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dN 1
qo ( x ) (1.1)
N dx
where
∞
∫ q ( x ) dx 1 (1.2)
0 0
Q0 ( x ) ∫ q0 ( x ) dx
x
(1.3)
0
Therefore,
dQ0 ( x )
q0 ( x ) (1.4)
dx
(a a2 ) or a1a2
1
2 1
Volume: v Equivalent Equivalent projection area Diameter of the circle having same area as
diameter diameter (Heywood diameter) projection area of particle, corresponding to
diameter obtained by light extinction
Surface: s Equivalent surface area diameter Diameter of the sphere having the same
(specific surface diameter) surface as that of a particle
(s/p)1/2
Equivalent volume diameter Diameter of the sphere having the same
(6v/p)1/3 volume as that of a particle, corresponding
to diameter obtained by (electrical sensing
zone method)
Stokes diameter Diameter of the sphere having the same
gravitational settling velocity as that
of particle obtained by gravitational or
centrifugal sedimentation and impactor
Aerodynamic diameter Diameter of the sphere having unity in
specific gravity and the same gravitational
settling velocity as that of a particle
obtained by the same methods as above
Equivalent light-scattering Diameter of the sphere giving the same
diameter intensity of light scattering as that of a
particle, obtained by the light-scattering
method
The size distributions thus defined are on a number basis. In the case of mass or volume basis,
total mass M and fractional mass dM are used instead of N and dN, respectively, and also the sub-
script value is changed from 0 to 3, so that q3(x), Q3(x) should be used. In general the subscript is
described as r, and r 0, 1, 2, 3 corresponds to number, length, area, and mass or volume basis,
respectively. Density distribution qr (x) can be transformed to another basis distribution qr(x) by
x sr qr ( x ) dx
qs ( x ) (1.5)
x sr qr ( x ) dx
∫0
When particle size distributes widely, the distributions are plotted versus ln x instead of x and
defined as
Qr ( ln x ) Qr ( x ) (1.6)
dQr ( x )
q∗r (ln x ) xqr ( x ) (1.7)
d ln x
Q r , i Qr ( xi ) Qr ( xi1 )
q r,i (1.8)
xi xi xi1
∗ Qr ,i Qr ( xi ) Qr ( xi1 )
q r ,i (1.9)
ln xi ln( xi xi1 )
Normal Distribution
The normal or Gaussian distribution function is defined as
1 ⎡ ( x x )2 ⎤
qr ( x ) exp ⎢ ⎥
50
(1.10)
⎢⎣ ⎥⎦
2
s 2p 2 s
where x 50 is the 50% or median diameter defined as Qr (x50 ) 0.5 and is the standard deviation
expressing the dispersion of the distribution.
Log-Normal Distribution
The log-normal distribution function is given by substituting ln x and ln g, respectively, for x and
in Equation 1.10 as follows:
1 ⎡ ( ln x ln x )2 ⎤
∗
q r (ln x ) exp ⎢ 50
⎥ (1.12)
ln s g ⋅ 2p ⎢⎣ 2 ln 2 s g ⎥⎦
x84.13 x
sg 50 (1.13)
x50 x15.87
If a size distribution obeys the log-normal form, the other distribution converted by Equation 1.5
also obeys the log-normal form. The geometric standard deviation of any distribution is the same
value; meanwhile, the median diameters are different but can convert each other. In the case of the
volume and number distribution the median diameters, x50,3 , x50,0, , can convert each other by Hatch’s
equation.
⎡ ⎛ x ⎞n⎤
Qr ( x ) 1 exp bx( n
) or Qr ( x ) 1 exp ⎢ ⎜ ⎟ ⎥
⎢⎣ ⎝ xe ⎠ ⎥⎦
(1.15)
where b is a constant equal to xe–n and x e is an absolute size constant defined as x e x 63.2 , that is,
xe x63.2 . n is the distribution constant expressing the dispersion of particle sizes. The density
distribution is written as
1⎛ x ⎞
n
⎡ ⎛ x ⎞n⎤
qr ( x ) nbx n1
exp(bx ) or qr ( x ) ⎜ ⎟ exp ⎢ ⎜ ⎟ ⎥
n
(1.16)
x ⎝ xe ⎠ ⎢⎣ ⎝ xe ⎠ ⎥⎦
Graphical Representation
As an example, a set of data obtained by a sieving test is illustrated in Table 1.2, and the size dis-
tributions are illustrated in Figure 1.1 with a general abscissa and Figure 1.2 with a logarithmic
abscissa.
Q3,i in Table 1.2 is plotted on log-normal and Rosin–Rammler probability paper, as shown in
Figure 1.3. Since the plots are on a straight line on a log-normal probability graph, the particle size
distribution obeys the log-normal function of which x50 1.0 mm and x84.13 2.2 mm. If we read the
two values of x15.87, x50 or x84.13, g can be calculated. From Figure 1.3 x50 1.0 mm and x84.13 2.2 mm,
then g 2.2. The dotted line in Figure 1.3 is the number distribution converted from measured volume
distribution by Hatch’s equation.
ISO 9276-1 (JIS Z 8819-1) standardizes the graphical representation of particle size analysis data.
M kr ,0 M kr3,3
x k ,r k M k ,r k k (1.17)
Mr ,0 Mr3,3
∞
M k ,r ∫ x k qr ( x ) dx (1.18)
0
∞
ln x geo, r ∫ ln x ⋅ qr ( x ) dx (1.19)
0
Although a lot of average diameters can be defined, the several listed in Table 1.3 are generally used.
If a density distribution is given as a histogram, Mk,r is calculated by the following equations.
Equation 1.18 is rewritten as follows if k –1.
xi
∫ x dx k 1 ∑ q ( x )
m m
1
M k ,r ∑ q r ,i k
r ,i
k1
i xik11
i1 xi1 i1
100
80 Q3
q* [%], q* [%], Q [%]
3
60
q
3
40
3
q
20 3
0
0.1 1 10
x [mm]
FIGURE 1.1 A graphical representation of particle size distribution with a linear abscissa.
If k –1,
x
m m
ln i
xi xi1
M1,r ∑ q r ,i ln ∑ Qr ,i (1.21)
i1 xi1 i1 xi xi1
.
m xi m
q r ,i m
Qr ,i
ln x geo, r ∑ q r ,i ∫ ln xdx ∑ x x ∑ (1.22)
i1 xi1 i1 i i1 i1 ( xi xi1 )2
The values of the average diameters listed in Table 1.3 can be calculated from the data in Table 1.2.
The calculation results are illustrated in Table 1.3.
The spread of a size distribution is represented by its variance, which represents the square of the
standard deviation, . The variance, 2 , of a qr (x) -distribution is defined as
( x x ) q ( x)dx M ( )
2
2 ∫
2
100
Q3
80
q* [%mm–1], q* [%mm–1], Q3 [%]
q3
60
3
40
3
20
q3
0
0 2 4 6 8 10
x [mm]
From a histogram,
2
1⎡ m ⎤ 1⎡ m ⎤
( ) ( )
⎢ ∑ q r ,i x 3i x 3i1 ⎥ ⎢ ∑ q r ,i x i2 x i21 ⎥
2
The standard deviation of the particle sizes illustrated in Table 1.2 is calculated as 1.29 mm by
Equation 1.24.
ISO 9276–2 (JIS Z 8819-2) standardizes the calculation of average particle sizes.
Notation
i number of the size class with upper particle size xi
k power of x
m total number of size classes
Mk,r complete kth moment of a qr (x) -distribution
n distribution constant
99.9 99.9
99 99
90 90
70 70
50 50
30 30
20
Q0.Q3 [%]
20
Q3 [%]
10 10
5 5
1 1
0.1 0.1
0.01 0.1 1 10
x [mm]
N particle number
qr(x) density distribution
qr qr(x)
qr*(ln x) density distribution in a representation with a logarithmic abscissa
q r* qr*(x)
q–r,i average density distribution of the class Δ xi , histogram
q–r,i average density distribution of the class Δ In xi, histogram
Qr(x) cumulative distribution
Qr Qr(x)
ΔQr,i Qr(xi)Qr(xi1)
x particle size, diameter of a sphere
xe absolute size constant
xi upper size of a particle size interval
xi1 lower size of a particle size interval
Δ xi xixi1, width of the particle size interval
x15.87, x50, x63.2, x84.13 defined as Qr(x15.87) 0.1587,Qr(x50) 0.5 ,Qr(x63.2) 0.632 Qr(x84.13) 0.8413
x50,3 median particle size of a cumulative volume distribution
x50,0 median particle size of a cumulative number distribution
r, s type of quantity of a distribution, r, s 0, 1, 2, 3
s standard deviation
sg geometrical standard deviation of log-normal distribution