My nn CO nn CO n p sut gii hn ca phn ng.

Sau khi tch loi hi m, CO

c phun vo l phn ng carbonyl ha.
nng cao hiu qu hp th, methanol sch c chia thnh 2 dng. Dng th nht
c a vo thp hp th cao p (HP absorber), dng th hai c a vo thp hp th
thp p (LP absorber). C hai dng u i ngc chiu vi dng CO a vo thp. Mt
phn nguyn liu methanol i ra theo offgas ca HP absorber gm CO cha phn ng,
methyl iodide, methyl acetate mt phn khc ra theo phn light gas ca LP absorber.
Phn lightgas ca LP absorber c x ra t cm chng ct p sut thp. Mc ch
chnh ca qu trnh hp th ny nhm ti a ha kh nng thu hi methyl acetate, methyl
iodide. Nu khng thc hin qu trnh ny, cc sn phm c gi tr s c x b, dn n
tiu tn ha cht cn thit cng nh lm gim nng sut qu trnh.
Dng methanol nguyn liu ra khi thp hp th c ha v phi trn vi dng lng
tun hon li v dng make-up methyl iodide t thp to methyl iodide. Dng sau khi
c phi trn s c np vo p ca riser ca l phn ng carbonyl ha.
Thp phn ng carbonyl ha s dng h thng bubble-column 3 pha bao gm 1 riser, 1
thit b tch, downcomer v reactor cooler. Phn ng xy ra 170-190 oC v 3-4,5 MPa.
Methanol, CO v dng lng tun hon li t thp chng s c np vo y ca riser
ca thp phn ng carbonyl ha. Kh CO sau khi c nn c phun vo thp nh b
phn phn phi dng. Tt c nhng nguyn liu ny cng nh xc tc s ha trn vi
nhau, chy qua downcomer sau i ln riser ti riser, phn ln CO v methanol
chuyn ha thnh acid acetic thng qua c ch carbonyl ha. ng lc ca dng lu
chuyn c c nh s chnh lch ca pha hi giu CO riser v pha hi ngho CO
downcomer. Qu trnh khuy trn tin hnh tc nhanh c pha lng v pha hi lm
cho CO nhanh chng c ha vo trong pha lng, ni xy ra qu trnh phn ng. Do ,
qu trnh ny khng phi qu trnh iu khin truyn khi.
CO cha phn ng v tt c nhng sn phm ph pha hi c x ra t nh ca thit
b tch a n HP absorber. Mt phn sn phm lng (acid acetic th) c ly ra v
a v thp chng ct tinh ch acid acetic. Phn hn hp xc tc-hn hp lng cn li
s c chuyn qua downcomer, sau c lm lnh bi reactor cooler ri dn v y
ca riser tip tc thc hin quy trnh. Trong quy trnh ny, xc tc c tun hon gn
nh 100%.
Sn phm sau qu trnh ny t tinh khit acid acetic trn 99,9%, hm lng acid
formic di 0.05%, aldehyde di 0.005%, acid propionic di 100 ppm