S gio dc o to Ninh Bnh Trng THPT Yn M A

thi hc sinh gii lp 12

Mn: Ha hc Nm : 2009-2010 Thi gian : 180 pht

Cu 1: a, Cc cht A, B, C c cng cng thc phn t C4H9O2N. Bit rng A tc dng c c vi

HCl v Na2O. B tc dng c vi H mi sinh to ra B'. B' tc dng c vi H2SO4 to ra B''. B'' tc dng vi NaOH to li B'. C tc dng c vi NaOH to mt mui v mt kh NH3. Cho bit A, B, C ng vi ng phn chc no? Vit cc phng trnh phn ng xy ra. b, Cc cht X, Y, Z, T c cng thc phn t l C4H7ClO2. Xc nh cng thc cu to v vit cc phng trnh phn ng. Bit: - X + NaOH t Mui + C2H5OH + NaCl t0 - Y + NaOH Mui + C2H4(OH)2 + NaCl t0 - Z + NaOH Mui + CH3OH + NaCl - Khi thy phn T trong mi trng kim thu c cc sn phm trong c 2 sn phm c th tham gia phn ng trng gng. Cu 2: a, Cht 3MCPD ( 3-Mono Clo Propadiol) c trong nc tng c th gy ra bnh ung th cho ngi. Cng thc cu to 3MCPD l g? b, Ha tan 22,95 gam BaO vo nc c dung dch A. Cho 18,4 gam hn hp CaCO3 v MgCO3 ha tan ht trong dung dch HCl thu c kh B. Nu cho dung dch A hp th ht vo kh B th c kt ta to thnh hay khng? Nu 14,2 gam hn hp hai mui trn trong c a % MgCO3 ri tin hnh th nghim tng t nh trn th a c gi tr bng bao nhiu cho lng kt ta c trong dung dch A l cao nht, thp nht? Cu 3: a, Hp cht N c to t 3 nguyn t X, Y, Z c tng s n v in tch ht nhn l 16, hiu s n v in tch ht nhn ca X v Y l 1, tng s electron trong YX 3 l 32. Xc nh v tr ca X, Y, Z trong HTTH. Tm cng thc phn t ca N. b, Ha tan 22 gam hn hp A gm Fe, FeCO3, Fe3O4 vo 448 ml dung dch N 2M (va tm c a) th thu c dung dch B v hn hp kh X gm CO2 v NO. Lng N d c trong B tc dng va vi 2,968 gam Na2CO3. C mt bnh kn dung tch 8,96 lt cha khng kh gm O2 v N2 theo t l th tch l 1:4 c p sut l 0,375 at, nhit 0oC. Np hn hp kh X vo bnh trn sau gi bnh nhit 0oC thi trong bnh khng cn O2 v p sut cui cng l 0,6 at. Tnh % theo khi lng mi cht trong A Cu 4: Mt hn hp X gm 3 ng phn mch h X1, X2, X3 u cha C, H, O. Bit 4 gam X 136,5 oC, 2 atm th c cng th tch vi 3 gam C5H12 273 oC, 2 atm. a, Xc nh cng thc phn t ca X1, X2, X3. b, Cho 36 gam hn hp tc dng va vi dung dch NaOH c cha m gam NaOH. C cn dung dch c cht rn Y v hn hp Z. Z tc dng va vi dung dch AgNO3/NH3 sinh ra 81 gam Ag. Nung cht rn Y vi NaOH d c hn hp kh G. un G vi Ni xc tc c hn hp kh F gm 2 kh c s mol bng nhau. 1, Xc nh cng thc cu to ca X1, X2, X3, bit rng mi cht ch cha mt loi nhm chc. 2. Tnh thnh phn phn trm ca X1, X2, X3 trong hn hp X 3. Tnh m ( Khng c s dng h thng tun hon) ..Ht.
0