SO GIAO DUC - DAO TAO KY THI CHON HOC SINH GIOI CAP TINH LOP 12 THPT BINH DINH NAM HQC 2010-2011 BE CHINH THUC Ménthi: HOA HOC . Thoi gian lam bai: 180 phut (khéng ké thoi gian phat dé) Negay thi: 22/10/2010 Cau 1: (2,0 diém) (1) Cho Fe (Z=26). Viét cau hinh electron cia Fe; Fe”*; Fe™*. lon nao bén hon? Tai sao? (2) Can cit vao céu tric phan tir cua CO va N>, gidi thich vi sao CO ¢6 kha nang tao phite véi mot s8 kim loai chuyén tiép, trong khi 46 No khéng c6 tinh chat nay. CA 2: (2,0 diém) (1) Khi héa tan phén KAI(SO4)2.12H2O vao nucu: tao ra dung dich cé méi trudng axit, bazo hay trung tinh? Hay giai thich két lun 6 bing phin ting héa hoc. (2) Tinh pH cia dung dich hon hgp CHyCOOH 0,1M va CHxCOONa 0,2M. Cho biét pKa cia cartoon ia 475 Cftu 3: (2,0 diém) (1) Xét phan tng N,O, —3N,0, + : O, 6 25°C. Sau timg thai gian phn img ngudi ta do néng 46 celia NOs nur sau: of 184 2,08 | 319 91 Xée dinh tc d6 trung dinh cia phan ting trong khodng thoi gian tir 184 dén 319 giay (2) Hang sé can bang ctia phan img H, +1, ==*2HI, 6 600°C 1a 70,0. Tinh higu sudt ciia phan ting trén véi ti 1é sé mol Hz va Ip ban dau tuong ting 8 2:1. Chu 4: (2,0 diém) ‘Xéc dinh cdc chat va hoan thanh cée phan img héa hoc sau A—“+B+C+DT C+E—“9F+G 1 +H,0 A+E—9H+F+G 7 +H,0 H+H,O—SSE 14K t +6 K+ 2B F Biét A 1a mot mu6i trong dé e6 nguyén t6 Mn Cau 5: (2,0 diém) Dung dich A chita x mol HCI; dung dich B chtta y mol Na;CO3. Cho tir tir dén hét A vao B ta duge dung dich C. Hai trong dung dich C cé nhiing chat gi? Bao nhiéu mol? Chu 6: (2,0 diém) . : (2) Sap xép theo chiéu tng din tiah bazo cia amoniac, metyl amin, anilin. Giai thich. (2) Thue hign thi nghiém sau: Lay mot it propyl clorua va phenyl clorua cho vio hai 6ng nghiém, thém tigp vao hai éng nghiém mot it dung dich NaOH loang réi dun s6i ca hai 6ng nghiém. Dé ngudi va trung hoa NaOH bing dung dich HNOs va sau dé thém tiép vao dung dich AgNOs, Néu hign tuwong quan sat duge 6 timg dng nghiém: va viét cdc phuong trinh phan tmg xay raCfu 7: (2,0 diém) . (1) Viét céng thite edu tgo ciia sin phdm tao thanb ti cde phan tmg sau (ae EKON@/EtOH (3 + CH;CHO A t A CL (Cry dur Ny Ncx, 2488 | CH; (2) Hoan thinh day chuyén hod sau: MgBr cH, Cau 8: (2,0 diém) Chat X o6 cng thite sau: H CHOH Hi A HO. ‘OH H H (1) Vidt céng thie cdu tao mach he cita X. - (2) ¥ la mét epime cia X. Khi cho X va Y tac dung véi phenylhydrazin thi cho cing mt séa pham. ‘Viet céng thitc Fisher cia Y. (3) Cho X téc dung voi dung dich mudc brom duge chat X;, cho X; tac dung voi CaCO; 10i oxihéa san phdm bing H,0,/Fe(SO,)s duige chat X>. Tim céng thitc Fisher ca X va Xo. Cau 9: (2,0 diém) Cho 0,02 mol mét este phin img vita hét véi 200 ml dung dich NaOH 0,2M, sén phim thu duce gém Gt mudi va mot ancol 4éu o6 s6 mol bing s6 mol cia este vi déu c6 cfu tao mach thing. Mat khée 2,58 gam este trén phan tg vira di véi 20 ml dung dich KOH 1,5M, tha duge 3,33 gam muéi, Tim cOng thite phan tir ‘va cng thite cflu tao cia axit, ancol va este. Cau 10: (2,0 diém) Hop chat A c6 eéng thite C6Hlg0s. A tc dung voi cianol cé axit v6 co lam xtc téc cho hop chat B cé cong thie CioHieOs. A phan img véi H2O2 va axit HCOOH, tiép theo 1a H2O cho. hop chat C 06 céng thite CiHigOs. C khong c6 d6i quang. Hidro héa c6 Ni xtic tac A bién thanh D 6 céng thite CsHi9Qs. D mat muse ign thanh chat E c6 céng thitc C6Hs03. Ca hai chat E, D déu cé chét d6i quang. Xéc din cdu mic cla céc chit A, B, C, D, E va chi ra héa lép thé cia cac chat 46