P6-10 (a)
Species A:
Species Be
Species C:
fe = kiCy
Plugging into POLYMATH! ges the following.
vacshe ae me ve nn oe fase
i tent one
mote 2 ce
626‘Sce Polymath program P6-10-b.pol
POLYMATH Ress
Tae =
Olesssies Toaeeie a
560
“hsenaye
[LES Report cafenewt)
Noninger equations
TIT Ga) sta rah Ca) =0
[21 Hn) = taureoyco =o
151 We} =tav'veyce
Expl equations
ny aes,
(1 Te760
(3) Ki= 72% -10000(1.967"n)
fy akon
cs)
‘el
0
saeee
F vasee
eat
“Therefore, Cy mamma T=760K,
onP6-10 (c) : i.
Dart is similar to part excep fortwo ate laws
® eeet,-b ec,
£70, -ky*C,-k,*C,
Using tose rate laws nPOLYMATH produce the following
‘Equations Inicial value
aeat/a(e) ere 1s
ated) dit arb a
alee) /attr=re °
vas
4
xbekif¥ca-klr*eb-42%2b ner None
mene i So
= % Ss 350000 : Se,
Variable sig) value Yucimun value Minin value £$nal value
c 350000 ° 350000,
ca 16 0.436326 0436336
as 0.833237, ° 0.5159
se 0.647784, ° 0.647786
fae 3.33008 8.33e-05, 3.33e-05, 8.338-05
war 0.0002 2.0002 0.0002 o.c002
ke 2, 780-06 2.78008 2.788-06 2.280008
re ° 2.3164e-05 0 2.4342e-06
ra 0.00016 -6.57168e-07 -0.00016 ~6.571680-07
rb 0.00016 0.00036 -1.206326-05 | -7.770340-07
6-10 (d)
‘Thisis similar to part d except for one rate law:
mak *Cy— ks °C,
‘Using that in POLYMATH produces the following: