tHourExam SA September 30,2015 1, Please write your name below. Keep the exam closed until the start of the exam is, announced, 2. Read ail parts of each problem. MANY OF ‘THE LATTER PARTS OF A PROB! CAN BE SOLVED WITHOUT HAVING SOLVED FARLIER PARTS, However, if you need a numerical result that you were not successful in obtaining, make a physically reasonable approximation for that quantity (and indicate it as such) and use it to solve the latter parts, 3. A problem that requests you to “calculate” implies that several caleulation steps may be necessary for the problem's solution, You must show these steps clearly and indicate all values, including physical constants used to obtain your quantitative result. Significant figures must be correct. 4. If you don’t understand wiat the problem is requesting, raise your hand to for clarification. 5. Physical constants, formulas and a periodic table are given on the last page. You may detach this page once the exam has started. 1. Limiting Reagents / Reaction Yields page 2(18 points) 2. Light / 3. Photoelectric Effect page 3 (18 points) _ 4. One-Electron Atoms/ fons page 4 (14 points) 5, Multi-Electron Atoms/lons page 5 (20 points) 6.Short Answer page 6-7 (30 points) Total (100 points) (100 points) Name Answer Key1. Limiting reagents and reaction yields (a) ( points) Balance the skeletal reaction below. For each set of reaction conditions, — Teagent or state that neither reagent is limiting, © Baad 1 noo ~[2.noxad - L sow v (ii) What is sho eikiigy rage if you react 1.0 mol of NO: with 1.0 mo! of tt I \" vhs ND Ting me (iii) Whats the limiting reagent if you react 2/3 mol of NO» with 1/3 mol of 1:0? 73 ee ee \N0> 1S Vent tieg veg (6) 10 pointsy Rote He halanced reaction for the sy thesis af aspirin from salicylic acid \ Bo Low sce! oo * X HOS OA 0H Hof ° salicylic acid aspirin, @) (CoHa04, CHa nw: 13BY) (If 10g of salicylic acid and 2. produce 0.80 g of aspi Smw= 4A(D)ITT vod (i) Determine the molecular HO, +H 0, OD2. Properties of electromagnetic radiation (light). t Consider a green laser with an intensity of 1.67 Watts. For each question, check () all that apply. (a) (5 points) In comparision to the green laser, a purple laser MUST have: o—lower intensity light o_ higher-intensity-light g. lower frequency light (©) higher frequency light Justify your answer(s). 4 pus pe > highy every ) (b) (5 points) Light with the same intensity, but lower frequency musthave: © f.--> (© more photons emitted per second ” “S. less photons emitted per second @ redder light o bluer light Justity your answer{s). 8 owe foque 9 u 2. Photoelectric effect. ” lolio A metal surface is irradiated with light with an energy of 1.6.x 10+!¥| per photon, resulting in the ejection of electrons with a maximum KE OF 9.1 x 10] (a) (4 points) Determine the workfunction of the metal.ns (14 points) (a) Calculate the energy (in k] photon) and the wavelength (in nm) of the light adsorbed when a hydrogen atom electron transitions fram a 2s to.a Ss orbital (b) Would the transition of a hydrogen electron from a 2s toa Sp orbital require light with a longer wavelength, shorter wavelength or the same wavelength as calculated in part (a)? Briefly justify your answer, (©) Would the transition of a Li? electron from a 2s toa Ss orbital require light with a longer wavelength, shorter wavelength or the same wavelength as calculated in part (aJ? Briefly justify your answer. (€) The energy diagram below represents the transition from a Ss to a 2s arbital, resulting in visible light. On the same diagram, (i) draw and clearly label a transition resulting in the emission of higher frequency light in the visible region. (ii) Draw and clearly label a transition resulting in the | emission of higher frequency light that is NOT in the visible \ region of the spectrum. 4 Why5. Multi-electron atoms (@) G points) Which feels a stronger effective nuclear charge: a 2s electron in an F atom or a 2s electron in an F ion, Briefly explain. Eaton ave &@ higher Gave 2eG¢ (b) (4 points) If the core clectrons were totally effective at shielding the valence electrons, and the valence electrons provided no shielding of each other, what would the effective nuclear charge be for: or qwW ac 7 Vv (ia: | (ii) Br: 7 C14 alse accepted for cvedif > (©) (9 points) The actual Zer for the valence electrons of F, Cl, and Br ranges from 5.1 to 10.6. For each value, fill in the blanks with the type of valence electrons (2s, 4p, etc) and the appropriate element (either F, Cl, or Br), electrons and Zeff = 5.12 for the 4s electrons of _hc v electrons of Ci _¥ example: Z.y= 1 for the_1s__ electron of _H ‘Zen = 5.10 for the 4 Zen= 6.11 for the A> clectrons and Zeff. 07 for the c den 03 pr the 2» electrons and Zef DSS Jor the 25 electrons of_= Qeod Note typo ” T please hand back 419 yas exams fw points back 0a long as P . (d) (4 points) Calculate the ionization energy (in kJ/mol) for an electron with a Zeff mn of 5.10 from part (d).. colu ; and s in re ~BE othey g 2 Ry columh ce = Batts S . ¥ y ota ¢ 2i34l.is at s 2O6, Short answer: {a) (8 points) Provide the electron configuration expected for the following atoms. You may use the noble gas configuration as an abbreviation. PRI) ve atv “et (i) Ge (z= 32) Tretia of 2) tveatuets ee? o/ . Gi) Pb (b) (4 points) Consider a photoelectron spectroscopy (PES) experiment in which the incident x-rays have an energy greater than that of the 1s electrons of the elements being examined. What is the total number of spectral lines representing distict kinetic energies on PES spectrum for: aes {c} (6 points) Circle the atom or ion in each of the following pairs with the higher ionization energy. w@ Giu=14) or Ge[Z=32) \/ (ii)/ Ca)or Ca @=2) V (iii) B(Z=5) or (Be(Z=4) (@) G points) In general, clectron affinity increases with increased electronegativity. Although magnesium (Mg, Z = 12) is more electronegative than sodium (Na, Z = 11), sodium has a positive electron affinity, while magnesium has a negative electron. affinity. Briefly explain why. we Lhy cenve 40 edd bn electasats edo Gu foun bere lod 2s ER ot en tek cnuiler ertciny wm the eek Me hey 2 slecintat an ghee 2k ocbiel, end ds edd onner Ase 1p othnttl, tae 6(©) 2 points) Name one ion that is isoelectric with the chloride anion (Cl). (0 (4 points) Determine the number of electrons in a single atom that can have the following quantum numbers. my = +3 (i)n=6,1=2 () (3 points) For the radial probability distribution below, cross out any orbitals. that are not consistent with the nodal structure indicated: | ‘2h as a8 Bp Sp ap 2a 34 > J : RPD radius fede ote