cng n tp hc phn: Ha hc phn tch 2

CNG N TP HA HC PHN TCH 2

(Dnh cho sinh vin lp K1 H SP Ha hc)
Cu 1: Chun 25 ml dung dch NH3 nu dng ch th Metyl (pT = 5) th ht 12,3 ml HCl 0,1M.
a) Tnh nng chnh xc ca NH3
b) Tnh th tch ca HCl (ml) phi dng nu mun kt thc chun pH = 4.
c) Dng ch th c pT = 6 c c khng?
d) Tnh pH dung dch sau khi thm 12; 12,6 ml dung dch HCl. Cho K NH = 10-4,75.
Cu 2: Chun 25 ml dung dch HA dng ch th pT = 8 ht 12,5 ml dung dch NaOH 0,025M.
a) Tnh chnh xc nng ca HA.
b) Tnh pH ca dung dch sau khi thm 12ml; 13ml dung dch NaOH.
c) Nu dng ch th c pT = 6 c c khng?
Tnh cho 2 trng hp:
+ HA l HCl
+ HA l CH3COOH c pKA = 4,75.
Cu 3: Chun 25 ml dung dch B c pT = 6 ht 17,5 ml dung dch HCl 0,05M.
a) Tnh chnh xc nng ca B.
b) C th chn nhng cht ch th c khong i mu nm trong khong pH no lm ch th
cho cc trng hp chun trn vi q = 0,2%. Tnh cho 2 trng hp: B l NaOH ; B l KCN.
c) Nu dng PP lm ch th (pT = 9) cho trng hp B l KCN c c khng ? KHCN = 10-9,25.
Cu 4: 1) Lp cng thc tnh q khi chun dung dch H3A n nc 1, 2 bng dung dch NaOH.
2) Chun 25 ml dung dch H3PO4 dng PP (pT = 9) ht 23,4 ml dung dch NaOH 0,05M.
a) Tnh chnh xc nng H3PO4.
b) Nu dng MO (pT = 4) th th tch dung dch NaOH cn dng l bao nhiu?
Bit H3PO4 c: pK1 = 2,15; pK2 = 7,21; pK3 = 12,32.
Cu 5: 1) Lp cng thc tnh q khi chun Na2CO3 n nc 1, nc 2 bng dung dch HCl.
2) Chun 25 ml dung dch Na2CO3 dng PP (pT = 9) ht 8,2 ml dung dch HCl 0,05M.
a) Tnh chnh xc nng ca Na2CO3.
b) Nu dng MO (pT = 4) th th tch dung dch HCl l bao nhiu? (pK1 = 6,35; pK2 = 10,33).
Cu 6: 1) Thit lp phng trnh chun dung dch n axit yu bng baz mnh.
2) Chun 25 ml dung dch CH3COOH ht 12,5 ml dung dch NaOH 0,05M. Tnh:
a) pH dung dch sau khi thm 12ml, 13 ml dung dch NaOH.
b) Sai s nu kt thc chun pH = 10.
c) Th tch dung dch NaOH nu kt thc chun pH = 9. K CH COOH = 10-4,75.
Cu 7: 1) Thit lp phng trnh chun dung dch n baz yu bng axit mnh.
2) Chun 25 ml dung dch NH3 ht 12,5 ml dung dch HCl 0,05M. Tnh:
a) pH ca dung dch sau khi thm: 12 ml; 13 ml dung dch HCl.
b) Tnh sai s chun nu kt thc pH = 5.
c) Tnh th tch dung dch HCl cn dng nu kt thc chun pH = 4. K NH = 10-4,75.
Cu 8: Nu cc phng php chn cht ch th trong php chun axit, baz? p dng xem
xt c th dng cht ch th no: MO (pT = 4), P (pT = 7), PP (pT = 8) lm ch th cho cc php
chun sau:
a) Chun NaOH 0,01M bng HCl cng nng .
b) Chun NH3 0,01M bng HCl cng nng . q = 0,1%.
Cu 9: Chun 25 ml dung dch HA (KA = 10-5) bng dung dch NaOH 0,05M. Khi thm 20 ml
NaOH th pH ca dung dch l 5,0.
a) Tnh nng HA.
b) Tnh pH ca dung dch sau khi thm 39 ml; 41 ml dung dch NaOH.
c) C th dng PP lm ch th hay khng
d) Nu HA l HCl th sai s chun l bao nhiu khi s dng PP lm ch th.
Cu 10: 1) Bc thy chun trong phng php chun axit-baz l g? N ph thuc vo
nhng yu t no?
3

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 cng n tp hc phn: Ha hc phn tch 2

2) Chun 50 ml dung dch NH3 0,03M bng HCl 0,06M n mu hng ca MO (pT = 4).
a) Tnh sai s chun .
b) Tnh th tch dung dch HCl dng?
c) Tnh pH ca dung dch sau khi thm 24,5; 25,5 ml dung dch HCl.
Cu 11: Chun 25 ml CdSO4 bng trilonB 0,1M pH = 10 c thit lp bi h m NH3 +
NH4Cl trong C NH = 0,1M. Khi i mu ch th ETOO ht 10 ml trilonB. Nng Cd2+ ti
im tng ng c thuc khong i mu ca ch th hay khng? Cho:
lg CdY = 16,6 ; lg Cd ( NH ) = 6,6 ; lg CdIn = 12,7 ; pK NH = 9,25 ; ETOO: pK2 = 6,5; pK3 = 11,6;
3

2+
3 4

+
4

H4Y: pK1 = 2; pK2 = 2,67; pK3 = 6,16; pK4 = 10,26;

Cu 12: Chun 50 ml dung dch cha Mg2+ ht 20 ml EDTA 0,1M. lm i mu ETOO
pH = 10 lc ny c 10% ch th dng t do. Tnh chnh xc nng ca Mg2+.
Cho: lg MgdY = 8,7 ; lg MgIn = 7 ; * Mg (OH ) = 10 12 ,8 ; ETOO: pK2 = 6,5; pK3 = 11,6; H4Y: pK1 = 2;
2

pK2 = 2,67; pK3 = 6,16; pK4 = 10,26;

Cu 13: Chun 25 ml dung dch cha Cu2+ bng EDTA 0,02M trong dung dch m NH3 + NH4Cl,
C NH = 1M, C NH Cl = 1,8M. Khi i mu ch th Murexit ht 18,75 ml EDTA. Hi nng ca
Cu2+ ti im tng ng c thuc khong i mu ca ch th khng?
Cho: lg CuY = 18,8 ; lg Cu ( NH ) = 12,03 ; lg CuIn = 17,9 ; pK NH = 9,25 ; Murexit: pK2 = 9,2; pK3 = 10,9;
3

2+
3 4

+
4

H4Y: pK1 = 2; pK2 = 2,67; pK3 = 6,16; pK4 = 10,26;

Cu 14: Murexit (H4In-): pK1 = 0; pK2 = 9,2; pK3 = 10,9. Mu ca cc dng cht ch th t do l:
H4In-: tm; H3In2-: tm; H2In3-: xanh tm. Phc ca Ca2+ vi ch th c mu v hng s bn l
105. Chun Ca2+ bng ETDA pH = 12.
a) Tnh khong i mu ca ch th.
b) Gii thch s i mu im cui ca chun ? C th thc hin php chun trn
pH = 9 c khng? Cho *Ca ( OH ) = 10 11, 6 ; lg CadY = 10,57
Cu 15: Chun 25 ml Ni2+ bng ETDA 0,01M dng murexit lm ch th trong dung dch m
NH3 + NH4Cl vi tng nng l 0,5M, pH = 10 ht 50 ml ETDA. im cui chun , 10%
ch th dng t do. Tnh chnh xc nng ca Ni2+. Bit: lg NiY = 18,62 ; lg Cu ( NH ) = 8 ;
+

2+
3 5

lg NiIn3 = 11,3 ; pK NH + = 9,25 ; Murexit: pK2 = 9,2; pK3 = 10,9; H4Y: pK1 = 2; pK2 = 2,67; pK3 = 6,16;
4

pK4 = 10,26.
Cu 16: Chun 25 ml dung dch Ca2+ ht 15 ml EDTA 0,05M lm i mu ch th
canmagit pH = 12. Ti thi im ny 90% ch th dng t do. Tnh chnh xc nng Ca2+,
bit: Canmagit: H2In- (), HIn2- (xanh), In3- (da cam). Phc ca ch th vi Ca2+ c mu vng
v lg CaY = 10,6 ; lg CaIn = 6,1 ; *Ca ( OH ) = 10 12 ,6 ; pK2 = 8,1; pK3 = 12,4; H4Y: pK1 = 2; pK2 = 2,67;
pK3 = 6,16; pK4 = 10,26;
Cu 17: Chun 25 ml dung dch Ca2+ ht 15 ml EDTA 0,05M lm i mu ch th Murexit
pH = 12. Ti thi im ny c 90% lng ch th tn ti dng t do. Tnh chnh xc nng
ca Ca2+. Bit lg CaY = 10,6 ; lg CaIn = 5 ; *Ca ( OH ) = 10 12 ,6 ; pK2 = 9,2; pK3 = 10,5; H4Y: pK1 = 2;
pK2 = 2,67; pK3 = 6,16; pK4 = 10,26;
Cu 18: Chun 50 ml Co2+ 0,02M bng EDTA 0,04M trong dung dch m NH3 + NH4Cl c
pH = 9 v C NH = 0,1M. Tnh pCo sau khi thm 20 ml; 25ml; 26 ml EDTA. Cho lg CoY = 16,2 ;
2

lg Co ( NH

2+
3 )6

= 4,4 ;

Co ( OH ) +

= 10

12 , 6

; pK NH = 9,25 ; H4Y: pK1 = 2; pK2 = 2,67; pK3 = 6,16; pK4 =

+
4

10,26;
Cu 19: Chun 50 ml Pb2+ 0,01M bng Complexon III 0,02M pH = 5 thit lp bng h m
axetat ( C CH COOH = 0,1M). Tnh pPb sau khi thm 20; 25; 26 ml Complexon III. Cho: lg PbY = 18,3 ;
2

lg Pb (CH CCO )+ = 2,52 ; * Pb (OH )+ = 10 6 ,18 ; pK CH COOH = 4,75 ; H4Y: pK1 = 2; pK2 = 2,67; pK3 = 6,16;
3

pK4 = 10,26.
Minh.leduc@htu.edu.vn, T L Ha, khoa S phm T nhin, trng i hc H Tnh

 cng n tp hc phn: Ha hc phn tch 2

Cu 20: Chun 50 ml Zn2+ bng Complexon III 0,1M pH = 9 thit lp bi h m NH3 + NH4Cl:
C NH = 0,1M . Khi i mu ch th ETOO ht 25 ml Complexon III. Hi nng ca Zn2+ ti im
+
4

tng ng c thuc khong i mu ca ch th hay khng? Bit: lg ZnY = 16,5 ; lg Zn ( NH ) = 8,7 ;

2

2+
3 4

lg ZnIn = 12,9 ; ETOO: pK2 = 6,5; pK3 = 11,6; H4Y: pK1 = 2; pK2 = 2,67; pK3 = 6,16; pK4 = 10,26;
pK NH + = 9,25 .
4

Cu 21: Cho a gam M tc dng vi KI d trong H2SO4 2N. Chun I2 gii phng ra ht 16,25
ml dung dch Na2S2O3 c chun theo iot TNa S O / I = 0,0127(g / ml) .
a) Tnh s gam M dng trong cc trng hp: M l K2Cr2O7; M l KMnO4.
b) Trong th nghim trn khng cho H2SO4 c c khng? Ti sao?
Cu 22: Thm lng d KI v HCl vo 0,12 gam mui M, chun I2 thot ra ht 22,85 ml dung
dch Na2S2O3.
a) Tnh CN(Na2S2O3) khi: M l K2Cr2O7; M l KMnO4.
b) Trong hai cht , cht no dng cho php chun ha Na2S2O3 tt hn? V sao?
Cu 23: C 100 ml dung dch hn hp Fe2+ v TiO2+.
+ Ly 20 ml dung dch cho qua ct kh Zn, dung dch nhn c em chun bng
KMnO4 c TKMnO / H C O = 2,25.10 3 (g / ml) ht 30,3 ml.
+ Ly 20 ml dung dch qua ct kh Ag, dung dch thu c em chun bng
K2Cr2O7 0,005M ht 20,3 ml.
Tnh khi lng Fe3+, TiO2+ trong dung dch ban u?
Cu 24: xc nh Fe, Cu trong hn hp ngi ta ch ha v thu c 100 ml dung dch cha
Cu2+ v Fe3+ (dung dch A).
+ Ly 20 ml dung dch A, thm vo dung dch m NH3 + NH4Cl, lc b kt ta, nc lc
em axit ha n mi trng axit yu, thm vo lng KI d, chun I2 thot ra bng Na2S2O3
0,05M th ht 18,5 ml.
+ Ly 20 ml A cho qua ct kh Zn, dung dch thu c cho vo bnh cha 50 ml dung
dch KMnO4 0,02M, lng d dung dch KMnO4 chun bng Fe2+ 0,05M ht 16,5 ml.
Tnh khi lng Cu, Fe trong hn hp ban u?
Cu 25: Ha tan 0,2596 gam mu cha FeC2O4 trong axit. Chun dung dch ny cn 44,77 ml
dung dch KMnO4 0,1156N.
a) Tnh phn trm khi lng FeC2O4 trong mu.
b) Vit phng trnh phn ng khi thay KMnO4 bng K2Cr2O7.
Cu 26: Ha tan 0,24 gam KMnO4 v K2Cr2O7 trong dung dch KI khi c H2SO4 2N. Chun I2
thot ra ht 60 ml Na2S2O3 c TNa S O / I = 0,0127(g / ml) . Tnh phn trm khi lng Cr, Mn trong
hn hp?
Cu 27: Ha tan 0,3085 gam mu x cha st trong HCl, kh Fe3+ thnh Fe2+ bng SnCl2. Chun
Fe2+ ht 20,94 ml KMnO4 0,0153M.
a) Tnh phn trm khi lng Fe theo Fe2O3.
b) Tnh th tch K2Cr2O7 0,025M cn chun ht Fe2+ ni trn.
Cu 28: Ha tan 1 gam CaCO3 trong axit, lm kt ta ht Ca2+ dng CaC2O4. Ch ha CaC2O4
vi 25 ml KMnO4, TKMnO / H C O = 2,25.10 3 (g / ml) . KMnO4 d phn ng ht vi 9,37 ml Fe2+ 0,1M.
Tnh phn trm khi lng Ca trong loi vi trn?
Cu 29: Chun 50 ml Sn2+ 0,01M bng FeCl3 0,1M trong HCl 1M.
a) Tnh E khi thm 9; 10; 10,05 ml FeCl3.
o
o
b) Tnh q nu EC = 0,45V. Cho: E Fe
= 0,77V; E Sn
= 0,138V
/ Fe
/ Sn
2+
Cu 30: Chun 20 ml Fe 0,1M bng Ce(SO4)2 0,2M.
a) Tnh E sau khi thm 9,8; 10,2 ml Ce4+.
b) Tnh q khi chun n i mu ch th Feroin sang xanh ( E In (ox ) / In ( kh ) = 1,06V , dng
2 2

2 2

2 2

2 2

3+

2+

o
oxi ha dng kh ch trao i 1 electron). Cho: E Fe

4+

3+

/ Fe 2+

2+

= 0,77V; E oCe 4+ / Ce 2+ = 1,44V

Minh.leduc@htu.edu.vn, T L Ha, khoa S phm T nhin, trng i hc H Tnh

 cng n tp hc phn: Ha hc phn tch 2

Cu 31: Tnh tan ca CaC2O4 trong dung dch c pH = 4, bit H2C2O4 c: pK1 = 1,25; pK2 = 4,27.
T = 2,3.10-9.
Cu 32: Tnh tan ca Ag2S trong nc. Bit TAg2S = 6,3.10-50; H2S c: pK1 = 7; pK2 = 15.; pH = 7.
Cu 33:.Tnh tan ca CuS trong nc, bit TCuS = 6,3.10-36, hng s bn ca phc gia Cu2+
v OH- ln lt l: 1 = 107; 2 = 1013,68; 3 = 1017; 4 = 1018,5; pH = 7.
Cu 34: Tnh sai s khi chun dung dch NaCl 0,1M bng dung dch chun AgNO3 cng nng
nu kt thc chun khi pAg = 4,3. TAgCl = 10-10.
Cu 35: Chun dung dch NaCl 0,1M bng dung dch AgNO3 0,1M. Mun sai s chun
khng vt qu 0,2% th phi kt thc chun trong khong pAg no? Cho TAgCl = 10-10.
Cu 36: Tnh sai s v rt ra nhn xt khi chun dung dch CH3COOH 0,1M bng dung dch
NaOH 0,1M dng cc ch th c phn t bng:
a) 4,0.
b) 8,0.
c) 9,0.
Cu 37: Cn 1,25 gam axit yu HA, ha tan trong nc thnh 50 ml dung dch A. Chun 50
ml A bng dung dch NaOH 0,09M. Bit khi thm vo A 8,24 ml NaOH th pH ca dung dch
bng 4,3 v khi thm vo 41,2 ml NaOH th t c im tng ng. Tnh khi lng phn
t ca HA v pKA ca axit ?
Cu 38: Gi s chun axit yu HA 0,1M bng dung dch chun NaOH 0,1M vi cht ch th
c phn t = 7. Nu mun sai s khng vt qu 0,1% th hng s axit KA ca n phi c gi tr
nh th no?
Cu 39: Chun 25 ml dung dch NH3 dng metyl (phn t = 5) lm ch th th ht 20 ml
dung dch HCl 0,1M.
a) Tnh chnh xc nng ca dung dch NH3.
b) C th dng MO (pT = 4) lm ch th cho php chun trn c khng? K NH = 10-4,75, sai s
3

cho php l 0,2%.

Cu 40: Cn thm bao nhiu ml HCl 0,2M vo 50 ml NH3 0,1M :
a) pHC = 9;
b) pHC = 7;
c) pHC = 4.
Cu 41: nh gi sai s khi dng EDTA 0,1M chun Zn2+ 0,001M pH = 9 c thit lp
bi h m NH3 + NH4Cl c tng nng 0,1M. Kt thc chun khi 90% ch th ETOO tn
ti dng t do. Bit: lg ZnY = 16,5 ; lg Zn ( NH ) = 2,21 ; lg Zn ( NH ) = 4,4 ; lg Zn ( NH ) = 6,76 ;
2

2+

2+
3 2

lg Zn ( NH

2+
3 )4

2+
3 3

= 8,79 ; lg ZnIn = 12,9 ; * Zn ( OH )+ = 10 8,96 ; * Zn ( OH )3+ = 10 28, 4 ; * Zn ( OH )4+ = 10 40 ,5 ; ETOO:

pK2 = 6,5; pK3 = 11,6; H4Y: pK1 = 2; pK2 = 2,67; pK3 = 6,16; pK4 = 10,26; pK NH = 9,25 .
+
4

Cu 42: Chun 100 ml Zn2+ 0,01M bng EDTA 0,02M pH = 9 s dng dung dch m
NH3 + NH4Cl vi tng nng l 1,8M. Tnh bc nhy chun pZn khi sai s q = 0,1%.
Bit: lg ZnY = 16,5 ; lg Zn ( NH ) = 2,21 ; lg Zn ( NH ) = 4,4 ; lg Zn ( NH ) = 6,76 ; lg Zn ( NH ) = 8,79 ;
2

2+

2+
3 2

2+
3 3

2+
3 4

H4Y: pK1 = 2; pK2 = 2,67; pK3 = 6,16; pK4 = 10,26; pK NH = 9,25 .

+
4

2+

Cu 43: Chun Ca 0,025M bng EDTA 0,02M pH = 12. Tnh nng Ca2+ ti im
tng ng. Cho: lg CaY = 10,6 ; H4Y: pK1 = 2; pK2 = 2,67; pK3 = 6,16; pK4 = 10,26.
Cu 44: Tnh bc nhy chun st tng ng khi chun dung dch Fe3+ pH = 2 bng
EDTA cng nng :
a) 0,2M.
b) 0,02M.
c) 0,002M.
Cu 45: Tnh pFe trong qu trnh chun dung dch Fe3+ 0,02M bng EDTA cng nng ,
pH = 2 khng i, p = 0,5; 0,998; 1; 1,002; 1,5. Cho bit: lg FeY = 25,1 ; H4Y: pK1 = 2; pK2 = 2,67.
2

Minh.leduc@htu.edu.vn, T L Ha, khoa S phm T nhin, trng i hc H Tnh