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. Le Trong Trng (GV H o a THPT N guyenB nh Khie m _ a klak ) E KIEM TRA MOT TIET (Tiet 9)

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Mon: Hoa Hoc - Lp: 12 (e so 02)

Cau 1 (4,0 iem). a) Viet CTCT cuatat ca ca cankanol (ru no n chc)ba c I c o t kho ihi so v iH2 la 44. Ne u ten cuach ung theo danh phap quoc te . b) Lay ru b ac I co nhieu nhanh nhat c au a, cho ta c dung lan lt vi:kim loai kali, ong (II) 0 oxit khi un n o n gv av iH2SO4 ac 140 C. Viet ca cphng trnh phanngx ay ra. Cau 2 (3 iem). 1. Hoan thanhcacphng trnh phanngsau: a) C6H5ONa + HCl b) C6H5NH3Cl + KOH c)C6H5NH2 + CH3COOH 2. T bezen v a c ac chat vo c ca n thiet c o u ,viet ca c phng trnh phan ng (ghi ro ie u kien) ieu che axit picric (2,4,6- trinitropheno l). Cau 3 (3 iem). 1. un nong ru etylic v i H2SO4 ac, thu c etilen. Tnh khoilng ru c an thiet e ieu che c 5,6 lt etilen (o ktc) g ia s hieu suat phan ng at 50%. 2. Cho dung dch ch a 3,05 gam chat ong ang cuaphenol n chc. Cho dung dch tren ta cdung v i n c brom (d) thu c 8,975 gam hp chat cha ba nguyen t brom trong pha n t .Xa c nh CTPT chatongangcu a phenol, g ia s phan ngxayra hoan toan. . . . . . . . . . . . . H et . . . . . . . . . . . .

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A A N E SO 02 P M on :H oa,L 12 (Tiet9) p:

C au1

a)

Viet cong thc ca u tao, goi ten Go i congth ccu aankanol la CnH2n+2O Mru = 44x2=88 14n + 18 = 88 n=5 CTPT: C5H12O CH3 CH2 CH2 CH2 CH2 OH; Pentanol- 1 CH3 CH3 CH2 CH CH2 CH3 CH CH2 CH2 CH3 CH3 CH3 C CH3 CH2 OH ; 3,3-imet ylpropanol-1 CH3 2CH3 C CH3 CH3 C CHO + Cu + H2O CH3
CH3 CH2 OH H2SO4 ac 140 C
0

OH ; 2-metylbutanol- 1 OH ; 3-metylbutanol-1

b)

Viet phng trnh phanng CH3 2CH3 C CH3 CH3 CH3 C CH2 OH + CuO CH3
CH3 2CH3 C CH3 CH C 3 CH 2

CH2 OH + 2K

CH2

OK + H2

CH3 t0

CH3 O CH2 C CH + H O 3 2

CH3

CH3

C au2

Hoan thanh ca cphng trnh phan ng C6H5ONa + HCl C6H5OH + NaCl C6H5NH3Cl + NaOH C6H5NH2 + H2O + NaCl C6H5NH2 + CH3COOH C6H5NH3OCOCH3 T benzen vietphung trnh ieu che 2,4,6-tr initrophenol C6H6 C6H5Br C6H5OH C6H2(NO2)3OH Tnh khoilng ru H 2 S O 4 , a c CH 2 CH 2 + H 2O C 2H 5OH 0 170 C (mol) 0,5=0,25.100/50= x H=50% 0,25 (mol) mru = 0,5x46 = 23 gam Xac nh CTPT CnH2n-7OH + 3Br2 CnH2n-10(Br)3OH + 3HBr (14n + 10) gam (14n + 247) gam

2 C au3 1

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e kiem tra lp 12 (Bai so 1) B nhKhiem _ aklak )

Le Trong Trng (GV H o a.THPT N guyen

Email: letron gtru ong@gmail.com - Phone: 0914.087.075

3,05 gam 8,975 gam 14n + 10 14n + 247 Ta c o: C 9 = n=8 Vay CTPT 8 H OH 3,05 8,975