K.S.K.

COLLEGE OF ENGINEERING & Technology

Department of chemistry
Engineering Chemistry- I, Important formula
1. Degree of Polymerization, Dp =M/m; M- Molecular weight of Polymer, m- Molecular
weight of monomer

2. Number averaged Molecular weight, Mn= niMi/ ni Mi- molecular mass of

monomer, ni- number of monomer molecules
3. Weight averaged Molecular weight, Mn= niMi2/ ni Mi- molecular mass of
monomer, ni- number of monomer molecules
4. Entropy Change, S= Sfinal- Sinitial
5. Entropy of fusion, Sfusion=Hfusion/T
6. Entropy of vaporization, S vaporization=H vaporization/T
7. Isochoric condition, SV= 2.303CV log T2/T1
8. Isobaric condition, SP= 2.303CP log T2/T1
9. Helmholtz free energy, A= E-TS
10. Gibbs free energy, G= H-TS
( G)
11. Gibbs Helmholtz Equation, G= H+T
T

12. G=H-TS
13. dP/dT=Hv/T(Vv-VL), Vv, VL= molar volume of vapour and liquid respectively.
14. Clausius-Clapeyron Equation, log(P2/P1)= Hv/2.303R[(T2-T1)/T1T2]
15. One Einstein, E= NAh, NA= Avagadro Number, h= Planks constant.
16. Beer- Lamberts Law, A=Cx, A=Optical density, C=concentration, x=length of
absorbing medium, = Molar absorptivity coefficient
17. Transmittance, -logT=A
18. Quantum yield, = Number of molecules reacted in a given time/ Number of quanta
absorbed in the same time
19. Phase Rule, F=C-P+2, C-Component, P=phase
20. Reduced Phase Rule, F=C-P+1