axit nitric - mui nitrat

Cu 1. Nung hon ton m gam Cu(NO3)2 thu c hn hp kh NO2 v O2. Hp th hon ton lng kh bng nc thu c 2
lt dung dch c pH = 1,0. Tnh m.
A. 9,4 gam
B. 14,1 gam
C. 15,04 gam
D. 18,8 gam
Cu 2. Cho 4,8 gam S tan hon ton trong 100 gam dung dch HNO3 63%, un nng thu c kh NO 2 (duy nht) v dung dch X.
Hy cho bit dung dch X c th ho tan ti a bao nhiu gam Cu. Bit phn ng gii phng kh NO.
A. 9,6 gam
B. 14,4 gam
C. 24 gam
D. p n khc.
0
0
O H O

O
/
Pt
,
t

O
2
2
Cu 3. Ngi ta sn xut HNO 3 trong cng nghip theo s sau:NH 3 NO / t thuong
NO2 2 2
HNO3
a/ Hy cho bit, khi lng kh NH3 cn ly c th iu ch c 1,0 mol HNO3 . Bit hiu sut qu trnh t 40%.
A. 17 gam
B. 21,25 gam
C. 42,5 gam
D. p n khc.
b/ Hy cho bit, khi lng kh O2 cn ly c th iu ch c 1,0 mol HNO3 . Bit hiu sut qu trnh t 40%.
A. 80 gam
B. 40 gam
C. 120 gam
D. 160 gam
Cu 4. Nhit phn 18,8 gam Cu(NO3)2 thu c 12,32 gam cht rn. Xc nh hiu sut ca phn ng nhit phn.
A. 40%
B. 60%
C. 80%
D. p n khc.
Cu 5. Cho 20,88 gam mt oxit st vo 400 ml dung dch HNO3 ly d, thu c 0,672 lt (ktc) mt kh B duy nht v dung dch
X. Xc nh cng thc ca oxit st v B. Bit rng trong dung dch X c cha 65,34 gam mui.
A. Fe3O4 v NO
B. Fe3O4 v NO2
C. FeO v NO
D. FeO v NO2
Cu 6. Nung m gam hn hp X gm Zn(NO 3)2 v NaNO3 nhit cao n phn ng hon ton thu c 8,96 lt hn hp kh Y
(ktc). Cho kh hp th vo nc thu c 2 lt dung dch Z v cn li thot ra 3,36 lt kh (ktc). Xc nh pH ca dung dch Z.
A. pH = 0
B. pH = 1
C. pH = 2
D. pH =3
Cu 7. Ho tan hon ton 0,1 mol FeS2 trong dung dch HNO3 c nng d, tnh th tch kh NO2 (duy nht ) bay ra (ktc).
A. 11,2 lt
B. 22,4 lt
C. 33,6 lt
D. p n khc.
Cu 8. Cho Cu d vo V(l) dung dch HNO 3 4M thu c V1(lit) kh NO. Cho Cu d vo V (l) dung dch cha HNO 3 3M v
H2SO4 1M thu c V2 (l) kh NO (V1, V2 o cng iu kin v t0, p).So snh V1 v V2 . NO l sn phm kh duy nht ca NO-3 .
A. V1 = V2
B. V1 > V2
C. V1 < V2
D. khng xc nh.
Cu 9. Cho hin tng sau : cho bt st d vo dung dch HNO3 long thu c dung dch X. Chia dung dch X thnh 2 phn bng
nhau : Phn I : cho vo dung dch NaOH thy c kt ta trng xanh v ho nu ngoi khng kh.
Phn II : cho dung dch H2SO4 long vo, thy c kh khng mu, ho nu ngoi khng kh.
Hy cho bit dung dch X cha cht g ?
A. Fe(NO3)3.
B. Fe(NO3)3 v HNO3
C. Fe(NO3)2
D. Fe(NO3)2 v Fe(NO3)3 .
Cu 10. Khi cho CuS tc dng vi HNO3 c nng, thu c kh duy nht. Hy cho bit l kh g?
A. H2S
B. SO2
C. SO3
D. NO2
Cu 11. Cho s phn ng sau:
Cht A + HNO3 c, nng -> ....+ NO2 + ....
(1)
Cho bit t l k = s mol NO2 / s mol A. Hy cho bit kt lun no sau y ng?
A. k l s electron m cht A c th nhng i khi tc dng vi HNO3 .
B. k l ho tr ca cht A .
C. k l ho tr ca kim loi trong cc mui nitrat.
D. tt c u ng.
Cu 12.Nhit phn hon ton 4,7 gam mt mui nitrat thu c 2 gam mt cht rn. Hy cho bit cht rn thu c l g?
A. oxit kim loi
B. kim loi
C. mui nitrit
D. p n khc.
Cu 13. Cho 19,2g Cu vo 500ml dung dch NaNO3 1M, sau thm 500ml dung dch HCl 2M . Tnh th tch NO bay ra ktc.
( NO l sn phm kh duy nht ca NO-3 ).
A. 4,48 lt
B. 5,6 lt
D. 3,36 lt
D. p n khc.
Cu 14. Nhit phn hon ton R(NO3)2 thu c 8 gam oxit kim loi v 5,04 lt hn hp kh X ( NO 2 v O2 ). Khi lng ca hn
hp kh X l 10 gam. Xc nh cng thc ca mui X.
A. Fe(NO3)2
B. Mg(NO3)2
C. Cu(NO3)2
D. Zn(NO3)2 .
Cu 15. m gam bt st ngoi khng kh thu c 12 gam hn hp cht rn gm st v cc oxit . Ho tan hon ton 12 gam hn
hp trn bng dung dch HNO 3 4M thu c dung dch B v 2,24 lit NO duy nht (ktc). Xc nh th tch dung dch HNO3
dng .
A. 100 ml
B. 120 ml
C. 140 ml
D. 160 ml
Cu 16. Cho 21,52 gam hn hp A gm kim loi R ch c ha tr II v mui nitrat ca n vo bnh kn dung tch khng i l 3 lt.
Nung bnh phn ng xy ra hon ton, sn phm nhit phn mui c RO, a nhit v 45,60C th p sut trong bnh l p
(atm). Chia cht rn thnh 2 phn bng nhau:
Phn I: tc dng va vi 2/3lt dung dch HNO3 0,38M c kh NO thot
ra.
Phn II: tc dng va vi 0,3 lt dung dch H2SO4 0,2M.
1/ Xc nh kim loi R v tnh % khi lng tng cht trong hn hp A.
2/ Tnh p ( bit th tch cc cht rn l khng ng k).
Cu 17.Ha tan hon ton 3,6 gam kim loi R (ha tr II) bng 197,5 ml dung dch HNO 3 2M, thu c dung dch A v hn hp
kh gm NO, N2O c t khi so vi H2 l 19,2. Chia dung dch A thnh 2 phn bng nhau:
a/ em c cn thu c cht rn E. Nung cht rn E n khi lng khng i thu c 3 gam cht rn. Xc nh kim
loi R.
b/ Thm 1,10625 lt dung dch H2SO4 0,2M vo phn II, nu cho lng d bt Al vo tip th thu c ti a bao nhiu lt
kh. Bit N+5 b kh thnh N0. ( Th tch cc kh o iu kin tiu chun).
Cu 18. Cho 2 ion: XO-3 v YO2-3. Trong XO-3 , oxi chim 77,42% v khi lng . Trong YO2-3 , oxi chim 60,00% v khi lng.
1/ Xc nh X, Y.
2/ Hon thnh cc phng trnh phn ng sau:
a/ XO-3 + H+ + Ag ..+ XO + ..
b/ XO2 + H2O + O2
c/ Al + XO-3 + OH- + H2O + XH3
d/ YO2-3 + XO-3 + H+ YO2-4 + XO + .. e/ FeaYb + XO-3 + H+ ...+YO2-4 +XO2+ .. f/ Al +XO-3+H+...+ XH+4 +
.....

Cu 19. Cho 2,56g Cu phn ng hon ton vi 25,2g dung dch HNO 3 60% thu c dung dch A. Xc nh C% dung dch A, bit
rng nu thm 210ml dung dch KOH 1M vo dung dch A ri c cn, nung sn phm n khi lng khng i th c 20,76g
cht rn.
Cu.20 Ho tan va ht hn hp X gm Cu, CuO , Cu(NO 3)2 (trong s mol Cu bng s mol CuO) vo 350 ml dung dch H 2SO4
2M (long) th thu c dung dch ch cha mt mui duy nht v c kh NO bay ra. Tnh khi lng Cu trong hn hp X.
A. 6,4 gam
B. 12,8 gam
19,2 gam
D. p n khc.
Cu 21. Khi cho cht rn no sau y tc dng vi HNO3 c nng th c kh NO2 bay ln.
A. Fe3O4
B. MgCO3
C. CuO
D. c A, B, C u ng.
Cu 22. Ho cht no sau y c th s dng phn bit cc dung dch : HNO3 long, H2SO4 long v HCl v Na2SO4
A. BaS
B. FeCO3
C. MgSO4
D. Al.
Cu 23. Cho 5,6 gam Fe vo 200 ml dung dch cha HNO3 4M v H2SO4 2M thu c kh NO v dung dch X. Hy cho bit dung
dch Y c th ho tan ti a bao nhiu gam Cu. Bit phn ng gii phng kh NO.
A.
Cu 24. Ho cht no sau y c th s dng phn bit Fe3O4, Fe2O3.
A. dung dch HClB. dung dch HNO3
C. dung dch H2SO4
D. dung dch CH3COOH
Cu 25. Ho tan hon ton 10 gam CuO trong dung dch HNO3 (ly d 20% so vi lng phn ng) thu c 100 gam dung dch
X. Trong dung dch X, nng % ca axit l 6,3%. Tnh C% ca dung dch HNO3 ban u.
A. 42%
B. 31,5%
C. 63%
D. p n khc.
Cu 26. Cho 34,8 gam mt oxit st vo dung dch HNO 3 c nng d , kh NO2 bay ra c hp th ht vo 100 ml dung dch
NaOH 2M (ly d) thu c dung dch A. C cn dung dch A th thu c 13,55 gam cht rn. Xc nh cng thc ca oxit st.
A. FeO
B. Fe3O4
C. Fe2O3
D. c A, B u ng.
Cu 27.Ha tan hon ton 3,6 gam kim loi R ha tr khng i bng 197,5 ml dung dch HNO 3 2M, thu c dung dch A v hn
hp kh gm NO, N2O c t khi so vi H2 l 19,2. Chia dung dch A thnh 2 phn bng nhau:
a/ em c cn thu c cht rn E. Nung cht rn E n khi lng khng i thu c 3 gam cht rn. Xc nh kim loi R.
b/ Thm 1,10625 lt dung dch H2SO4 0,2M vo phn II, nu cho lng d bt Al vo tip th thu c ti a bao nhiu lt kh. Bit
N+5 b kh thnh N0. ( Th tch cc kh o iu kin tiu chun).
Cu 28. Cho 21,52 gam hn hp A gm kim loi R ch c ha tr II v mui nitrat ca n vo bnh kn dung tch khng i l 3 lt.
Nung bnh phn ng xy ra hon ton, sn phm nhit phn mui c RO, a nhit v 45,60C th p sut trong bnh l p
(atm). Chia cht rn thnh 2 phn bng nhau:
Phn I: tc dng va vi 2/3lt dung dch HNO3 0,38M c kh NO thot ra.
Phn II: tc dng va vi 0,3 lt dung dch H2SO4 0,2M.
1/ Xc nh kim loi R v tnh % khi lng tng cht trong hn hp A. 2/ Tnh p ( bit th tch cc cht rn l khng ng k).
Cu 29. Hn hp X gm Al v Fe.
Th nghim I: Cho 11 gam hn hp X vo 200 ml dung dch HNO3 thu c 4,928 lt NO.Th nghim II: Cho 11 gam hn hp X
vo 400 ml dung dch HNO3 thu c 6,72 lt kh NO. Sau phn ng thu c dung dch Y. Th tch cc kh o iu kin tiu
chun v NO l sn phm kh duy nht ca NO-3 .
a/ Xc nh nng mol/l ca dung dch HNO3 v % khi lng cc cht trong hn hp X.
b/ Thm 200 ml dung dch H2SO4 2M vo dung dch Y . Hy cho bit dung dch Y c th ha tan ti a bao nhiu gam Cu.
Bit rng trong cc phn ng xy ra, NO-3 b kh duy nht thnh NO.
Cu 30. Cho 2,56g Cu phn ng hon ton vi 25,2g dung dch HNO 3 60% thu c dung dch A. Xc nh C% dung dch A, bit
rng nu thm 210ml dung dch KOH 1M vo dung dch A ri c cn, nung sn phm n khi lng khng i th c 20,76g
cht rn.
Cu 31. Cho 5,1 gam hn hp X gm Mg v Al tan hon ton trong dung dch HNO 3 thu c 0,1 mol NO v 0,2 mol NO 2. Tnh
% khi lng ca Al trong hn hp X.
A. 26,47%
B. 42,35%
C. 52,94%
D. p n khc.
Cu 32. Cho 6,4 gam Cu vo 200 gam dung dch HNO 3 (ly d) thu c mt kh duy nht v dung dch X (khng c NH 4NO3) c
khi lng 197,2 gam. Xc nh cng thc ca kh thot ra.
A. NO2
B. NO
C. N2O
D. N2 .
Cu 33. Cho 9,6 gam Cu tan hon ton trong 93,4 gam dung dch HNO 3 (ly d) thu c kh Y duy nht v dung dch Z. Trong
dung dch Z, nng % ca mui Cu(NO3)2 l 28,2%. Xc nh kh thot ra.
A. NO2
B. NO
C. N2O
D. p n khc.
Cu 34. Cho 4,59 gam kim loi R tan hon ton trong dung dch HNO 3 thu c 2,688 lt hn hp kh Y gm 2 kh khng mu
trong c mt kh ho nu ngoi khng kh. T khi ca Y so vi H2 l 16,75. Xc nh kim loi R .
A. Mg
B. Al
C. Ca
D. Zn
Cu 35. Ho tan hon ton 10 gam CuO trong dung dch HNO3 (ly d 20% so vi lng phn ng) thu c 100 gam dung dch
X. Trong dung dch X, nng % ca axit l 6,3%. Tnh C% ca dung dch HNO3 ban u.
A. 42%
B. 31,5%
C. 63%
D. p n khc.
Cu 36. Ha tan ha ton 10,44 gam hn hp X gm Al v Fe trong dung dch HNO 3 long d thu c 6,496 lt kh NO duy nht
bay ra iu kin tiu chun. Tnh % khi lng ca Al trong hn hp X.
A. 51,72%
B. 38,79%
C. 25,86%
D. p n khc.
Cu 37. Cho 6,4 gam Cu vo dung dch HNO 3 c, un nng thu c dung dch B v hn hp kh NO 2 v NO. Khi lng dung
dch B ng bng khi lng dung dch HNO3 ban u. Tnh th tch kh NO2 (o 270C v 1 atm).
A. 1 lt
B. 2 lt
C. 3 lt
D. p n khc.
Cu 38. Cho m gam S vo 100 gam dung dch HNO3 63% un nng thu c kh NO2 v dung dch A. trung ha axit trong
dung dch A cn dng 300 ml dung dch NaOH 2M.
1/ Xc nh m v tnh C% cc cht trong dung dch A.
2/ Hy cho bit dung dch A c th ha tan ti a bao nhiu gam Cu. Bit rng phn ng gii phng kh NO.

Cu 39. Cho mt lng nh dung dch cha SO2 vo bnh ng y kh NO2. y nt li, lc ng, mu nu mt ht. Sau , m
nt, mu nu li xut hin tr li. Cho dung dch BaCl 2 vo dung dch trong ng nghim thy c kt ta trng. Gii thch hin
tng v vit cc phng trnh phn ng xy ra.