2000 Vel 26 No.8 FS % 8 LG remisy & Bcengnereg MASA FAs AAR KER ERR CF a RARE OCHA ER ee ERAT RAE AE a RIL 430074) MRAM AMMA T HSS. 3256 RULE 0.257 HOMER ARR, RECS CRIA (THEIC 909) AE CY A A EE A CECH AOS OARE ARANDA ATTRA ICRA RMA RRL Bh, & THEIC MEH 0.02 mol HOLT RA St EL CRAIN EH 30 mL yn(THEIC) # n(ECH) #1 #12, ACM ME A 0.165 gy NaOH MEH 2.8 g KAM MH B~9h, SMU AM ARM RA pms HS TQ 514. 248, SERRA SAL BERR CEP) FA th BY HL SE HE PE Ti RE MEA, BL LAMAREF AF RBAMEMS SETA. AG FR A SR BO a A i «(ZH A FEL TN BE HMMA. (Eh FD ee Oe eS Ot OS SUR SUA WG AR HE (TE MR eat PP BABS PRP ORT OO ER + Pi WR HE 10 AE RR AS FE TR TR MER OOO, eR ALBEE HE — ‘i FR BL WA SS» FAN al Fae EL WT SOAR aR A BE OD EE - FAEKRALUBRAR-—HAAEM BREEDS RAK BH MRA RT ERAT Rit. HE Eo ca 0H OL cone HEI nacre —N~ ~y—c,80Ne oA, bone at :0-0— oH RIM 11672 —5425(2008)08—0012—03, 1 2 L1 RASS RRMA BEECH) SPIGA SPT » LH 2 FALE RIA A RA «= 9, 98 SE BRE THEIC) . SP LIM ALI KZ PT HARA AAP AL 5 OT I PTF TE TEA ALATA TF EP A 5 FE TR TAK OA A, a PUA RAD OR OTA TTF RAL A BORE RASH PANS SARA RITE GHKAS EMI L TT FLEA PIE LEER A, LE HA a. 1.2 BRK Rm 1 AAR. AN WC OCH Hot AA, C bal ‘0 Taras HL RRR OI Fig. 1 Synthetic route of novel nitrogen-containing heterocyclic epoxy resin RAKE RH RAK 34M W (YZZ06018) 108-04~07 RMS KITA) FA TEI I MNMOKSHA OO He /2008 EM 8 HE HAMAR TH NoOH FEMEZ AP 78°C li 1 EZ. A HE THEIC DREN BP eI RM CAH. Bisa 2 RH IP TAZ, AA OT BOE BE USCHE DRRM. REAR, Fe RL UE 5 VBR AE RY ACH UL BA Be BO A ANB 98 J 7k Be BEE LR AZ, BA 1 A SPA He FW GA Be A th HR BEY EC, are. 13 MRS RE ‘HE GB 1677 —81 fy kh Be — PAD WHR. 2 BR Ste 2.1 PAE Fe OH AY i a 9 FETE LGR 5 TUB FEL HELLER GA HEF POKERL ER RISE 2 A BE AL = 9 ZI SRI BAY BE BR RL TH A AT BF ZB PERE «Wilt A BB A at EZ AE 2S BB SY Be «FZ. BE a A AT A BEA MLA Bt 8 ME HAZ ED a OB mT. 2.2 MURR R be RR a a OH OO HF SB BFR (THEIC) 8 REE 3,H8i¢.E 1 mol THEIC RL EHH 3 mol KM PER CECH), 4 Bi HA I REF, 4K THEIC 5 TECH 0) BE AR He A it A AE RHI. 21 SHE RIKEN RARE Tab, Effect of molar ratio of THEIC to ECH om the yield and the epoxy valve of EP MTHEIC) (BCH) 166 0 1+8 L810 ded? dede RIL FRI — 26.09 20.50 22.01 25.04 22.94 Sei FEMME — 0,090 0,171 0,185 0,220 0,196 CRD PRIA 30.06 aon a2 5.07 Sei? HMM — 0.192 0,184 0,154 0.186 0.170 BEdeHF LNOOH 2. 4 (0.08 mol) .Z.Bb 50 mL, THEIC 0.02 mol, WUT AM HE 0.11 GAOL MA 6.5 by MM 2 NOH 2.6 @ (0.085 mob ZMK 30 mL,THEIC 0. 02 mol. IT MBC 0.11 gy RMA SH 2 1 TR, EMAAR AE, 4 THEIC 5 TECH fA, He 39 1 + 12 Bt EB = HR, Dy FF AR 9 ECH MA a Qi tt it (8 MARR RAS BS BORA Bie 9% ALR EE RE, ak ae AR a OY n(THEIC) | n(ECH) % 1# 12. 2.3 AAC FAL A MER Sa A a LO HE NaOH 2.6 g(0.065 mol) 2.8% 30 mL, THE- IC 0. 02 mol, ECH 0. 24 mol 5 KAY TBI 9 6.5 h 83% EE 4 AGS A A FAL TE A FP FO BH Ae 2, 22 SAAN Tah 2 Effect of catalyst dosage on the yield and the epoxy value of EP WTRM LRM 0.1 0.165) 22 eI% 27.98 32.03 32.28 a 0192 0.203 0.125 by Be 2 SR, AL FF 6 8 « SB SARRS HALEN ARM CAE HE Dye TR EAB BR. Ay WE A AL SE 5 FLEA HAC TSH AEH 0. 165 ge 2.4 NaOH FUME phe A05 BOO Hh FSB Z. HF AR ARC THEIC) fr BE FE 3,HHi¢.E 1 mol THEIC Bi 3 mol =HBZ IH UR MRAR HEN FE 3 mol RMB. (EAR BL Fe A 5 SAF PE THEI AZ BEST BE DEA RR IE RD A HR APY EZ I LRA AC AAT ‘BE 1M, » Bi » — WO A AP AB OR at a, NaOH A FE AR HE A a AT A AS HEAT. EE dh Ja Se tm A ECH, Hh ECH {2855 NaOH RM. Atk, NaOH AR tt kG RIE. hE MIC RH NaOH 2.4 g, FLL NaOH FRR BEREVA 2.4 g yke Aa 7B OHM Hm» Lh AS a IE SP AL A #£Z BE 30 mL, THEIC 0.02 mol, ECH 0.24 mol, POT 2 46 0. 165 g, Be BBE fay 7 b BY A OF 5 NaOH Fil tt HR AA i 9 HH WH RR 3, Hl 3 FTIR. NaOH AY FARES 2.8 gt SRA PRA. Blt ie HE EY NaOH Fat 2.88.GR MATAR 9 Le /2008 ERE 8 A 23 NAOH RR OI RRO OE 3 wie Tw3 Effect of NaOH dosage on the yield and the epory value of CORAL HLRES WOE Bl ZB FEA = IBZ, 3 SEU ARB THETIC) fn 3 2 ES Zo A ‘IRLO RUE TERIA TE AF 6 RTS FRI, 2.95 W018 A298 OS HBO gaan ua ah he AD BLA IBSL PEORIA 55.32% FF HMM 0.215 0.230 0.274 0.225 0.201 IHL 0. 257 AUSF ID A OIR SR LG TTT OO (2) 46 THEIC HAR 0.02 mol HEE Ha HE eee eee eee LE He UR FZ BE HE 30 mLy #EZMK 30 mL. THEIC 0.02 mol, ECH 0.24 (THEIC) + m(ECH) 3 1. 12, ALIA FH 0.165 mol. POT BBG BE 0.165 g.NeOH 2.8 g MARAE > — g NaOH AIR 2.8 go KIMURA 8~9 hy AB LE LTR A BPE AOR HCO gape. RRA. (1). Wang C'S, Berman J R.WalkerL Ls et a. Mete-bromobiphenol spony sins, Appleton a eleronk pacagig and plated exit baud]. Journal of Applied Polymer Science, 1991,43(7)« MOHHi/e = 24-26 28 0 ae R4 RAMON REE Tab 4 Etfect of reaction time on jas i321 EI? Ce] mane cee, RA eo aR A MEL. FAL. 2007. Ram 6ST BG 34(2) 46-47, 1 af eet ee. 9. somes mit), PR 2644 44,26 54.62 $5.32 54.51 aeice nan ar acento ial we 0.251 0.245 0,269 0.257 0.209 A). MAL, RAR AMAR DAR EER AF BELT. HEAR T Mb. 2007.25, 4.2225, (S} Wa $-¥, HameronL Recent developments in the chemise of GRATE MARR A EC RAM RT halogen-free flame retardant polymers[J]. Progress in Polymer RAM OLEAIEM. 4 RLALBE A y 8 h wt FRAC een IAA s MR MEO 9 h Bt IRS. PERE HE C6) MN BP AE. TER A HM YC). a 2 FB faa 202. 1100.67, BR. uk PRE TO Ty B~9 hy Preparation of A Novel Nitrogen-Containing Heterocyclic Epoxy Resin ZHOU Ji-liang, ZHANG Dac-hong, REN Hong-bo (Key Laboratory of Catalysis and Materials Science of the State Ethnic Af fairs Commission & Ministry of Education, Hubei Province» South-Central University for Nationalities, Wuhan 430074 China) Abstract; In this papers a novel nitrogen-containing heterocyclic epoxy resin with the yield of 55. 32% and the epoxy value of 0. 257 was synthesized. The specific synthetic routes were the preparation of sodium ethylate using ethanol and sodium hydroxide firstlys then the preparation of sodium salt by the reaction of sodium ethyl- ate with tris(2-hydroxyethyDisocyanurate (THEIC); finally the product prepared by the reaction of the sodium salt with epichlorohydrin (ECH) using tetrabutyl ammonium bromide as the catalyst. The effects of different technology factors on yield and epoxy value of the product were investigated, When the amount of THEIC was 0.02 mol, the optimum synthetic conditions were determined as follows; using 30 mL ethanol as solvent, (THEIC) * n(ECH) was 1 + 12, catalyst dosage was 0.165 g,NaOH dosage was 2.8 g and reaction time was 8~9h, Keywords: epoxy resin; synthesiss tris(2-hydroxyethyl)isocyanurate epichlorohydrin