TOLCIDE MBT Page 1 0f9 @Phodia Material Safety Data Sheet TOLCIDE MBT Date Prepared: 11/2006 ‘Supersedes Date: 12/10103 1, PRODUCT AND COMPANY IDENTIFICATION RHODIA ING. RHODIA NOVECARE eN7500 8 Ceoar Brook Drive Cranbury N085"2-7500 Emergency Phone Numbers: FOR EMERGENCIES INVOLVING A SPILL. LEAK FIRE, EXPOSURE OR ACCIDENT CONTACT: CHEMTREC (800-424-5200 wins tne Unites States or 703-627-8087 for international calle! cals) or Rhoda CAERS. {Communication and Emergency Response System) st 800.016.3232, For Product information: (8) 778-7337 EPA FIFRA Registration Number: CChomical Name or Synonym: THIOCYANIC ACID, METHYLENE ESTER; METHYLENE BIS(THIOCYANATE) Molecular Formula: CHAS, 2. HAZARDS IDENTIFICATION ‘A. EMERGENCY OVERVIEW: Physical Appearance and Odor: ‘hie to pee yellow crystaline sold, sharp tating odor. Warning Statements: DANGER! HIGHLY TOXIC IF INHALED. TOXIC IF SWALLOWED, CORROSIVE TO SKIN AND EYES. CAUSES SEVERE SKIN AND EVE BURNS, POSSIBLE SENSITIZER, Nay cause nervous syatem, Wer, Key respiratory Vacl and gastontesinel tract effects based on ermal dala, 1B, POTENTIAL HEALTH EFFECTS: Acute & ‘Wil cause comosive effects burns or ineversible damage) fo the eyes, Can cause redness, bums, tating ‘tp /ioimsd/ftes/0900102890001300010121500017.TM er22009‘TOLCIDE MBT. Page 2.0f9 ‘Acute Skin Gorrie. Severe tant. Harmful if absorbed through skin, Gan cauee redness, bums, sensitization ‘Acute inhalation: Extrema tovle Finheled. Causes coughing, shortness of breath, chest pai, signifeant respiratory tact irtaton Acute Ingestion: ‘Torte Fngestod. Can cause iitstion, nauses, vomiting, Chronie Etfects: {See Secion 11-Chronic for @ discussion of animal studies) 3. COMPOSITION/INFORMATION ON INGREDIENTS Component easRegttumter OSHA. x wr [METHYLENE BIS(THIOCYANATE) est7-1088 yo ~99 4, FIRST AID MEASURES FIRST AID MEASURES FOR ACCIDENTAL: Eye Exposure: Hol eyes open an fush with a stead, gone stream of water for atleast 15 minutes. Seek immediate ‘medical attention, Skin Exposure: Incase of contact, immediately wash with panty of soap and water for atleast 15 minutes. Seek medical atenion. Remove contaminated cothing and shoes while washing. lean contaminated eithing and shoes belore reuse or éscard i they cannot be thoroughly cleaned, Inhalation: Femove vicim fom immaciats source of exposure and assure thatthe victims breathing, If breathing is dificult, administer oxjgen, if avaiable, vim isnt breathing, acmnislet CPR (eardio-pumonary resusciaton). Seok Immeciate medial attention, Ingestion: NEVER attempt to induce vomiting. Consuit a doctr it necessary, Wash out mouth with water and keep atrst Seek immediate medica! atenton MEDICAL CONDITIONS POSSIBLY AGGRAVATED BY EXPOSURE: Skin, ver, kidney dlsease may be aggravates by exposure, NOTES TO PHYSICIAN: Al restments should be based on obsarved signs and symptoms of dtress in the patient. Consideration shouts be given to tha possaily hat overexposure to materia other han ti product may nave occured ‘Treat symplomaticaly, No specie antidote availabe hitp:riimsdsfiles/0004 :289000130001012100017. HTM e/12/2009‘TOLCIDE MBT 5. FIRE FIGHTING MEASURES. FIRE HAZARD DATA: Flash Point: Not Appicable Extinguishing Media Recommended: Gry crema, foam, water fog, carbon sSoxide, Use extinguishing method su fre efor surrounding Special Firo Fighting Procedures: Frefghters should wear NIOSHIMSHA approved secontained breathing appsatus and fl protective clothing Stay Upwend; Keap cut of ow areas, Personnel involved with handing Ps product should be thoroughly femiar swith its hazarés ane the proper methods fr fre ghing, {Unusual Fite and Explosion Hazards: Hazardous Decomposition Materials (Under Fire Conlon): oxides of nitrogen oxides of sur oxides of carbon Hazardous Decomposition Materials (Under Fire Conditions) ‘oxides of nv ‘ides of sulur Skides efearbon 6. ACCIDENTAL RELEASE MEASURES Evacuation Procedures and Safety: Personnel handling ths matoral shouldbe thoroughly waned to handle spils and releases. Wear appropiats protecive gear forthe sivation. See Peceonal Protection information i Section 6 Containment of Spi Follow procacire described below under Cleanup and Disposal of Spi. Dike area to prevent reno Collect and contain contaminated absoroent and ke metaral for eeposal, Cleanup and Disposal of Spil ‘Shovel up into an appropiate cosad container (see Secton 7: Hanlin and Storage). Avold creation of dusty Conditions, The material shouldbe properly packaged and lsposed ofn complanee with apoleable regulations, Environmental and Regulatory Reporting: Product may be harm to aquatic fein very ow concentrations. Do not fush to dain. Rut tom re control or luton water may cause pollen. Prevent material rom entorng puble sewer system or any waterways, Splls ‘may be reportable othe National Response Canter (800-424-8002) and lo sale andor oral agencies, 7. HANDLING AND STORAGE Minimumyaximum Storage Temperatures: 500 (122 F) Handling WARNING. Exercise care n handling and using his product Personnel handling his product should be thoraughy tamed as tos Nazards, Do nol breathe dusis, Avod director prolonged contac wih skin and eyes. Intpstrio/massiles/000010289000130001012100017.HTM 6112/2009TOLCIDE MBE age ao 9 READ LABEL CAREFULLY BEFORE USE, KEEP OUT OF REACH OF CHILDREN AND ANIMALS. Do not release dusts crecty to the atosohere. Storage: Store on area thats 9, dy, wel-ventated, coo, Keep out of direct sunlight Store away from; acid, bases alto aval: mls tee 8, EXPOSURE CONTROLS/PERSONAL PROTECTION Introductory Remarks: ‘These recommendations provide general quisance for handing thie product, Because specific work environments ans materal hancling pratees vary, safely proveduree should be developed far exch intended aoptcation. Whe developing sate hencling procedures, do nol overiode te need fo Sean equipment and piping systame for malstonanee and repairs. ase asuling "om tege procedures shou be hansled In accordance wah Section 43: Disposal Considerations. ‘Assistance wth selection, use and maintena equipment manufacturers ‘of worker protection equipments generaly availabe from Exposure Guidelines: Notexposure limits wore found for his proctor any of ts ingredients Engineering Controls: \Where engineoring cortots ae indicated by use conctons or a potential for excessive exposure exis, the folowing traditional exposure cont techniques may beused io effectively minimize employee exposures, Respiratory Protection Respirators are equled, Select NOSHMSHA approved equipment based on acual or potential alrbome ‘oncenivations and in accordance with he appropiate reguiatby standards andlor industrial recommendations, EyolFace Protection: Eye and face protecton requirements il vary dependent upon work environment cantons and material handing practoas. Aoproprats ANSI 287 approved equipment shoUls be Selected fr the paris use nlendec forthis materal ye contact shouldbe prevented through use of chemical safely glassas wit ade ele o splash proot goggles. An emergency eye wash ust be ready sccessibie he work area. Face contact shouls be prevented Through use of face shield Skin Protection: Skin contact shouldbe prevented through use of suitable preci clothing, gloves ans footwear, solactes with regard for use condions and exposure potontal. Consderation must be gven both to durabiy 28 wel as permeation resistance, Work Practice Controls: Personal yaiene isan important work precce exposure contol measute andthe following general measures should be taken when werking with or handling fis materia (1) Donot ster, use, andor consume foods, beverages, bacco produels, or cosmetic in reas where thie materials storea Arnking, using tobacco, applying cos (@) Wash exposed sin promptly to remove accenta splashes or contact with his material, Jnttprio/msds/files/0000102890001300010121500017.1TM 6112/2009‘TOLCIDE MBT 9, PHYSICAL AND CHEMICAL PROPERTIES. _Page Sof Physical and Chemical propotes here represent typical properties ofthis product Contac the business area tang the Prod! Infarmation phone number n Secon 1 fo ts exact spetiicaions Physical Appearance: ‘whe fo pale yelow syetaline soli, oo: Sharp eating odor. pl Bho 5 at 100 what, ‘Specific Gravity: Notavailade Density: ‘1048 giml at 20.6 (68). Water Solubility slightly soluble Motting Point Range: 408 to 108 C (221 0229 F) Bolling Point Range: NotAvaistle Vapor Pressure: Notavailabie Vapor Density: Net Avaiie ‘OctanotWater Partition Coefficient: 23 Molecular Weight 130.2 a 10. STABILITY AND REACTIVITY Chemical Stability: ‘Tris materiale stale under normal handling and storage conlions described in Section 7. Conditions To Be Avolded: feat IMaterals/Chemicale To Be Avoided: strong bases strong acs ‘ong axdlzing agents _nttpfrio/msdfiles/000010289000130001012100017.HTM 6122009TOLCIDE MBT Page 6 of 9 Decomposition Temperature Range: > 1100 (230 F) “The Following Hazardous Decomposition Products Might Be Expected: Decomposition Type: thermal oxces ot nitegen Sues of sul ‘oxides of earbon Hazardous Polymerization Wil Not Occur. Avoid The Following To Inhibit Hazardous Polymerization: ane known 14. TOXICOLOGICAL INFORMATION ‘Acute Eye eration: “Toxicological Information and Interpretation: oye eyeiritaion, rabbit Corosve, This material is expected to cause significant itation to the eyes. Acute Skin tnitation: “Toxicological information and Interpretation: skin - sensitization guinea pig. Senitzing ‘i -skn iflaion, belt. Corrosive, This materials expected to cause sigaeant iriaton tothe sn. ‘Acute Dermal Toxicity Toxicological information and interpretation: LD5O- lethal dose 80% of test species, > 2000 mah, rat. ‘Acute Respiratory Iitation: Toxleologica information and interpretation: lung -lungitaton(qualtave),*. This material is expected to cause significant ration othe resprstoy tact Acute inhalation Toxicity “Toxicological Information and Interpretation: 1LG50- lethal concentration 50% of test species, 0.032 mall hr, rat. Very Tonic. Acute Oral Toxicity “Toxicological information and Interpretation: LD50 aha dose 50% of test species, 81.4 maf, at Tox Chron Toxicity: ‘This product doesnot contain any substances tha are consiered by OSHA, NTP, IARC or ACGIH to be "provable or "suspected" human carenagens “Torleoiogical Information ana interpretation - MUTAGENICITY, *. Ames Test Negative, - MUTAGENICITY,“ Chinese namester ovary cels (chromosomal aberrations) Poste, - MUTAGENICITY, , Mouse micronuceus. (Gs vo} Negatve,- MUTAGENICITY," Rouse Lymphoma Posiive. - TERATOGENICITY, rat Reported not {o'be# teratogan. - TERATOGENICITY, rat Reported rot fo bea lersiogon. - SUB.CHRONIC EXPOSURE, 2 ‘malkgio0 days, rat. note level (NOEL) ‘niprio/msdisiles/0000102890001300010121E00017. HTM 611212009,TOLCIDE MBP age 20 42. ECOLOGICAL INFORMATION Ecotoxicologleal information: ay cause aaverse environmental impact material reaches waterways. Ecotoxological information and Interpretation: ECO fective concenration 50% of test species, 0.07 mg tr, Daphnia, {CSO lel concentration 50% of test speces, 0.24 m9 hr, rainbow trout (Oncorhynchus mykis) {C50 lethal concentration 50% of test species, 0.21 ma96 hy, blveil sunsh (Lepomis macrochirs) ECS0 effective concantraton 50% of test species, 0012 mgil72 hr, algae Chemical Fate Information: “The material snot realy biodegradable (OECD 301E}, Product isnot expectad to bioaccumulate, 13. DISPOSAL CONSIDERATIONS waste Disposal Method: Chemical altons, processing or cerwise altering this matevial may make the waste management ntermation presented In fis MSDS incempete, inaccurate or oherwise Inappropriate, Please be diced that state an local fanuirements for waste dispase! may be more resvictve or athensse diferent rom fadaa’ late and regulations Consul cate and local regulations ragarding the proper disposal of bis materia. Open dumping is erchbted Pesticide wastes afe acutely hazardous. improper dsposal of excess pesticide fs 8 vokalon of Federal Law. If ‘nastes cannot be deposed of by use according fo labs) intrusions, conta your Sate Psctakde oF Environmental Contel Agency or ihe Hazardous Waste representative atthe nearest Urited Siatos Environmental Protection Agency Regonal Os fr guidance, EPA Hazardous Waste - NO 44, TRANSPORT INFORMATION ‘Transportation Status: IMPORTANT! Statements below provide additional data on listed DOT classification, ‘a isted Transportation Ciassitcaton does nol address regulatory variations due tochangos in package size, mode of shipment or other regulatory desentos. us bor: Hazara Gass... (6.1) Shipping Nar CORROSIVE SOLID, TOXIC, NOS. Technical Sipping Name METHYLENE 819 THIOGYANATE. ID Number... UN2O23 Packing Grou... Lets... CORROSIVE AND POISON Emergency Guide #... 154 DOT Marie Potutanis ‘The ingredients sted below have been determined to be present in cancenttions tnt make tham reportable as repusror severe DOT Marne Polutants -npfrio/msdsiles/00001.02890001300010121100017. ATM 671272008——-ronerbe Mp age 9 ‘ngreslenvChemicat Family Marine Polutant Class METHYLENE SIS(THIOCYANATE) DOT MARINE POLLUTANT ‘we: Hevard Cass... 86.1) Shipping Nama: CORROSIVE SOLID, TOXIG, N.O.S. ‘Tesnnleal Shipping Name: METHYLENE SIS THIOCYANATE ID Numer... UN2SZ3 Packing Group. I imo: Hazard Cass... 8 (84) Shipping Nama: CORROSIVE SOLID, TOXIC, NOS. “Technical Shipping Name: METHYLENE BIS THIOGYANATE. Ip Number. UN2923 Paexing Group. ATA: Hazard Clas... (61) Shipping Nama: CORROSIVE SOLID, TOXIC, NOS. “Technical Shipping Name: METHYLENE BIS THIOGYANATE. ID Number... UN2823 Packing Group... 15, REGULATORY INFORMATION Inventory Status Inventory Status UNITED STATES (TSCA) ‘CANADA (OSL) EUROPE (EINECSIELINCS) AUSTRALIA (RICS) JAPAN (MT) SOUTH KOREA (KECL) Y= All ingrediants are on the Inventory. = Alingredients are on the inventory or exempt fom sting. = One or more ingredients fal under the polymer exempon ar are onthe no longer polymer ist. AN oher Ingrediants are on the Inventor or exempt fom iting. N= Not determined ar one or more ingredients are nat on the inventory and are rot exert fom sting FEDERAL REGULATIONS. Inventory tesuos: ‘This proguet is excluded from TSCA because ils solely for FIFRA regulated uso, ‘SARA Tile Il Hazard Class Fe Hazard -NO Reactive Hazard NO) Rolease of Pressure =NO Acute Health Hazard “yes CChronis Health Hazard NO hp/riomsds/iles/000010289000130001012100017.HTM 11272009‘STATE REGULATIONS: {Ths protect does not contain any components that are regulated under California Proposition 65, 46, OTHER INFORMATION National Fie Protection Assoclation Hazard Ratings -NFPA(R}: ‘3 Health Hazard Rting-Serious 4 Flammabity Rating-Sight 4) Instabilly Rating-Stght "National Paint & Coating Hazardous Materials Mentifeation System-HMIS(R): 3 Health Hazard Rating Serious 4 Flammabilly Reting-Sight 4 Reactily Rating-Sight Reason for Revisions: hange anclorsddtion made to Secon 11, Regulatory Review and Update Key Legend Information: IAGGit Amercan Conference of Goverymentl Industral Hyginiss OSHA- Oovupationl Salty and Heatly Acranistaton TLV" Threshold Lint Value PEL -Permiseable Exposure Limit “TWA - Time Weigtisa Average. STEL - Short Tor Exposure Lint NIP Natlonal Todolegy Program TARC.- Intemational Agency for Research on Cancer ND = Not determined RHODIA Rhoda Established Exposu Limits Disclaimer: The information hereln fs given in good faith but ro warrenty, expressed or imped, made. ** End of MSDS Document ** ttp/ri/msds/fites/0000102890001300010121 00017. HTM