,

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15.03.01 27.11.00 25.07.00 09.06.00 Date

AS BUILT

UP TO DATE MODIFICATION

EM HG JFN FOD Drawn

RR
RR RR RR

TAGE NUMBERS UP TO DATE FIRST ISSUE Modifications

by

Controled

by

Customer's

references

: ADP / CO2 PLANT

Order

10304

Concern .

SCHEMA PFD

Head Office STRASBOURG

6.
rue de i'Atome

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67801
Post box ;
B.P.9_ BISCHHElUCedex

THAT DOCUIAENT. PROPERTY 01' QUIRI REFRIGERATION IS ISSUED CONFIOENTIALLY ON THE UNDERSTANDING THAT NO PART THERE OF SHALL BE USED. COPIED WITHOUT AUTHORIZATION (FRENCH OR COIAIAUNICATED TO A THIRO PARTY IN WRITING FRO ... QUIRI RErRIGERATION. LAW IAARCH 11th 1902)

C02 LOWER PRESSURE

C02 LIQUEfIER &: CQ~P.

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9 - 67801

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PFD-01 Rev.D CO2 circuit Phase Pressure (bar,a) Temperature (0C) Flow rate (kg/hr) Piping (DN) CO2 Composition N2 % mass O2 H2O 1 G 4,8 2 (water) L 4,8 +20 10000 50 3 (water) L 4,8

o
4 G 4,7 +20 7893 200 99,114 0,028 0,162 0,25

AIRLIQUIDE Aff. 10304

o
,

o
9 G 4,1 +24 8086 200 10 G 3,9 II G 3,4 +500 8086 250 97,973 0,109 0,037 1,877 12 G 3,3

AFFAIRE 10304 - AIR LIQUIDE FLOW SHEET AT MAXIMUM 5 G 4,7 +24 7893 200 ---+ ---+ ---+ ---+ 6 G 4,2 +24 7893 200 ---+ ---+ ---+ ---+

& LINDE - LISBONNE

UNIT CAPACITY 8 G (02) 4,5

+15/+25
8012 200 98,764 0,028 0,165

+15/+25
10 119 50 1,126

7 G 4,2 +24 7893 200 ---+ ---+ ---+ ---+

+51+25
170 40

+270/+350
8086 200

+232/+368
8086 200 ---+ ---+ ---+ ---+

1 1 1
100

1
3,52 96,48

1 1
98,627

.1

,I
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.::1 ,I

.~I
..
AFFAIRE 10304 - AIR LIQUIDE & LINDE - LISBONNE FLOW SHEET AT MAXIMUM UNIT CAPACITY 14 G+L 3,1 +36 8086 200 97,973 0,109 0,037 1,877 15 G 3,0 +7 178 200 20 16 L 3,0 +7 7908 200 99,88 0,112 0,038 0,112 17 G 3,0 +7 3954 150 ---+ ---+ ---+ ---+ 18 G 15 -30 336 25 99,94 0,01 0,05 19 G 1 oil 20 +86 20 G 19,7 +86 4290 50 ---+ ---+ ---+ ---+
21

,'1

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1

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CO2 circuit Phase Pressure (bar,a) Temperature (0C) Flow rate (kg/hr) Piping (DN) CO2 Composition N2 % mass O2 H2O

13 G 3,2 +207/+368 8086 200 ---+ ---+ ---+ ---+

4290/125 99,755 0,106 0,035 0,104

G 19,4 +86 4290 50 ---+ ---+ ---+ ---+

22 G+L 19,3 +36 4290 50 ---+ ---+ ---+ ---+

1 1
80

23 G 19,2 +]6 4282,2 50 99,828 0,108 0,035 0,029

24 L 19,2 +16 7,8 2050 60

1 1
40

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08.03.2001

RRiVElO1038

Page 1/7

o
" PFD-Ol Rev.D
CO2 circuit Phase Pressure (bar.a) Temperature COc) Flow rate (kg/hr) Piping (DN) CO2 Composition N2 % mass O2 H2O 25 G 18,9 +16 4282,2 50 99,828 0,108 0,035 0,029 26 G 18,5 +16 4282,2 50 ---+ ---+ ---+ ---+ 27 G 18,1 +18 4281 50 99,857 0,108 0,035 /
:: ,
)

A1RLlQUIDE Afl. 10304

o
,

AFFAIRE 10304 - AIR LIQUIDE & LINDE - LISBONNE FLOW SHEET AT MAXIMUM UNIT CAPACITY
28 G 18,0 +18 4281 50 ---+ ---+ ---+ ---+ 29 G 17,9 -7 4281 50 ---+ ---+ ---+ 30 G 17,9 -28 145 20 94,82 4,40 0,780 31 G 17,8 -28 445 20 98,313 1,433 0,254 32 G 1,6 33 G 1,1 34 L 17,8 -28 4275 50 99,985 0,005 0,005 / 35 L 19,1 -28 4275 40 ---+ ---+ ---+ ---+ 36 L 17,7 -22 640 25 99,995
/

.,

-301+200
445 40 ---+ ---+ ---+ ~

+25/+140
445 40 ---+ ---+ ---+ ---+

/ /

..

AFFAIRE 10304 - AIR LIQUIDE & LINDE - LISBONNE FLOW SHEET AT MAXIMUM UNIT CAPACITY Boil-off

CO2 circuit Phase Pressure (bar,a Temperature (OC) Flow rate (kglhr) Piping (DN) CO2 Composition N2 % mass O2 H2O
.',

37 G 17,7 -22 640 32 99,995

38 G 17,8 -28,9 640 20 99,995

39 L 17,7 -22 3835 40 99,995

40 (AL) L 17,2 -30 3835 40 99,995

40 (Linde) L 18,2 -30 3835 40 99,995

18 G 18 -20

30 G 17,9 -30

34 L 17,5 -30

1
99,95 0,01 0,05 I Page 2/7

1
90 3,4 6,6 /

/
99,99 I / I

40 L later -30 I 99,99

1
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RRJVEI01038

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08.03.2001

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AIR LlQUfDE

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PFD-Ol Rev.D
NH3 circuit Phase Pressure (bar,a) Temperature (0C) Flow rate (kg/hr) Piping (ON)

AFFAIRE 10304 - AIR LIQUIDE & LINDE - LISBONNE FLOW SHEET AT MAXIMUM UNIT CAPACITY

.;,..

, ",

.l

50
G

51
G

52
G/oil

53
G

54
G

55
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56
G/oil

57
G

58
G

59
L

60
L

61
G

1 -34 1 205 15

3,5 -5,6 3957 50

12,6 +72
1 602/-

125

12,4 +72 I 602 80

1 -34 1205 150

3,5 -5,6 3957 50

12,6 +72 1 602/125

12,4 +72 1602 80

12,4 +72 3205 100

12,3 +32 3205 65

12,3 +32 314 20

4,3 +0 314 40

..
NH3 circuit Phase Pressure (bar,a) Temperature (0C) Flow rate (kglhr) Piping (ON)

AFFAIRE 10304 - AIR LIQUIDE & LINDE - LISBONNE FLOW SHEET AT MAXIMUM UNIT CAPACITY

62
L

63
G

64
L

65
G

66
L

67
L

68
L

69
L

70
L

71
G

72
G

73
L

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12,3 +32 82 20

4,3 +0 82 32

12,3 +32 82 20

4,3 +0 82 32

12,3 +32 1392 50

12,3 +32 667 40

12,2 +3 667 40

12,3 +32 667 40

12,2 +3 667 40

4,3 +0 478 50

4,3 +0 794 65

4,3 +0 2410 65

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08.03.2001

RRiVElOJ038

Page 3/7

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"

AIRLIQU/DE AjJ. 10304

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."

PFD-Ol Rev.D

AFFAIRE 10304 - AIR LIQUIDE & LINDE - LISBONNE FLOW SHEET AT MAXIMUM UNIT CAPACITY Boil-off

.,
)

NH3 circuit Phase Pressure (bar,a) Temperature (DC) Flow rate (kglhr) Piping (ON)

74 L 4,3 +0 1205 40

75 L 4,3 +0 1205 40

50/54

51155

0,7 -40 885 150

4,3 +0 367 50

52/56 a/oil 12,6 +78 I 252/125

53/57

58

12,4 +78 1 252 80

12,4 +32 2504 100

59 L 12,3 +32 2504 65

66 L 12,3 +32 2504 50

72

4,3 +0 367 65

73 L 4,3 +0 1770 65

74/76 L 4,3 +0 885 40

,',

,
.
,

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AFF AIRE 10304 - AIR LIQUIDE & LINDE - LISBONNE FLOW SHEET AT MAXIMUM UNIT CAPACITY
91 L 19,4 +50 9360 65 92 L 19,1 +50 9360 65 93 L 19,1 +50 4920 40 94 L 19,1 +50 4440 50 95 L 21,1 +50 4440 40 100 L 12,6 +72 16560 65 101 L 12 +50 16560 65 102 L 11,7 +50 16560 65 103 L 11,7 +50 9000 40 104 L 11,7 +50 7560 50 105 L 13,7 +50 7560 40

Oil circuit
Phase Pressure (bar, a) Temperature Flow rate (kg/hr) Piping (DN)

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90 L 20 +84 9360 65

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08.03.2001

RRiVElOJ038

Page 4/7

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AIR LlQUlDE

Aff 10304

r "
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PFD-Ol Rev.D
Water circuit Phase Pressure (bar,a) Temperature (0C) Flow rate (kglhr) Piping (ON)

AFF AIRE 10304 - AIR LIQUIDE & LINDE - LISBONNE FLOW SHEET AT MAXIMUM UNIT CAPACITY

;
I

110
L

III

112
L
I

113
L

114
L

115
L

116
L

117
L

118
L

119
L

120
L

121
L

6 +20 7200 50

1 +28 3600 40

+27 174238 150

3 +27 174238 150

2,8 +27 154217 150

1,8 +32 154217 150

2,5 +27 10 010 40

2,3 +32 10010 40

2,5 +27 10010 40

2,3 +32 10010 40

1,8 +32 174238 40

4,5 +27 15050 50

AFFAIRE 10304 - AIR LIQUIDE & LINDE - LISBONNE FLOW SHEET AT MAXIMUM UNIT CAPACITY
Water circuit Phase Pressure (bar,a) Temperature COC) Flow rate (kglhr) Piping (ON)

122
L

123
L

124
L

125
L

126
L

127
L

128
L

., ,,-

...

3,5 +37 15050 50

4,5 +27 15050 50

3,5 +37 15050 50

4,5 +27 15910 50

3,5 +37 15910 50

4,5 +27 15910 50

3,5 +37 15910 50

n..

08_03_2001

RR/VEl01038

Page 5/7

AIR LlQUIDE Aff. 10304

CO2 COMPOSITION I PFD-Ol - Rev. D

COMPONENT

POINT 1 95,7% 5ppmv 2200 ppmv 440 ppmv 5ppmv 0,1 ppmv 15000 to 30 000 ppmv 400 to 4 000 ppmv 5 000 to 8 000 J?pmv 2 000 to 3 000 ppmv 5 to 20_ill:}_mv 1 pg_mv 1 ppmv 0,1 ppmv 40 99,995% 20 ppmv 20 ppmv 40 ppmv 0,1 ppmv 5ppmv 5 ppmv 10 ppmv 5 ppmv 5ppmv

CO2 H2O O2 N2 H2S S02 + COS H2 CH30H CO Cf4 C2H6 C3Hg C4HlO Benzene Total BTX Acetaldehyde Non volatile residue (inorganics) Non volatile residue (organics) NH3 NOX Bromides Nitrates Chlorides Sulphates

5 ppmv 0,1 ppmv 0,01 ppmv 0,01 ppmv

° ° ° ° °

0,022 ppmv 0,2 ppmv 10 ppmv 1 ppmv 1 ppmv 1 ppmv 0,1 pQ_mv 0,1 ppmv 0,01 ppmv 0,01 ppmv

()
08.03.2001

RRlVElOlO38

Page 617

AIR LIQUIDE Aff. 10304

CO2 COMPOSITION / PFD-Ol - Rev. D

COMPONENT

POINT 4 95,7% sature 2200 ppmv 440 ppmv 5 ppmv 0,1 ppmv 15000 to 30 000 ppmv 5 ppm v 5 000 to 8 000 ppmv 2 000 to 3 000 ppmv 5 to 20 ppmv 1 ppmv 1 ppmv 0,1 ppmv 0,1 ppmv 0,1 ppmv 0,1 ppmv 0,01 ppmv 0,01 ppmv

6
95,7%

CO2 H2O 02 N2 H2S S02 +COS H2 CH30H CO CRt C2H6 C3HS C4HIO Benzene Benzene Bromides . Nitrates Chlorides

sature

2200 ppmv 440 ppmv 0,1 ppmv

11 95,25% 4,47% 1000 ppmv 1675 ppmv 0,1 ppmv 5ppmv 5 ppmv 10ppmv 20ppmv 5ppmv 0,01 ppmv O,lppmv 0,1 ppmv O,Ol_ppmv 0,01 ppmv

Sulphates

15000 to 30 000 ppmv 5 ppmv 5 000 to 8 000 ppmv 2 000 to 3 000 ppmv 5 to 20 ppmv 1 ppmv 1 ppmv 0,1 ppmv 0,1 ppmv 0,1 ppmv 0,1 ppmv 0,01 ppmv 0,01 ppmv

(J
08.03.2001 RR/VE/01038

Page 7/7