C H 44 + H220

+ CO22

3 H22

-74850
-241830
-110520
0

186190
188720
197910
130590

-50790
-228600
-137270
130390

COMPONENTES
CH4
H2O
CO2
H2

Hallando

(298)

H (298) = H (co) + 3H (H2) - (H (CH4) + H

(H20))
H (298) =

Hallando

206160 J/mol

(298)

S (298) = S (co) + 3S (H2) - (S (CH4) + S

(H20))
S (298) =

Hallando

214770

(298)

G = H - T S (298)

G =

-63795300

HALLANDO DELTA CP
CP = CP (co) + 3CP (H2) - (CP(CH4) +
CP(H20))
CP
CO
H2
H20
CH4

29.556 -0.0065807
76.197
0.060534
33.933
-0.08418
34.942
-0.039967

CP=

36.878

0.1781003

0.00002013
-0.0115647
0.000029906
0.00019184

-0.011766316

36.878 + 0.102338 T - 0.01177 T ^2

CP=

HALLANDO DELTA H (t)

H (t) = H (298) +1_298^

10989.644 7908.00952 103792.995

36.878 0.08905015 -0.00392211
291055.342

36.878

0.08905015 -0.00392211

H (t) = 291055.3+36.878 T +0.08905 T^2 - 0.00392211

T^3

HALLANDO DELTA S (t)

s (t) = s (298) +1_298^
/
-210.097413595 -53.0738894 522.447963
36.878 0.1781003 -0.00588316
215029.27666

36.878

0.1781003

-0.005883158

S (t) 474.0467+ 36.878 LN T + 0.1781 T -0.0058831 6T

^2

HALLANDO DELTA G (t)

G = H - T S
291055.3418018 -214992.399 -0.08905015

0.0019610527

-36.878

291055.3-437.16866 T - 0.08905 T ^2 + 0.001961053 T^3 - 36.878 Ln

T

GRAFICOS

Cp

36.878 + 0.102338 T - 0.01177 T ^2

CP

100
200
300
400
500
600
700
800
900
1000

-62.97513
-398.15458
-968.66035
-1774.49244
-2815.65085
-4092.13558
-5603.94663
-7351.084
-9333.54769
-11551.3377

CP
0
-2000

200

400

600

800

-4000
-6000
-8000
-10000
-12000
-14000

H
H (t) = 291055.3+36.878 T +0.08905 T^2 - 0.00392211
T^3
T

H
100 291711.538

1000000
500000
0
-500000 0
-1000000
-1500000

H
200

400

600

200
300
400
500
600
700
800
900
1000

1000000
500000
0
-500000 0
-1000000
-1500000
-2000000
-2500000
-3000000
-3500000
-4000000

270616.105
204236.411
69039.8245
-158506.287
-501934.556
-984777.614
-1630568.09
-2462838.62
-3505121.84

H
200

400

600

TEMPERATURA

HALLANDO DELTA S
S (t) 474.0467+ 36.878 LN T + 0.1781 T -0.0058831 6T
^2
T
S
100
215158.085
200
215024.962
216000
300
214763.567
400
214380.165
214000
500
213876.72
212000
600
213254.106
700
212512.79
210000
800
211653.051
208000
900
210675.068
206000
1000
209578.963
0

200

400

600

800

1000

HALLANDO DELTA G
291055.3-437.16866 T - 0.08905 T ^2 + 0.001961053 T^3 - 36.878 Ln
T
T
100
200
300
400

G
-21207284
-42695493
-64161941
-85594866

Energia de Gibb
0
200
-200000
-400000
Energa de Gibbs

-600000

300

400

500

Energia de Gibb
500
600
700
800
900
1000

-106982504
-128313090
-149574859
-170756043
-191844878
-212829596

0
200
-200000

300

400

500

-400000
Energa de Gibbs

-600000
-800000
-1000000
-1200000

T
298
300
350
400
450
500
550
600
700
800
900
1000

Ln Kp
-57.4055871
-58.4397975
-82.0209164
-102.653759
-121.724068
-140.061502
-158.192889
-176.468692
-214.352434
-254.94584
-298.930974
-346.715284

0
200
-50
-100
-150
Axis Title

-200
-250
-300
-350
-400

GRAFICOS DEL AMONIACO

T
298
320
350
400
450

G
93153.7686878
96723.9493573
98834.94966
94473.0293428
78977.1941003

300

400

500

600

700

500
550
600
650
700

50873.0943614
8691.78085077
-49031.777848
-123759.68005
-216951.77089
150000
100000
50000
0
250
G

300

350

-50000
-100000
-150000
-200000
-250000

SINTESIS DEL AMONIACO

1800000
1600000
1400000

H
298 -92291.787
320 -69297.17
350 -32160.98
400 46131.87
450 147439.22
500 274663.57
550 430707.42
600 618473.27
650 840863.62
773 1553662.8

400

450

500

550

600

650

700

750

1800000
1600000
1400000
1200000
1000000
H

800000

Polynomi

600000

Linear (H

400000
200000
0
200
-200000

300

400

500
Temperatura

T
298
320
350
400
450
500
550
600
650
700

2500

2000

1500

1000

500

S
-197.99851
-123.68475
-13.011228
195.2521
433.12006
700.46495
997.19571
1323.2451
1678.562
2063.1068

600

700

800

900

1500

1000

500

0
250

300

350

400

450

500

550

600

650

700

750

-500

(
)
T
298
320
350
400
450
500
550
600
650
700

(
)
13.462413
21.178833
31.089173
46.681655
61.796472
76.932887
92.407429
108.43033
125.1466
142.65942

160
140
120
100
K
p

80
60
40
20
0
250

300

350

400

450

500

550

600

650

700

750

40
20
0
250

300

350

400

450

500

550

600

650

700

750

CP
29.556-6.5807*10^3T+2.0130*10^5T^2
25.399+2.0178*10^-2T -3.8549*10^-3 T^2
33.933-8.418*10^3 T + 2.9906*10^-5 T^2
39.942-3.9967*10^-2 T + 1.9184*10^-4 T ^2

^3 - 36.878 Ln

CP

600

800

1000

1200
CP
Linear (CP)

H
200

400

600

800

1000

1200

H
200

400

600

800

1000

1200

H
Linear (H)

TEMPERATURA

S
S
Linear (S)

600

800

1000

1200

053 T^3 - 36.878 Ln

ergia de Gibbs

300

400

500

Temperatura K
600

700

800

900

ergia de Gibbs

300

400

500

400

600

500

700

Temperatura K
600

800

700

900

800

900

1000 1100

Ln Kp
Linear (Ln Kp)

650

700

750
G
Linear (G)

H
Polynomial (H)
Linear (H)

900

S
Polynomial (S)
Linear (S)

S
Polynomial (S)
Linear (S)

650

700

750

Column L
Linear (Column L)

650

700

750

650

700

750