Professional Documents
Culture Documents
3063 Exam3 Solutions Sp06
3063 Exam3 Solutions Sp06
Field
the eigenfunctions so that the probability of finding the particle somewhere in the box is one.
2
Answer: ψ n ( x) = sin( nπx / L)
L
Solution: For the region outside of 0 < x < L ψ ( x) = 0 and inside the region
h 2 d 2ψ ( x) d 2ψ ( x) h 2k 2
− = Eψ ( x ) or = − k 2
ψ ( x ) with E =
2me d 2 x d 2x 2me
The most general solution is of the form
ψ ( x) = A sin(kx) + B cos(kx) .
The boundary condition at x = 0 givesψ (0) = B = 0 and the boundary condition at x = L gives
ψ ( L) = A sin(kL) = 0 which implies that kL = nπ with n = 1, 2, 3,… Thus,
n 2π 2h 2
ψ n ( x) = A sin(nπx / L) with En = . The normalization is arrived at by requiring that
2mL2
+∞ L nπ nπ
LA2 LA2 y sin(2 y ) LA2
∫ψ ( x)ψ n ( x)dx = 1 = A ∫0 sin (nπx / L)dx = nπ ∫0 sin ( y)dy = nπ 2 − 4 0 = 2
∗ 2 2 2
n
−∞
Thus, A = 2 / L . These states are called stationary because the probability density and all the
expectation values are independent of time.
(b) (5 points): Show that the allowed energy levels of the system are, En = E0 n2,
where E0 = h 2π 2 /(2mL2 ) is the ground state energy and n = 1, 2, 3, …. Why is n = 0 excluded as
a possible energy level?
n 2π 2 h 2 π 2h 2
Solution: We see from above that En = = n E0 with E1 = E0 =
2
. The state with
2mL2 2mL2
n = 0 correstions to ψ0(x) = 0 which is not normalizable.
(c) (10 points): Consider the operator, O = (x)op(px)op (i.e. the product of the position operator
times the momentum operator). Is the operator O hermitian? Calculate the expectation value of
the operator Q for the nth stationary state (i.e. calculate <ψn|O|ψn>).
Answer: O is not hermitian and < xpx > n = ih / 2 .
Solution: We see that O ↑ = ( xpx )↑ = ( p x )↑ x ↑ = px x ≠ xpx since (x)op and (px)op do not commute.
Also,
+∞ +∞
dψ n ( x )
< xpx > n = ∫ψ n∗ ( x)( xpx )opψ n ( x)dx = −ih ∫ ψ n∗ ( x) x dx
−∞ −∞
dx
2 nπ 2 nπ
L L
− ih ∫ x sin(nπx / L) cos(nπx / L)dx = −ih ∫ x sin( 2nπx / L)dx =
L L 0 L 2 L 0
2 2 nπ
2 nπ L 1 − 2 nπ i h
(sin y − y cos y ) 0 = −ih
2 nπ
= −ih ∫ y sin( y )dy = −ih =
L 2 L 2nπ 0 4 nπ 4 nπ 2
where I used sin θ cosθ = 12 sin 2θ and I let y = 2nπ/L.
(d) (15 points): Suppose the particle in this infinite square well has an initial wave function at
t = 0 given by
Ψ ( x,0) = A sin 2 (πx / L) .
What is the normalization A? If you measure the energy of this particle, what is the probability
that you will measure the ground state energy E0?
8 768
Answer: A = and P1 = ≈ 0.96067
3L 81π 2
Solution: The normalization is arrived at by requiring that
+∞ L π
LA2
∫ Ψ ( x,0)Ψ( x,0)dx = 1 = A ∫ sin (πx / L)dx = ∫ sin ( y)dy
∗ 2 4 4
−∞ 0
π 0
π
LA2 3 y sin(2 y ) sin(4 y ) LA2 3π 3LA2
= − + = =
π 8 4 32 0 π 8 8
8
and hence A = . The overlap of Ψ(x,0) with ψ1(x) is given by
3L
+∞ L π
2 8 2 8 L
c1 =< ψ 1 | Ψ >= ∫ψ 1 ( x)Ψ ( x,0)dx =
∗
∫ sin 3 (πx / L)dx = ∫ sin 3 ( y )dy
−∞
L 3L 0 L 3L π 0
π
2 8 L cos3 ( y ) 2 8 L 1 1 4 16 16 3
= − cos( y ) = − + 1 − + 1 = =
L 3L π 3 0 L 3L π 3 3 3π 3 9π
and the probability, P1, of measuring E0 = E1 is
2
16 3 768
P1 =| c1 | =
2
=
≈ 0.96067 .
9π 81π
2
Problem 2 (35 points): Consider the case of two non-interacting particles Two Particles in a Box
both with mass m in a one-dimensional infinite square well given by
V(x) = 0 for 0 < x < L, and V(x) = ∞. For one particle we know that the
stationary states of Schrödinger’s equation are given by ψ(x2)
Ψn ( x, t ) = ψ n ( x)e −iE n t / h and En = n 2 E0 , and n is a positive integer and
π 2h 2 ψ(x1)
E0 = and where you calculated ψn(x) in the previous problem. For
2mL2
two (non-interacting) particles we look for a solution of the form
Ψ ( x1 , x 2 , t ) = ψ ( x1 , x 2 )e − iEt / h = ψ ( x1 )ψ ( x 2 )e − iEt / h with 0 L
2 2
(p ) (p )
+ x 1
=E. x 2
2m 2m
(a) (15 points): Show that ψ αβ ( x1 , x2 ) = ψ α ( x1 )ψ β ( x2 ) , is a solution to the two particle non-
interaction Schrödinger equations, where α and β are positive integers and ψα(x) and ψβ(x) are
the one particle stationary state solutions from the previous problem. Show that the allowed
energy levels are given by Eαβ = (α 2 + β 2 ) E0 . This solution corresponds to the case where the
two particles are distinguishable. The probability of finding both particles on the left side of the
box (0 < x < L/2) is given by
L/2 L/2
Pαβ = ∫ ∫ | ψ αβ ( x , x ) |
LL 2
1 2 dx1dx2 .
0 0
Calculate PαβLL for the state where α = 1 and β = 2 (i.e. 1st excited state) for the distinguishable
case.
1
Answer: ( P12LL ) D =
4
Solution: In this case we have
2
ψ αβ ( x1 , x2 ) = ψ α ( x1 )ψ β ( x2 ) = sin(απ x1 / L ) sin( βπ x2 / L )
L
4
ραβ
D
( x1 , x 2 ) =| ψ αβ ( x1 , x 2 ) | 2 = 2
sin 2 (απx1 / L) sin 2 ( βπ x 2 / L )
L
and
L/2L/2
4
(P ) = 2 ∫ ∫ sin (πx1 / L) sin 2 (2πx2 / L)dx1dx2
LL 2
12 D
L 0 0
L/2 L/2
2 2 1 1 1
∫ sin (πx1 / L)dx1 ∫ sin (2πx2 / L)dx2 = =
2 2
L 0
L 0 2 2 4
where I used
nπ / 2 nπ / 2
2 nπ 1
L/2
2 2 L 2 L y sin(2 y )
∫0 sin (nπx / L)dx = L nπ ∫0 sin ( y)dx = L nπ 2 − 4 0 = nπ 4 = 2
2 2
L
and I let y = nπ/L.
(b) (10 points): For two identical bosons (i.e. particles with integral spins) we must use the
symmetric wavefunction
ψ αβ
S
( x1 , x 2 ) =
1
(ψ αβ ( x1 , x 2 ) + ψ αβ ( x 2 , x1 ) ) (α ≠ β symmetric under 1↔2)
2
1
ψ αα
S
( x1 , x 2 ) = (ψ αα ( x1 , x2 ) + ψ αα ( x2 , x1 ) ) (α = β symmetric under 1↔2)
2
Calculate PαβLL for the state where α = 1 and β = 2 (i.e. 1st excited state) for two indistinguishable
bosons.
2
1 4 1
Answer: ( P ) = + ≈ + 0.18 ≈ 0.43
LL
4 3π
12 BE
4
Solution: In this case we have
2
ψ αβ
S
( x1 , x2 ) = [sin(απx1 / L) sin( βπ x2 / L ) + sin( βπ x1 / L) sin(απx2 / L )] (α ≠ β)
L
2
ψ αα
S
( x1 , x2 ) = sin(απx1 / L ) sin(απx2 / L )
L
and
ραβ
BE
( x1 , x2 ) = ραβ
classical
( x1 , x2 ) + ραβ
int
( x1 , x2 ) (α ≠ β)
where
ραβ
int
( x1 , x2 ) ≡ Re (ψ αβ ( x1 , x2 )ψ βα
∗
( x1 , x2 ) ) (α ≠ β)
and
ραα
BE
( x1 , x2 ) = ραα
classical
( x1 , x2 ) .
We see that
ραβ
classical
( x1 , x2 ) =
L
2
2
(
sin 2 (απx1 / L) sin 2 ( βπx2 / L) + sin 2 ( βπx1 / L) sin 2 (απx2 / L) )
4
ραβ
int
( x1 , x2 ) = 2 (sin(απx1 / L) sin(βπx1 / L) sin(απx2 / L) sin( βπx2 / L) )
L
and
ραβ
classical
( x1 , x2 ) = 12 ( ραβ
D
( x1 , x2 ) + ραβ
D
( x2 , x1 )) .
We see that
L/2 L/2 L/2 L/2 L/2 L/2
( P12LL ) BE = ∫ ∫ ρ12 ( x1, x2 )dx1dx2 = ∫ ∫ ρ12 ( x1, x2 )dx1dx2 + ∫ ∫ρ
BE classical int
12 ( x1 , x2 )dx1dx2
0 0 0 0 0 0
2
1 4 1
= + ≈ + 0.18 ≈ 0.43
4 3π 4
where I used
(c) (10 points): For two identical fermions (i.e. particles with half-integral spins) we must use
the symmetric wavefunction
4 3π 4
Solution: In this case we have
2
ψ αβA ( x1 , x2 ) = [sin(απx1 / L ) sin( βπ x2 / L) − sin( βπ x1 / L) sin(απx2 / L )]
L
and
ραβ
FD
( x1 , x2 ) = ραβ
classical
( x1 , x2 ) − ραβ
int
( x1 , x2 )
where
ραβ
int
( x1 , x2 ) ≡ Re (ψ αβ ( x1 , x2 )ψ βα
∗
( x1 , x2 ) ) (α ≠ β)
and we get
L/2L/2 L/2L/2 L/2L/2
= ∫ ∫ρ ( x1 , x2 )dx1dx2 = ∫ ∫ρ ( x1 , x2 )dx1dx2 − ∫ ∫ρ
LL FD classical int
(P )
12 FD 12 12 12 ( x1 , x2 )dx1dx2
0 0 0 0 0 0
2
1 4 1
= − ≈ − 0.18 ≈ 0.07
4 3π 4
where I used
2 × 6 = 7 + 5 (j1 = 1/2, j2 = 5/2, j = 3, 2)
2 × 4 = 5 + 3 (j1 = 1/2, j2 = 3/2, j = 2, 1)
2 × 2 = 3 + 1 (j1 = 1/2, j2 = 1/2, j = 1, 0)
(c) (20 points): Now consider the case where j1 = 1 and j2 = ½ (i.e. 3 × 2) and define the states as
follows:
| Y11 >1 =| 11 >
|↑>2 =| 12 12 >
| Y10 >1 =| 10 > and
|↓>2 =| 12 − 12 >
| Y1−1 >1 =| 1 − 1 >
Now consider the two superposition states
1 2 2 1
| + >≡ | Y11 >1|↓> 2 + | Y10 >1|↑> 2 and | − >≡ | Y11 >1|↓> 2 − | Y10 >1|↑> 2 .
3 3 3 3
Calculate the following and express your answer in terms of |±>:
(1) J z | ± > (2) J1 | ± > (3) J 2 | ± >
2 2
+ − − +
(4) 2 J1z J 2 z | ± > (5) ( J1 J 2 + J1 J 2 ) | ± > (6) J | ± >
2
Are the states | ± > eigenstates of the J and Jz and if so what are their eigenvalues?
Answer:
(1) J z | ± >= 12 | ± > (2) J1 | ± >= 2 | ± > (3) J 2 | ± >= 34 | ± >
2 2
(
(4) 2 J1z J 2 z | ± >= − 13 (( 32 m 12 ) | ± > + 2 | m > )
(5) ( J1+ J 2− + J1− J 2+ ) | ± >= ± 43 | ± > + 3
2
|m>
(6) J | ± >= ( 94 ± 64 ) | ± >
2
J1− | Y11 >1 = J1− | 11 >= 1(1 + 1) − 1(1 − 1) | 10 >= 2 | Y10 >1
J 2+ |↑>2 = J 2+ | 12 12 >= 0
J 2+ |↓>2 = J 2+ | 12 − 12 >= 1
2 ( 12 + 1) + 12 (− 12 + 1) | 12 12 >=|↑> 2
J 2− |↑>2 = J 2− | 12 12 >= 1
2 ( 12 + 1) − 12 ( 12 − 1) | 12 − 12 >=|↓>2
J 2− |↓>2 = J 2− | 12 − 12 >= 0
and hence
1 2 1 2
J z | + >= ( J1z + J 2 z ) | Y11 >1|↓> 2 + | Y10 >1|↑> 2 = (1 − 12 ) | Y11 >1|↓> 2 +(0 + 12 ) | Y10 >1|↑> 2 = 12 | + >
3 3 3 3
2 1 2 1
J z | − >= ( J1z + J 2 z ) | Y11 >1|↓> 2 − | Y10 >1|↑> 2 = (1 − 12 ) | Y11 >1|↓> 2 −(1 − 12 ) | Y10 >1|↑> 2 = 12 | − >
3 3 3 3
1 2 1 2
J12 | + >= J12 | Y11 >1|↓> 2 + | Y10 >1|↑> 2 = (2) | Y11 >1|↓> 2 +(2) | Y10 >1|↑> 2 = 2 | + >
3 3 3 3
2 1 2 2
J12 | − >= J12 | Y11 >1|↓> 2 − | Y10 >1|↑> 2 = (2) | Y11 >1|↓> 2 −(2) | Y10 >1|↑> 2 = 2 | − >
3 3 3 3
1 2 1 2
J 22 | + >= J 22 | Y11 >1|↓> 2 + | Y10 >1|↑> 2 = ( 34 ) | Y11 >1|↓> 2 +( 34 ) | Y10 >1|↑> 2 = ( 34 ) | + >
3 3 3 3
2 1 2 2
J 22 | − >= J 22 | Y11 >1|↓> 2 − | Y10 >1|↑> 2 = ( 34 ) | Y11 >1|↓> 2 −( 34 ) | Y10 >1|↑> 2 = ( 34 ) | − >
3 3 3 3
We also see that
1 2
2 J 1 z J 2 z | + >= 2 J 1 z J 2 z | Y11 >1 |↓> 2 + | Y10 >1 |↑> 2
3 3
1 2 1
= 2 (1)( − 12 ) | Y11 >1 |↓> 2 + 2( 0)( + 12 ) | Y10 >1 |↑> 2 = − | Y11 >1 |↓> 2
3 3 3
=−
1 1
3 3
( 1
|+ >+ 2|−> =− |+ >+ 2|−>
3
) ( )
and
2 1
2 J1z J 2 z | − >= 2 J1z J 2 z | Y11 >1|↓> 2 − | Y10 >1|↑> 2
3 3
2 1 2
= 2(1)(− 12 ) | Y11 >1|↓> 2 −2(0)(+ 12 ) | Y10 >1|↑> 2 = − | Y11 >1|↓> 2
3 3 3
=−
2 1
3 3
( 1
)
|+ > + 2 |− > = − 2|− > + 2 |+ >
3
( )
and hence,
2 J1z J 2 z | ± >= −
3
(
1 3 1
)
(( 2 m 2 ) | ± > + 2 | m > .
Also,
1 2
( J1+ J 2− + J1− J 2+ ) | + >= ( J1+ J 2− + J1− J 2+ ) | Y11 >1|↓> 2 + | Y10 >1|↑> 2
3 3
1 2 1 2
= 2 | Y10 >1|↑> 2 + 2 | Y11 >1|↓> 2 = 2 | Y11 >1|↓> 2 + | Y10 >1|↑> 2
3 3 3 3
2
3
(
|+>+ 2|−> +
3
2
) ( 2 |+ > −|− > = ) 4
3
|+>+
3
2
|−>
and
2 1
( J1+ J 2− + J1− J 2+ ) | − >= ( J1+ J 2− + J1− J 2+ ) | Y11 >1|↓> 2 − | Y10 >1|↑> 2
3 3
2 1 2 1
= 2 | Y10 >1|↑> 2 − 2 | Y11 >1|↓> 2 = − | Y11 >1|↓> 2 +2 | Y10 >1|↑> 2
3 3 3 3
=−
3
2
(
|+>+ 2|−> +
2
3
) ( 4
)
2 |+ > −|− > = − |− > +
3 3
2
|+>
Hence,
4 2
( J 1+ J 2− + J1− J 2+ ) | ± >= ± |±>+ | m >,
3 3
where I used
| Y11 >1|↓> 2 =
1
3
(
|+>+ 2|−> ) and | Y10 >1|↑> 2 =
1
3
( 2 |+ > −|− > . )
We see that
J 2 | ± >= ( J12 + J 22 + J1+ J 2− + J1− J 2+ + 2 J1z J 2 z ) | ± >
3 4
= 2|± > + |± > ± |± > +
4 3 3
2 1
(
| m > − (( 32 m 12 ) | ± > + 2 | m >
3
)
3 4 1 2 2
= 2 + ± − ( 32 m 12 ) | ± > + − |m >
4 3 3 3 3
3 4 1 1 27 18 9 6
= 2 + ± − ± | ± >= ± | ± >= ± | ± >
4 3 2 6 12 12 4 4
and hence
9 6 15 9 6 3
J 2 | + >== + | + >= | + > and J 2 | − >== − | − >= | − > .
4 4 4 4 4 4
Thus |+> correspomds to j = 3/2 m = ½ and |-> corresponds to j = ½ and m = ½.