BI TP

1. Cho nguyn t Fe c Z= 26. Vit cu hnh electron ca Fe2+

a) Xc nh v tr ca Fe trong bng h thng tun hon?
b) Xc nh in tch ca Fe2+ v bn s lng t ng vi e cht cng ca Fe?
2. Electron cui cng ca hai nguyn t X v Y c bn s lng t nh sau:
X
n = 4, = 2, m = 1, ms = +
Y
n = 3, = 1, m = 1, ms =
a) Vit cu hnh electron nguyn t, in tch ht nhn ca X v Y.
b) Xc nh v tr (chu k, phn nhm), tnh kim loi, phi kim ca X v Y.
c) Vit cu hnh electron nguyn t ca cc ion c th c ca X v Y
3. Ion A2+ c 24 electron.
a) Hy xc nh v tr ca A trong bng h thng tun hon.
b) Vit gi tr bn s lng t ca electron cht cng ca A.
4. Ion X2+ c phn lp ngoi cng l 3p2
a) Vit cu hnh electron ca nguyn t X v ion X2+.
b) Xc nh in tch ht nhn ca X2+.
c) Xc nh v tr, tnh kim loi, phi kim ca X.
d) Hai electron 3p2 ng vi nhng gi tr no ca s lng t chnh n v s
lng t ph .
5. Ion X2 c phn lp ngoi cng l 3p5
a) Vit cu hnh electron ca nguyn t X v ion X2.
b) Xc nh in tch ht nhn ca X2.
c) Xc nh v tr, tnh kim loi, phi kim ca X.
6. Cc ion X+, Y v nguyn t Z cng c cu hnh electron l 1s22s22p63s23p6
a) Vit cu hnh electron nguyn t ca X v Y.
b) Xc nh v tr, tnh kim loi, phi kim;
c) Vit gi tr bn s lng t ca electron cui cng ca X, Y v Z.
7. Cho bit phn ng sau xy ra iu kin tiu chun

2NH3(k)
H0tt,298(kcal/mol)

-11,00

S0298(cal/molK)

N2(k)

3Cl2(k)

45,97

6HCl(k)

-22,40

53,30

45,77

46,04

a. Phn ng ta nhit hay thu nhit trong iu kin ng p v ng tch?

b. Phn ng xy ra theo chiu no 250C v 1000C?

CO2(k)

8. Cho phn ng

C(gr)

2H2O

Bit H0tt,298(kJ/mol)

-241,6

-393,5

S0298(J/molK)

5,7

188,5

213,6

+ 2H2(k)
0
130,5

a. Tnh H, U, S, G ca phn ng trn iu kin tiu chun?

b. Xc nh nhit ti phn ng xy ra theo chiu thun?

9. Cho bit phn ng sau xy ra iu kin tiu chun
2Mg(r) +

CO2(k)

2MgO(r) +

H0tt,298(kJ/mol) 0

-393,5

-601,8

S0298(J/molK)

213,6

26,8

32,5

C(t)
0
5,00

a) Phn ng trn thu nhit hay ta nhit?

b) Phn ng din ra theo chiu no? Xc nh nhit ti phn ng t

cn bng?
10. Tnh PH dung dch Ba(OH)2 0.01M
11. Tnh PH dung dch HCl 0.001M
12. pH cua mot dung dch acid HA 0,15Mo c la 2,8.
Tnh pKa cua acid nay.
13. pH cua mot dung dch acid HA 0,0015 M o c la 2,9.
Tnh pKa cua acid nay.
14. Tnh pH dung dch CH3COOH 0,1M, bit Ka = 1,86.10-5
15. Tnh pH dung dch NH3 0,01M, bit Kb = 1,8.10-5
16. pH dung dch NH3 0,3 M l 10,6. Tnh pKb ca dung dch ny?
17. Tnh pH dung dch NH4Cl 0,42M. Bit pKb = 4,76.
18. Tnh pH ca dung dch CH3COOK 0,01M, bit Ka = 1,8.10-5

19. Cho phn ng

CO(k) + H2O(k)

CO2(k)

H2(k)

Khi cn bng s mol CO l 0.25 mol, H2O l 2.25 mol CO2 l 0.75mol, H2 l
0.75 mol. Tnh Kc, Kp.
20. Trn 1mol CO v 3 mol H2O nhit 8500C thu c 1 lt dung dch. Khi cn
bng s mol CO2 l 0.75mol. Tnh Kp
21. Trn 0,9mol kh A vi 0,5mol B trong bnh ng 1 lt 2500C. Khi cn bng
c thit lp 2A(k) + B(k)

C (k)

D(k) s mol C thu c 0,35 mol.

Tnh gi tr hng s cn bng Kc, Kp.

22. Cho cn bng sau:
4HCl(k)

O2(k)

2H2O (k)

+ 2Cl2(k)

Bit H0tt,298(kJ/mol)

-92,3

-241,8

S0298(J/molK)

187

205

188,7

223

Tnh hng s cn bng Kp v Kc ca phn ng nhit 250C?

+

CO2(k)

CO(k)

23. Cho phn ng sau

H2(k)

H2O (k)

Bit H0tt,298(kJ/mol)

-393,5

-110,5

-241,8

S0298(J/molK)

130,6

213,6

197,5

188,7

Tnh hng s cn bng Kp v Kc ca phn ng nhit 250C?

24. 250C tan ca Ag3PO4 l 1,6. 10-5. Tm tch s tan ca Ag3PO4
25. 250C, tch s tan ca BaSO4 200C l 1,1.10-10. Tm tan ca BaSO4 , khi
trn 200ml dung dch BaCl2 0,004M vi 600ml dung dch K2SO4 0,008M, kt ta
BaSO4 c xy ra khng?