Run google talk with the following switch: /nomutex

If you installed google talk to the default location, you can easily create a shortcut to this setting.

1. Right-click on the desktop

2. Select New
3. Select Shortcut
4. Paste this into the text box:
"c:\program files\google\google talk\googletalk.exe" /nomutex

5. Click Next6. Name it whatever: Google Talk Multiple, etc.

7. Click OK until you are done.