http://en.wikipedia.

org/wiki/Rate_equation

First Order Rate Equation

mole/liter hours
Ao t½ k
10.03E-3 4:48 Err:501
Second Order Rate Equation

TTime A_Meas A_Calc

0:00 10.10E-3 10.03E-3
1:00 8.335E-3 8.299E-3
2:00 6.984E-3 7.079E-3
3:00 6.198E-3 6.171E-3
4:00 5.408E-3 5.470E-3
5:00 5.032E-3 4.912E-3
6:00 4.357E-3 4.457E-3
7:00 4.030E-3 4.079E-3
8:00 3.557E-3 3.761E-3
9:00 3.503E-3 3.488E-3
10:00 3.259E-3 3.252E-3
11:00 3.054E-3 3.047E-3
12:00 2.832E-3 2.865E-3
13:00 2.634E-3 2.704E-3
14:00 2.600E-3 2.560E-3
15:00 2.614E-3 2.431E-3
16:00 2.428E-3 2.314E-3
17:00 2.282E-3 2.208E-3
18:00 2.031E-3 2.111E-3
19:00 1.895E-3 2.022E-3
20:00 1.872E-3 1.941E-3
21:00 2.004E-3 1.866E-3
22:00 1.807E-3 1.796E-3
23:00 1.784E-3 1.731E-3
24:00 1.624E-3 1.671E-3
--98.324E-9
1.2E-02

1.0E-02

Solver Curve
(Second order rate curve)

8.0E-03

A_Meas
6.0E-03
Exponential (A_Meas)
A_Calc
Exponential Trendline
(First order rate curve)

4.0E-03

Measured Data

2.0E-03

0.0E+00
0:00 3:00 6:00 9:00 12:00 15:00 18:00 21:00 24:00
Kappa days offset
Ao t½ k b
9.007 2.91 Err:501 0.514 326.71E-3

Days A_Meas A_Calc

0 8.58 9.520
5 5.80 3.828
14 2.04 2.064
21 1.42 1.610
28 1.28 1.362
35 1.15 1.205
42 1.05 1.097
49 0.99 1.019
56 0.89 0.959
63 0.81 0.911
70 0.78 0.873

Second Order Rate Equation

with offset
 10.00

9.00

8.00

7.00

6.00
Kappa

5.00
A_Meas
A_Calc
4.00

3.00

2.00

1.00

0.00
0 10 20 30 40 50 60 70 80

Days