Bi ton t chy.
Dng 3: Bi ton oxh ancol v bi ton trng bc.
Dng 4: Andehit tc dng vi H2.
Dng 5: Bi ton hn hp
CC CU HI THEO CC CP NHN THC
1. Cp nhn bit
Cu 1. ng vi cng thc phn t C4H8O c bao nhiu ng phn anehit ?
A. 1
B. 2
C. 3
D. 4
Cu 2. Andehit axetic c kh nng phn ng vi tt c cht trong dy no sau y?
A. H2 (xt, t0C); Na2CO3, dd AgNO3/NH3 (t0C)
B. H2 (xt, t0C); dd AgNO3/NH3 (t0C)
C. H2 (xt, t0C); dd NaOH; dd AgNO3/NH3 (t0C)
D. H2 (xt, t0C); dd NaBr; dd AgNO3/NH3 (t0C)
Cu 3. Phng php hin i sn xut axetanehit l
A. Cng H2O vo C2H2
B. Oxi ho etanol
C. Oxi ho etilen
D. Cng H2O vo etilen
Cu 4. Sc hn hp etin v metanal vo dung dch AgNO3/NH3 un nng, to ra kt ta l
A. C2H2Ag2 v Ag
B. C2H2Ag v Ag
C. C2Ag2 v Ag
D. C2HAg v Ag
Cu 5: Fomalin hay fomon c dng ngm xc ng vt, thuc da, ty u, dit trng, Fomalin l
A. dung dch rt long ca anehit fomic.
B. dung dch axetanehit khong 40%.
C. dung dch 37 40% fomanehit trong nc.
D. dung dch fomandehit trong cn.
Cu 6: Pht biu no sau y l khng ng?
A. Trong phn t anehit, cc nguyn t ch lin kt vi nhau bng lin kt .
B. Hp cht RCHO c th iu ch c t RCH2OH.
C. Hp cht hu c c nhm CHO lin kt vi H l anehit.
D. Anehit c c tnh kh v tnh oxi ha.
Cu 7: Th t gim dn nhit si ca cc cht CH3CHO, C2H5OH, H2O l
A. H2O, CH3CHO, C2H5OH.
B. H2O, C2H5OH, CH3CHO.
C. CH3CHO, H2O, C2H5OH.
D. CH3CHO, C2H5OH, H2O.

Cu 8: Axetandehit c cng thc cu to thu gn l

A. CH3CH2CHO
B. HCHO
C. CH3CHO
D. CH2=CHCHO
Cu 9: un nng m gam andehit axetic vi lng d AgNO3 trong dung dch NH3 th khi lng Ag thu c
21,6 gam. Bit hiu sut phn ng t 100%, gi tr ca m l
A. 4,4 gam
B. 3 gam
C. 5,8 gam
D. 8,8 gam
Cu 10: Trong thc t trng gng hoc rut phch, ngi ta un nng dung dch cht hu c X vi lng
d AgNO3 trong dung dch NH3, cht hu c X l
A. Andehit fomic
B. Andehit axetic
C. Glucoz
D. Saccaroz
2. Cp hiu.
Cu 11: Dy gm cc cht u tc dng vi AgNO3 trong dung dch NH3, l:
A. anehit axetic, butin-1, etilen.
B. anehit axetic, axetilen, butin-2.
C. axit fomic, vinylaxetilen, propin.
D. anehit fomic, axetilen, etilen.
Cu 12. Dy gm cc cht u iu ch trc tip (bng mt phn ng) to ra anehit axetic l:
A. C2H5OH, C2H4, C2H2. B. HCOOC2H3, C2H2, CH3COOH.
C. C2H5OH, C2H2, CH3COOC2H5.
D. COOH, C2H2, C2H4.
Cu 13: C th dng mt cht no trong cc cht di y nhn bit c cc cht: ancol etylic, glixerol,
anehit axetic ng trong ba l mt nhn?
A. Cu(OH)2/OH-.
B. Qu tm.
C. Kim loi Na.
D. dd AgNO3/NH3.
Cu 14: Cho cc cht sau: CH3CH2CHO (1), CH2=CHCHO (2), (CH3)2CHCHO (3), CH2=CHCH2OH (4).
Nhng cht phn ng hon ton vi lng d H2 (Ni, t) cng to ra mt sn phm l
A. 2, 3, 4.
B. 1, 2, 4.
C. 1, 2, 3.
D. 1, 3, 4.
Cu 15. t chy mt hn hp cc ng ng ca anehit ta thu c s mol CO2 = s mol H2O. Cc cht
thuc dy ng ng no trong cc dy sau?
A. Anehit khng no n chc
B. Anehit hai chc no
C. Anehit n chc no
D. Anehit vng no
Cu 16: Xt cc loi hp cht hu c mch h sau: Ancol n chc no (X); anehit n chc no (Y); ancol
n chc khng no c 1 ni i (Z); anehit n chc, khng no c 1 ni i (T). ng vi cng thc tng qut
CnH2nO ch c 2 cht, l nhng cht no?
A. X, Y
B. X, T
C. Y, Z
D. Z, T
Cu 17: Cho 2,9 gam mt anehit X phn ng hon ton vi lng d AgNO3 trong dung dch NH3 thu c
21,6 gam Ag. Cng thc cu to thu gn ca X l
A. HCHO.
B. CH2=CHCHO.
C. O=CHCHO.
D. CH3CHO.
Cu 18: Dy cc ancol no sau y khi tc dng c vi CuO nung nng thu c sn phm c phn ng
trng bc:
A. etylic, isobutylic, benzylic, etilen glicol.
B. metylic, tert-butylic, benzylic, etilen glicol.
C. butan-2,3-iol, tert-butylic, benzylic, propenol.
D. etylic, isopropylic, benzylic, etilen glicol.
Cu 19. S ng phn anehit (c vng benzen) c cng thc phn t C8H8O l :
A. 3
B. 4
C. 1
D. 2
Cu 20: Dy gm cc cht c xp theo chiu nhit si tng dn t tri sang phi l:
A. C2H6, CH3CHO, C2H5OH, CH3COOH.
B. C2H6, C2H5OH, CH3CHO, CH3COOH.
C. CH3COOH, C2H6, CH3CHO, C2H5OH.
D. CH3CHO, C2H5OH, C2H6, CH3COOH.
3. Cp vn dng thp.
Cu 21: S ng phn mch h ng vi cng thc C3H6O l :
A. 2
B. 4
C. 1.
D. 3.
Cu 22: Anehit X mch h c cng thc phn t l C5H8O. Hiro ha X thu c ancol 3-metylbutan-1-ol.
Hy cho bit X c bao nhiu cng thc cu to?
A. 3
B. 2
C. 5
D. 4
Cu 23: Cho 6,6 gam mt anehit X n chc, mch h phn ng vi lng d AgNO3 trong dung dch NH3,
un nng. Lng Ag sinh ra cho phn ng ht vi axit HNO3 long, thot ra 2,24 lt kh NO (sn phm kh duy
nht, o ktc). Cng thc cu to thu gn ca X l:

A. CH2 = CHCHO
B. CH3CH2CHO
C. HCHO
D. CH3CHO
Cu 24: Chia m (g) mt anehit thnh hai phn bng nhau. Phn 1 : t chy hon ton thu c 3,36 lit CO2
v 2,7 g H2O. Phn 2 : cho tc dng vi AgNO3 / NH3 d thu c Ag c t l mol nX : nAg = 1 : 4. Anehit X l :
A. Anehit fomic
B. Anehit no, hai chc
C. Anehit no, n chc D. khng xc nh c
Cu 25: Oxi ha 15 gam anehit n chc thu c 21,4 gam mt hn hp X gm axit v anehit d. Hy cho
bit nu cho hn hp X tc dng vi lng d AgNO3 trong dung dch NH3, un nng thu c bao nhiu gam
Ag?
A. 129,6 gam
B. 21,6 gam
C. 64,8 gam
D. 43,2 gam
Cu 26: A l hn hp gm anehit fomic v mt axit no n chc c trn theo t l mol 1:2 . trung ha
A cn va 200 ml dung dch NaOH 1M, A tc dng vi lng d AgNO3/NH3 d, phn ng hon ton thu
c 86,4 gam bc kt ta. Khi lng hn hp A l
A. 1,2 gam
B. 12,2 gam
C. 1 gam
D. 15,2 gam
Cu 27: Cho a gam anehit X tc dng ht vi AgNO3 d trong dung dch NH3, thu c 43,2 gam Ag. Hiro
ha hon ton a gam X thu c ancol Y. Y tc dng vi Na thu c 1,12 lt H2 (ktc). Vy X l:
A. HCHO
B. OCH-CHO
C. C2H3CHO
D. CH3-CH(CHO)2
Cu 28: t chy hon ton a mol mt anehit X mch h to ra b mol CO2 v c mol H2O (bit b = a + c).
Trong phn ng trng bc, mt phn t X ch cho 2 electron. X thuc dy ng ng anehit
A. no, n chc.
B. khng no c hai ni i, n chc.
C. khng no c mt ni i, n chc.
D. no, hai chc.
Cu 29 : X, Y, Z l cc hp cht mch h, bn c cng cng thc phn t C 3H6O. X tc dng c vi Na v
khng c phn ng trng bc. Y khng tc dng c vi Na nhng c phn ng trng bc. Z khng tc dng
c vi Na v khng c phn ng trng bc. Cc cht X, Y, Z ln lt l:
A. CH3-CO- CH3, CH3- CH2-CHO, CH2=CH- CH2-OH.
B. CH3- CH2-CHO, CH3-CO- CH3, CH2=CH- CH2-OH.
C. CH2=CH- CH2-OH, CH3-CO- CH3, CH3- CH2-CHO.
D. CH2=CH- CH2-OH, CH3- CH2-CHO, CH3-CO- CH3.
Cu 30: Hn hp X gm cc anehit ( oxalic, acrylic, axetic, benzoic). t hon ton m gam hn hp X thu
c 39,6 gam CO2 v 9,9 gam H2O. Mt khc un nng cng m gam X vi lng d AgNO3/NH3 th thu c
86,4 gam Ag. Tnh m
A. 16,5 gam
B. 18,3 gam
C. 13,8 gam
D. 17,3 gam
4. Cp vn dng cao.
Cu 31: t chy hon ton m gam hn hp X gm hai anehit no, n chc, mch h thu c 0,4 mol CO2.
Mt khc hiro ho hon ton m gam X cn va 0,2 mol H2 (Ni, to), sau phn ng thu c hn hp hai
ancol. t chy hon ton hn hp hai ancol ny th s mol H2O thu c l bao nhiu?
A. 0,3 mol.
B. 0,4 mol.
C. 0,6 mol.
D. 0,8 mol.
Cu 32: t 0,6 mol hn hp hi A gm axit acrylic, axit propionic v propan-1,2-iol, propanial (t khi hi
ca hn hpA so vi oxi bng 2,3125). Dn ton b sn phm chy vo bnh ng dung dch Ca(OH)2 d, sau
p thy bnh tng m gam. Gi tr m l
A. 146g.
B. 116g.
C. 93g.
D. 111,6g.
Cu 33: t chy ht m gam hn hp X gm hai anehit n chc, mch h (c mt lin kt i C = C trong
phn t) thu c Vlt kh CO2 ktc v a gam H2O. Biu thc lin h gia m; a v V l
5V 9a
5V 7a
4V 9a
4V 7a

A. m = 4
B. m = 4
C. m = 5
D. m = 5
7
9
7
9
Cu 34: Ancol X, andehit Y, axit cacboxylic Z c cng s nguyn t H trong phn t thuc cc dy ng ng
no, n chc mch h. t hon ton hn hp 3 cht ny ( c s mol bng nhau) thu c t l mol CO2 : H2O
= 11: 12. Cng thc phn t ca X, Y, Z l:
A. C4H10O, C5H10O, C5H10O2.
B. C3H8O, C4H8O, C4H8O2.
C. C2H6O, C3H6O, C3H6O2.
D. CH4O, C2H4O, C2H4O2.
Cu 35: Hn hp X gm mt anehit, mt axit cacboxylic v mt este (trong axit v este l ng phn ca
nhau). t chy hon ton 0,2 mol X cn 0,625 mol O2, thu c 0,525 mol CO2 v 0,525 mol H2O. Nu em

ton b lng anehit trong X cho phn ng hon ton vi lng d dung dch AgNO3/NH3 th thu c m
gam Ag kt ta. Gi tr ca m l.
A. 64,8 gam.
B. 16,2 gam.
C. 32,4 gam.
D. 21,6 gam.
Cu 36: Cho m gam mt ancol no X qua bnh ng CuO (d), nung nng. Sau khi phn ng hon ton thu
c hn hp Y (gm kh v hi) c t khi i vi hiro l 18. Khi cho 3 mol hn hp Y tc dng hon ton
vi lng d AgNO3 trong dung dch NH3 thu c 2 mol Ag. Cng thc cu to thu gn ca ancol X l:
A. CH2(OH)CH2CH2OH. B. C2H5OH.
C. CH3CH(OH)CH2OH. D. HOCH2CH2OH.
Cu 37: Hn hp X gm hiro, propen, propanal, ancol anlylic. t 1 mol hn hp X thu c 40,32 lt CO2
dY
(ktc). un X vi bt Ni mt thi gian thu c hn hp Y c X = 1,25. Nu ly 0,1 mol hn hp Y th tc
dng va vi V lt dung dch Br2 0,2M. Gi tr ca V l:
A. 0,1 lt
B. 0,2 lt
C. 0,3 lt
D. 0,25 lt
Cu 38: hiro ho hon ton 0,035 mol hn hp X gm hai anehit c khi lng 2,2 gam cn 1,568 lt
H2 (ktc). Mt khc, khi cho cng lng X trn phn ng vi mt lng d dung dch AgNO3 trong NH3 th
thu c 10,8 gam Ag. Cng thc cu to ca hai anehit trong X l
A. CH2=C(CH3)-CHO v OHC-CHO.
B. OHC-CH2-CHO v OHC-CHO.
CH
=CH-CHO
v
OHC-CH
-CHO.
C.
D. H-CHO v OHC-CH2-CHO.
2
2
Cu 39: un nng a mol hi anehit X vi 3a mol kh H2 (xc tc Ni) mt thi gian thu c mt hn hp kh
v hi 3a mol Y. Hn hp Y lm mt mu va a mol Br2 trong nc. Mt khc a mol X tc dng hon ton
vi dung dch AgNO3 trong NH3 thu c 2a mol Ag. X l anehit.
A. no, hai chc.
B. no, n chc.
C. khng no (cha mt ni i C=C), n chc.
D. khng no (cha mt ni i C=C), hai chc.
Cu 40: Hiro ho hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong
dy ng ng thu c (m + 1) gam hh hai ancol. Mt khc, khi t chy hon ton cng m gam X th cn
va 17,92 lt kh O2 ( ktc). Gi tr ca m l
A. 10,5.
B. 17,8.
C. 24,8.
D. 8,8.
B AXIT CACBOXYLIC
CC DNG BI THNG GP
Dng 1: L thuyt tng hp.
Dng 2: Bi ton t chy.
Dng 3: Bi ton axit tc dng vi kim loi, baz, mui.
Dng 4: Bi ton este ha.
Dng 5: Bi ton hn hp.
CC CU HI THEO CC CP NHN THC.
1. Cp nhn bit.
Cu 1: Axit axetic c cng thc cu to thu gn l
A. HCOOH
B. CH3COOH
C. CH3CH2COOH
D. C6H5COOH
Cu 2: Dy gm cc cht c sp xp theo chiu tng dn nhit si t tri sang phi l
A. CH3COOH, HCOOH, CH3CHO, C2H5OH.
B. HCOOH, CH3COOH, C2H5OH, CH3CHO.
C. CH3CHO, C2H5OH, HCOOH, CH3COOH.
D. CH3COOH, C2H5OH, HCOOH, CH3CHO.
Cu 3: Cht khng phn ng vi axit axetic (CH3COOH) l
A. Na.
B. KOH.
C. CH3OH.
D. KCl.
Cu 4: Cng thc chung no khng phi ca axit caboxylic
A. CnH2n+2-2k-a(COOH)a
B. R(COOH)a
C. CxHy(COOH)a
D. CnH2n+1-a (COOH)a
Cu 5: Axit acrylic c th tc dng vi tt c cc cht trong dy no sau y?

A. Na, Cu, Br2, dd NH3, dd NaHCO3, CH3OH (H2SO4 c)

B. Mg, H2, Br2, dd NH3, dd NaHCO3, CH3OH (H2SO4 c)
C. Ca, H2, Cl2, dd NH3, dd NaCl, CH3OH (H2SO4 c)
D. Ba, H2, Br2, dd NH3, dd NaHSO4, CH3OH (H2SO4 c)
Cu 6: un nng axit axetic vi ancol etylic xc tc H2SO4 c th thu c sn phm l
A. andehit axetic
B. etyl axetat
C. etyl fomat
D. axetilen
Cu 7: trung ha 0,15 mol axit axetic trong dung dch th cn dung dch cha a mol NaOH, gi tr ca a l
A. 0,3
B. 0,2
C. 0,15
D. 0,075
Cu 8: Hin nay trong cng nghip, ngi ta iu ch axit axetic bng cch
A. ln men t ru etylic
B. oxi ha anehit axetic
C. cho methanol tc dng vi CO c xc tc, nhit ph hp
D. thy phn etyl axetat trong mi trng axit
Cu 9: Cho cc dung dch sau: etanol (1); andehit axetic (2); axit axetic (3); phenol (4); axit fomic (5). Dung
dch lm qu tm ha l
A. (1); (2); (3)
B. (2); (3); (5)
C. (3); (5)
D. (3); (4); (5)
Cu 10: Axit stearic l axit bo c trong cht bo c s dng sn xut x phng, cng thc phn t ca
axit stearic l
A. C2H5COOH
B. C17H33COOH
C. C17H31COOH
D. C17H35COOH
2. Cp hiu
Cu 11: Cht X c cng thc phn t l C 5H10O2. Bit X tc dng vi Na v NaHCO 3. C bao nhiu cng thc
cu to tho mn?
A. 4
B. 3
C. 6
D. 5
Cu 12: Cho m gam hn hp X gm ancol propylic v axit axetic tc dng vi Na d thu c 2,24 lt H 2
(ktc). Gi tr m l:
A. 9 gam.
B. 15 gam.
C. 12 gam.
D. 6 gam.
Cu 13: Cho s iu ch kh Y trong phng th nghim nh sau:

Cp cht X v Y tng ng l
A.
Na2SO3 v SO2.
B. HCOOH v CO.
C.
NaCl v HCl.
D. NaNO3 v HNO3.
Cu 14: Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l:
A. CH3CHO, C2H5OH, C2H5COOCH3.
B. CH3CHO, C6H12O6 (glucoz), CH3OH.
C. C2H4(OH)2, CH3OH, CH3CHO.
D. CH3OH, C2H5OH, CH3CHO.
Cu 15: A l axit cacboxylic mch h, cha no (1 ni i C=C), cng thc CxHyOz. Ch ra mi lin h ng
A. y = 2x-z.
B. y = 2x + 2-z.
C. y = 2x.
D. y = 2x + z-2.
Cu 16: Cho cc cht : HCHO, CH3CHO, HCOOH, C2H2. S cht c phn ng trng bc l
A. 1.
B. 3.
C. 2.
D. 4.
Cu 17: Axit cacboxylic X c cha vng benzen v c cng thc phn t l C8H8O2. S ng phn cu to ca
X l:
A. 3
B. 5
C. 2
D. 4
11a
240
Cu 18: Cho Na d tc dng vi a gam dung dch CH3COOH. Kt thc phn ng, thy khi lng H2 sinh ra l
.
Vy nng C% dung dch axit l
A. 36%
B. 10%
C. 4.58%
D. 25%

Cu 19: Cho 23 gam C2H5OH tc dng vi 24 gam CH3COOH (xt: H2SO4 c) vi hiu sut phn ng 60%.
Khi lng este thu c l
A. 21,12 gam
B. 26,4 gam
C. 22 gam
D. 23,76 gam
Cu 20: Mt s axit cacboxylic nh axit oxalic, axit tactric gy ra v chua cho qu su xanh. Trong qu trnh
lm mn su ngm ng, ngi ta s dng dung dch no sau y lm gim v chua ca qu su?
A. Phn chua.
B. Mui n.
C. Nc vi trong.
D. Gim n.
3. Cp vn dng thp
Cu 21: t chy hon ton x mol axit cacboxylic E, thu c y mol CO 2 v z mol H2O (vi z=yx). Cho x
mol E tc dng vi NaHCO3 (d) thu c y mol CO2. Tn ca E l:
A. axit acrylic.
B. axit oxalic.
C. axit aipic.
D. axit fomic
Cu 22: Mt hn hp M gm 0,06 mol axit cacboxylic X v 0,04 mol ancol no a chc Y. t chy hon ton
hn hp M trn thu c 3,136 lt CO2. % khi lng ca Y trong hn hp M l
A. 52,67%.
B. 66,91%.
C. 33,09%.
D. 47,33%.
Cu 23: Cho 2,16 gam axit cacboxylic n chc X tc dng hon ton vi dung dch cha 0,02 mol KOH v
0,03 mol NaOH. C cn dung dch thu c sau khi phn ng kt thc cn li 3,94 gam cht rn khan. Cng
thc ca X l
A. CH3-CH2-COOH.
B. CH2=CH-COOH.
C. CHC-COOH.
D. CH3-COOH.
Cu 24: Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C2H4O2 ln lt tc dng
vi: Na, NaOH, NaHCO3. S phn ng xy ra l
A. 2.
B. 5.
C. 4.
D. 3.
Cu 25. t chy hon ton a mol axit cacboxylic X mch h thu c b mol CO2 v c mol H2O trong a + c
= b. X tc dng vi Na2CO3 thu c s mol CO2 ng bng s mol X phn ng. Vy X thuc dy ng
ng no sau y?
A. 2 chc v c 1 lin kt C=C
B. n chc no
C. n chc v c 1 lin kt C=C
D. 2 chc, no
Cu 26: Cho 28,8 gam hn hp X gm ancol etylic v axit axetic tc dng vi Na d thu c 6,16 lt H 2
(ktc). Khi un nng 28,8 gam hn hp X c H 2SO4 c (xc tc) thu c 17,6 gam este. Tnh % v khi
lng mi cht trong X v hiu sut ca phn ng este ha?
A. 47,92% C2H5OH; 52,08% CH3COOH v hiu sut 75%
B. 47,92% C2H5OH; 52,08% CH3COOH v hiu sut 80%
C. 45,0% C2H5OH; 55,0% CH3COOH v hiu sut 60%
D. 52,08% C2H5OH; 47,92% CH3COOH v hiu sut 70%
Cu 28. t chy hon ton 1,760 gam mt axit hu c X mnh thng c 1,792 lt kh CO2 (ktc) v 1,440
gam H2O. Cng thc cu to ca X l.
A. CH3CH2CH2COOH.
B. HOOCCH2COOH.
C. C2H5COOH
D. CH3CH=CHCOOH.
Cu 29. trung ha m gam dung dch 6% ca mt axit n chc cn m gam dung dch NaOH cha r nng
thu c dung dch trong nng % ca mui l 4,1%. Cng thc ca axit v nng % ca NaOH
tng ng l:
A. CH3-COOH v 4%
B. CH3-COOH v 3,6%
C. H-COOH v 8%
D. C2H3-COOH v 3,2%
Cu 30: t chy hon ton x gam hn hp gm hai axit cacboxylic hai chc, mch h v u c mt lin kt
i C=C trong phn t, thu c V lt kh CO 2 (ktc) v y mol H2O. Biu thc lin h gia cc gi tr x, y v V
l
28
( x 30 y )
55

28
( x 62 y )
95

28
( x 30 y )
55

28
( x 62 y )
95

A. V =
.
B. V =
C. V =
. D. V =
.
4. Cp vn dng cao.
Cu 31: trung ho m gam hn hp X gm CH 3COOH, CH2(COOH)2, CH(COOH)3, C(COOH)4 cn 540ml
dung dch NaOH 2M. t chy hon ton m gam hn hp X cn 17,92 lt O2 (ktc). Gi tr ca m l
A. 54,68.
B. 52,16.
C. 53,92.
D. 51,88.

Cu 32. Hn hp X gm axit no n chc X1 v ancol no n chc X2 c cng s nguyn t H trong phn t.

t chy hon ton 0,1 mol hn hp X thu c 0,16 mol CO2 v 0,2 mol H2O. un nng 0,2 mol hn hp X
thu c 4,44 gam este. Xc nh hiu sut phn ng este ha.
A. 25%
B. 65%
C. 40%
D. 75%
Cu 33. Hn hp X gm axit axetic, axit fomic v axit oxalic. Khi cho m gam X tc dng vi NaHCO3 (d) th
thu c 15,68 lt kh CO2 (ktc). Mt khc, t chy hon ton m gam X cn 8,96 lt kh O2 (ktc), thu c
35,2 gam CO2 v y mol H2O. Gi tr ca y l A. 0,2. B. 0,8.
C. 0,6. D. 0,3.
Cu 34. Cho 27,3 gam hn hp A gm 3 axit cacboxylic ch cha chc cacboxyl tc dng vi lng d dung
dch NaHCO3 th thu c 10,08 lt CO2. Mt khc t chy hon ton 27,3 gam hn hp A thy cn 19,6 lt O2
th thu c m gam kh CO2. Bit cc kh u o iu kin tiu chun, cc phn ng xy ra hon ton. Gi tr
ca m l
A. 33,0 gam
B. 41,8 gam
C. 13,5 gam
D. 17,1 gam
Cu 35. Hn hp X gm 2 axit cacboxylic no, mch h. t chy hon ton a mol hn hp X thu c a mol
H2O. Mt khc, cho a mol hn hp X tc dng vi NaHCO3 thu c 1,4a mol CO2. Vy % khi lng ca
axit c phn t khi nh hn trong hn hp X l:
A. 26,4%
B. 35,8%
C. 43,4%
D. 27,3%
Cu 36. Oxi ho a gam ancol metylic bi oxi nung nng thu c hn hp kh v hi X. Chia X thnh 3 phn
bng nhau:
- Phn 1: Cho tc dng vi dung dch AgNO3/NH3 d thu c 64,8 gam Ag
- Phn 2: Cho tc dng vi dung dch NaHCO3 d sau phn ng thu c 2,24 lt kh CO2 ktc
- Phn 3: Cho tc dng vi Na d thu c 4,48 lt kh H2 ktc. Hiu sut phn ng oxi ho CH3OH l:
A. 66,67%
B. 75%
C. 100%
D. 50%
Cu 37. Cho 4,0 mol axit axetic tc dng vi 1,0 mol glixerol (xt H2SO4 c). Tnh khi lng sn phm este
thu c, bit rng c 50% axit v 80% ancol phn ng. A. 156,7 gam
B. 176,5 gam C. 165,7 gam
D. 157,6 gam
Cu 38: Hn hp X gm mt anehit, mt axit cacboxylic v mt este (trong axit v este l ng phn ca
nhau). t chy hon ton 0,2 mol X cn 0,625 mol O 2, thu c 0,525 mol CO2 v 0,525 mol H2O. Nu em
ton b lng anehit trong X cho phn ng hon ton vi lng d dung dch AgNO 3/NH3 th thu c m
gam Ag kt ta. Gi tr ca m l
A. 64,8 gam.
B. 21,6 gam.
C. 16,2 gam.
D. 32,4 gam.
Cu 39: Cho X, Y l hai cht thuc dy ng ng ca axit acrylic v M X < MY; Z l ancol c cng s nguyn
t cacbon vi X; T l este hai chc to bi X, Y v Z. t chy hon ton 11,16 gam hn hp E gm X, Y, Z, T
cn va 13,216 lt kh O2 (ktc), thu c kh CO2 v 9,36 gam nc. Mt khc 11,16 gam E tc dng ti a
vi dung dch cha 0,04 mol Br2. Khi lng mui thu c khi cho cng lng E trn tc dng ht vi dung
dch KOH d l:
A. 4,68 gam
B . 5,44 gam
C. 5,04 gam
D. 5,80 gam
Cu 40: Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon). Chia X
thnh hai phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H2 ( ktc). t chy hon
ton phn hai, sinh ra 26,4 gam CO2. Cng thc cu to thu gn v phn trm v khi lng ca Z trong hn
hp X ln lt lA. HOOC-COOH v 42,86%.
B. HOOC-CH2- COOH v 58,42%.
C. HOOC-CH2- COOH v 70,87%.
D. HOOC-COOH v 60,00%.