~ I Series SSR/1'1

Code No. 5611/1 ~';j.

Candidates must write the Code No. on the tItle page of the answer-book. m-rm :.rrR -9(fRlCfl II it ~$ :;i.. ~ ~I

• Please check that this question paper contains 15 printed pages ..

• Code number given on the right hand side of the question paper should be : written on the title page of the answer-book by the candidate.

• Please check that thisquestion paper contains 30 questions.

, "

• Please write down the Serial Number of tbequestion beforeattempting it. I

• ~ ~ ~ Q1 flr; ~ ~-q;{ it ~ ~ 15 ~ I

• ~-Jm it ~ QT~.rcfrr ~ ~ ~ cnTs~ cir ~ ~ -:!M#'II ~ WSf-y1.PI~ fulj II

• ~ ~ ~ -a- ftfi,~ ~-11;{ it' 30 ~ ~I

• '441 '!T.A qrr ~ WI&'11 ~ enR "it ~', ~. 'esT i:h1l ii5fi ~ '~I

CHEMISTRY (Theory) ~flllI1 - fCI ~ll::t (<<4 I RdeJi )

[Maximum marks " 70 [ 3Jf'~ 3icn : 70

Time allowed ;. 3 hours] Fr~ '"f[qlf : 3 'EfU2" ]

General Instructions:

(i) All questions are compulsory.

(ii) Question nos. 1 to 8 are very' short answer questions and carry 1 mark each.

(iii) Question nos. 9 to 18 are short answer questions and carry 2 marks each.

(iv) Question 'nos. 19 to 27 are also short answer questions and carry 3 marks each.

(v) Question nos .. 28 to 30 are long answer questions andcarry 5 marks each.

(vi) Use log tables if necessary; use of calculators is not allowed.

[P.T.O.

(i) ffJft JlR JOfRCI/4' g I

{ii) Sfi11.:if&rr 1 it 8 .~ >fR aiftT· ~ df1t14 ~I (J6 ~-T{Cn:W.n. ~ 61 (hi) ?fi1f ~ 9 it 1 8 if, >rR' eft -cit :Wit ~. ~ 3ft(j;q JfR g I

(tv) 551f ~ 19 it 2 7 .~ J[R iff ffR -rft;{ 3fqif ~ ~ Jd(jij .JrR g,

(v) f,P1f "fi&.H 28 :it 30 ifi >rH 'r:ff.q-qj:q. 3icif~ cfiEf .3'td};Q >rR ~·I

(vi) 31k/::?21Cf1rlJ it rit MPI ~ >PiPr fchit ~ ~ ? I :?n61Efi'ic12<7 it·.JI7ip-r

eft ~;rff ~t

1. What is the coordination number of each type of ions in arock-salt type

crystal structure ? 1

Ucn-mFG WfiR ~f?t;fltfl· fihHI ,q"~ WSfiR ~ J1TlR efitH4;qlj ti&-IT ~ irffli?

2. Define the term 'order of reaction' for chemical reactions.

1

3. What causes Brownian movement in a colloidal solution ?

1

4,. In which one of the two structures, NO; and NO~, the bond angle has a higher value?

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,5. Writ~ the IUPAC name ofthe fgllowing compound: _

1

H3CiH--CHz-1H~1H-CH20H

CM} OH CH3

R RiB retd 7fl fi'12h- Cf1T IUPA C ;w:r R1 f@ t; :

H3C-CH-CT-J -CH-CH-CI-T OH

_- I ~-'2 I I "~

CH3 OH CH.,

:J

6. Arrange the following compounds in an increasing order of their acid strengths:

1

(CH})2CHCOOH, CH}CH2CH(Br)COOH, CH}CH(Br)CH_2COOH HAfR1f@~ em ~ ~ ~ ~ l1Ttf~ ~ ~ 'ij ~q~ cf))~l(: (CH3)2CHCOOH, CH3CH2CH(Br)COOH, CH3CH(Br)CH_2COOH

7. Write a chemical reaction in which the iodide ion replaces the diazoniurn group in a diazonium salt.

1

~- {Jft I~Rq; ~ iftf@J{ ~ ~ :S1;q~R~·q ~ ~it 61-;q~lf2!;qJ:i ~ ~F41sl~\S 3m:R ~_~ mar ml

8. Name a substance that can be used as an antiseptic as well as a disinfectant,

1

~ ~ ~- CfiT;rn:r~. bt*'lZhI 3Q4)PI ~ (f~ DlllWll?n iR1 ~ if Ql:ffi m I

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9. Explain as to why haloarenesaremueh less reactive than haloalkanes towards nucleophilic substitution reactions.

2

OR

Whichcompound in each of the following pairs win react faster in Sw2 reactionwith -OH ?Why ?

0) CH3Br or CH3I

(Ii) (CH3)3CC1 or CH3Cl

;ali,$i1~4 f4> ~3?i"fCnfclCh'~ ~14Rh'z{lm $m "~ffioJ~J '~-&11o;~;f;. ttl" ?N~ tfliT" ~"cpJ" fi;;"~I~nt:l mill~'?

FII:Oiif8lroaa "Sle42h ~ -ij il* m lfllfi'lldfi -OH"~ ~. SN2 ~ .q ~ ~ "it "~q:;~lll afu" <ml"?

(i) CH3Br 3l"~ CH1[

(ii) (CH_3)3CC1 3t~ CH]CI

10. (a) 'State the IUPAC name of the following compound ::

He H

3'~H

lt~Br H

2:

(b) Complete the following chemica] equation :

He H

3~H

r)L-Bl'

H

('af) f.?iRf&1ft:rcr (lfHlIf.?iq) etflCh(OI <it ~ c€l0lLJ; : . . .. = . ... + .. 11\.a:JT'#u~:s

CH3CH2CH c~ RBr.... . .

n. State Henry's law correlating the pressure of a gas and its sol ubili ty in a solvent and mention two applications for the law.

2

~ fR:r it ~ 3ftt 3"W€t.fepffi Wi'i I'4Ch 'ij f4Ji4dl ~ ~tT .q %:Rt Cfi1 ~ afR ~ ~ ~ it 3"1j>l4111 Rif@q:l

12. A first order decomposition reaction takes 40 minutes for 30% decomposition. Calculate its tlh. value.

~ '!i2Jl1 'ClilR cRt 344EO{24 ~ 30% 3"14~21 it ~ 40 fi:r;rc Cf)T 'W=Rl ~ II ~~. tYi em: QftCf)d4 cfi)~ttl

2

13. What is meant by the 'rate constant, k' of a reaction? If the concentration be expressed in mol L -1 units and time in seconds, what would be the

units for k (i) for a zero order reaction and (ii) for a first order reaction? 2

~ ~~ <f; 'G! fi:~ k' CfiT Cf[IT ~ WID~? ~ ~ ~ ~ mol L -1 afu ~ em ilCf)u;g m "ffi (i) ~ cfitR: .'E€t ~, afp; (ii) ~ eiIR: cfiT .3lf~ ~ ftm k Cfif lWf fcf;;t. ~ * mm ?

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5

a '0

' . .0.

------~~~--~------------------------ -

---

14. Define the following terms in relation to proteins:

2

(i) Peptide linkage

(ii) Denaturation

>ftiR ~ ~.q if Rkl R1 fuh1 :cfu ~ R1 R<a~ : (i) qQI$5 ~

(ii)il-~"i!{!tFi (fCi'tlRlCfi{Ul) I

1.5. List the reactions of glucose which cannot be explained by its OP€TI chain structure.

2

. ,

lttcn1fl cfit &f~m'<fiT R1f@~ ~ ~ ~ ~ ~(:q'"ll it ~~ -qr fI ~ $jIll I -;rcff \lIT BCRIlI

16. Assign a reason for each of the following statements:

(i) Ammonia is a stronger base than phosphine.

(ii) Sulphur in vapour state exhibitsa paramagnetic behaviour.

Pp:'1R1Rg(( ~ -q if ~ ~ m CfiRUT R1fu!,~ : (i) g)1flh'l"1 eft ~lffT ~tiIH~1 ~ ~ ~ il

(ii) "EfT&:r ~ it ~ 34:ft)ktch111 oqcnH{$l~~i(j Cfi«fT ~ I

17. Draw the structures of the following molecules:

2

(i) SF 4 (ii) XeF4

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~~. ~m em- B(-q"'lI.~I~fuH1C@fSll{ : (i) SF4

(ii) XeF4

18. What are biodegradable and non-biodegradable detergents? Give one example of each class.

1\C!R4tcb(Un'4 3=iQIiI'5{<:h .~ <rm Rl"";i'letl(oA;q <AqAI~6f) ~ mit ~? ~ >refiT( Cfil ~-~ 3~1i5(Ol ~ I

19. What is a semiconductor? Describe the two main types of semiconductors and explain mechanisms for their conduction.

3l~ 1 M 6f) q:lff iRrr i ? it ~ !fCfiT( ~ 31dil] if! €hi "6f)l.qof;:f ch'l f3t Q; 3ltt ~ ~ Ql'4r~fu col· ~ chlN1Q; I

20. Calculate the temperature at which a solution containing 54 g of glucose, (~6H1206)' in 250g of water will freeze,

(Ks for water - 1.86 K mol " kg)

m:r {fTtf. efit qF{EfiRid ebl~l{ ~ 1R 250 g ~ .q 54 g lctcfflH, (C6H1206) ~. CfK: ~ ~(i1'4""t ~ ~ I (Kf (~) = 1,86 K mol:" kg)

21. What are lyophilic and lyophobic sols? Give one example of each type. Which one of these two types of sols is easily coagulated and why?

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2

3

3

3

[P.T.O.

w;r -~ 3fR W-J - fcritm ~ (sol) qq:rr ~ ~? ~"SJCfIT{ Cflf 'tzyn-~ dGI~HOI ~QJ ~ ~ >rcnR it ~ ii: ~Rt;{1CfiI !(4i~~- 31f~ Wll1ctl :if m -~ ~ 3fR~?

22. State briefly the principles which serve as basis for the following operations in metallurgy ':

3

(i) Froth floatation process (ii) Zone refining

(iii) Refining by liquation

~-Cfili it AJ21Rif@a ~ ~ 31f~~ Rl:&I==dl cpt 'B~ it R1f@~ : (i) WI (~) ~ )f$fill

(ii) ~ (~) tfI'"'(&fl{OI

23. Write chemical equations for the following processes ::

3

(i) Chlorine reacts with a hot concentrated solution of sodium hydroxide

(ii) Orthophosphorous acid :is heated

(iii) PtF6 and xenon are mixed together

OR

Complete the following chemical equations :

(1) Ca3P zcs) + H20(I) ----7 ......

- -

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~------------------~~-

.~

(ii) Cu2+(aq) + NH3(aq)~ .

(excess)

(iii) Fig) + H20(I) -------------t .•••••

~ mn:qJ :an m {IBI"-'lREfl ft41Cfi(OI R1f@1I;

(i) r.t(1IJJ'1.'l"f)~"-'llj ~q~~TCR1I~$ ~ ~ (ffi fciicl4'i ~ ~ ~ i I (ii) ~ ~ c@ lllf ~ ~ ~ 1

(iii) PtF 6 3fR. ~ "CfiT "lffiJl{ i1lcl141 QfRfT ~ I

(ii) Cu2+(aq) + NH3 (aq) -.........f ••.••• (~)

24. (a) What is a ligand? Give an example ofa bidentate ligand. 3

(b) Explain as to how the two complexes of nickel, [Ni(CN)4f- and Ni(CO)4' have different structures but do not differ in their magnetic behaviour. (Ni = 28)

(31) ~ (ligand) W iRt ~? ~ Wl11;::sl CfiT ~ 3GI${UI ~I (~) &l1€l11 4?lf1W: fr.fi tit· ~ ~ GT Q;1P0tcru [Ni(CN)4f- 3fR Ni(CO)4 11m"-~ ~ mffi ~ .'4T "BllR 1k(<i);q c;qq$I{$IG~fa !5fl@: ~I (Ni = 28)

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[P.T.O.

. 9

25. Name the reagents which are used in the following conversions: 3

(i) A primary alcohol to an aldehyde

(ii) Butan-2-one to butan-2-o1

(iii) Phenol to 2, 4, 6-tribromophenoI

(i) ~ >l1~A{l ~15TIi1 cor"Q(-P QrR~QI~:S if (ii) ~-2- -31R em ~-2- 31fR it

26. Account for the following observations:

3

0) pKb for aniline is more than that for methylamine.

(ii) Methylamine solution in water reacts with ferric chloride solution to give a precipitate of feme hydroxide.

(iii) Aniline does not undergo Friedel-Crafts reaction.

RLOO1f&ifuia 3i*'11Ch<:il ~ CfiRUl R1f@ll :

(i) QPlclI<i ~ ft14 pKb ·CfiT l1R ilf~d~Al"1 it··~ it ~ ~ ~I

(ii) ~. it· #rndQ:41~ .q)J ~ ~ ·'-k1~kl$:S ~ ~ it aTI~ ~ ~ ~1~'!i11"fl1$i$ 'fiT .31cf~ ~ ~ I

(iii) ~Rcll'i $I-%t9-i1l!Y{{it 3lf~ ~. Cfi\ID ~ I

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27. Write the names and structures of the monomers of the following polymers :

3

(i) Buna-S

(ii) Neoprene

(iii) Nylon-f

f4~f8f@d it§eJ:2hl ~ t;&It1Ch1 ~ ;rrq ~ ~ W:-.q;n~. fRf~ : (i) ¢fIT-S

(ii) H~·

(iii) ~1~(f11"1-6

28. Conductivity ofO,.00241M acetic acid solution is 7,896 x lO~s S cm'".

Calculate its molar conductivity in this solution, If A~~ for acetic acid be

390.5 S cm2 mol-l; what would he its dissociation constant? 5

OR

Three electrolytic cells A,. Band Ccontaining solutions of zinc sulphate, silver nitrate and copper sulphate, respectively are connected in series. A steady current of 1 . .5 ampere was passed through them until 1.45 g of silver were deposited at the cathode of eel] B, How long did the current flow? What mass of copper and what mass of zinc were deposited in the concerned cells? (Atomic masses of Ag = 108, Zn = 65.4, Cu = (5J..5)

O.00241M ~lR:Cfi ~ ~cffi- ~[{,'Ff;(11 7.896 x 10-5 S crn " ~ 1 ~ ~ if· ~;fft. ~ tll(1Cbfll: Cf)f qftCfl·e?H ®RlL{1 ~ Q:«1R:q:; ~ ~ ~ A~ 390.5 S cm2mol-1 m m ~ ~'!l;G1"'1. i?~ ~ mrrr ?

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[ P.T.O.

, '

"ffR~-~cAl~A,B~c~~:m~,~~'~ CflfcR .~ iF f~(1;q1 W ~~, ~Onii1O& \if~ ~, ~I ~it 1.5' ~JV-1<;j{ c€! 3"jqf{qm ~qrn (FSf ~ Slq I!%d efit ~ t ~ {fCf) ~. efit 1.45 g 11m ~ B ~ ~ 1f{'~ ~~ I enftR' 3fR m ~ fep&t-~~Hr'"l'~ itffi it' R~ ~. 6Ft? (~ ~p414H, Ag = lQ8, ZIi == 65A~ en = 63.5)

29. Assign reasons for the following:

(i) The enthalpies of atomisation of transition elements are high.

(ii) The transition metals and many of their compounds act as good catalyst.

5

(iii) From element to element the actinoid contraction .is greater than the lanthanoid contraction.

(iv) The EO value for the Mn3+/Mn2+ couple is much more positive than that for Cr3+ /Cr2+.

(v) Scandium (2 = 21) does not exhibit variable oxidation states and yet it is regarded asa transition element.

OR

(a) What may be the possible oxidation states ofthetransition metals with the following d electronic configurations in the, ground state of their atoms:

3d34s2, 3d54s2 and 3d64sz. Indicate relative stability of oxidation states in eachease.

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56/1

-~

_- ~=-.....~----- - ~

I'

I C

(0) Write steps involved in thepreparation of (i) Na2Cr04 from chromite ore and (ii) Kzl\tInO 4 from pyrolusite ore.

3,2

ill)~ (Rq if ~ :wra ~ (fqi QW:'ilJ<ls ("j~:q'1 ai.r~ ~~ B~;i:H it ~ men ~ I

~,-) Mn3+/Mn2+ ~ m EO Cfif 11R C~+/cr2+~· E°llFl' cfiT 3¥t.~ ~ lFII'rl4Q;; itm % I

v) ~R·~q (2 = 21) qf{4df aQ:q4'"i ~ ~ !>IG~rd ~ i m m ~4EiSfiqol ~ lfRT ~ t'l

~ I .qit, ~m~l@ ~il d ~8tt?TRCh fuT"4lftl ~ B$filOjOI~:m ~ ~.:rrFcrn aq"tlJ<l;r ~~. ~ m ~ ~ :

(~ 1 Sfj'Il-IIS,c ~'it Na2Cr04 am: (ii) ql'4i1~(4IS.c 31m?lilt ~Mn04

if;.~~~~ R1f{9~1

561111

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[P.T.O.

30. (a) Complete the following reaction statements by giving the missing

starting material, reagent or product as required:

3· 2

,.

°2

(i) --~ 2C>=o

Zn-H20

,(¥CH2CH3 KJ\,1nO 4

(iii) V KOH~ heat) .......

(b) Describe the' following reactions:

0) Cannizaro reaction

(ii) Cross aldol condensation

OR

( a) How would you account for the following:

(i) Aldehydes are more reactive than ketones towards nucleophiles.

(ii) The boiling points of aldehydes and ketones are lower than of the corresponding acids,

(iii) The aldehydes and ketones undergo a number of addition reactions.

(b) Give chemical tests to distinguish between : (i) Acetaldehyde and benzaldehyde

(ii) Propanoneand propanol

3,2

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31) ~. '({G1:4, ~Cf)I~etl 3T~ ~, ~ ::fRr ::r ~ 1fQ;. m, ~ k1@ d ~. Rkiklfum 31Th~' fctq (urt cfit ~cffiNlIl!\ :

(i) __ °_2_.--) .2 <=>= 0

Zn-H20

(ii) <=>::=CH2--4.<=>-CHO

.. ,.' cr-...::::. CH2CH3 . KM·. ' .. !!lO.·, 4

(UI) I . . .

. . . ..-; KOH ~

)

RY f&I fisiCl ~. Cf)T quA' chi N1 Q\ : (1) &;Pl~ a 31f~

(ii) ~ l(<7%lCrl Bf.:l'90'1

RklfMRsH11 ~ enRUT'R1f@~ ;

(i) ~~q;I'~ct1 ~ -srm cAill;f1 em ~~ itwsgl~;g ~ {1f$n;q; i:Rr 51

(ii) ~g!5l~it altt. ~it;i($ crq~ ~m .~ efit ~ijl cpq m~1

(iii) QfR;~I~g 3:ftt chll1g ~ m '411IlrJ4Ch. ~ ~. ~ I

~;j:;rRrf@ (11 it ~. fum 1"2f ~ ~ {1 ffI~ FfCfi ~a:run <it f~r~11; : (i) ~RHQf?-$61~$ ~ ~";§H{:%51~:S "ij

(ii) $ilq~T., ~. shq.,T~ . .q