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Equations
Equations
1 ∂ ∂ 1 ∂ ∂ ∂2
+ r2 sin1 2 (θ) ∂φ
Spherical Laplacian: ∇2 = r2 ∂r
r 2 ∂r + r2 sin(θ) ∂θ sin(θ) ∂θ 2
H 0 0
0 0 3 0 0 ∂G(x,x ) 0 ∂V (x )
da0
R
Green’s Functions Potential: V (x) = −4π V G(x, x )ρ(x ) d x + S V (x ) ∂n0 − G(x, x ) ∂n0
P∞ r< l l
1
P∞ Pl 1 r< ∗ 0 0
Spherical Harmonic Expansion: |x−x 0| = l=0 r l+1 Pl (cos(γ)) = 4π l=0 m=−l 2l+1 r l+1 Ylm (θ , φ )Ylm (θ, φ)
> >
R ρ(x0 ) 3 0 P∞ Pl
Ylm (θ , φ )r ρ(x0 ) d3 x0 Ylm (θ,φ)
1 1 1
R ∗ 0 0 0l
Multipole Expansion: V (x) = 4π 0 |x−x0 | d x = 0 l=0 m=−l 2l+1 r l+1
BAC-BAC (Back to Back) Vector Identity: A × (B × C) = B(A · C) − (B · A)C
Fundamentals Angular Momentum
2 ∂
Probability Postulate: P (λ) = | hλ| ψi | Lz Operator: Lz = −i~ ∂z
~2 2 ∂ Definition of J: J=L+s
Shrodinger’s Equation: − 2m ∇ ψ + V ψ = i~ ∂t ψ
Momentum Operator: p = −i~∇ Jz Eigenvalue: Jz |j mi = ~m |j mi
de Broglie Relation: p = λh = ~k J 2 Eigenvalue: J2 |j mi = ~2 j(j + 1) |j mi
Expectation Value: hAi = hψ|A|ψi Angular Momentum Operators: (J¯i )jkP= −iijk
Definition of Unitary: U † = U −1 Commutator: [J¯i , J¯j ] = i k ijk J¯k
Stationary States: |ψ(t)i = e −iHt/~
|ψ(0)i Ladder Operators: p J± = Jx ± iJy
Canonical Commutation Relation: [xi , pj ] = i~δij Ladder: J± |j, mi = ~ j(j + 1) − m(m ± 1)|j, m ± 1i
Jacobi Identity: [A, BC] = B[A, C]P− [B, A]C
Identity Operator: I = i |φi i hφi |
Hermitian Conjugate: hψ1 |A† |ψ2 i = hψ2 |A|ψ1 i∗ Spin and Magnetism
Definition of Hermitian: A† = A
Hermitian Conjugate of Product: (AB) = B † A†
† Pauli Matrices: σx = (01 10 ) σy = (0i −i 1 0
0 ) σz = (0 −1 )
1
Uncertainty Principle: σA σB ≥ − 14 hψ|[A, B]|ψi2
2 2 Spin Singlet: |0, 0i = 2 (|+−i − |−+i)
√
Variational Method: hψ|H|ψi ≥ E0 D∀ |ψi Spin Triplet (m = 0): |1, 0i = √12 (|+−i + |−+i)
E
dhQi i ∂Q Spin Triplet (m 6= 0): |1, 1i = |++i |1, −1i = |−−i
Expectation Evolution: dt = ~ h[H, Q]i + ∂t
∂L Magnetism: Hmag = −µ · B = µB (L · B + σ · B)
Generalized Coordinates: p ≡ ṗ = − ∂H q̇ = ∂H
∂ q̇ ∂q ∂p Electron Magnetic Moment: µ = −µB L
e~
Bohr Magneton: µB = 2m
dP
Spin Half Polarization: dt = H × P
Mathematics α 1
Spin-Orbit Hamiltonian: HLS = 2m 2 r3 L · s
α0 j 0 m0 Tqk αjm = 0 unless m0 = m + q and |j − k| ≤ j 0 ≤ j + k
Selection Rules:
X |hψ 0 |H 0 |ψ 0 i|2
m n
Perturbation Theory: ∆n = En − En0 = hψn0 |H 0 |ψn0 i − 0 − E0
+ ...
Em n
m6=n
Rt
0
hψ | ψ(t)i ∼
Time-Dependent Perturbation Theory: = δf i − ~i 0 φf H 1 (t0 )φi eiωf i t dt0
R x2 pf
WKB Approximation for Semi-Infinite Potential: 0
2m(En − V (x)) dx = (n − 41 )π~ (n ∈ Z+ )
n
Baker-Hausdorff Lemma: eiB Ae−iB = A + i[B, A] − 21 [B, [B, A]] + ... + in! [B, [B, [B..., [B, A]]]] + ...
Fundamentals Legendre Transformations
Fundamental Relation: dE = T dS − pdV + µdN Energy: E(S, V, N ) ≡ E
Heat Definition: Q ≡ ∆E + W Enthalpy: H(S, p, N ) ≡ E + pV
Entropy Definition: S ≡ k ln(Ω) Helmholtz Free Energy: F (T, V, N ) ≡ E − T S
∂Ω
Beta Definition: β ≡ ∂E Gibbs Free Energy: G(T, p, N ) ≡ E − T S + pV
1
Temperature Definition: T ≡ kβ
Boltzmann Factor: P () ∝ e−β
Ideal Gas Law: pV = N kT Kinetic Theory
Ideal Gas Energy: E = 32 N kT 3 2
Pressure: p = − ∂V ∂E
Maxwell Distribution: f (v) = n m
2πkT
2
e−mv /2kT
S 1 2
m
e−mvx /2kT
2
Heat Capacity Definition: Cy ≡ dQ Component Dist.: g(vx ) = n 2πkT
dT 1
y Mean Lifetime: τ = nv̄σ
∂E ∂S
Heat Capacity (Volume): CV = ∂T V = T ∂T V
q
∂S ∂E Mean Velocity: v̄ = π8 kT
q m
Chemical Potential: µ ≡ −T ∂N EV M
= ∂N SV N
Magnetic Susceptibility Definition: M0 = χH RMS Velocity: vrms = 3 kT
Magnetization:
P
M̄0 = N0 µ̄H = r µHr nr q m
Magnetization Relation: M0 = M/V Most Probable Velocity: ṽ = 2 kT
m
Magnetic Moment: µ = gµB s/~
Efficiency: η = T1T−T 1
2
Alpha: α = ∂ ln(Z)
∂N
Chemical Potential: µj = −kT ∂ ∂N
ln(Z)
j