Hydro ha cc hp cht cha oxi

GVHD: TS.Nguyn Hng Lin

SVTH:

Dng Vn An Trn Cao Cng Phm S ng Nguyn Vn inh Lng t Mnh H Th Nga

- HD1 - HD1 - HD1 - HD1 - HD1 - HD1

Ni dung thuyt trnh:

1.

Tng quan v qu trnh hydro ha 2. Hydro ha este 3. Hydro ha axit 4. Hydro ha ru 5. Hydro ha xeton

1.1. Tng quan v qu trnh

1.1. Khi nim Hydo ha l qu trnh chuyn ha cc hp cht hu c di tc dng ca H2 phn t.

1.2. Phn loi qu trnh hydro ha

Cng

hydro theo lin kt khng no: thun nghch,gi nguyn mch C. Hydro ha km tch nc, hoc cc hp cht khng cha C: khng thun nghch. Hydro ha phn hy Phn b li hydro

1.3. c im ca qu trnh
Hydro

ha l qu trnh ta nhit,gim th tch nn n thng c tin hnh nhit thp: 100- 3500C, p sut cao,phn ng c pha lng v pha kh. Trong cng nghip thng tin hnh p sut: 1-1,5 kg/cm2, nhit : 3005000C. nng cao chuyn ha thng dng d H2

1.4. Xc tc
Thng

dng kim loi hot ng: Fe,Pt,Pd,Cu Dng s dng: huyn ph,ht,vin,mang trn cht mang. Thng iu ch xc tc hydro ha bng phng php: kh mui Kim loi trong dung dch,kh mui hoc oxyt kim loi trc tip bng H2,kh mui kim loi trong dung dch.

1.5. Cc qu trnh cng ngh

Hydro

ha hydrocacbon Hydro ha cc hp cht cha nit Hydro ha cc hp cht cha oxy ( Este, axit, ru, xeton)

1.6. ng dng
Hydro

ha du bo Hydro ha nitril thnh amin iu ch diamin lm nguyn liu cho tng hp t si. Hydro ha lm sch cc sn phm du m nh hydro ha lm sch du nhn, hydro ha kh hydrocacbon thm trong nhin liu phn lc, my bay.

2.Hydro ha este
2.ng dung 2.1 San xut Butanediol (BDO) -Cng ngh Davy (Anh) +La cng ngh bin i maleic anhydride (mAh) cho 1,4 butanediol (BDO)--(tetrahydrofuran (THF) v butyrolactone gamma (GBL) +Co 8 d an san xut BDO khac nhau c thc hin vi cng sut at 11.000-100000 tn mi nm -

nm 1989, su nh my c cp php vi tng cng sut 300.000 tn / nm. Kinh t: sn xut 1 tn ca BDO tng ng: Maleic anhydride 1,125 t Hydrogen 0,116 t Methanol 0,050 t in lc, kWh 164 Hi nc, 3,6 t Nc, lm mt, 326 m3

S sn xut butandiol

S cng ngh

2.2. Hyro ha metyl laurat lauryl ancol

Xuc

tac:c ch to t cc ha cht gAl2O3, SiO2, Ru (C5H7O2)3 99%, Na2SnO3 . 3H2O 95%, Cu (C5H7O2)3 99%, Pd(C5H7O2)3 99%. Cc kim loi Ru, Rh v Sn c phn b ln cht mang c din tch b mt ring ln, kh nng bn nhit cao nh g Al2O3, SiO2, C (than hot tnh) v zeolit NaY. Xc tc to thnh c kh di dng kh H2 450oC trong 2 gi. Xc tc cha 5% Ru hoc Rh, t l Sn/Ru = 2.

3.Hydro ha axit
3.1 Tng quan v qu trnh hydro ha axit 3.2 Cc ng dng v cng ngh sn xut

3.1 Tng quan v qu trnh hydro ha axit

Qu

trnh hydro ha axit gm 2 phn: -Hydro ha axit khng no(c lin kt C=C) thnh axit no -Hydro ha nhm chc axit thnh ru

Hydro ha axit khng no(c lin kt C=C) thnh axit no

Hydro

ha axit maleic thnh axit succinic:

Phn

ng tng hp axit succinic c rt nhiu ng dng : Thnh phn chnh thuc gii ru RU-21(n chuyn ru thnh CO2 v H2O,trnh to thnh andehit gy say ru)

Hydro ha axit khng no(c lin kt C=C) thnh axit no

Hydro

ha axit bo :

 Hydro

ha axit bo ngoi mt phn b hydro ha thnh axit bo no thi mt phn chuyn ha t dng cis sang trans.V chuyn dch lin kt i To phn t c nng lng thp hn Qu trnh chuyn t dng cis sang trans tuy ko di thi gian s dng nhng d gy bo ph nhanh chng v mt s bnh tim mch v tiu ng

Cng ngh hydro ha axit

Tng quan
Reduction

of the Carbonyl Value in Distilled Fatty Alcohols ??? Yu cu ca th trng v hm lng cacbonyl trong cc phn on ru bo l ch c vi chc ppm trong khi hm lng cacbonyl trong ru bo th ln n hng ngn ppm. Sau khi thc hin cng ngh ny th iu c gii quyt!!!

Nguyn liu:Phn on ru bo vi
hm lng cacbonyl ln n 1500 ppm.

Sn phm:Ru bo vi hm lng
cacbonyl <50ppm,hydrocacbon..

routed to the tank farm.

Process
After distillation or fractionation, the fatty alcohols are processed through a reactor packed with a Ni-based catalyst at a hydrogen pressure of approx. 26 bar and a temperature of approx. 130 C. If defined fractions of a fractionated feedstock are to be processed simultaneously, each fraction requires a separate reactor. As the fatty alcohol feed trickles down the catalyst bed, the carbonyl groups are reconverted in the presence of a surplus of hydrogen.

The fatty alcohol product is expanded and liberated from dissolved hydrogen in a degasser, cooled down and finally routed to the tank farm.

The reaction mixture discharging from the reactor bottom goes to the gas/liquid separator where the surplus hydrogen is separated from the fatty alcohols. The hydrogen can be routed back to the suction side of the hydrogen compressor.

Technical Data
Unit capacities: according to the composites or fractions produced in the upstream distillation or fractionation unit. Consumption figures per ton of fatty alcohol: as the consumption figures vary with the feedstock to be processed, the figures given below only provide a rough guideline. Exact figures will have to be determined on a case-to-case basis.

5. Hydro ha xeton
Hydro ha xeton trong cng nghip ha cht rt quan trng, n gp phn to ra cc sn phm lm nguyn liu cho cc ngnh khc nh: ha du, thc phm, sinh hc, y t Phng php hydro ha khng i xng ca xeton ang l mt lnh vc quan trng trong tng hp cc hp cht hu c. - Cc phng php hydro ha hin i khng i xng ca xeton:

Hydro ha xeton
5.1Chuyn hydro ha khng i xng 5.1.1 n 1

Hydro ha xeton
Phn

ng c din ra ti nhit phng vi cht xc tc [RuCl 2 (p-cymene) 2] l trn phi t trong nc. Phi t khi kt hp vi [RuCl 2 (pcymene) 2] l mt cht xc tc hiu qu, c tnh n nh cao. n ny l ca Hc vin Khoa hc Trung Quc

Hydro ha xeton
5.1.2 n 2

Hydro ha xeton
y

l n ca Will v ng nghip t i hc Conventry(Anh) n 2 - khng i xng chuyn hydro ha ca vng , -khng bo ha xeton 7xc tc bi 6 -p-cymene/ruthenium (II) v 5pentamethylcyclopentadienyl/rodhium (III) phc.

Hydro ha xeton
5.1.3 n 3 n 3 - khng i xng chuyn hydro ha (ATH) ca mch h , -khng bo ha xeton 12 vi cht xc tc (R, R) - 9.

Hydro ha xeton
2. Palladium-xc tc khng i xng hydro

Hydro ha xeton
Xc

tc bng cch s dng mt Pd / phc tp phosphine trong trifluoroethanol-2,2,2 (TFE) n ca Zhou v ng nghip t Hc vin Khoa hc Trung Quc

Ti liu tham kho:

TI Cng

LIU THAM KHO

ngh tng hp hu c-hoa du, Pham Thanh Huyn - Nguyn Hng Lin. Ullmann's Encyclopedia of Industrial Chemistry, Copyright 2007 by John Wiley & Sons, Inc. All Rights Reserved. PetrochemicalProcesses2005. www.lurgy.com

The end