Ácido Bórico

Carlos Agustín Manzo Rosas

IQ552982

Mayo de 2010
Reacciones

H₃BO₃+H₂O→H₂BO₃⁻¹+H₃O⁺

H₂BO₃⁻¹+H₂O→HBO₃⁻²+H₃O⁺

HBO₃⁻²+H₂O→BO₃⁻³+H₃O⁺

Constantes de disociación

Ka 1 Ka 2 Ka 3
5.8076E-10 1.8197E-13 1.5849E-14

Cálculos

C a  H3 BO3   H2 BO3 1   HBO3 2   BO3 3  Ca  1

H 2 BO 31 H 3 O   H 3 BO 3  K a1
K a1  H 3 BO 3 
 H2 BO3 1   H 3 O  

H 3 BO 3  Ka1
HBO 32 H 3 O   H 2 BO 31  K a2  K a2
H 3O 
K a2   HBO3 2   H 3 O  
 H 3 O  
H 2 BO 31

H 3 BO 3  Ka1
 Ka2
H 3O 
 K a3
H3O 
BO 33 
H 3 O  HBO 32  K a3
K a3   BO3 3   H 3 O  
 H 3 O  
HBO 32
 H 3 BO 3  Ka1
 Ka2
H 3O 
 K a3
H 3 BO 3  Ka1 H 3O
 K a2
H 3 BO 3  K a1 H 3O 
1  H3 BO3   H 3 O  
 H 3 O  
 H 3 O  

H 3 BO 3  K a1 H 3 BO 3  K a1  K a2 H 3 BO 3  K a1  K a2  K a3
1  H3 BO3   H 3 O  
  2

H 3 O  H 3 O   3

1 K a1 K a1  K a2 K a1  K a2  K a3
 1 H 3 O  
 
H 3 BO 3  H 3 O   2 H 3 O   3

1
H3 BO3   Ka1 Ka1  Ka2 Ka1  Ka2  Ka3
1  
H 3O  H 3O 2 H3O  3

H3 O   10  pH

Resultados

pH [H3BO3] [H2BO31-] [HBO32-] [BO33-] [H3O+]

0.99999999
0 5.80764E-10 1.05682E-22 1.67494E-36 1
9
0.99999999 0.3162277
0.5 1.83654E-09 1.05682E-21 5.29663E-35
8 7
0.99999999
1 5.80764E-09 1.05682E-20 1.67494E-33 0.1
4
0.99999998 0.0316227
1.5 1.83654E-08 1.05682E-19 5.29663E-32
2 8
0.99999994
2 5.80764E-08 1.05682E-18 1.67494E-30 0.01
2
0.99999981 0.0031622
2.5 1.83654E-07 1.05682E-17 5.29663E-29
6 8
0.99999941
3 5.80764E-07 1.05682E-16 1.67494E-27 0.001
9
0.99999816 0.0003162
3.5 1.83653E-06 1.05682E-15 5.29662E-26
3 3
0.99999419
4 5.80761E-06 1.05681E-14 1.67493E-24 0.0001
2
0.99998163
4.5 1.8365E-05 1.0568E-13 5.29654E-23 3.1623E-05
5
0.99994192
5 5.80731E-05 1.05676E-12 1.67485E-21 0.00001
7
5.5 0.99981638 0.00018362 1.05662E-11 5.29566E-20 3.1623E-06
0.99941957 0.00058042
6 1.0562E-10 1.67397E-18 0.000001
3 7
 0.99816682 0.00183317
6.5 1.05488E-09 5.28692E-17 3.1623E-07
7 2
0.99422587
7 0.00577411 1.05072E-08 1.66527E-15 0.0000001
9
0.98196571 0.01803417
7.5 1.03776E-07 5.20111E-14 3.1623E-08
9 7
0.94511035 0.05488864 0.0000000
8 9.98809E-07 1.58301E-12
5 6 1
0.84483405 0.15515701
8.5 8.92835E-06 4.47478E-11 3.1623E-09
8 4
0.63256304 0.36737010
9 6.68504E-05 1.05951E-09 1E-09
2 7
0.35241108 0.64721646 0.00037243
9.5 1.86659E-08 3.1623E-10
2 5 4
0.14666597 0.85178378 0.00154999
10 2.45657E-07 1E-10
4 9 2
0.05135811 0.94321154 0.00542761
10.5 2.72025E-06 3.1623E-11
9 5 6
0.01662926 0.96576877 0.01757410
11 2.78531E-05 1E-11
9 5 3
0.00512098 0.94048832 0.05411945
11.5 0.00027124 3.1623E-12
4 2 4
0.00145112 0.15335729 0.00243054
12 0.84276103 1E-12
4 7 9
0.00033929 0.62312099 0.35856870 0.01797100
12.5 3.1623E-13
1 6 7 6
0.32172173 0.58543731 0.09278556
13 5.53963E-05 1E-13
2 1 1
0.10375074 0.59702320 0.29922040
13.5 5.64926E-06 3.1623E-14
2 2 7
0.02081713 0.37880965 0.60037284
14 3.58444E-07 1E-14
9 7 6

Gráfica
 1
0.9
0.8
0.7 [H3BO3]
0.6 [H2BO3
1-]
0.5 [HBO32-
]
0.4 [BO33-]
0.3
0.2
0.1
0
0 2 4 6 8 10 12 14

La gráfica muestra el aumento y decremento de las concentraciones conforme el pH va cambiando

Referencias Bibliográficas

 R. A. Day Jr, A. L Underwood, Química Analítica Cuantitativa, 5ª Ed.

 Stephen Claydon, In a coloured rectangle at the top of pages, Science Aid,
http://scienceaid.co.uk/chemistry/physical/acidbases.html