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    FPharmacy Twentythirteen
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    62 views1 page

    First Half

    Uploaded by

    FPharmacy Twentythirteen

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as DOCX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 1

    1.

    Hydrolysis of Acid Derivatives


    a. Acyl Halides
    CH3COCl + H2O → CH3COOH + HCl

    b. Acid Anhydrides
    CH3COOCOCH3 + H2O→ 2CH3COOH

    c. Esters
    RCOOR+ + NaOH → RCOO-Na+ + R+OH
    RCOO- Na+ +HCl → RCOOH + NaCl

    CH3COOCH2CH3 + NaOH →CH3COO-Na+ + CH3CH2OH


    CH3COO-Na+ + HCl → CH3COOH + NaCl

    d. Amides
    RCONR+2 + NaOH → RCOO-Na+ + R2+NH
    RCOO-Na+ + H+ → RCOOH + Na+

    2. Alcoholysis: Schotten-Baumann Reaction


    a. Carboxylic Acid
    Sulfuric Acid
    ↔
    CH3COOH Ethanol CH3COOCH2CH3 + H3O+

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