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Definitions of The SI Base Units: Metre
Definitions of The SI Base Units: Metre
231
Appendix I
Metre (m): The metre is the length of path travelled by light in vacuum during a time
interval of 1/299 792 458 of a second (17th CGPM, 1983).
Kilogram (kg): The kilogram is the unit of mass; it is equal to the mass of the
international prototype of the kilogram (3rd CGPM, 1901).
Second (s): The second is the duration of 9192631770 periods of the radiation
corresponding to the transition between the two hyperfine levels of the ground state
of the caesium-133 atom (13th CGPM, 1967).
Ampere (A): The ampere is that constant current which, if maintained in two straight
parallel conductors of infinite length, of negligible circular cross-section, and placed
1 metre apart in vacuum, would produce between these conductors a force equal to
2 10-7 Newton per metre of length (9th CGPM, 1948).
Kelvin (K): The kelvin, unit of thermodynamic temperature, is the fraction 1/273.16
of the thermodynamic temperature of the triple point of water (13th CGPM, 1967).
Mole (mol): The mole is the amount of substance of a system which contains as
many elementary entities as there are atoms in 0.012 kilogram of carbon-12. When
the mole is used, the elementary entities must be specified and may be atoms,
molecules, ions, electrons, other particles, or specified groups of such particles
(14th CGPM, 1971).
Candela (cd): The candela is the luminous intensity, in a given direction, of a source
that emits monochromatic radiation of frequency 540 1012 hertz and that has a
radiant intensity in that direction of (1/683) watt per steradian (16th CGPM, 1979).
(The symbols listed here are internationally agreed and should not be changed in
other languages or scripts).
231
C:\ChemistryXI\Appendic\Appenxix.pmd 19.1.6
232
CHEMISTRY
Appendix II
Element
Actinium
Aluminium
Americium
Antimony
Argon
Arsenic
Astatine
Barium
Berkelium
Beryllium
Bismuth
Bohrium
Boron
Bromine
Cadmium
Caesium
Calcium
Californium
Carbon
Cerium
Chlorine
Chromium
Cobalt
Copper
Curium
Dubnium
Dysprosium
Einsteinium
Erbium
Europium
Fermium
Fluorine
Francium
Gadolinium
Gallium
Germanium
Gold
Hafnium
Hassium
Helium
Holmium
Hydrogen
Indium
Iodine
Iridium
Iron
Krypton
Lanthanum
Lawrencium
Lead
Lithium
Lutetium
Magnesium
Manganese
Meitneium
Mendelevium
Symbol
Atomic
Number
Molar
mass/
(g mol1)
Element
Ac
Al
Am
Sb
Ar
As
At
Ba
Bk
Be
Bi
Bh
B
Br
Cd
Cs
Ca
Cf
C
Ce
Cl
Cr
Co
Cu
Cm
Db
Dy
Es
Er
Eu
Fm
F
Fr
Gd
Ga
Ge
Au
Hf
Hs
He
Ho
H
In
I
Ir
Fe
Kr
La
Lr
Pb
Li
Lu
Mg
Mn
Mt
Md
89
13
95
51
18
33
85
56
97
4
83
107
5
35
48
55
20
98
6
58
17
24
27
29
96
105
66
99
68
63
100
9
87
64
31
32
79
72
108
2
67
1
49
53
77
26
36
57
103
82
3
71
12
25
109
101
227.03
26.98
(243)
121.75
39.95
74.92
210
137.34
(247)
9.01
208.98
(264)
10.81
79.91
112.40
132.91
40.08
251.08
12.01
140.12
35.45
52.00
58.93
63.54
247.07
(263)
162.50
(252)
167.26
151.96
(257.10)
19.00
(223)
157.25
69.72
72.61
196.97
178.49
(269)
4.00
164.93
1.0079
114.82
126.90
192.2
55.85
83.80
138.91
(262.1)
207.19
6.94
174.96
24.31
54.94
(268)
258.10
Mercury
Molybdenum
Neodymium
Neon
Neptunium
Nickel
Niobium
Nitrogen
Nobelium
Osmium
Oxygen
Palladium
Phosphorus
Platinum
Plutonium
Polonium
Potassium
Praseodymium
Promethium
Protactinium
Radium
Radon
Rhenium
Rhodium
Rubidium
Ruthenium
Rutherfordium
Samarium
Scandium
Seaborgium
Selenium
Silicon
Silver
Sodium
Strontium
Sulphur
Tantalum
Technetium
Tellurium
Terbium
Thallium
Thorium
Thulium
Tin
Titanium
Tungsten
Ununbium
Ununnilium
Unununium
Uranium
Vanadium
Xenon
Ytterbium
Yttrium
Zinc
Zirconium
Symbol
Atomic
Number
Hg
Mo
Nd
Ne
Np
Ni
Nb
N
No
Os
O
Pd
P
Pt
Pu
Po
K
Pr
Pm
Pa
Ra
Rn
Re
Rh
Rb
Ru
Rf
Sm
Sc
Sg
Se
Si
Ag
Na
Sr
S
Ta
Tc
Te
Tb
Tl
Th
Tm
Sn
Ti
W
Uub
Uun
Uuu
U
V
Xe
Yb
Y
Zn
Zr
80
42
60
10
93
28
41
7
102
76
8
46
15
78
94
84
19
59
61
91
88
86
75
45
37
44
104
62
21
106
34
14
47
11
38
16
73
43
52
65
81
90
69
50
22
74
112
110
111
92
23
54
70
39
30
40
The value given in parenthesis is the molar mass of the isotope of largest known half-life.
232
C:\ChemistryXI\Appendic\Appenxix.pmd 19.1.6
Molar
mass/
(g mol1)
200.59
95.94
144.24
20.18
(237.05)
58.71
92.91
14.0067
(259)
190.2
16.00
106.4
30.97
195.09
(244)
210
39.10
140.91
(145)
231.04
(226)
(222)
186.2
102.91
85.47
101.07
(261)
150.35
44.96
(266)
78.96
28.08
107.87
22.99
87.62
32.06
180.95
(98.91)
127.60
158.92
204.37
232.04
168.93
118.69
47.88
183.85
(277)
(269)
(272)
238.03
50.94
131.30
173.04
88.91
65.37
91.22
APPENDIX
233
Appendix III
A. Specific and Molar Heat Capacities for Some Substances at 298 K and
one Atmospheric Pressure
Substance
0.720
4.184
2.06
0.797
0.360
4.70
2.46
2.42
2.06
0.861
0.5980
0.817
1.03
0.477
0.473
0.460
0.385
0.902
0.128
0.720
20.8
75.4
35.1
29.1
29.1
79.9
113.16
152.52
37.08
132.59
72.35
39.2
20.7
33.8
75.6
25.1
24.7
24.35
25.2
8.65
air
water (liquid)
ammonia (gas)
hydrogen chloride
hydrogen bromide
ammonia (liquid)
ethyl alcohol (liquid)
ethylene glycol (liquid)
water (solid)
carbon tetrachloride (liquid)
chlorofluorocarbon (CCl F )
2 2
ozone
neon
chlorine
bromine
iron
copper
aluminium
gold
graphite
B.
Gas
Monatomic*
helium
argon
iodine
mercury
Diatomic
hydrogen
oxygen
nitrogen
hydrogen chloride
carbon monoxide
Triatomic
nitrous oxide
carbon dioxide
Polyatomic
ethane
Cp
Cv
C p - Cv
Cp / Cv
20.9
20.8
20.9
20.8
12.8
12.5
12.6
12.5
8.28
8.33
8.37
8.33
1.63
1.66
1.66
1.66
28.6
29.1
29.0
29.6
29.0
20.2
20.8
20.7
21.0
21.0
8.33
8.33
8.30
8.60
8.00
1.41
1.39
1.40
1.39
1.41
39.0
37.5
30.5
29.0
8.50
8.50
1.28
1.29
53.2
44.6
8.60
1.19
233
C:\ChemistryXI\Appendic\Appenxix.pmd 19.1.6
234
CHEMISTRY
Appendix IV
Physical Constants
Quantity
Acceleration of gravity
Atomic mass unit (1/12
the mass of 12C atom)
Avogadro constant
Bohr radius
g
amu
or u
NA
ao
Boltzmann constant
Charge-to-mass
ratio of electron
Electronic charge
k
e/m
e
me
Faraday constant
Gas constant
980.6 cm/s
1.6606 10-24 g
9.806 m/s
1.6606 10-27 kg
6.022 1023
particles/mol
0.52918 C
5.2918 10-9 cm
1.3807 10-16 erg/K
1.7588 l08 coulomb/g
6.022 1023
particles/mol
5.2918 10-11 m
0.8206
1.987
L atm
mol K
cal
mol K
Vm
22.710981 L/mol
mn
Planck constant
Proton rest mass
h
mp
Rydberg constant
1.67495 10-24 g
1.008665 u
6.6262 10-27 ergs
1.6726 10-24 g
1.007277 u
3.289 1015 cycles/s
2.1799 10-11 erg
2.9979 1010 cm/s
(186,281 miles/second)
Speed of light
(in a vacuum)
SI Units
8.3145
6.6262 10-34 J s
1.6726 10-27 kg
1.0974 107 m-1
2.1799 10-18 J
2.9979 108 m/s
e = 2.71828
C:\ChemistryXI\Appendic\Appenxix.pmd 19.1.6
mol K
234
8.3145 J/mol.K
= 3.1416
ln X = 2.303 log X
kPa dm
APPENDIX
235
Appendix V
C =
F 32
1.8
* Force: 1 newton (N) = 1 kg m/s2, i.e.,the force that, when applied for 1 second, gives a
1-kilogram mass a velocity of 1 metre per second.
** The amount of heat required to raise the temperature of one gram of water from 14.50C to
15.50C.
Note that the other units are per particle and must be multiplied by 6.022 1023 to be strictly
comparable.
235
C:\ChemistryXI\Appendic\Appenxix.pmd 19.1.6
236
CHEMISTRY
Appendix VI
Enthalpy of formation,
fHJ/ (kJ mol1)
Entropy,*
SJ/(J K1 mol1)
Aluminium
Al(s)
Al3+(aq)
Al2O3(s)
Al(OH)3(s)
AlCl3(s)
0
524.7
1675.7
1276
704.2
0
481.2
1582.3
628.8
28.33
321.7
50.92
110.67
Antimony
SbH3(g)
SbCl3(g)
SbCl5(g)
145.11
313.8
394.34
147.75
301.2
334.29
232.78
337.80
401.94
0
169.0
888.14
0
168.6
648.41
0
537.64
553.5
1216.3
1214.78
0
560.77
525.1
1137.6
1088.59
62.8
9.6
70.42
112.1
47.3
0
1272.8
1137.0
0
1193.7
1120.3
5.86
53.97
254.12
Arsenic
As(s), gray
As2S3(s)
AsO43(aq)
35.1
163.6
162.8
Barium
Ba(s)
Ba2+(aq)
BaO(s)
BaCO3(s)
BaCO3(aq)
Boron
B(s)
B2O3(s)
BF3(g)
Bromine
Br2(l)
Br2(g)
Br(g)
Br(aq)
HBr(g)
BrF3(g)
0
30.91
111.88
121.55
36.40
255.60
0
3.11
82.40
103.96
53.45
229.43
152.23
245.46
175.02
82.4
198.70
292.53
0
178.2
542.83
0
144.3
553.58
41.42
154.88
53.1
Calcium
Ca(s)
Ca(g)
Ca2+(aq)
(continued)
236
C:\ChemistryXI\Appendic\Appenxix.pmd 19.1.6
APPENDIX
237
Substance
Enthalpy of formation,
fHJ/ (kJ mol1)
Entropy,*
SJ/(J K1 mol1)
Calcium (continued)
CaO(s)
Ca(OH)2(s)
Ca(OH)2(aq)
CaCO3(s), calcite
CaCO3(s), aragonite
CaCO3(aq)
CaF2(s)
CaF2(aq)
CaCl2(s)
CaCl2(aq)
CaBr2(s)
CaC2(s)
CaS(s)
CaSO4(s)
CaSO4(aq)
635.09
986.09
1002.82
1206.92
1207.1
1219.97
1219.6
1208.09
795.8
877.1
682.8
59.8
482.4
1434.11
1452.10
604.03
898.49
868.07
1128.8
1127.8
1081.39
1167.3
1111.15
748.1
816.0
663.6
64.9
477.4
1321.79
1298.10
39.75
83.39
74.5
92.9
88.7
110.0
68.87
80.8
104.6
59.8
130
69.96
56.5
106.7
33.1
Carbon**
C(s), graphite
C(s), diamond
C(g)
CO(g)
CO2(g)
CO32(aq)
CCl4(l)
CS2(l)
HCN(g)
HCN(l)
0
1.895
716.68
110.53
393.51
677.14
135.44
89.70
135.1
108.87
0
2.900
671.26
137.17
394.36
527.81
65.21
65.27
124.7
124.97
5.740
2.377
158.10
197.67
213.74
56.9
216.40
151.34
201.78
112.84
0
696.2
537.2
0
672.0
503.8
0
121.68
167.16
92.31
167.16
0
105.68
131.23
95.30
131.23
223.07
165.20
56.5
186.91
56.5
0
71.67
64.77
168.6
157.3
771.36
2279.7
0
49.98
65.49
146.0
129.7
661.8
1879.7
33.15
40.6
99.6
93.14
42.63
109
300.4
Cerium
Ce(s)
Ce3+(aq)
Ce4+(aq)
72.0
205
301
Chlorine
Cl2(g)
Cl(g)
Cl(aq)
HCl(g)
HCl(aq)
Copper
Cu(s)
Cu+(aq)
Cu2+(aq)
Cu2O(aq)
CuO(s)
CuSO4(s)
CuSO4.5H2O(s)
237
C:\ChemistryXI\Appendic\Appenxix.pmd 19.1.6
(continued)
238
CHEMISTRY
Substance
Enthalpy of formation,
fHJ/ (kJ mol1)
Entropy,*
SJ/(J K1 mol1)
Deuterium
D2(g)
D2O(g)
D 2O(l)
0
249.20
294.60
0
234.54
243.44
144.96
198.34
75.94
Fluorine
F2(g)
F(aq)
HF(g)
HF(aq)
0
332.63
271.1
332.63
0
278.79
273.2
278.79
202.78
13.8
173.78
13.8
0
203.25
0
237.13
228.57
120.35
134.03
130.68
114.71
0
69.91
188.83
109.6
143.9
0
19.33
51.57
1.70
116.14
260.69
111.3
206.59
0
78.90
4.7
1015.4
742.2
100.4
6.9
166.9
27.28
137.7
315.9
146.4
87.40
60.29
52.93
0
1.7
277.4
919.94
278.7
244.8
0
24.43
217.33
813.14
261.92
232.34
64.81
10.5
68.6
148.57
161.5
175.3
0
147.70
466.85
601.70
1095.8
524.3
0
113.10
454.8
569.43
1012.1
503.8
32.68
148.65
138.1
26.94
65.7
117.2
Iodine
I2(s)
I2(g)
I(aq)
HI(g)
0
62.44
55.19
26.48
Iron
Fe(s)
Fe2+(aq)
Fe3+(aq)
Fe3O4(s), magnetite
Fe2O3(s), haematite
FeS(s,)
FeS(aq)
FeS2(s)
0
89.1
48.5
1118.4
824.2
100.0
178.2
Lead
Pb(s)
Pb2+(aq)
PbO2(s)
PbSO4(s)
PbBr2(s)
PbBr2(aq)
Magnesium
Mg(s)
Mg(g)
Mg2+(aq)
MgO(s)
MgCO3(s)
MgBr2(s)
(continued)
238
C:\ChemistryXI\Appendic\Appenxix.pmd 19.1.6
APPENDIX
Substance
239
Enthalpy of formation,
fHJ/ (kJ mol1)
Entropy,*
SJ/(J K1 mol1)
Mercury
Hg(1)
Hg(g)
HgO(s)
Hg2Cl2(s)
0
61.32
90.83
265.22
0
31.82
58.54
210.75
76.02
174.96
70.29
192.5
0
90.25
82.05
33.18
9.16
174.10
207.36
205.0
46.11
80.29
132.51
114.2
294.1
50.63
365.56
314.43
295.31
0
86.55
104.20
51.31
97.89
80.71
111.25
108.74
16.45
26.50
79.31
328.1
149.34
183.87
202.87
88.75
191.61
210.76
219.85
240.06
304.29
155.60
146.4
146.4
192.45
111.3
113.4
238.97
121.21
151.08
94.6
186.2
0
142.7
229.99
0
163.2
157.24
205.14
238.93
10.75
0
58.91
5.4
2984.0
964.8
1266.9
1277.4
319.7
287.0
374.9
0
24.44
13.4
2697.0
1018.7
272.3
267.8
305.0
41.09
279.98
210.23
228.86
217.18
311.78
364.6
0
89.24
252.38
424.76
482.37
567.27
0
60.59
283.27
379.08
440.50
537.75
64.18
160.34
102.5
78.9
91.6
66.57
Nitrogen
N2(g)
NO(g)
N2O(g)
NO2(g)
N2O4(g)
HNO3(1)
HNO3(aq)
NO3 (aq)
NH3(g)
NH3(aq)
NH+4 (aq)
NH2OH(s)
HN3(g)
N2H4(1)
NH4NO3(s)
NH4Cl(s)
NH4ClO4(s)
Oxygen
O2(g)
O3(g)
OH(aq)
Phosphorus
P(s), white
P4(g)
PH3(g)
P4O10(s)
H3PO3(aq)
H3PO4(1)
H3PO4(aq)
PCl3(1)
PCl3(g)
PCl5(g)
Potassium
K(s)
K(g)
K+(aq)
KOH(s)
KOH(aq)
KF(s)
(continued)
239
C:\ChemistryXI\Appendic\Appenxix.pmd 19.1.6
240
CHEMISTRY
Substance
Enthalpy of formation,
fHJ/ (kJ mol1)
Entropy,*
SJ/(J K1 mol1)
Potassium (continued)
KCl(s)
KBr(s)
KI(s)
KClO3(s)
KClO4(s)
K2S(s)
K2S(aq)
436.75
393.80
327.90
397.73
432.75
380.7
471.5
409.14
380.66
324.89
296.25
303.09
364.0
480.7
82.59
95.90
106.32
143.1
151.0
105
190.4
Si(s)
SiO2(s,)
0
910.94
0
856.64
18.83
41.84
Silver
Ag(s)
Ag+(aq)
Ag2O(s)
AgBr(s)
AgBr(aq)
AgCl(s)
AgCl(aq)
AgI(s)
AgI(aq)
AgNO3(s)
0
105.58
31.05
100.37
15.98
127.07
61.58
61.84
50.38
124.39
0
77.11
11.20
96.90
26.86
109.79
54.12
66.19
25.52
33.41
42.55
72.68
121.3
107.1
155.2
96.2
129.3
115.5
184.1
140.92
0
107.32
240.12
425.61
470.11
411.15
407.3
361.06
287.78
947.7
1130.9
0
76.76
261.91
379.49
419.15
384.14
393.1
348.98
286.06
851.9
1047.7
51.21
153.71
59.0
64.46
48.1
72.13
115.5
86.82
98.53
102.1
136.0
0
0.33
33.1
296.83
395.72
813.99
909.27
909.27
20.63
39.7
1209
0
0.1
85.8
300.19
371.06
690.00
744.53
744.53
33.56
27.83
1105.3
31.80
32.6
14.6
248.22
256.76
156.90
20.1
20.1
205.79
121
291.82
Silicon
Sodium
Na(s)
Na(g)
Na+(aq)
NaOH(s)
NaOH(aq)
NaCl(s)
NaCl(aq)
NaBr(s)
NaI(s)
NaHCO3(s)
Na2CO3(s)
Sulphur
S(s), rhombic
S(s), monoclinic
S2(aq)
SO2(g)
SO3(g)
H2SO 4(l)
H2SO4(aq)
SO42(aq)
H2S(g)
H2S(aq)
SF6(g)
(continued)
240
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APPENDIX
241
Substance
Enthalpy of formation,
fHJ/ (kJ mol1)
Entropy,*
SJ/(J K1 mol1)
Tin
Sn(s), white
Sn(s), gray
SnO(s)
SnO2(s)
0
2.09
285.8
580.7
0
0.13
256.9
519.6
51.55
44.14
56.5
52.3
0
153.89
348.28
+130.73
0
147.06
318.30
+95.14
41.63
112.1
43.64
160.93
Zinc
Zn(s)
Zn2+(aq)
ZnO(s)
Zn(g)
*The entropies of individual ions in solution are determined by setting the entropy of H+ in water equal to
0 and then defining the entropies of all other ions relative to this value; hence a negative entropy is one
that is lower than the entropy of H+ in water.
ORGANIC COMPOUNDS
Substance
Enthalpy of
Enthalpy of
Gibbs Energy of
combustion,
formation,
formation,
Entropy,
cHJ/ (kJ mol1) fHJ/ (kJ mol1) fGJ/ (kJ mol1) SJ/(J K1 mol1)
Hydrocarbons
CH4(g), methane
C2H2(g), ethyne (acetylene)
C2H4(g), ethene(ethylene)
C2H6(g), ethane
C3H6(g), propene (propylene)
C3H6(g), cyclopropane
C3H8(g), propane
C4H10(g), butane
C5H12(g), pentane
C6H6(l), benzene
C6H6(g)
C7H8(l), toluene
C7H8(g)
C6H12(l), cyclohexane
C6H12(g),
C8H18(l), octane
890
1300
1411
1560
2058
2091
2220
2878
3537
3268
3302
3910
3953
3920
3953
5471
74.81
226.73
52.26
84.68
20.42
53.30
103.85
126.15
146.44
49.0
12.0
156.4
249.9
50.72
209.20
68.15
32.82
62.78
104.45
23.49
17.03
8.20
124.3
113.8
26.7
6.4
186.26
200.94
219.56
229.60
266.6
237.4
270.2
310.1
349
173.3
221.0
204.4
358
726
764
1368
1409
3054
238.86
200.66
277.69
235.10
164.6
166.27
161.96
174.78
168.49
50.42
126.8
239.81
160.7
282.70
144.0
(continued)
241
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242
CHEMISTRY
Substance
Enthalpy of
Enthalpy of
Gibbs Energy of
combustion,
formation,
formation,
Entropy,
cHJ/ (kJ mol1) fHJ/ (kJ mol1) fGJ/ (kJ mol1) SJ/(J K1 mol1)
Carboxylic acid
HCOOH(l), formic acid
CH3COOH(l), acetic acid
CH3COOH (aq)
(COOH)2(s), oxalic acid
C6H5COOH(s), benzoic acid
255
875
254
3227
424.72
484.5
485.76
827.2
385.1
361.35
389.9
396.64
697.9
245.3
128.95
159.8
86.6
120
167.6
571
108.57
102.53
218.77
1166
192.30
128.12
160.2
1192
1790
166.19
248.1
128.86
155.4
250.3
200
2808
2810
5645
1268
1266
2222
910
917
1545
212
360
Nitrogen compounds
CO(NH2)2(s), urea
C6H5NH2(l), aniline
632
333.51
197.33
104.60
3393
31.6
149.1
191.3
NH2CH2COOH(s), glycine
969
532.9
373.4
103.51
CH3NH2(g), methylamine
1085
242
22.97
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32.16
243.41
APPENDIX
243
Appendix VII
E J /V
Reduction half-reaction
E J /V
+
Ag + e Ag
Co3+ + e Co2+
H2O2 + 2H+ + 2e 2H2O
Au+ + e Au
Pb4+ + 2e Pb2+
2HClO + 2H+ + 2e Cl2 + 2H2O
Ce4+ + e Ce3+
2HBrO + 2H+ + 2e Br2 + 2H2O
Hg 2+
2 +2e 2Hg
3+
Fe + e Fe2+
BrO + H2O + 2e Br + 2OH
Hg2SO4 +2e 2Hg + SO42
MnO42 + 2H2O + 2e MnO2 + 4OH
MnO4 + e MnO42
I2 + 2e 2I
I3 + 2e 3I
+3.0
+2.87
+2.07
+2.05
+1.98
+1.81
+1.78
+1.69
+1.67
+1.63
+1.61
+1.60
+1.51
+1.51
+1.40
+1.36
+1.33
+1.24
+1.23
+1.23
+1.23
+1.20
+1.09
+0.97
+0.96
+0.92
+0.89
+0.86
+0.80
+0.80
+0.79
+0.77
+0.76
+0.62
+0.60
+0.56
+0.54
+0.53
Cu+ + e Cu
NiOOH + H2O + e Ni(OH)2 + OH
Ag2CrO4 + 2e 2Ag + CrO42
O2 + 2H2O + 4e 4OH
ClO4 + H2O + 2e ClO3 + 2OH
[Fe(CN)6]3 + e [Fe(CN)6]4
Cu2+ + 2e Cu
Hg2Cl2 + 2e 2Hg + 2Cl
AgCl + e Ag + Cl
Bi3+ + 3e Bi
+0.52
+0.49
+0.45
+0.40
+0.36
+0.36
+0.34
+0.27
+0.27
+0.20
+0.17
+0.16
+0.15
+0.07
0.00
0.0 by
definition
0.04
0.08
0.13
0.14
0.14
0.15
0.23
0.26
0.28
0.34
0.34
0.36
0.37
0.40
0.40
0.41
0.44
0.44
0.48
0.49
0.61
0.74
0.76
Fe3+ + 3e Fe
O2 + H2O + 2e HO2 + OH
Pb2+ + 2e Pb
In+ + e In
Sn2+ + 2e Sn
AgI + e Ag + I
Ni2+ + 2e Ni
V3+ + e V2+
Co2+ + 2e Co
In3+ + 3e In
Tl+ + e Tl
PbSO4 + 2e Pb + SO2
4
Ti3+ + e Ti2+
Cd2+ + 2e Cd
In2+ + e In+
Cr3+ + e Cr2+
Fe2+ + 2e Fe
In3+ + 2e In+
S + 2e S2
In3+ + e In2+
U4+ + e U3+
Cr3+ + 3e Cr
Zn2+ + 2e Zn
(continued)
243
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244
CHEMISTRY
Appendix continued
Reduction half-reaction
E J /V
Reduction half-reaction
E J /V
Cd(OH)2 + 2e Cd + 2OH
2H2O + 2e H2 + 2OH
Cr2+ + 2e Cr
Mn2+ + 2e Mn
V2+ + 2e V
Ti2+ + 2e Ti
Al3+ + 3e Al
U3+ + 3e U
Sc3+ + 3e Sc
Mg2+ + 2e Mg
Ce3+ + 3e Ce
0.81
0.83
0.91
1.18
1.19
1.63
1.66
1.79
2.09
2.36
2.48
La3+ + 3e La
Na+ + e Na
Ca2+ + 2e Ca
Sr2+ + 2e Sr
Ba2+ + 2e Ba
Ra2+ + 2e Ra
Cs+ + e Cs
Rb+ + e Rb
K+ +e K
Li+ + e Li
2.52
2.71
2.87
2.89
2.91
2.92
2.92
2.93
2.93
3.05
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